加入增益介质的表面等离子体激元耦合共振波导传输特性理论研究

将增益介质加入金属环构成的表面等离子体激元耦合共振波导,利用传输矩阵及时域有限差分方法研究了不同增益系数下该耦合共振波导的透射谱线、色散关系以及群折射率.结果表明,增益介质共振频率附近的反常色散及正常色散变化能有效影响由共振波导几何结构决定的色散关系曲线,且具有相反的效果,分别使其变得平坦和陡峭,从而放大和缩小由共振波导几何结构决定的群折射率.另外,增益系数随外加抽运光改变的特点使得加入增益介质的耦合共振波导具有传输性能可灵活调节特性.文章的研究对促进耦合共振波导在高密度光学集成中的广泛应用具有积极意义. 关键词： 增益介质 耦合共振波导 表面等离子体激元 群折射率     

Numerical simulation of nanoparticle images in scanning near-field optical microscopy

The images of magnetic and nonmagnetic nanoparticles obtained by scanning near-field microscopy in the photon collection mode are numerically simulated. A theoretical approach that uses tensor electrodynamic Green’s functions to find the optical near field in a given observation scheme is considered. Typicalimages of nanoparticles with various shapes are obtained by numerical simulation. Subject to boundary conditions, the plane of polarization is shown to change at topographic features (edges and angles) of objects studied. This makes the observation of the magnetic structure of a nanoparticle with a magnetooptic method difficult. The near-field study of the magnetization distribution in homogeneous thin films appears to be more effective, since the rotation of plane of polarization is associated primarily with the magnetic properties of the sample in this case.     

Controlling near-field optical intensities in metal nanoparticle systems by polarization pulse shaping

Coherent control of near-fields in the proximity of nanoparticles is a promising tool for shaping the temporal and spatial properties of light at the nano-scale. Numerical simulations on a series of progressively more complex metallic nanoparticle systems were carried out to explore in detail the mechanisms of control. We find that an important element for the controllability of intensity localization is the spatial variation of the phase in the near-field that is due either to the interference between the plane incident wave and the near-field of the nanosystem or to the interference of fields generated by different parts of the nanosystem. For a collection of random nanoparticles we show that it is possible to select the appearance of highly localized hot spots.     

Polarization mapping of nanoparticle plasmonic coupling

We propose the use of polarization mapping as a tool to better separate the effects of plasmonic coupling from the local refractive index for molecular imaging and biosensing using gold nanoparticles. Polarization mapping allows identification of the orthogonal excitation mode when the particle dimer orientation is unknown, as may be the case when using plasmonic nanoparticles for cell labeling. This information can be used to sense relative changes in the dielectric environment, or for absolute dielectric sensing with additional a priori interparticle distance information. First, the theoretical scattering by nanoparticle pairs is modeled under parallel and orthogonal polarization orientations and increasing interparticle separation. Second, polarization mapping of substrate bound nanoparticles using dark-field microspectroscopy is investigated as a method to isolate the individual plasmonic coupling modes associated with a pair of nanoparticles without reorientation of the sample. The results of this study provide useful insight toward potential avenues for monitoring distances using plasmonic nanoparticles and sensing the local refractive index using nanoparticle pairs when the pair orientation is not known, as may be the case when using nanoparticles for cell receptor labeling.     

Theoretical study of broadband near-field optical spectrum of twisted bilayer graphene

We theoretically study the broadband near-field optical spectrum of twisted bilayer graphene (TBG) at various twist angles near the magic angle using two different models. The spectrum at low Fermi energy is characterized by a series of peaks that are almost at the same energies as the peaks in the far-field optical conductivity of TBG. When the Fermi energy is near a van Hove singularity, an additional strong peak appears at finite energy in the near-field spectrum, which has no counterpart in the optical conductivity. Based on a detailed calculation of the plasmon dispersion, we show that these spectroscopic features are associated with interband and intraband plasmons, which can provide critical information about the local band structure and plasmonic excitations in TBG. The near-field peaks evolve systematically with the twist angle, so they can serve as fingerprints for identifying the spatial dependent twist angle in TBG samples. Our findings pave the way for future experimental studies of the novel optical properties of TBG in the nanoscale.     

Stable Fano-like plasmonic resonance: its impact on the reversal of far-and near-field optical binding force

Even for a 100 nm interparticle distance or a small change in particle shape,optical Fano-like plasmonic resonance mode usually vanishes completely.It would be remarkable if stable Fano-like resonance could somehow be achieved in distinctly shaped nanoparticles for more than 1μm interparticle distance,which corresponds to the far electromagnetic field region.If such far-field Fano-like plasmonic resonance can be achieved,controlling the reversal of the far-field binding force can be attained,like the currently reported reversals for near-field cases.In this work,we have proposed an optical set-up to achieve such a robust and stable Fano-like plasmonic resonance,and comparatively studied its remarkable impact on controlling the reversal of near-and far-field optical binding forces.In our proposed set-up,the distinctly shaped plasmonic tetramers are half immersed(i.e.air-benzene)in an inhomogeneous dielectric interface and illuminated by?circular?polarized light.We have demonstrated significant differences between near-and far-field optical binding forces along with the Lorentz force field,which partially depends on the object’s shape.A clear connection is shown between the far-field binding force and the resonant modes,along with a generic mechanism to achieve controllable Fano-like plasmonic resonance and the reversal of the optical binding force in both far-and near-field configurations.     

Size-dependent optical properties of VO2 nanoparticle arrays

The size effects on the optical properties of vanadium dioxide nanoparticles in ordered arrays have been studied. Contrary to previous VO2 studies, we observe that the optical contrast between the semiconducting and metallic phases is dramatically enhanced in the visible region, presenting size-dependent optical resonances and size-dependent transition temperatures. The collective optical response as a function of temperature presents an enhanced scattering state during the evolving phase transition. The effects appear to arise because of the underlying VO2 mesoscale optical properties, the heterogeneous nucleation behind the phase transition, and the incoherent coupling between the nanoparticles undergoing an order-disorder-order transition. Calculations that support these interpretations are presented.     

Synthesis and optical properties of coated nanoparticle composites

The synthesis of coated nanoparticles is a new direction in engineering, specifically in the study of physical properties of materials. We examine semiconductor coated semiconductor particles, CdS/PbS, and metal coated particles, Au₂S/Au, and the theoretical basis for their unique properties. Coated self-assembled nanoparticles are also studied and recent progress is reported.     

金纳米颗粒的有序制备及其光学特性

采用纳米球蚀刻技术在石英衬底上制备了不同高度的金纳米颗粒阵列.通过扫描电子显微镜对其表面形貌进行了观测,表明金纳米颗粒为有序分布的三棱柱结构.通过红外—紫外吸收光谱仪在190—900nm波长范围内对其光吸收特性进行了测量, 并成功观测到了金纳米颗粒表面等离子体振荡效应引起的光吸收峰,结果表明随着金纳米颗粒高度的增加,其吸收峰的位置向短波方向移动(蓝移).同时对金纳米颗粒的光吸收特性进行了基于离散偶极子近似的理论计算,并与实验结果进行了比较. 关键词： 纳米球蚀刻技术 金纳米颗粒 离散偶极子近似     

Synthesis and nonlinear optical properties of branched pyrroline chromophores

New tricyanopyrroline (TCP) chromophores with rigid–flexible dendron were prepared for second‐order nonlinear optical (NLO) application. The chromophores were fully characterized using ultraviolet‐visible spectroscopy, nuclear magnetic resonance spectroscopy and mass spectrometry. Thermal gravimetric analysis (TGA) revealed that the chromophores had excellent thermal stability. Large λ_max and high solvate chromic effects revealed that the chromophores had large second‐order optical nonlinearity. The electro‐optic coefficients (r₃₃) were measured in the chromophores‐doped poly(bisphenol A carbonate) films at the fundamental wavelength of 1310 nm, and the highest γ₃₃ achieved was 217 pmV^?1. Copyright © 2010 John Wiley & Sons, Ltd.     

Nonlinear optical properties of periodic gold nanoparticle arrays

Periodic Au nanoparticle arrays were fabricated on silica substrates using nanosphere lithography. The identical single-layer masks were prepared by self-assembly of polystyrene nanospheres with radius R = 350 nm. The structural characterization of nanosphere masks and periodic particle arrays was investigated by atomic force microscopy. The nonlinear optical properties of the Au nanoparticle arrays were determined using a single beam z-scan method at a wavelength of 532 nm with laser duration of 55 ps. The results show that periodic Au nanoparticle arrays exhibit a fast third-order nonlinear optical response with the nonlinear refractive index and nonlinear absorption coefficient being n₂ = 6.09 × 10⁻⁶ cm²/kW and β = −1.87 × 10⁻⁶ m/W, respectively.     

Irregular elliptical plasmonic rings for engineering near-field and phase

Metallic glasses find wide applications in nanotechnology and micro electro-mechanical systems because of their unique physical properties due to their amorphous structures. The material removal mechanism in nanometric cutting of Cu₅₀Zr₅₀, a typical metallic glass, is studied using molecular dynamics method. The chip formation, workpiece deformation and scratching forces under various scratching depths, scratching velocities and temperatures are investigated. The effect of void defect on the cutting behaviors of metallic glass is also explored. The results show that the material removal in nanometric cutting process is based on extrusion instead of shearing, achieving a good understanding of material removal at the nanoscale.     

Nonlinear optical properties of Au/ZnO nanoparticle arrays

The triangular-shaped Au/ZnO nanoparticle arrays were fabricated on fused quartz substrate using nanosphere lithography. The structural characterization of the Au/ZnO nanoparticle arrays was investigated by atomic force microscopy. The absorption peak due to the surface plasmon resonance of Au particles at the wavelength of about 570 nm was observed. The nonlinear optical properties of the nanoparticle arrays were measured using the z-scan method at a wavelength of 532 nm with pulse duration of 10 ns. The real and imaginary part of third-order nonlinear optical susceptibility, Re χ⁽³⁾ and Im χ⁽³⁾, were determined to be 1.15 × 10⁻⁶ and −5.36 × 10⁻⁷ esu, respectively. The results show that the Au/ZnO nanoparticle arrays have great potential for future optical devices.     

Uniform plasmonic near-field nanopatterning by backward irradiation of femtosecond laser

We present localized optical field distribution properties in the vicinity of gold particles on a silicon substrate by backward and forward irradiation. It is technically difficult to fabricate nanostructures on the surface by a conventional forward laser incident to the substrate because gold nanoparticles easily aggregate to form double-layered particle arrays. We calculated enhanced optical field properties in order to pattern the substrate surface only with a template of the bottom-layered particle arrays in the case that the backward irradiation of a femtosecond laser is used in the system of aggregated double-layered gold nanoparticle arrays. With the backward irradiation, the optical field intensity in the substrate for the double-layered hexagonal arrays is found to be only 30% lower than the mono-layered system. Moreover, a near field cannot be generated with the forward irradiation. As a result, only the backward irradiation scheme is found to be effective for uniform surface nanopatterning at enhanced plasmonic near-field zones.     

Scanning near-field optical microscopy

Scanning Near-field Optical Microscopy (SNOM) allows the investigation of optical properties on subwavelength scales. During the past few years, more and more attention has been given to this technique that shows enormous potential for imaging, sensing and modification at near-molecular resolution. This article describes the technique and reviews recent progress in the field.     

Photoemission electron microscopy of a plasmonic silver nanoparticle trimer

Anodic aluminum oxide (AAO) films with different porosities were fabricated on the surfaces of InGaN/GaN multiple quantum wells (MQWs). We measured the photoluminescence spectra of these samples and then calculated the light extraction enhancement factors (E). It was found that the light extraction of the MQWs with the AAO films has been greatly enhanced compared to the area without AAO coverage. The maximum value of E reaches 3.5 at a certain wavelength and 2.29 in the integral intensity. The increase of E with the decrease of the porosities demonstrates that the nano-hole structure in the AAO films plays an important role in enhancing the light extraction efficiency.     

Review of near-field optical microscopy

This review has introduced a new near-field optical microscope (NOM)—atomic force microscope combined with photon scanning tunneling microscope (AF / PSTM). During scanning, AF/PSTM could get two optical images of refractive index image and transmissivity image, and two AFM images of topography image and phase image. A reflected near-field optical microscope (AF/RSNOM) has also been developed on AF/PSTM platform. The NOM has been reviewed in this paper and the comparison between AF/PSTM & RSNOM and the commercial A-SNOM & RNOM has also been discussed. The functions of AF/PSTM & RSNOM are much better than A-SNOM & RNOM.     

Near-field optical polarimetry of plasmonic nanowires

Local polarization properties of a gold subwavelength grating with plasmon-induced linear dichroism are studied by scanning near-field optical dynamic polarimetry. Periodic modulation of linear dichroism with the period corresponding to the period of the grating and the contrast of 0.3 is found at the distance of λ/20 from the sample.     

Measuring local optical properties: near-field polarimetry of photonic block copolymer morphology

Ultrahigh molecular weight polystyrene-b-polyisoprene block copolymers (BCs), noted for their photonic behavior, were imaged using transmission near-field scanning optical microscopy (NSOM) and NSOM polarimetry. Our improved scheme for polarization modulation (PM) polarimetry, which accounts for optical anisotropies of the NSOM aperture probe, enables mapping of the local diattenuation and birefringence (with separately aligned diattenuating and fast axes) in these specimens with subdiffraction limited resolution. PM-NSOM micrographs illuminate the mesoscopic optical nature of these BC specimens by resolving individual microphase domains and defect structures.