On the theory of non-Newtonian polymer flow

The Eyring-Frenkel theory of viscosity of low-molecular liquids has been extended to solutions of high-molecular compounds. It is shown that there are flow units of different sizes in the system, their mean size being proportional to the molecular weight of the polymer. An expression is obtained for the non-Newtonian viscosity of polymer solutions. In the limiting case of high shear rates the viscosity of the solution coincides with that of the solvent. At low shear rates Flory's empirical relation for the viscosity of polymer solutions is theoretically obtained.Mekhanika Polimerov, Vol. 2, No. 5, pp. 779–784, 1966     

Theory of flow of concentrated polymer solutions and melts

Starting from the concept of a polymer system as a collection of macromolecules forming an effective network, an expression is obtained for the stress tensor of a flowing concentrated polymer solution or melt. It is shown that the variation of the effective viscosity of polymer systems is associated with the orientation of the macromolecules and changes in the equilibrium number of nodes during flow. A system of equations describing the flow of polymer systems characterized by a gradient dependence of the effective viscosity and normal stresses in shear is written in the single relaxation time approximation.Institute of Chemical Physics, Moscow Region, Academy of Sciences of the USSR. Translated from Mekhanika Polimerov, Vol. 4, No. 4, pp. 724–730, July–August, 1968.     

Forced viscosity anisotropy of polymers

For two-dimensional flow the viscosity of an anisotropic medium is determined by two quantities. In relation to polymer melts, one of these corresponds to the viscosity for tension in the direction of orientation and the other to viscosity for shear in planes parallel to the orientation. By solving the problem of the flow of such a medium in a plane convergent channel and making optical-polarization measurements we were able to observe and quantitatively describe this phenomenon.Mekhanika Polimerov, Vol. 1, No. 5, pp. 13–18, 1965     

Numerical study on viscoelastic fluid flow past a rigid body

Viscoelastic non-Newtonian fluids can be achieved by adding a small amount of polymer additives to a Newtonian fluid. In this paper, numerical simulations are used to investigate the influence of such polymer additives on the behavior of flow past a circular cylinder. A numerical method is proposed that discretizes the non-linear viscoelastic system on a uniform Cartesian grid, with a penalization method to model the presence of the cylinder. The drag of the cylinder and the flow behavior under the effect of different Reynolds numbers ($\mathrm{Re}$), Weissenberg numbers (Wi) and polymer viscosity ratios (ε) are studied. Numerical results show that different flow characteristics are exhibited in different parameter zones. The polymer viscosity ratio plays an important role at low Weissenberg and Reynolds numbers, but as the Reynolds and Weissenberg numbers increase, the influence of ε weakens. The drag force of the cylinder is mostly affected by the Reynolds and Weissenberg numbers. At low Reynolds numbers, the drag of the cylinder and the flow fields are only affected by a large value of Wi when the elastic forces are strong. Non-trivial drag reduction occurs only when there is vortex shedding in the wake flow, whereas drag enhancement happens when the vortex shedding is inhibited.     

Relation between the shear and longitudinal viscosity coefficients for concentrated polymer solutions

A relation between the shear and longitudinal viscosity coefficients is obtained on the basis of the theory of flow of polymeric systems in the single relaxation time approximation. A comparison of the shear and longitudinal viscosity coefficients for polymer melts and solutions shows that the relation obtained is valid over a broad stress region.Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow. Scientific-Research Institute of Synthetic Fibers, Moscow. Translated from Mekhanika Polimerov, No. 1, pp. 124–131, January–February, 1973.     

Normal stresses in non-Newtonian polymer flows

The calculation of the normal stresses from the flow curve is considered on the basis of the method of correlation of the frequency and stationary characteristics of flowing polymer systems. Simple expressions are given for finding the initial normal stress coefficient and the high-elastic modulus from the point corresponding to the beginning of non-Newtonian flow. A necessary condition for the appearance of normal stresses is a viscosity anomaly. It is shown that for a bounded value of the initial normal stress coefficient to exist the derivative of the effective viscosity with respect to shear rate must be zero at the initial point.Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 3, pp. 506–514, May–June, 1971.     

非牛顿流体内流传热研究

在本文中,研究了注入轴对称模腔非牛顿流体非定常流动.本文的第二部份研究了上随体Maxwell流体管内热流动.对于注入模腔流动.其本构方程采用幂律流体模型方程.为了避免在表现粘度中温度关系引起的非线性.引进了一特征粘度的概念.描述本力学过程的基本方程是,本构方程、定常状态的运动方程、非定常能量方程及连续方程.该方程组在空间是二维问题,在数学上是三维问题.采用分裂差分格式求得本方程组的数值解答.分裂法曾成功应用于求解牛顿流体问题.在本文中,首次将分裂法成功地应用解决非牛顿流体流动问题.对于圆管内热流,给出了差分格式,使基本方程组化为一个三对角方程组.其结果,给出了不同时刻的模腔内二维温度分布.     

Multicritical phenomena in flow of viscoelastic liquids. 1. Zaremba-Fromm-De Witt liquid

It has been shown that multicritical phenomena caused by nonlinearity of viscosity and high elasticity, and forced anisotropy at finite shear rates take place during flow of viscoelastic polymer melts which are isotropic in the resting state. The sign of the low-frequency asymptotic values of the dynamic viscosity and elasticity measured during steady flow is a criterion of the appearance of instability. These arguments are illustrated by the solution and analysis of the complex reaction to low-amplitude, periodic shear of a steady-flowing, very simple viscoelastic liquid — ZFD liquid. It was shown that the instability of viscoelastic liquids for a given steady shear rate is due to the effect of perturbations lasting for no less than some limiting value and its manifestations are caused by superposition of different types of instability — multicritical phenomena.Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 4, pp. 555–572, July–August, 1995.The study was conducted based on Topic 93,177 of the Latvian Science Council.     

Compaction and Consolidation of Aramid and Composite Fibers. 1. Compaction of Aramid Fibers

The transverse compaction and consolidation of various aramid fibers used as a reinforcement of plastics are studied with the aim to assess the behavior of the fibers during their processing. The transverse deformation of fiber bundles is considered in the context of viscoplastic flow of the fiber-forming polymer squeezed out into the interfiber space upon the contact interaction of the fibers. This process is analyzed as a flow of a polymer melt having a certain viscosity. A gradual increase in the viscosity with development of transverse deformations is revealed, which corresponds to the morphology of fibers of the skin-core type. It is found that, under these conditions, the transverse deformation and sintering of Terlon fibers are insignificant compared with that of SVM fibers, therefore, they are preferably used for reinforcing heat-resistant thermoplastics.     

Viscosity,rubber elasticity,and viscoelasticity of concentrated polymer solutions

The results of a comparative investigation of the effect of the nature of the polymer and the solvent on the viscosity, rubber elasticity, and viscoelasticity of concentrated polymer solutions in the region of linear mechanical behavior are presented. It is established that in the case of nonpolar polymers the solvent affects only the free volume of the solution, whereas for polar polymers it also affects the entanglement network. This leads to the equality of the viscosities of solutions of nonpolar polymers in different solvents when compared in corresponding states (relative to the glass transition temperature) and to the dependence of the shear modulus of solutions of polar polymers on the nature of the solvent and temperature. It is shown that there is a universal relaxation spectrum in the flow zone for solutions of different polydisperse polymers after normalization with the shear modulus and the natural relaxation time determined as the ratio of the viscosity to the shear modulus.A. M. Gor'kii Ural State University, Sverdlovsk, A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 4, pp. 729–736, July–August, 1973.     

Structure and rheological properties of polymers

The viscoelastic properties of linear flexible-chain polymers with a narrow distribution, for which M > 5M_c (M_c corresponds to the formation of a three-dimensional entanglement network), their mixtures, and concentrated solutions are examined. It is established that under the influence of deformation the polymer may undergo a transition to the rubbery state, which thus defines the limit of its flow state; this transition is also observed in mixtures and concentrated solutions of high-molecular-weight polymers with a narrow distribution. The relative simplicity of the rheological properties of linear high-molecular-weight polymers and their mixtures is determined by the sharpness of the transition to the rubbery state. It has been found that in mixtures of high-molecular-weight polymers the apparent viscosity mechanism associated with a decrease in dissipative losses on transition of the high-molecular-weight components to the rubbery state is dominant; on a broad range of molecular weights (M > M_c), and moreover for polymer solutions, the decrease in entanglement network density under the influence of deformation acquires considerable importance. It is established that the separate effect of the high-molecular-weight components on the viscoelastic properties of their mixtures contradicts the idea of a random network of macromolecular chains. Attention is drawn to the temperature dependence of the viscosity of polymers with a narrow distribution and the dynamic properties of their mixtures. Problems of theoretical and practical interest associated with the particular rheological properties of polymer systems at high deformation rates are defined.     

Low-volume-fraction limit for polymer fluids

We study a stationary, purely viscous polymer flow through a porous medium modelled as a periodic array of cells consisted of a fluid part and a solid one. Solid parts of the domain present impermeable obstacles, whose impact on fluid flow may be seen as a slowing factor through averaged quantities such as the permeability function, obtained by the homogenization process. In that way, the influence of the microstructure is implemented in the homogenized equations through a kind of nonlinear Darcy's law. Our goal is to find more explicitly the dependence of the permeability function on the size η of the obstacle in the unit cell and the so-called low-volume-fraction limit. Main difficulties arise from the nonlinear character of the power-law viscosity and the apparent weak convergence of the solutions involved.     

Effect of fillers on the viscosity and viscoelasticity of low-density polyethylene melts. Communication 1

An investigation of low-density polyethylenes filled with up to 30% by volume dispersed particles, has shown that for both the matrix and the composites the apparent viscous flow activation energy does not depend on the shear stresses and increases starting from a certain filler concentration at which the conformation range in the matrix is depleted. The dependence of the relative viscosity of the compositions on the volume filler content is satisfactorily described by an equation that contains the reduced filler concentration, defined as the ratio of the nominal filler concentration to the limiting concentration at which the adsorption layers on the particles extend throughout the matrix. The thickness of the polymer layer adsorbed on the particles must be determined from the specific exterior particle surface, with allowance for the volume of the polymer in the sorption space of the porous filler.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 478–486, May–June, 1976.     

化学驱粘性指进微观渗流模拟研究

化学驱是提高原油采收率的重要方法,化学剂的加入使得地下流体粘度界面张力发生变化,粘性指进演变特征更为复杂.基于格子玻尔兹曼伪势多相流模型,综合考虑油水两相间相互作用、聚合物增粘与非牛顿特性、表面活性剂传质扩散作用及降低界面张力机理,建立了化学驱微观渗流格子玻尔兹曼模拟方法.基于数值模拟方法了研究二维单通道内粘性指进发展...     

Simulating of a pressing process of a viscoelastic polymer melt

A well known and often used method to obtain anisotropic polymer films is the so-called pressing process. Here, films are squeezed under high temperatures, pressure and deformation rates. To simulate such a process, the polymeric matrix is treated as a non-Newtonian, viscoelastic melt. The modeling of such melts is done with the anisotropic molecule movement tensor generalization of the Maxwell Model for high deformation rates. The viscoelastic flow simulations are done with DEVSS stabilization techniques and an ALE based dynamic mesh Method. In this work we present simulations in order to show the difference between classical approaches using a generalized Newtonian viscosity to model the melt and the used viscoelastic models. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

A note on the flow of a fluid with pressure-dependent viscosity in the annulus of two infinitely long coaxial cylinders

The dependence of the viscosity of fluids on pressure has been well established by experiments and it needs to be taken into consideration in problems where there is a large variation of pressure in the flow domain. In this paper we consider the flow of a fluid in the annulus between two cylinders whose viscosity depends on the pressure. First we consider the steady flow in the annulus due to the rotation of one cylinder with respect to the other. Then we study the problem of flow in the annular region due to torsional and longitudinal oscillations of one cylinder with respect to the other. In both the problems considered the flow is found to be markedly different from that for the incompressible Navier–Stokes fluid with constant viscosity.     

Two-Phase Flow in Single-Screw Extruders

This work concerns numerical simulation of free-surface flows of highly viscous liquids in single-screw extruders.The numerical treatment of a partially filled extruder is a challenging task due to the complex geometry and the large differences in density and viscosity between the two phases, e.g. polymer melt and air. Furthermore, the rotation of the screw leads to a continuous renewing of the free-surface. For this purpose the Volume of Fluid (VOF) method is used. First a simplified two-dimensional model of a single-screw extruder is considered. Good agreement is obtained between the numerical results and experimental data. Finally, the three dimensional free-surface flow in a partially filled single-screw extruder with dynamic mesh motion is presented. In addition, the power characteristics of a conveying screw element with varying degree of filling is discussed. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Dynamic deformation of a stationary rubber flow

The effect of dynamic deformation on the stationary flow of a rubber composition has been experimentally investigated for comparable values of the stationary and dynamic strain rates. The dependence of the effective viscosity on the stationary shear rate is not equivalent to its dependence on the periodic shear rate amplitude. An expression is given for calculating the effective viscosity in the case of combined stationary and dynamic shear deformation. The effectiveness of the dynamic deformation, estimated in terms of the effective viscosity, depends on whether it is superimposed on the stationary flow at constant stationary shear rate or at constant stress. It is proposed to estimate the effectiveness of dynamic deformation of a stationary non-Newtonian flow in terms of the change in the power of the stationary forces. When the effective viscosity is reduced by dynamic deformation of the stationary flow, the power of the stationary forces increases at constant shear stress and falls at constant stationary shear rate.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 489–496, May–June, 1971.     

Fluid flow in an inhomogeneous granular medium

The seepage of a compressible fluid in an inhomogeneous undeformable granular medium is investigated. It is assumed that the fluid flow in a porous space is described by the Navier–Stokes equations. It is shown that, in the case of an inhomogeneous velocity field, a tensor of additional effective stresses occurs in connection with the transfer of fluid particles in a transverse direction when flow occurs around the granules of the medium in a longitudinal direction. Using the fundamental propositions of Reynolds’ averaging theory and Prandtl's mixing path, the structure of the effective viscosity coefficient is determined and hypotheses are formulated which enable it to be assumed to be independent of the flow velocity. It is established by comparison with experimental data that the effective viscosity coefficient can exceed the viscosity coefficient of the flowing fluid by an order of magnitude. The equations of average motion are obtained, which in the case of an incompressible fluid have the form of the Navier–Stokes equations with body forces proportional to the velocity. It is established that, in addition to the well-known dimensionless flow numbers, there is a new number which characterizes the ratio of the Darcy porous drag forces to the effective viscosity forces. The proposed equations are extended to the case of the flow of an aerated fluid. The components of the angular momentum vector are used as the required functions instead of the components of the velocity vector. This enables a solving system of equations to be obtained, which, apart from the notation, is identical with the similar equations for the case of an incompressible fluid. The solution of a new problem of the fluid flow in a plane channel with permeable walls is presented using three models: Darcy's law for an incompressible and aerated fluid, and also of an aerated fluid taking the effective viscosity into account. It is established that, for the same pressure drop, the maximum flow rate corresponds to Darcy's law. Compressibility leads to its reduction, but by simultaneously taking into account the compressibility and the effective viscosity one obtains minimum values of the flow rate. The effective viscosity and aeration of the fluid has a considerable effect on the flow parameters.     

Quasi-One-Dimensional Flow of a Fluid with Anisotropic Viscosity in a Pulsating Vessel

The problem on a fluid flow in a pulsating vessel is considered in the framework of the quasi-one-dimensional hemodynamic equations. The fluid viscosity is assumed to be anisotropic; i.e., the viscosity coefficient depends on the flow direction. The possible solutions are studied analytically and numerically.