Synchronisation effects in broadband FIR raman scattering in NH3

By using a short pulse broad band (2 GHz) CO₂ laser around a single well detuned line (15 GHz), it is possible to analyse, with sub-ns resolution, the dynamics of a broadband FIR Raman scattering. When the Raman gain is large, well modulated ns emissions are detected also for resonant lines. Generally the pseudo cavity effects, are always present. They have important effects on the gain, in particular an aligned input window has a large positive effect on the Raman gain and on the generation of mode-locked FIR forward emissions     

探测大气中CO2的Raman激光雷达

基于大气激光后向散射光谱，研究和设计了探测大气CO₂浓度的Raman激光雷达,其发射机采用Nd∶YAG激光的三倍频354.7nm作为工作波长,发射的单脉冲能量350mJ,重复频率20Hz；接收机采用了光电倍增管(量子效率25%)和光子计数器(计数速率200MHz),探测CO₂的Raman散射371.66nm(频移1285cm^-1)信号,(1小时累加)近地面2.5km以内信噪比不小于8.采用组合滤光片来抑制强的354.7nm Mie-Rayleigh后向散射和氧气375.4nm Raman后向散射对信号的严重干扰. 比较分别来自大气CO₂和参考气体N₂的Raman后向散射回波,可反演出大气中CO₂的相对浓度. 关键词： 大气光学 激光雷达 Raman散射光谱 参考气体 Mie-Rayleigh散射     

Very high power line-selective CO2 laser with (line-selective) unstable resonator

By replacing the conventional (non line-selective) unstable resonator, we succeeded in developing the very high power line-selective (line-tunable) CO₂ laser as a pumping source for high power molecular gas (e.g.NH₃) lasers in the infrared and far-infrared regions.The experiments were performed by using the very high power CO₂ laser (4A unit of Lekko VIII) at The Institute of Laser Engineering, Osaka University.The output power of 9R(30)9.22µ m line from the developed CO₂ laser, for instance, exceeded 0.5GW/pulse (50J/pulse with pulse width of 100nsec).     

TE CO2 infrared emission apparatus with a half cavity

A TE CO₂ infrared emission apparatus with a half cavity is described . Via grating-tune the emissions p(12)–p(28), 00°1–10°0 of CO₂ are obtained for gas mixtures of 15%CO₂:20% N₂:65%He and 20%CO₂:15%N₂:65%He at a total pressure of 60 kPa; the output energy and pulse width are 20–850 mJ and 60–70 ns, respectively.     

Small angle x—ray scattering study on the conformation of polystyrene in toluene during adding anti—solvent CO2

The conformatiopn of polystyrene in the anti-solvent process of supercritical fluids(compressed CO2 polystyrene toluene)has been studied by small angle x-ray scattering with synchrotron radiation as an x-ray source.Coilto-globule transformation of the polystyrene chain was observed with the increase of the anti-solvent CO2 pressure;i.e.polystrene coiled at a prssure lower than the cloud point pressure(Pc)and turned into a globle with a uniform density at pressures higher than Pc.Fractal behaviour was also found in the chain contraction.and the mass fractal dimension increased with increasing CO2 pressure.     

A compact TEA CO2 laser for field-based spectrochemical analysis of geological samples

A compact capacitor-transfer TEA CO₂ laser of 180 mJ output energy and 50 ns pulse duration in half width was designed and constructed for field use. This laser is suitable for laser microprobe spectrochemical analysis on geological and mining samples. Experiments show that the use of helium as a surrounding gas suppresses the continuous emission spectrum of the plasma, thus increasing the S/N ratio. Using glass as standard samples, the minimum detectable concentrations are estimated with Zn neutral line and F ionic line to be 60 ppm and 500 ppm, respectively.     

Dynamical analysis of acousto-optically Q-switched CO2 laser

A compacted size high power CO₂ laser has been developed using an acousto-optically (AO) Q-switch. Performance characteristics have been investigated as a function of output mirror transmittance. The theory of six-temperature model for CO₂ lasers has firstly been utilized to analyze the dynamical process in the AO Q-switched CO₂ laser. This theory perfectly explains the behavior of energy transfer between different molecules in laser gain medium, and describes the shape of pulse laser. The calculated pulse waveforms are in good agreement with the experimental result. Both the experimental and theoretical results present that the optimal value of output mirror transmittance is 39%. Under this condition, the measured peak power is 4750 W and pulsed width is 160 ns, which is consistent with the calculations. Six-temperature model is a perfect theory for CO₂ laser kinetics, which will lay a theoretical foundation for the laser optimum design.     

Short single-mode CO2 laser pulse generation by pulsed Q-switching

A simple method for the generation of short, single-mode CO₂ laser pulses produced by applying two voltage gates (of amplitude 3U_λ/4 and U_λ/4) to an electro-optic Q-switch placed in a three-mirror cavity is proposed. Single, single-mode, well-synchronizable pulses of 3 ns duration and of 3 mJ energy have been experimentally achieved from a TEA CO₂ laser with an intracavity Pockels cell with 3 ns switching time. Using a numerical simulation it is shown that with shorter switching time (≈1 ns) the method enables one to obtain, from such a laser, a single, megawatt pulse of 1 ns duration.     

Gas breakdown with nanosecond CO2 laser radiation

The thresholds for CO₂ laser induced breakdown and their variation with pulse width have been measured at various pressures for Ar, N₂ and an 8/1/1 laser mixture of He/CO₂/N₂ using 3–40 ns duration pulses. These measurements indicate that excited state production plays a dominant role in determining the threshold for nanosecond duration pulses. This has been confirmed by the good agreement obtained between the measured and theoretical thresholds.     

Optically pumped high-pressure DF-CO2 transfer laser

Pulsed sealed off CO₂ laser operation at 19 atm gas pressure has been demonstrated by pumping DF/CO₂/He mixtures with radiation from a pulsed DF laser. DF acts as an absorber for the pumping radiation, and the CO₂ upper laser level is populated via subsequent energy transfer. CO₂ pulse energy at 19 atm was 0.5 mJ corresponding to a photon conversion efficiency of 4% measured relative to the number of absorbed pumping photons.     

Picosecond stimulated Raman scattering of BaWO4 crystal

In single-pass configuration, a picosecond pulse laser was used to investigate the stimulated Raman scattering in different BaWO₄ crystals. Using the thresholds for the first Stokes line along the a- and c-axis, the Raman gain coefficients of the BaWO₄ crystals were calculated along their respective direction. The higher Stokes (fourth) and anti-Stokes (third) lines were observed. Compared with other well-known Raman crystals, such as KGd(WO₄)₂ and Ba(NO₃)₂, BaWO₄ has favorable properties for scattering the pump radiation with picosecond pulse duration. The Raman gain coefficients of BaWO₄ are different, but do not vary for different transmission directions, which means that this Raman material can be selected more freely.     

High pressure X-ray diffraction study of CdAl2Se4 and Raman study of AAl2Se4 (A=Hg, Zn) and CdAl2X4 (X=Se, S)

We report the results of an X-ray diffraction study of CdAl₂Se₄ and of Raman studies of HgAl₂Se₄ and ZnAl₂Se₄ at room temperature, and of CdAl₂S₄ and CdAl₂Se₄ at 80 K at high pressure. The ambient pressure phase of CdAl₂Se₄ is stable up to a pressure of 9.1 GPa above which a phase transition to a disordered rock salt phase is observed. A fit of the volume pressure data to a Birch-Murnaghan type equation of state yields a bulk modulus of 52.1 GPa. The relative volume change at the phase transition at ∼9 GPa is about 10%. The analysis of the Raman data of HgAl₂Se₄ and ZnAl₂Se₄ reveals a general trend observed for different defect chalcopyrite materials. The line widths of the Raman peaks change at intermediate pressures between 4 and 6 GPa as an indication of the pressure induced two stage order-disorder transition observed in these materials. In addition, we include results of a low temperature Raman study of CdAl₂S₄ and CdAl₂Se₄, which shows a very weak temperature dependence of the Raman-active phonon modes.     

Polarization enhancement of anti-Stokes emission in a para-H2 Raman laser

The effect of polarization can influence the frequency conversion and enhance the anti-Stokes emission in a rotational para-H₂ Raman laser. Stokes (16 μm) and anti-Stokes (7 μm) radiations were obtained from a line tunable CO₂ laser at 10 μm.     

Spikes in raman spectrum of miniature optically pumped NH3 fir laser

In this paper, the semiclassical density matrix equation was solved to calculate the spectral characteristics of V₂:a--sR(0,0) transition in a miniature optically pumped NH₃ far infrared laser (mini-NH₃-OPFIRL), which was pumped by CO₂-10R(6) line. The results of theoretical calculation showed that the spikes in Raman spectrum of V₂:a--sR(0,0) would appear when the operating NH₃ gas pressure was higher than a certain critical value or pumping power density was lower than a certain critical value, which was caused by Raman processes interaction of AC-Stark splitting. In our experiment, 298 µm FIR spetral line of a--sR(0,0) pumped by a TEA-CO₂ laser with 10R(6) line was observed but the spikes could not be observed owing to the limitation of the resolution of the F-P interferometer.Supported by the National Natural Sciences Foundation of P.R.China.     

New far infrared laser lines in optically pumped CD3F

Summary Using a high pressure CO₂-laser we have studied laser action in¹²CD₃F stimulated by R-branch pumping. We used an arrangement with low-feedback mirrors as suitable for Raman laser action. However, no Raman laser action has been observed in¹²CD₃F though similar experimental conditions were met as for¹²CH₃F and¹³CH₃F. The reason for the different behavior of the gases is not yet clear.Instead of Raman laser action we found 15 FIR resonant laser lines with 13 of them unknown up to now in the frequency range from 50 cm^–1 to 68 cm^–1. We reached FIR pulse energies up to 900 J, corresponding to a photon conversion efficiency of 12%. For our arrangement the optimum operation pressure varied from 40 torr at low J values (J=36) to 70 torr at high J values (J=49).     

Single mode oscillation of TEA CO2 laser with an interference resonator

An effective single-longitudinal mode (SLM) pulse TEA CO₂ laser operation was demonstrated using a Michelson’s type resonator with a tilting Fabry-Perot etalon. A modified numerical model of the interference resonator was investigated for designing the laser. The experimentally measured values were found to have good agreement with the numerical model. A pulse width of about 90 ns and the maximum pulse energy of about 300 mJ were achieved at 10.59 μm in SLM and TEM₀₀ mode. The reliability of producing SLM pulses was 100% and there was no damage on the etalon. By turning the interference resonator, the SLM output was tuned 44 lines of the CO₂ spectrum.     

Raman spectra of TiO2-II,TiO2-III,SnO2, and GeO2 at high pressure

Raman spectra of the orthorhombic (II) and high pressure (III) phases of titanium dioxide at pressures to 372 kbar and effects of temperature and hydrostatic pressure on Raman spectra of the tetagonal cassiterite-like phases of TiO₂, GeO₂ and SnO₂ are described. At room temperature, the TiO₂ II–III transition is sluggish, and metastable coexistence was observed from 200 to 300 kbar. The Raman spectra of TiO₂-III imply that its primitive cell contains at least four formula units; however, the structure could not be established from the Raman spectra and available powder X-ray diffraction patterns.The temperature and pressure dependences of the spectrum of the tetragonal MO₂ phases together with bulk moduli and thermal expansion data were used to evaluate the pure-volume and pure-temperature contributions to the isobaric temperature dependence of the Raman frequencies. Large anharmonicities in TiO₂ are attributed to hybridization of the oxygen p states with the d states of the Ti ion. GeO₂, where p-electron bonding is involved, is much less Enharmonic.     

Subnanosecond mid-infrared laser pulse generation by synchronous mode-locked CO2 laser pumping

An injection mode-locked CO₂ laser has been used to synchronously pump NH₃ and C₂D₂ mid-infrared lasers resulting in the generation of short (? 1 ns) and powerful (> 1 MW) pulse trains.     

Single line high efficiency tunable fir generation by resonant four-wave mixing in CH3 pumped by a multiatmosphere tunable CO2 laser

By pumping CH₃F with a high pressure tunable TE-CO₂ laser, the resonant four-wave mixing process (RFWM) generates a very efficient tunable single line FIR emission at the Raman frequency. This result is strictly related to the spectroscopic structure of the CH₃F molecule. By means of this process, a tunable FIR emission on a 0.1 cm^–1 bandwidth 150 kW (8 mJ) single line, is obtained which can be used for many FIR multiphoton applications.     

High precision spectroscopy of SF6 with cw high pressure tunable CO2 laser

Investigations are reported on the frequency characteristics of the cw high pressure CO₂ laser and its use for high precision spectroscopy. The problem of using a cw tunable CO₂ laser with a mixture of a few isotopes (¹²C¹⁶O₂, ¹²C¹⁸O₂, ¹²C¹⁶O¹⁸O and others) in a cw high pressure tunable CO₂ laser is discussed. Broadening of the tuning range has given us the opportunity to find seven new absorption lines of SF₆ near the transition P(20) of the 00⁰1–10⁰0 band of the CO₂ laser.