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1.
Diatomic antimony molecules have been produced in a heat-pipe oven at pressures from 10?2 to 10 Torr. Laser induced fluorescence of Sb2 has been studied in the spectral range 420–730 nm with various laser sources. In order to investigate different isotopic molecules and to enhance fluorescence intensity, intracavity measurements have been performed. For the isotopic molecules rotational and vibrational constants of the ground state X(1Σg+) and for the excited state B(Ou+) have been determined. RKR potential curves have been calculated and used to comput Franck—Condon factors. 相似文献
2.
The reactions of 2,3-dihydrothiazolo[2,3-b]benzothiazolium bromide 1 (A? ?Br?) with certain nucleophilic reagents have been performed for the purpose of ascertaining the reaction pathways and identifying the group that is displaced from the central carbon atom of the dithiocarbamate system. The nature of complex salt-like intermediates formed initially from 1 (A? ?Br?) has been studied and confirmed. For comparison, a number of nucleophilic substitution reactions of 2-methylthio-3-methylbenzothiazolium iodide 17 and 2-dimethylamino-3-methylbenzothiazolium perchlorate 18 have been examined. 相似文献
3.
David J. Lingley Robert A. Shaw Michael Woods S. S. Krishnamurthy 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):379-382
Abstract The three isomers of N3P3Cl4(NHPr1)2 have been prepared and separated by gas-liquid chromatography. Their structures have been assigned on the basis of 1H and 31P nmr data. 相似文献
4.
Joseph D. Connoly Christopher O. Facunle David S. Rycroft 《Tetrahedron letters》1984,25(34):3773-3776
The structures of five ingol esters and a 17-hydroxyingenol ester from the latex of have been determined. The 13C n.m.r. spectra of these compounds have been assigned using 2D δC/δH correlations. The specific positions of attachment of esters have been assigned unambiguously using 13C n.m.r. methods including 2D long range δC/δH correlation. 相似文献
5.
A. A. Ibragimov N. D. Abdullaev Z. Osmanov S. Yu. Yunusov 《Chemistry of Natural Compounds》1987,23(5):569-573
The chemical properties of sibirinine have been studied, its synthesis has been performed, and its1H and13C NMR spectra have been analyzed. From the results obtained its structure and absolute configuration have been deduced. 相似文献
6.
Robert M. K. Deng Keith B. Dillon Andrew W. G. Platt 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-3):93-96
Abstract Several new pseudo-halogeno phosphorus species, including isomeric N- and O-bonded cyanato-derivatives of the PCl6 ? ion, cyano-derivatives of RPCl5 ? ions (R [dbnd] Ph or Me), and organo-phosphorus (III) cyanide adducts RP(CN)2X? (R [dbnd] Me, Et, Ph or C6F5; X [dbnd] Cl, Br or I) have been prepared in solution, and identified by means of 31P n.m.r. spectroscopy. Isomeric configurations in the six-coordinate species have been assigned by the method of pairwise interactions. 相似文献
7.
T. G. Dekker K. G. R. Pachler P. L. Wessels 《Magnetic resonance in chemistry : MRC》1976,8(10):530-531
Different applications of the selective population inversion technique in an n.m.r. study of 3,6-epoxypentacyclo-[6.2.1.02,7.04,10.05,9] undecane have been demonstrated. The intensity gain accompanying heteronuclear 13C—{1H} experiments allowed the detection of fine structure due to long range C? H couplings otherwise hidden in normal proton coupled 13C spectra. Definite assignments of two very similar, directly bonded, C? H couplings within a methylene group have been made. 相似文献
8.
The 1-NH structure for 3-azidoindazole has been demonstrated by the observation of 1H? 1H and 13C? 1H couplings involving the hydrogen atom attached to nitrogen. A comparison between 3-azidoindazole and indazole shows that both compounds have the same tautomeric structure. 相似文献
9.
The radiotracer method has been used for investigation of the adsorption and desorption of traces of radium on ferric hydroxide and quartz under conditions similar to those prevailing in waste and surface waters. The effects of pH, liquid to solid ratio, ionic strength and presence of Ca2+ or SO
4
2-
ions have been studied. It has been concluded that at pH less than 7 and at concentration of suspended sediments (of common composition) less than 100 mg·1–1 ferric hydroxide and quartz have negligible effect on the state and migration of radium in surface waters. Radium adsorbed on quartz can be easily desorbed with dilute solutions of hydrochloric acid or sodium chloride. 相似文献
10.
M. A. Madre É. É. Liepin'sh R. A. Zhuk O. V. Sakhartova M. Yu. Lidak 《Chemistry of Heterocyclic Compounds》1986,22(4):425-431
The reaction of bis(trimethylsilyl)hypoxanthine with methyl trichloromethyl ether has been investigated. 1-Methoxymethyl-, 7-methoxymethyl-, and 9-methoxymethyl-hypoxanthine, as well as 1,7-, 1,9-, and 3,7-bismethoxymethylhypoxanthine, have been isolated from the reaction mixture. The structures of the isomers have been established on the basis of an analysis of their UV, IR, 1H NMR, 13C NMR, and 15N NMR spectra. The influence of the conditions under which the reaction is carried out on the yield of the alkylation products and the isomeric composition of the reaction mixture has been studied.For report 2, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 518–524, April, 1986. 相似文献
11.
Peter van de Weijer Dirk M. W. van den Ham Douwe van der Meer 《Magnetic resonance in chemistry : MRC》1977,9(5):281-284
The 13C chemical shifts of the diazanaphthalenes have been recorded as a function of the pH value, providing classical titration curves. From these curves the pK1 and pK2 values have been determined taking into account the activity coefficients. The changes in 13C chemical shift under the influence of nitrogen protonation (Δδ) can be described by two protonation parameter sets. 相似文献
12.
Robert E. Botto Philip W. Westerman John D. Roberts 《Magnetic resonance in chemistry : MRC》1978,11(10):510-515
15N chemical shifts of the Z and E isomers of twenty-two ketoximes and fourteen aldoximes have been determined at the natural-abundance level of 15N, using Fourier transform methods. The influences of π delocalization, methyl substituents and solute concentration on the oxime nitrogen shielding have been determined. The 15N shifts for oximes of several cycloalkanones have been measured and the influence of ring size on the chemical shifts is discussed. 相似文献
13.
Fasih A. Siddiqi N. Lakshminarayanaiah Mohammad N. Beg 《Journal of polymer science. Part A, Polymer chemistry》1971,9(10):2853-2867
The permeability of various electrolytes through parchment-supported ferrocyanide membranes of manganese, cobalt, silver, and cadmium has been measured at 10, 15, 20, 25, and 30°C. The order of permeability at a given temperature was Cl- > NO3- > CNS- > CH3COO- > SO42- for both monovalent and divalent cations. For any given anion, the cations followed the sequence NH4+ > Li+ > Ba2+ > Ca2+ > Mg2+ > Al3+. This sequence has been correlated with the size of the hydrated ion. Further, the data have been considered from the standpoint of the theory of rate processes and the values for the entropy of activation (ΔS′) have been derived assuming an equilibrium distance of 3 Å in the membrane. The values of ΔS′ were all negative and decreased with increasing valence of the ions. This was interpreted to mean electrolyte permeation with partial immobilization in the membrane. 相似文献
14.
Raphaël Sabbah 《Thermochimica Acta》1980,41(1):33-40
Enthalpies of sublimation for pyrazole and imidazole have been obtained by calorimetry at 298.15K. The ΔH0sub (298.15 K) values for these two compounds are, respectively, 69.16 ± 0.32 and 74.50 ± 0.40 kJ mole?1. From literature data obtained by combustion calorimetry for ΔH0f (c, 298.15 K), the enthalpies of formation of these compounds in the gaseous state (pyrazole: 185.1 ± 2.3 kJ mole?, imidazole: 133.0 ± 1.7 kJ mole?1) have been derived. Several energy values related to the molecular structure of these two compounds (as resonance energy, enthalpy of isomerization, …) have been determined. The study of pyrazole has enabled us to contribute to the evaluation of some characteristics of the NN bond. 相似文献
15.
Summary Samples of zirconium tungstate have been prepared under different conditions and their physico-chemical properties, composition, IR spectra and cation-exchange behaviour are reported. Separations of a number of metal ions from Bi3+ and from Pb2+ have been worked out.Part X. Ref. [1]. 相似文献
16.
The Raman spectra (50–1200 cm?1) of gaseous, liquid, and solid (Cl3Si)2O have been recorded. The infrared spectra of the gas and solid have been recorded from 55–2000 cm?1 . The spectra of the gas have been interpreted in detail on the basis of C2v symmetry with the A1 skeletal Si-O-Si bend assigned at 63 cm?1. The spectra gave evidence that there are structural changes upon condensation of the gas and the Si-O-Si angle approaches linearity in the solid state. The opening of this angle is probably due to crystal packing factors. 相似文献
17.
On Chalcogenolates. 134. Studies on Esters of Haloformic Acids 2. Synthesis and Properties of Se-Alkyl Esters of Chloromonothiomonoselenoformic Acid The hitherto unknown esters RSe? CS? Cl with R ? C2H5 and nC3H7 have been prepared by reaction of thiophosgene with the corresponding alkane selenol. The compounds have been characterized with electron absorption, nuclear magnetic resonance (1H, 13C, and 77Se), infrared, and mass spectra. 相似文献
18.
Roger Hollenstein Wolfgang von Philipsborn Rudolf Vgeli Markus Neuenschwander 《Helvetica chimica acta》1973,56(3):847-860
Carbon-13 and proton NMR. spectra of pentafulvene and of a series of 6-substituted fulvenes have been analysed and assigned by homo- and heteronuclear double resonance and with the aid of iterative computation. 13C and 1H chemical shifts are interpreted in terms of substituent effects and compared with π-electron charges calculated for the unsubstituted fulvene. From 13C shifts a 10 percent contribution of dipolar structures to the electronic configuration of fulvene may be estimated. All long-range proton-proton coupling constants including relative signs and some proton-carbon couplings in the fulvene spin system have been determined and assigned. 相似文献
19.
The infrared spectra of gaseous and solid tertiary-butylphosphine, [(CH3)3CPH2], have been recorded from 50 cm?1 to 3500 cm?1. The Raman spectra of gaseous, liquid and solid (CH3)3CPH2 have been recorded from 10 to 3500 cm?1. A vibrational assignment of the 42 normal modes has been made. A harmonic approximation of the methyl torsional barrier from observed transitions in the solid state gave a result of 4.22 kcal mol?1 and 3.81 kcal mol?1 in the gaseous state. Hot band transitions for the phosphino torsional mode have been observed. The potential function for internal rotation about the C-P bond has been calculated. The two potential constants were determined to be: V3 = 2.79 ± 0.01 kcal mol?1 and V6 = 0.07 ± 0.01 kcal mol?1. 相似文献
20.
A. Pizzi 《Journal of polymer science. Part A, Polymer chemistry》1982,20(3):739-764
The kinetic behavior of copper–chromium–arsenic (CCA) wood preservatives in their reaction with wood, lignin, cellulose, and their respective simple model compounds, guaiacol and D(+)-glucose, has been elucidated. Copper chromatesVI/lignin guaiacyl units and chromiumIII arsenates/lignin guaiacyl units, which are stable and insoluble complexes formed during the reaction, have been characterized. No copper arsenates were formed during the reactions (which were carried out using a CCA of type C). The sequence, nature, and combined effect of the reactions of CCA with wood, lignin, and cellulose are similar to that already described for the “CrO3 alone,”1 Cu/Cr2, and Cr/As3 systems. Rate constants, energies of activation, and Arrhenius equations have been obtained and reported. The distribution of CrVI, CrIII, Asv, and Cu2+ in CCA-C-treated wood has been calculated. The results obtained have allowed meaningful comparisons of several commercial CCA formulations. 相似文献