THE ANALYTICAL SOLUTION FOR SEDIMENT REACTION AND DIFFUSION EQUATION WITH GENERALIZED INITIAL-BOUNDARY CONDITIONS

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Effective Diffusion Coefficient: From Homogenization to Experiment

In this paper, an example of the application of the homogenization approach (asymptotic expansion technique) to predict the effective diffusion coefficient for an equivalent continuum, together with the experimental verification of the theoretical results is presented. The experimental setup was constructed for the measurements of diffusion in a model periodic porous medium made of Plexiglas. The computer program using the FEM was elaborated to solve the local boundary value problem for a period and to calculate the effective diffusion coefficient. The comparison between the theory and the experiment indicates good agreement between the numerical and experimental values of the effective diffusion coefficient. Interpretation of the test data from the point of view of the homogenization theory is also incorporated.     

Analytical Solutions for Partitioned Diffusion in Laminates: I. Initial Value Problem with Steady Cauchy Conditions

Studies of the transport of contaminants and nutrients in industrial and environmental systems are complicated by the heterogeneous nature of the supporting porous or permeable media, and by the numerical problems associated with high Peclet number advection and sharp interface models. In order to provide independent theoretical checks of numerical transport theories, this set of papers presents analytical solutions to diffusive transport equations in simplified (one-dimensional) laminate systems subject to partitioning interactions. Here, in Part I, a standard separation of variables technique is used to develop analytical eigenfunction expansions of the concentration solution in an N-laminate system subject to steady Cauchy (third-type) nonhomogeneous boundary conditions. Both Cartesian and radial (axisymmetric) coordinate systems are considered. The solutions are developed for two different interface partitioning formulations, allowing the partitioning processes to be described by instantaneous equilibration mechanisms, or in terms of gradual equilibration mediated by mass transfer coefficients. Worked examples are presented and limitations of the approach discussed.     

Moving Boundary Problem for Diffusion Release of Drug from a Cylinder Polymeric Matrix

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Coupled Water and Salt Transport in Porous Materials: Rapid Determination of a Varying Diffusion Coefficient from Experimental Data

A direct method for an accurate and rapid evaluation of a varying salt diffusion coefficient, \(D\) , from experimental data is proposed for a coupled water and salt transport in porous materials. The evaluation uses data on the moisture and salt concentration profiles and is based on a formula obtained from the Boltzmann-Matano method. The coupled transport is described by the diffusion-advection model of Bear and Bachmat. A simple expression for \(D\) in the center of the concentration interval is deduced from the formula to provide a rapid estimate on \(D\) . Possible extensions of this analytical approach are pointed out, suggesting that it can serve as a convenient general tool in engineering calculations. The theoretical results are applied to a laboratory experiment in which a coupled moisture and chloride transport had been investigated in a lime plaster, and the chloride diffusion coefficient had been obtained numerically in dependence on the chloride concentration. The agreement with the numerical results is shown to be rather good, except at low concentrations where our analytical results should be more reliable. It is also shown that the unusually high value of the calculated chloride diffusion coefficient—about three orders of magnitude higher than for free chloride ions in water—cannot be explained by possible inaccuracies in the measurements and/or numerical calculations. The reason is that changes in the measured profiles’ data could cause a change in \(D\) of just the same order of magnitude. This shows that, besides diffusion and advection, additional mechanisms take part in the considered chloride transport.     

Diffusion of macromolecular solutions in the turbulent boundary layer of a cylindrical pipe

A model is presented describing the changes that occur in the diffusion boundary layer upon injection of a macromolecular solution (PEO) into a cylindrical pipe under turbulent flow conditions (Re 40,000). A shape parameter was introduced to describe the shape of the turbulent plume. The value of this parameter was found to be the same for water and various dilute PEO solutions. The proposed model gives a good approximation at low homogeneous concentrations. x downstream distance from the slot - y normal distance from the wall - R radius of the pipe - C concentration - C _w wall concentration - Q _i flow rate injection - Q _t flow rate - C _j =C _i *Q _i /Q _t equivalent homogeneous polymer concentration - L _tf characteristic length of the diffusion plume - characteristic height of the diffusion plume, i.e. the value ofy at whichC/C _w = 0.5 - thickness of the diffusion boundary layer - x ₀ characteristic distance from the slot, i.e. the value ofx at which/R = 1/2 - ⁺ shape parameter of the diffusion boundary layer - ⁺ —/R nondimensionalized variables - x ⁺ —x/L _tf nondimensionalized variables     

An Analytical Solution for Contaminant Transport in nonuniform Flow

We obtain an analytical solution for two-dimensional steady state mass transport in a trapezoidal embankment in a spatially varying velocity field through its replacement with a hydrologically equivalent rectangular embankment. Application of the Dupuit approximation and conform transformation allow for computation of the concentration field in the resulting rectangle in the complex potential plane. The latter allows deriving expression for the mass flow rate of contaminants, which is analogous to the Dupuit--Forchheimer discharge formula for volumetric water flow rate. Numerical simulation of advection- dispersion in the actual domain compares favorably with these analytical results, and provides limits of the ratio between transverse and longitudinal dispersivities within which the Dupuit approximation is applicable to mass transport problems.     

Analytical solutions of thermal stress distribution in plastic encapsulated integrated circuit packages

IntroductionElectronicpackagesarecomplexcompositestructure.Theyhavemyriadcornersandinterfacesthatcanactaspotentialfailuresitesduringfieldoperation .Atpresenttime ,plasticencapsulatedintegratedcircuits (ICs)arewidelyusedinengineering .AplasticencapsulatedICpackageconsistsofasilicondie,dieattachment,passivation ,wireinterconnects,aleadframe ,andplasticmoldingcompound .Thermalexcursionduringpackagequalificationfromthermalcycling thermalshock ,orpowercyclingduringnormaloperationcansetupthermomec…     

Analytical solution of basic equations set of atmospheric motion

On condition that the basic equations set of atmospheric motion possesses the best stability in the smooth function classes, the structure of solution space for local analytical solution is discussed, by which the third-class initial value problem with typicality and application is analyzed. The calculational method and concrete expressions of analytical solution about the well-posed initial value problem of the third kind are given in the analytic function classes. Near an appointed point, the relevant theoretical and computational problems about analytical solution of initial value problem are solved completely in the meaning of local solution. Moreover, for other type of problems for determining solution, the computational method and process of their stable analytical solution can be obtained in a similar way given in this paper.     

Analytical Solutions for Partitioned Diffusion in Laminates: II. Harmonic Forcing Conditions

The migration of organic compounds in stratified media is of fundamental concern in environmental and chemical engineering research. The diffusive transport of volatile organic compounds through laminate systems is characterized by partitioning, i.e., the development of concentration discontinuities at the interfaces between the individual laminae. If the transport is governed by cyclic transients, the relevant equations can be written in terms of coupled systems of diffusion equations subject to sinusoidal boundary conditions. This paper solves these systems of equations to present new algebraic solutions for propagation of the sinusoidal modes through arbitrary (finite) numbers of contiguous one-dimensional laminae. Both Cartesian and radial coordinate systems are considered. Two independent formulations of the lamina interface matching conditions are considered, corresponding to (1) an instantaneous partitioning model and to (2) a mass-limited partitioning model. It is shown that sinusoidal components of the concentration solutions propagate dispersively throughout the laminates. This is manifested, for example, in changes in shape of concentration pulses as measured at different points in the laminate system. Algorithms for generating exact dispersion relations for partitioning laminates are given, and an experimental technique for studying interfacial dynamics via frequency domain measurements is proposed.     

Analytical Solution for the Effect of Viscous Dissipation on Mixed Convection in Saturated Porous Media

A new analytical solution is introduced for the effect of viscous dissipation on mixed convection flow and heat transfer about an isothermal vertical wall embedded in Darcy and non-Darcy porous media with uniform free stream velocity. The effect of viscous dissipation on mixed convection in both regimes has been analyzed for both the aiding and opposing flows using Gebhart number, Ge _x =gx/c _p. The governing parameters are Re, Ra, Pe and Ge _x . The case of Re=0 corresponds to Darcy mixed convection region and Re/Pe is identified as the mixed convection governing parameter, Ra=0 leading to pure forced convection. A good agreement was found between the numerical and analytical solutions. It was found from the Nusselt number results that viscous dissipation lowers the heat transfer rate in both Darcy and Forchheimer flow regimes for aiding as well as opposing flows.     

Analytical solutions of the boundary-value problem of nonstationary flow of viscoplastic medium between two plates

Summary Nonstationary flow of a viscoplastic medium between two parallel plates is considered for the case of a varying pressure gradient. The problem is reduced to the Stephan problem, with the condition on the boundary separating the flow domain from the quasi-rigid domain. Four multiparameter families of exact solutions are found. The first family describes the flow decelerations up to a full stop. The second family determines the development of the flow from the state of rest as the pressure gradient increases. The third family describes the development of the flow for the case where (1) the pressure gradient is constant and exceeds the threshold value related to the yield stress, (2) the upper plate does not move, and (3) the lower plate moves with a constant acceleration. Finally, the fourth family determines the flow retardation, when the pressure gradient is constant and is less than the threshold value. The decrease in the flow of the viscoplastic medium can be achieved for certain values of parameters by increasing the quasi-rigid domain, whereas the viscoplastic flow remains unchanged. Received 7 October 1998; accepted for publication 8 April 1999     

Analytical Solutions for Solute Transport in a Spherically Symmetric Divergent Flow Field

Exact analytical solutions for an equation describing advection, dispersion, first-order decay, and rate-limited sorption of a solute in a steady, hemispherical or spherically symmetric, divergent flow field are presented for constant concentration and constant flux boundary conditions in a porous medium. The partial differential equation describing transport is a confluent hypergeometric equation that may be solved with variable substitution and Laplace transform, and the solutions are expressed by parabolic cylindrical functions. The novel solutions derived here may be applied to predict concentration distributions in space and time for porous media transport in a spherically symmetric flow field or for the special case where injection is just below a confining layer (hemispherical flow). The analytical solutions can be used to simulate wastewater injection from short-screened wells into thick formations or to analyze tracer tests that use short-screened wells to create approximately spherical flow fields in thick formations.     

Application of a n-Phase Model to the Diffusion Coefficient of Chloride in Mortar

The determination of the chloride diffusion coefficient of a concrete is needed to help the prediction of the service life of concrete structure. In this paper, we propose first a critical review of models for chloride diffusion coefficients already used in literature at different scales and then we develop an analytical model, which takes into account the characteristics of the different phases of concrete. These materials are treated as a three-phase composite, consisting of a cement continuous phase, of an aggregates dispersed phase and of an interface transition zone. Chloride diffusion coefficient using an n-layered inclusion-based micromechanical modeling is predicted. The details of calculations are summarized hereafter and experimental measurements obtained on mortars are compared with predicted results.     

Analytical solution of magnetohydrodynamic sink flow

An analytical solution to the famous Falkner-Skan equation for the magnetohydrodynamic (MHD) flow is obtained for a special case, namely, the sink flow with a velocity power index of −1. The solution is given in a closed form. Multiple solution branches are obtained. The effects of the magnetic parameter and the wall stretching parameter are analyzed. Interesting velocity profiles are observed with reversal flow regions even for a stationary wall. These solutions provide a rare case of the Falkner-Skan MHD flow with an analytical closed form formula. They greatly enrich the analytical solution for the celebrated Falkner-Skan equation and provide better understanding of this equation.     

On Vertical Diffusion of Gases in a Horizontal Reservoir

Exact and approximate solutions to vertical diffusion in gravity-stable, ideal gas mixtures in gas reservoirs, depleted oil reservoirs, or drained aquifers are presented, and characteristic times of diffusion are obtained. Our solutions also can be used to test numerical simulators that model diffusion after gas injection. First, we consider isothermal, countercurrent vertical diffusion of carbon dioxide and methane in a horizontally homogeneous reservoir. Initially, the bottom part of the reservoir, with no flow boundaries at the top and bottom, is filled with CO₂ and the upper part with CH₄. At time equal zero, the two gases begin to diffuse. We obtain the exact solution to the initial and boundary-value problem using Fourier series method. For the same problem, we also obtain an approximate solution using the integrated mass balance method. The latter solution has a particularly simple structure, provides a good approximation and retains the important features of the exact solution. Its simplicity allows one to perform calculations that are difficult and non-transparent with the Fourier series method. It also can be used to test numerical algorithms. Furthermore, we consider diffusion of CO₂ with partitioning into connate water. We show that at reservoir pressures the CO₂ retardation by water cannot be neglected. The diffusion-retardation problem is modelled by a non-linear diffusion equation whose self-similar solution is obtained. Finally, we obtain a self-similar solution to a nonlinear diffusion problem. This solution is a good approximation at early times, before the diffusing gases reach considerable concentrations at the top and bottom boundaries of the reservoir.     

Analytical solution of magnetohydrodynamic sink flow

An analytical solution to the famous Falkner-Skan equation for the magnetohydrodynamic (MHD) flow is obtained for a special case, namely, the sink flow with a velocity power index of -1. The solution is given in a closed form. Multiple solution branches are obtained. The effects of the magnetic parameter and the wall stretching parameter are analyzed. Interesting velocity profiles are observed with reversal flow regions even for a stationary wall. These solutions provide a rare case of the Falkner-Skan MHD ...     

Analytical solutions of singularities moving with an arbitrary path when two fluids are present

The derivations are carried out for the velocity potentials of singularities moving withan arbitrary path either in the upper fluid or in the lower fluid with or without a horizontalbottom when two fluids are present.In such a case,the pressure distribution is no longerequal to a constant or zero at the free interface.Taking the influence of an upper fluid uponthe lower fluid into consideration,a series of fundamental solutions in closed forms arepresented in this paper.     

Analytical solution of bending-compression column using different tension-compression modulus

Based on elastic theory of different tension-compression modulus, the analyttcal solution was deduced for bending-compression column subject to combined loadings by the flowing coordinate systemaxis, stress, strain andand phased integration methoddisplacement were developed,The formulations for the neutralthe finite element program was compiled for calculation, and the comparison between the result of finite element and analytical solution were given too. Finally, compare and analyze the result of different modulus and the same modulus, obtain the difference of two theories in result, and propose the reasonable suggestion for the calculation of this structure.