共查询到19条相似文献,搜索用时 93 毫秒
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本以范德瓦尔斯气体为例,证明了在Cv为常数的条件下多方过程几种定义说法的等效性,并给出了范氏气体多方过程的功容定义,最后指出功容为常量才是多方过程最基本的特征。 相似文献
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本文把理想的可逆卡诺机热效率公式和致冷系数公式的形式推广应用到一类非卡诺机,为计算理想气体含有两绝热过程与多方过程组成的可塑机效率提供了一种简单计算方法。 相似文献
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多方过程几种定义说法等效性的证明 总被引:1,自引:0,他引:1
多方过程,又名多变过程,在热力工程中有重要的实用价值.在普通物理热学教材中对于多方过程的讲解,一般是不加推导直接利用理想气体的绝热过程得出多方过程方程,有关多方过程的定义说 相似文献
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我们把pV^m=常数(n为一常数)叫做多方过程,n为多方指数;而当n不是常数时为非多方过程,n不是多方指数.近年在一些文献中,误认为热容量C为常数是多方过程的基本特征,本文就此问题作些探讨,以期有助于对这个基本问题的进一步认识,从而也对热容量的计算作一些有益的分析. 相似文献
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《Journal of computational physics》2002,175(1):50-78
An extension of the Roe linearization method to nonideal gases is described and applied to the particular case of the van der Waals gas. A supplementary relation connecting the thermodynamic variables is introduced to decouple the evaluation of the intermediate velocity and total specific enthalpy from the determination of the intermediate density, needed in the Jacobian matrix of the linearization due to the general thermodynamic character of the gas. The density value is obtained by solving the supplementary equation, which involves the Roe average of velocity and enthalpy, and that in the case of the polytropic van der Waals gas is a third-order algebraic equation. Numerical results are shown including classical and nonclassical behaviour in one-dimensional shock tube problems. 相似文献
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范德瓦耳斯方程能够较好地描述实际气体的热力学过程,方程中的参数b是因实际气体分子的体积而引入的修正量.本文通过考察分子之间的相互碰撞事件,计算得到了范德瓦耳斯气体体积的修正值,约等于1 mol气体所有分子体积总和的4倍,结果与其他方法得到的结果一致.这是一种新的计算思路和方法. 相似文献
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Derivations of the van der Waals equation typically use standard recipes involving ensemble averages of statistical mechanics. In this work, we study a box of weakly interacting gas particles in one-dimension by explicitly incorporating the mechanical point of view. This has the merit that it not only reproduces the van der Waals equation but also tells us some extra interesting physics not immediately clear from a pure statistical mechanical approach. For example, we show that the traditional handwaving argument leading to van der Waals equation requires closer scrutiny if it is to get things right. 相似文献
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范德瓦耳斯气液状态方程纵横谈 总被引:5,自引:1,他引:4
首先强调了范氏方程是气液系统的状态方程,范氏方程可以很好地说明物质气态和液态的相互转变.分析了焦-汤效应,简述了气体的液化与低温的获得. 相似文献
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A. A. Dubinova 《Technical Physics》2009,54(2):210-213
The exact explicit barometric formula is derived for a warm isothermal Fermi gas in a uniform potential field. 相似文献
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本文提出了一种核梯度改进光滑粒子动力学(KGC-SPH)方法,模拟了黏性液滴形变自由表面问题.首先,通过模拟等温黏性液滴拉伸和旋转变形,验证了KGC-SPH法较SPH法具有较高精度和更好稳定性,且能很好地保持总角动量守恒.其次,基于非等温van der Waals模型对平衡态圆形液滴的形成过程进行数值研究,观察到小幅度振荡现象,并给出了一种新的克服张力不稳定性的方法和一种适合KGC-SPH方法的新的表面张力处理技术.最后,研究了van der Waals液滴的周期性振荡现象,讨论了初始椭圆形液滴长短半轴比
关键词:
光滑粒子动力学
黏性液滴
van der Waals模型
表面张力 相似文献
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MacIntyre F 《Ultrasonics sonochemistry》1997,4(2):85-93
The path of the gas in a sonoluminescent bubble must enclose an area in a P-V plot if the gas itself emits photons. Thermodynamic analysis thus delineates the playing field that may enable us to distinguish liquid-phase emissions from gas-phase emissions. The apparent importance of the van der Waals a (which parameterizes mean-square induced dipole attractions) in light intensity supports collision-induced emission as a likely mechanism. The suggested emitting object, containing 10(10) molecules in picosecond-long van der Waals contact, is novel, being neither plasma, gas, liquid nor blackbody. The bubble pursues a unique thermodynamic path. 相似文献
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Works, mostly experimental, concerning the most interesting features of application of the resonant tunneling spectroscopy to a new type of heterosystems, van der Waals heterostructures, have been briefly reviewed. These heterostructures appeared after the recent discovery of two-dimensional crystals, which are a new class of materials beginning with graphene. The role of the angular matching of crystal lattices of conducting graphene electrodes of van der Waals systems in carrier tunneling between them has been analyzed together with the closely related problems of satisfaction of conservation laws in tunneling transitions. Manifestations of multiparticle correlation interactions between carriers in van der Waals systems such as Wigner crystallization of electrons in a two-dimensional electron gas in a magnetic field and Bose condensation of excitons in parallel two-dimensional electron gases have been briefly discussed. 相似文献