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标准物质在检测实验室质量控制中的应用 总被引:1,自引:0,他引:1
【】 本文介绍了检测中使用标准物质进行质量控制的重要意义,分别在盲样测试、期间核查和质量控制图应用方面提出了使用标准物质进行质量控制的三种方法,并通过在实验室获得的检测数据对上述应用方法作了实例说明,对检测实验室应用标准物质进行质量控制工作具有指导意义。 相似文献
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V. I. Dvorkin 《Journal of Analytical Chemistry》2001,56(7):613-625
In this problem-oriented article, regarding the author's experience, a review of the methods of intralaboratory quality control based on systematic analysis of reference samples (control materials) is given. The requirements imposed on reference samples are briefly considered. The principles of selection of an inspection plan and the requirements on the evaluation period of statistical characteristics are formulated. The techniques for graphically representing the results of intralaboratory control and the algorithms for detecting out-of-control analytical processes are considered. Control charts for average values and ranges or charts for cumulative sums and geometric (exponentially weighted) moving averages are recommended as the main or auxiliary graphical representation, respectively. Westgard rules and the simplest rules for ranges are recommended as the main algorithms for revealing out-of-control analytical processes. Multivariate statistical process control methods, which are recommended for use in the cases of a great number of simultaneously determined factors, are briefly discussed. 相似文献
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《中国无机分析化学》2022,(1)
研制了尿素、磷酸氢二铵、氯化钾、高氮磷低氯复合肥、高氮低氯复合肥、高钾硫基复合肥、高钾中氯复合肥、高磷低氯复合肥和平衡型硫基复合肥系列化肥标准物质,样品严格按照相关标准要求进行采集、加工制备、均匀性检验、稳定性检验,由15家不同行业的权威实验室进行协作定值,并对不确定度进行评定。结果表明,样品粒度分布满足样品加工要求,具有良好的均匀性和稳定性。本系列化肥标准物质共定值45项元素(指标),包括N、P_2O_5、水溶性P_2O_5、有效性P_2O_5、K_2O、S、Cl、As、Hg、Cr、Cd、Cu、Pb、Zn、Ni、B、Se、Ge、Fe、Na、Ca、Mg、Al、Ti、V、Mn、Co、Sr、Mo、Ba、Y、La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu,量值准确可靠、不确定度范围评估合理,符合国家一级标准物质的要求。研制的9个化肥化学成分标准物质定值的元素含量梯度范围合理,填补了国内复合肥料标准物质空白,可为化肥样品分析质量控制、实验室仪器校准、分析方法和实验室检测能力验证与评价提供基础技术支撑。 相似文献
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介绍铝合金化学成分标准物质的研制过程。采用中频感应电炉熔炼法制备了铝合金化学成分标准物质候选物,并对标准物质候选物的均匀性和稳定性进行了考察。选择6家具有资质的实验室对研制的标准物质中各化学成分进行协作定值,并对各元素定值的不确定度进行评定。结果表明,在95%的置信区间内标准物质均匀性良好,经过13个月稳定性考察试验,标准物质稳定性良好。Si,Fe,Cu,Mn,Mg,Ti,Cd,V,Zr,B,Sn,Zn的定值结果分别为0.013 8%,0.012 5%,2.868%,0.185%,0.014 0%,0.082 8%,0.041 7%,0.032 9%,0.031 4%,0.003 8%,0.003 4%,0.025 6%,定值结果的相对扩展不确定度为1.4%~9.0%(k=2)。研制的标准物质达到相关技术要求,可用于该类铝合金材料的质量控制。 相似文献
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研制了尿素、磷酸氢二铵、氯化钾、高氮磷低氯复合肥、高氮低氯复合肥、高钾硫基复合肥、高钾中氯复合肥、高磷低氯复合肥和平衡型硫基复合肥系列化肥标准物质,样品严格按照相关标准要求进行采集、加工制备、均匀性检验、稳定性检验,由15家不同行业的权威实验室进行协作定值,并对不确定度进行评定。结果表明,样品粒度分布满足样品加工要求,具有良好的均匀性和稳定性。本系列化肥标准物质共定值45项元素(指标),包括N、P2O5、水溶性P2O5、有效性P2O5、K2O、S、Cl、As、Hg、Cr、Cd、Cu、Pb、Zn、Ni、B、Se、Ge、Fe、Na、Ca、Mg、Al、Ti、V、Mn、Co、Sr、Mo、Ba、Y、La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu,量值准确可靠、不确定度范围评估合理,符合国家一级标准物质的要求。研制的9个化肥化学成分标准物质定值的元素含量梯度范围合理,填补了国内复合肥料标准物质空白,可为化肥样品... 相似文献
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We report instrumental neutron activation analysis results for 15 elements (K, Fe, Sc, Cr, Co, Zn, As, Rb, Sb, Cs, Ba, Hf, Ta, Th, and U) in 16 geochemical reference samples, namely SDC-1, SCo-1, SGR-1, STM-1, RGM-1, BIR-1, MAG-1 and BHVO-1 from USGS (United States Geological Survey, Reston), Soil-5, Soil-7 and SL-1 from IAEA (International Atomic Energy Agency, Vienna), and GSS-1, GSS-4, GSS-7, GSR-2 and GSR-3 from IGGE Institute of Geophysical and Geochemical Prospecting, People's Republic of China), The results are compared with literature values. In general our results agree well with recommended or proposed values. 相似文献
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Chunxue Xu Yaping Wang Ziyi An Qian Wang Dezhong Sun Zongding Chen 《Analytical letters》2019,52(3):401-410
A multi-elemental certified reference material (CRM) based on Arctic marine sediment was prepared and labeled GBW 07481. Approximately 4.5?kg of the sediment was collected during the third Chinese Arctic Expedition. The sediment was processed in procedures that included air drying, debris removal, drying, and milling. The final product contained particles that were generally smaller than 74?;m representing 99% of the total mass. The powder was poured into clean 10-mL brown glass vials and a total of 300 vials were obtained. The homogeneity and stability were preliminarily investigated to assess the suitability of the marine sediment as a candidate CRM. The candidate material was demonstrated to be suitable for this purpose; and hence the certification project was accomplished with nine reputable laboratories. More than 10 reliable analytical methods, including inductively coupled plasma-mass spectrometry (ICP-MS), inductively coupled plasma-atomic emission spectrometry (ICP-AES), and x-ray fluorescence (XRF), were used for analyzing the sediment for 68 elements. The results should be useful for assessing the analytical accuracy of major, minor, and trace elements in marine sediments. Therefore, the CRM is expected to play an important role in Arctic geochemical surveys and environmental assessment. 相似文献
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J. E. Dobson M. J. Gardner A. H. Griffiths M. A. Jessep J. E. Ravenscroft 《Accreditation and quality assurance》1997,2(6):294-300
The approach to analytical quality control adopted for the UK National Marine Analytical Quality Control Scheme is described.
The Scheme began in 1991 and is in its fifth year of operation. The aim of the programme of work is to ensure adequate control
over the accuracy of analysis, such that the aims of the UK National Marine Monitoring Plan are satisfied. The results of
interlaboratory tests for the determination of nutrients in water samples and metals, organic compounds in waters, sediments
and biological samples are summarised.
Received: 7 October 1996 Accepted: 27 February 1997 相似文献
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Recknagel Sebastian Koch Matthias Wise Stephen A. Panne Ulrich 《Accreditation and quality assurance》2019,24(3):249-250
Accreditation and Quality Assurance - 相似文献
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