Demixing in Isotropic Binary Mixtures of Rodlike Macromolecules

A binary mixture of long rigid rods of diameters D _i and lengths L _i (i=1, 2) may demix into two isotropic phases, and we give necessary conditions on the molecular size parameters for this transition to exist. These conditions imply that the two diameters must be sufficiently unequal, D ₂/D ₁>( + )², or D ₂/D ₁<( + )², while the length ratio is limited to an interval f _–(D ₂/D ₁)<L ₂/L ₁<f ₊(D ₂/D ₁). The functions f _± are given explicitly.     

Theory of surface spin-exchange recombination of spin-polarized hydrogen

Calculations of the two-atom surface recombination rate for spinpolarized atomic hydrogen are carried out. Both the plane-wave Born approximation (PWBA) and the -dimensional distorted-wave model are employed. The field dependence forB=4 to 10 Tesla, and the temperature dependence for 0.2<T<1 K are examined for systems initially consisting of equal numbers ofa- andb-state atoms. The rates are analyzed with respect to para- and ortho-H₂ production, and to recombination to various vibrational and rotational states of H₂. The PWBA gives reasonable agreement with experiment with respect to the field-dependence and ortho-para production, but predicts an overall rate a factor of 40 above experiment. The -dimensional model underestimates the rate by a factor of 10³ and yields poorer agreement with experiment than the PWBA for the field-dependence and ortho-para production ratio. These results point out the need for a proper many-body treatment.     

Uniqueness of Gibbs State for Non-Ideal Gas in ℝd: The Case of Multibody Interaction

We study the question of existence and uniqueness of non-ideal gas in ^d with multi-body interactions among its particles. For each k-tuple of the gas particles, 2km ₀<, their interaction is represented by a potential function _k of a finite range. We introduce a stabilizing potential function , such that (x ₁,..., ) grows sufficiently fast, when diam{x ₁,..., } shrinks to 0. Our results hold under the assumption that at least one of the potential functions is stabilizing, which causes a sufficiently strong repulsive force. We prove that (i) for any temperature there exists at least one Gibbs field, and (ii) there exists exactly one Gibbs field at sufficiently high temperature, such that for any >0, C(V ₀)< for all volumes V smaller than a certain fixed finite volume V ₀. The proofs use the criterion of the uniqueness of Gibbs field in non-compact case developed in ref. 4, and the technique employed in ref. 1 for studying a gas with pair interaction.     

Local Primitive Causality and the Common Cause Principle in Quantum Field Theory

If (V) is a net of local von Neumann algebras satisfying standard axioms of algebraic relativistic quantum field theory and V ₁ and V ₂ are spacelike separated spacetime regions, then the system ( (V ₁ ), (V ₂ ), ) is said to satisfy the Weak Reichenbach's Common Cause Principle iff for every pair of projections A (V ₁ ), B (V ₂ ) correlated in the normal state there exists a projection C belonging to a von Neumann algebra associated with a spacetime region V contained in the union of the backward light cones of V ₁ and V ₂ and disjoint from both V ₁ and V ₂ , a projection having the properties of a Reichenbachian common cause of the correlation between A and B. It is shown that if the net has the local primitive causality property then every local system ( (V ₁ ), (V ₂ ), ) with a locally normal and locally faithful state and suitable bounded V ₁ and V ₂ satisfies the Weak Reichenbach's Common Cause Principle.     

Superconformal current algebras and their unitary representations

A natural supersymmetric extension is defined of the current (= affine Kac-Moody Lie) algebra ; it corresponds to a superconformal and chiral invariant 2-dimensional quantum field theory (QFT), and hence appears as an ingredient in superstring models. All unitary irreducible positive energy representations of are constructed. They extend to unitary representations of the semidirect sumS (G) of with the superconformal algebra of Neveu-Schwarz, for , or of Ramond, for =0.On leave of absence from the Institute for Nuclear Research and Nuclear Energy of the Bulgarian Academy of Sciences, BG-1184 Sofia, Bulgaria     

Algebras of observables with continuous representations of symmetry groups

Concrete C*-algebras, interpreted physically as algebras of observables, are defined for quantum mechanics and local quantum field theory.Aquantum mechanical system is characterized formally by a continuous unitary representation up to a factorU _g of a symmetry group in Hilbert space and a von Neumann algebra on invariant with respect toU _g . The set of all operatorsX such thatU _g X U _g ^–1 , as a function ofg , is continuous with respect to the uniform operator topology, is aC*-algebra called thealgebra of observables. The algebra is shown to be the weak (or strong) closure of .Infield theory, a unitary representation up to a factorU(a, ) of the proper inhomogeneous Lorentz group and local von Neumann algebras _C for finite open space-time regionsC are assumed, with the usual transformation properties of underU(a, ). The collection of allX_C giving uniformly continuous functionsU (a, )X U ^–1 (a, ) on is then a localC*-algebra , called thealgebra of local observables. The algebra is again weakly (or strongly) dense in _c . The norm-closed union of the for allC is calledalgebra of quasilocal observables (or quasilocal algebra).In either case, the group is represented by automorphisms V _g resp. V(a, ) — with V _g X=U _g X U _g ^–1 — of theC*-algebra , and this is astrongly continuous representation of on the Banach space . Conditions for V (a, ) can then be formulated which correspond to the usualspectrum condition forU (a, ) in field theory.Work supported in part by the Deutsche Forschungsgemeinschaft.     

On the parametrisation of unitary matrices by the moduli of their elements

The parametrisation of ann×n unitary matrix by the moduli of its elements is not a well posed problem, i.e. there are continuous and discrete ambiguities which naturally appear. We show that the continuous ambiguity is (n–1)(n–3)-dimensional in the general case and in the symmetric caseS _ij=S_ij. We give also lower bounds on the number of discrete ambiguities, the number of solutions being at least in the first case and for the symmetric one, where [r] denotes the integral part ofr.     

B c and $$b\bar bc\bar c$$ at theZ 0-boson pole

The cross-section for the production of quarks ine ⁺ e ^– annihilation, that proves to be at a level of for is calculated within the frames of the QCD perturbation theory. The cross sections for the associated production of 1S-and 2S-wave states ofB _c-meson in the reaction were calculated in the nonrelativistic model of a heavy quarkonium. The number of _bc -hyperons to be expected at LEP is estimated on the basis of the assumption on quark-hadron duality.     

Four-quark states and nucleon-antinucleon annihilation within the quark model with QCD vacuum-induced interaction

The spectrum of , J^p=0⁺, 2⁺ mesons is discussed. We have shown that due to instanton-induced forces the physical states are strong mixtures of theSU _f (3) group basis states. The cross-sections for annihilation of the system into mesons are obtained. Thea ₀(980) meson is considered as meson consisting of 9 _f and 36 _f plets. The branchings are also predicted for the cross-sections for production of thea ₀(980) and tensor mesons in annihilation.     

Control on arrangement of AgI clusters incorporated into zeolite LTA

AgI clusters were incorporated into Li, Na, and K-form LTA zeolites with a loading number of four AgI molecules per -cage. The X-ray powder diffraction (XRD) patterns and optical absorption spectra of the samples were obtained. The XRD patterns indicate that the sizes of the clusters and their arrangements depend on the type of alkali-cations. AgI clusters with different sizes, i.e., (AgI)_n and (AgI)_8–n (5n7), are arrayed alternatively in Na-form LTA conforming to the space group of P2₁3. AgI-loaded Li-form LTA also conformed to the space group of P2₁3, although (AgI)_n clusters seem to be distributed disorderly. On the contrary, (AgI)₄ cluster is in each cage in K-form LTA conforming to the space group of or . The optical spectra showed that Li and Na-form LTAs include (AgI)_n (5 n), and that K-form LTA includes (AgI)₄ cluster in each cage.     

Coordinates of the quantum plane as q-tensor operators in (\mathfrak{s}\mathfrak{u}(2)*\mathfrak{s}\mathfrak{u}(2))

The relation between the set of transformations of the quantum plane and the quantum universal enveloping algebra U _q (u(2)) is investigated by constructing representations of the factor algebra U _q (u(2))* . The noncommuting coordinates of , on which U _q (2) * U _q (2) acts, are realized as q-spinors with respect to each U _q (u(2)) algebra. The representation matrices of U _q (2) are constructed as polynomials in these spinor components. This construction allows a derivation of the commutation relations of the noncommuting coordinates of directly from properties of U _q (u(2)). The generalization of these results to U _q (u(n)) and is also discussed.     

The reunions of three dissimilar vicious walkers

We study the behavior of three vicious random walkers which diffuse freely in one dimension witharbitrary diffusivitiesb ₁ ² ,b ₂ ² ,b ₃ ² , except that their paths may not cross. The full distribution function is calculated exactly in the continuum limit; the exponent ₃ governing the decay of the probability of a simultaneousreunion of all three walkers aftern steps is found to varycontinuously according to . This variation has consequences for various interfacial wetting transitions in (1+1) dimensions. It may also be related heuristically to the marginality of direct interface-wall interactions decaying asW ₀/l ² in the intermediate fluctuation regime of (1+1)-dimensional wetting, where exponents varying continuously withW ₀ have recently been found.     

Modified Kolmogorov wave turbulence in QCD matched onto “Bottom-up” thermalization

We investigate modification of Kolmogorov wave turbulence in QCD calculating gluon spectra as functions of time in the presence of a low energy source which feeds in energy density in the infrared region at a time-dependent rate. Then considering the picture of saturation constraints as has been constructed in the “bottom-up” thermalization approach we revisit that picture for RHIC center-mass energy, W=130 GeV, and also extend it to LHC center-mass energy, W=5500 GeV, thus for two cases having an opportunity to calculate the equilibration time, τ_eq|therm, of the gluon system produced in a central heavy ion collision at mid-rapidity region. Thereby, at RHIC and LHC energies we can match the equilibration time, obtained from the late stage gluon spectrum of the modified Kolmogorov wave turbulence, onto that of the “bottom-up” thermalization and other evolutional approaches as well. In addition, from the revised “bottom-up” approach we find the gluon liberation coefficient to be on the average, ε0.81–1.06 at RHIC and ε0.50–0.56 at LHC. We also present other phenomenological estimates of τ_therm which, at QCD realistic couplings, yield 0.45–0.65 fmτ_therm0.97–2.72 fm at RHIC and 0.31–0.40 fmτ_therm0.86–2.04 fm at LHC. We show that the second upper-bounds of τ_therm in both cases are due to the late stage gluon spectrum of the original Kolmogorov wave turbulence in QCD, previously deduced with a low energy source which feeds in energy density at a constant rate. On the other hand, the lower-bounds and first upper-bounds of τ_therm are due to the late stage gluon spectrum of the modified QCD wave turbulence, deduced here at the specific time-dependent rate. In the latter case, at certain conditions, taking also into account both very small and realistic couplings we give estimates: 0.65 fmτ_therm1.29 fm at RHIC and 0.52 fmτ_therm1.16 fm at LHC, as well as at realistic couplings we find 0.53<τ_therm<0.7 fm at RHIC and 0.41<τ_therm<0.65 fm at LHC.     

SU q (2) covariant\hat R-matrices for reducible representations

We consider SU _q (2) covariant -matrices for the reducible3 1 representation. There are three solutions to the Yang-Baxter equation. They coincide with the previously known -matrices for SO _q (3) and SO _q (3, 1). Also, they are the three -matrices which can be constructed by using four different SU _q (2) doublets. Only two of the three -matrices allow a differential structure on the reducible four-dimensional quantum space.     

Commutator Representations of Covariant Differential Calculi on Quantum Groups

Let (, d) be a first-order differential *-calculus on a *-algebra . We say that a pair (, F) of a *-representation of on a dense domain of a Hilbert space and a symmetric operator F on gives a commutator representation of if there exists a linear mapping : L( ) such that (adb) = (a)i[F, (b) ], a, b . Among others, it is shown that each left-covariant *-calculus of a compact quantum group Hopf *-algebra has a faithful commutator representation. For a class of bicovariant *-calculi on , there is a commutator representation such that F is the image of a central element of the quantum tangent space. If is the Hopf *-algebra of the compact form of one of the quantum groups SL _q (n+1), O _q (n), Sp _q (2n) with real trancendental q, then this commutator representation is faithful.     

Limiting behavior of asymptotically flat gravitational fields

Couch and Torrence suggest that the vacuum Einstein equations admit a larger class of asymptotically flat solutions than those exhibiting the peeling property. Starting with the assumption that , (d/dr) and (/x ^A ) , wherex ^A (A = 2, 3) are angular coordinates, they show that , where ₁ 2 and ₁<₀; , where ₂ 1 and ₁< ₁; and ₄ and ₃ peel as they would under the stronger peeling conditions. The Winicour-Tamburino energy-momentun and angular momentum integrals for these solutions, in general, diverge. In fact, since Couch and Torrence determine only the radial dependence of the solution, it is not clear that the solutions are well defined. We find that the stronger assumption , (d/dr) , and (/x ^A ) does result in well-defined solutions for which both the energy-momentum and angular momentum intergrals are not only finite but result in the same expressions as are obtained for peeling space-times. This assumption appears to be the minimal assumption that is necessary for investigating outgoing radiation at null infinity.In part based on a dissertation by Stephanie Novak and submitted to Syracuse University in partial fulfillment of the requirement for the Ph.D. degree.     

The electrical performance of thinn +-window layers ina-Si: H solar cells

The electrical properties ofn ⁺-window layers inp-i-n a-Si:H solar cells were characterised as a function ofn ⁺-layer thickness, , by measuring firstly the activation energyE _a of the dark conductivity and secondly the built-in potentialV _bi of the cells.E _a was found to increase with decreasing attaining values as high as 0.8 eV for 5nm; bulk values, e.g.E _a . 2eV in the amorphous andE _a<0.01 eV in the microcrystalline case, were only observed for >20nm and for >200nm, respectively. In contrast,V _bi did not depend on at all and was further found to be consistent with expectations based on the Fermi level positions in bulkn ⁺ andp ⁺-material. As a consequenceE _a in very thin films can no longer be considered as a measure of (E _C –E _F), the distance of the Fermi level from the conduction band edge. The apparent inconsistency inherent to theE _a and theV _bi results can be resolved by assuming that the deposition of then ⁺-material proceeds via the growth and coalescence of small islands.     

Zero magnetic field splitting and anomalies of intensities in the Zeeman spectra of La(Pr)Cl3-crystals

Optical absorption and Zeeman effect measurements on La(Pr)Cl₃ show a zero magnetic field splitting of the degenerate Pr³⁺ levels and . The site symmetry of the Pr³⁺ ions is lowered fromC _3h toC _s . The resultant splittings of the doublet levels are:I ³ H ₄:2|T _ak |=(0.12±0.05)cm^–1;a ³ P ₁:2|T _al |=(0.10±0.05)cm^–1.The intensities of the optical transitions induced by the deformation decrease with increasing magnetic field. All observations are described by a first order perturbation calculation using a low symmetric part of the crystal field and Zeeman energy as simultaneous perturbations on a Pr³⁺ ion in a crystal field with site symmetryC _3h .Project of the Sonderforschungsbereich Festkörperspektroskopie SFB65, Darmstadt—Frankfurt, supported by the Deutsche Forschungsgemeinschaft.     

Bound States in a Locally Deformed Waveguide: The Critical Case

We consider the Dirichlet Laplacian for astrip in with one straight boundary and a width , where $f$ is a smooth function of acompact support with a length 2b. We show that in the criticalcase, , the operator has nobound statesfor small .On the otherhand, a weakly bound state existsprovided . In thatcase, there are positive c ₁,c ₂ suchthat the corresponding eigenvalue satisfies for all sufficiently small.     

Global conformal invariance in quantum field theory

Suppose that there is given a Wightman quantum field theory (QFT) whose Euclidean Green functions are invariant under the Euclidean conformal groupSO _e (5,1). We show that its Hilbert space of physical states carries then a unitary representation of the universal (-sheeted) covering group* of the Minkowskian conformal group SO _e (4, 2)₂. The Wightman functions can be analytically continued to a domain of holomorphy which has as a real boundary an -sheeted covering of Minkowski-spaceM ⁴. It is known that* can act on this space and that admits a globally*-invariant causal ordering; is thus the natural space on which a globally*-invariant local QFT could live. We discuss some of the properties of such a theory, in particular the spectrum of the conformal HamiltonianH=1/2(P ⁰+K ⁰).As a tool we use a generalized Hille-Yosida theorem for Lie semigroups. Such a theorem is stated and proven in Appendix C. It enables us to analytically continue contractive representations of a certain maximal subsemigroup of to unitary representations of*.