共查询到20条相似文献,搜索用时 31 毫秒
1.
Edgar Nagles Johisner Penagos-Llanos Olimpo García-Beltrán John Hurtado 《Journal of Analytical Chemistry》2018,73(5):504-511
A new sensor was developed using a screen-printed carbon electrode modified with single-walled carbon nanotubes (SWCNTs) and Prussian blue (PB) coated with chitosan. The modified electrode allowed the oxidation and reduction of rutin at 0.25 and 0.096 V, respectively, with a ΔE of 0.154 V. Furthermore, the peak currents increase nearly 100% compared with the electrode without modification. The process was more reversible compared with the electrode modified with only SWCNTs or PB. Cyclic voltammetry was used to characterize the modified electrode surface. The quantification of rutin was more sensitive with adsorptive stripping voltammetry than with anodic stripping voltammetry. Adsorption potential, adsorption time and pH were optimized based on the oxidation of rutin: Eads =–0.10 V, tads = 60 s, pH 3.0. The detection limit (3σ/b) was 0.01 μM and the relative standard derivation was 3%. The new sensor was used in the quantification of rutin in black tea, coffee and synthetic drink of tea with satisfactory results. 相似文献
2.
Daniele Gioia Alessandro Laurita Gerardo Di Bello Innocenzo G. Casella 《Journal of Solid State Electrochemistry》2016,20(12):3383-3391
A study regarding the electrodeposition of nickel oxide particles on the activated multi-walled carbon nanotubes from 2 M NaOH solution containing Ni(NO3)2 and EDTA was carried out. The electrodeposition process was carried out using an optimized double-pulse sequence of potentials: E 1 = ?0.2 V vs. SCE (t 1 = 0.3 s) and E 2 = 0.7 V vs. SCE (t 2 = 0.03 s). Spectroscopic XPS investigations and SEM analysis were used in order to characterize the surface and morphology of the studied modified electrode. Cyclic voltammetry and chronoamperometry were used in order to evaluate the electrochemical/amperometric performance of the GC/MWCNT-Ni electrode toward the oxidation of some aliphatic alcohols in strong alkaline medium. 相似文献
3.
Ya-Ping Li Hai-Bo Liu Tao Liu Zhang-Yu Yu 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2017,91(11):2176-2179
The standard redox electrode potential (E°) values of metallocene compounds are obtained theoretically with density functional theory (DFT) method at B3LYP/6-311++G(d,p) level and experimentally with cyclic voltammetry (CV). The theoretical E° values of metallocene compounds are in good agreement with experimental ones. We investigate the substituent effects on the redox properties of metallocene compounds. Among the four metallocene compounds, the E° values is largest for titanocene dichloride and smallest for ferrocene. 相似文献
4.
The reversibility of a two-electron pyrocatechol/o-benzoquinone system (ΔE p = 28 ± 1 mV) is found by cyclic voltammetry at a mechanically renewed electrode from a graphite-epoxy composite. The closeness of the found and theoretical values of ΔE p indicates the high electrochemical activity of the graphite-epoxy composite electrode renewed in situ by cutting a thin surface layer. The potentials of pyrocatechol anodic and cathodic peaks are proportional to E 0 ± 0.059pH in the pH range of 1–9. The pyrocatechol anodic and cathodic peak currents remain linear functions of pyrocatechol concentration in the concentration range from 0.01 to 0.08 and from 0.08 to 0.9 g/L, respectively. A procedure for the voltammetric determination of pyrocatechol in its individual solutions and in the presence of hydroquinone is proposed. Good precision and the absence of a systematic error in the determination of pyrocatechol by measuring its cathodic peak are demonstrated. 相似文献
5.
The influence of solvent (DMF, MeCN, and water) and R1, R2 substituent nature on the formal oxidation potential (E°´) of 4-R1,R2-2,2,6,6-tetramethylpiperidine 1-oxyls (1a—f) on a glass carbon electrode was studied by cyclic voltammetry. It was shown that for all the solvents the observed dependence had the form E°´ = ρ″σ″ + b, where σ″ is the substituent constant. The b values decreased with an increase of the solvent solvating ability, while the values ρ″ are similar for all the solvents, surpassing the corresponding values for nitroxyls of the imidazoline series with substituents at position 3, which can be interpreted as an abnormally strong influence of the substituent remote from the reaction center in 1a—f. The experimental values E°´ were linearly correlated with the reaction free energy values (ΔG) calculated by DFT B3LYP and MP2 for the gas phase contribution and by HF/PCM for the contribution of solvation effects. When applying the B3LYP and the HF/PCM approaches in combination, the dependence of E°´ on ΔG for all the considered solvents was described by a linear correlation equation with a slope close to unity and a constant term which was close to the theoretical value of the absolute potential of the reference electrode used. 相似文献
6.
H. X. Ma N. N. Zhao B. Yan Y. L. Guan J. F. Li J. R. Song 《Journal of Structural Chemistry》2012,53(3):534-541
Bis-(3,3-dinitroazetidinyl)-oxamide ((DNAZ-CO)2) is an acyl derivative of 3,3-dinitroazetidine (DNAZ). It is prepared and its crystal structure is determined. The crystal is orthorhombic, Fdd2 space group, a = 13.136(14) Å, b = 19.48(3) Å, c = 10.326(14) Å, V = 2642 (6) Å3, Z = 8. A density functional theory (DFT) method of the Amsterdam Density Functional (ADF) package is used to calculate the geometry, frequencies, and properties. The optimized geometry, frontier orbital energy, and main atomic orbital percentage are obtained. The thermal behavior is studied under a non-isothermal condition by DSC and TG/DTG methods. The apparent activation energy (E a) and pre-exponential factor (A) of the exothermic decomposition reaction of (DNAZ-CO)2 are 164.10 kJmol?1 and 1013.38 s?1 respectively. The critical temperature of thermal explosion is 272.20°C. The values of ΔS ≠, ΔH ≠, and ΔG ≠ of this reaction are 6.44 Jmol?1·K?1, 163.76 kJmol?1 and 160.34 kJmol?1 respectively. 相似文献
7.
Masahiro Mikuriya Mayu Hamagawa Natsuki Tomioka Rika Fujimori Daisuke Yoshioka Shoichi Hori Taro Kuriyama Hiroshi Sakiyama Makoto Handa Ryoji Mitsuhashi 《Chemical Papers》2016,70(1):69-74
A nickel(II) complex, [Ni(taetacn)](ClO4)2 ? H2O, where taetacn = 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane was synthesized. The crystal structure was determined by the single-crystal X-ray diffraction method at 293 K. The complex crystallizes in the orthorhombic space group Pna21 with a = 16.004(2) Å, b = 10.186(1) Å, c = 13.937(2) Å, V = 2271.9(5) Å3, Dx = 1.56 g cm?3, Dm = 1.59 g cm?3 (floatation method), and Z = 4. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0636 and 0.1672, respectively, for all 4845 independent reflections. The compound is composed of octahedral nickel(II) cation with three 2-aminoethyl pendant groups of taetacn, tetrahedral ClO 4 ? anion, and a water molecule of crystallization. Electronic spectra are consistent with the octahedral geometry. Temperature dependence of the magnetic susceptibility (4.5–300 K) can be interpreted considering the zero-field splitting of the nickel(II) ion (g = 2.14, D = 3.72 cm?1, and Nα = 300 × 10?6 cm3 mol?1). Cyclic voltammetry in DMF showed quasi-reversible and irreversible oxidation waves (Epa = 0.54 V, Epc = 0.45 V; Epa = 1.16 V, Epc = 0.71 V vs. Ag/Ag+). 相似文献
8.
V. N. Kiryushov L. I. Skvortsova T. P. Aleksandrova 《Journal of Analytical Chemistry》2007,62(2):161-167
The potentials of the anodic peak of ascorbic acid oxidation and the potential differences of anodic and cathodic peaks (ΔE p) of the hydroquinone/benzoquinone redox system at an electrode made of a graphite-epoxy composite are determined in weakly acidic and neutral supporting electrolytes by direct and cyclic voltammetry. The results obtained are compared with thermodynamic values and with the available values of these parameters at different solid electrodes for the above-mentioned redox systems. The effect of aging of the surface of electrodes made of graphite-epoxy composites on the potentials and peak currents of the anodic oxidation of ascorbic acid are studied. It is demonstrated that the regeneration of the electrode surface by mechanically cutting thin layers is important for reducing the δE p value of the hydroquinone/benzoquinone redox system down to 28–30 mV in supporting electrolytes with pH 2.0 and 7.0. This value is typical of thermodynamically reversible electrode reactions involving two-electron transfer at 20–25°C. 相似文献
9.
L. I. Skvortsova V. N. Kiryushov T. P. Aleksandrova O. V. Karunina 《Journal of Analytical Chemistry》2008,63(3):258-264
Differences of potentials of anodic and cathodic peaks (ΔE p) are determined in cyclic voltammograms of dihydroxybenzene/p-benzoquinone redox systems at an electrode made of a graphite-epoxy composite in a wide pH range. The data obtained (ΔE p = 29 ± 1 mV) are close to the thermodynamic values for two-electron reversible reactions. This indicates that the electrode mechanically renewed by cutting a 0.5-μm surface layer directly in a test solution exhibits a high activity in such electrochemical reactions. The potentials of anodic and cathodic peaks are proportional to the pH of the supporting electrolyte solution in the range from 1.0 to 9.0. A change of 58 ± 1 mV in E p per unit pH for all isomers shows that the first stage of the oxidation of each dihydroxybenzene isomer involves one electron and is accompanied by the detachment of one hydrogen ion, that is, an intermediate oxidation product, semiquinone, is formed. Despite the closeness of the potentials of hydroquinone and pyrocatechol peaks (ΔE = 100 mV), a scheme is proposed for the selective voltammetric determination of dihydroxybenzene isomers in a 0.1 M HCl solution in hydroquinone-pyrocatechol, pyrocatechol-resorcinol, and hydroquinone-resorcinol binary mixtures. The concentrations of hydroquinone and pyrocatechol are found from cathodic peaks and that of resorcinol, from the anodic peak. The results are well reproducible and contain no systematic error. 相似文献
10.
V. N. Kiryushov L. I. Skvortsova T. P. Aleksandrova O. V. Karunina 《Journal of Analytical Chemistry》2008,63(6):580-585
Peak potentials and the kinetics of hydroquinone oxidation at an electrode from a graphite-epoxy composite in activated and passivated states were studied in supporting electrolytes of different buffer capacities and pH varying from 0.1 to 8.8, using methods of direct-current and cyclic voltammetry. The electrode was activated before its polarization by mechanically cutting a 0.2–4-μm surface layer directly in a test solution. The electrode was passivated by storing in air for two or more days. The behavior of hydroquinone in its oxidation at the passivated and activated electrodes was compared using diagnostic criteria for the following functions: I a?v 1/2, logI a?logv, I a/v 1/2?v 1/2, and I a/c, where v is the rate of the potential sweep and c is the volumetric concentration of hydroquinone. The potential difference of anodic and cathodic peaks in cyclic voltammograms indicated the reversibility of the electrode reaction in all supporting electrolytes. 相似文献
11.
L. K. Shpigun E. Yu. Andryukhina P. M. Kamilova M. A. Suranova A. S. Protasov 《Russian Journal of Electrochemistry》2016,52(4):340-347
Experimental information on the electrochemical behavior of guanine synthetic derivatives (acyclovir, valacyclovir, ganciclovir, and famciclovir) with the strong antiviral activity on presynthesized activated carbosital electrode (CSE) in aqueous solutions of different acidity is obtained. The mechanism of irreversible oxidation of substances containing guanidine group (–NH–C(NH–)=N–) is discussed and the dependences of current and potential of experimental anodic peaks on the potential scan rate, the nature and acidity of supporting electrolyte solution, and also on the concentration of depolarizer and the time of its accumulation on the electrode surface are found. It is shown that all other factors being equal (0.1 М phosphate buffer, рН 6), the position of the observed anodic peak depends substantially on the nature of acyclic substituent at N(9) of imidazole ring in the aminopurine molecule: the susceptibility to oxidation decreases in the series Gua (Epa = 0.84 V), ACV (Epa = 1.00 V), VACV (Epa = 1.04 V), GCV (Epa = 1.07 V), FCV (Epa = 1.20 V). It is shown that the electrocatalytic activity and the high absorbability of the activated CSE with respect to substances tested make it possible to reach their lower detection limits (20–40 nM) in multicomponent solutions. 相似文献
12.
Poly(o-aminobenzoic acid) (o-ABA) film is deposited on glassy-carbon electrode (GCE) by electropolymerization in pH 7.0 phosphate buffer solution (PBS).
Electrochemical behavior of modified electrode is investigated by electrochemical impedance spectroscopy (EIS), different
pulse voltammetry (DPV), and cyclic voltammetry (CV). The results indicate that there is a greater resistance during the electron
transfer process in poly(o-ABA) film than in bare GCE for the redox of [Fe(CN)6]3−/[Fe(CN)6]4−. Further research indicates that epinephrine (EP) can be strongly absorbed on the surface of the poly(o-ABA) film-modified electrode. The modified electrode shows an excellent electrocatalytical activity on EP oxidation. The
EP cathodic peak potential shifts negatively with a slope of −53.5 mV/pH, indicating that equal amounts of proton and electron
are involved in the electrode reaction process. In pH 7.0 PBS, the peak current of EP and the concentration has a linear relationship
from 0 to 65 μM by amperometric current-time curve.
__________
From Elektrokhimiya, Vol. 41, No. 9, 2005, pp. 1059–1065.
Original English Text Copyright ? 2005 by Cheng, Jin, Zhang.
The text was submitted by the authors in English. 相似文献
13.
M. D. Vedenyapina V. A. Vil’ A. O. Terent’ev A. A. Vedenyapin 《Russian Chemical Bulletin》2017,66(11):2044-2047
The electrochemical behavior of phthaloyl peroxide C8H4O4 on an Au disk electrode in a 0.05 M aqueous solution of Na2SO4 was studied by cyclic voltammetry (CVA). It demonstrated a high activity in cathodic reduction with the formation of an irreversible peak on the CVA curve at E =–0.81 V. Additionally, during the anodic oxidation of C8H4O4, the surface of the Au electrode became passivated by compounds which prevented its oxidation during the registration of repeated cycles. Apparently, these compounds are surface complexes of phthaloyl peroxide with a gold cation. 相似文献
14.
Bruna C. Lourencao Tiago A. Silva Hudson Zanin Paul W. May Evaldo J. Corat Orlando Fatibello-Filho 《Journal of Solid State Electrochemistry》2016,20(9):2403-2409
Porous boron-doped diamond (p-BDD) electrodes of high-surface-area have been prepared on vertically aligned carbon nanotube substrates, and their electrochemical performance has demonstrated promising results for application in electroanalysis. The electrochemical features of the p-BDD electrodes were investigated and compared with those of a conventional flat BDD electrode (f-BDD). From cyclic voltammetry studies performed for the electrochemical probes [Fe(CN)6]3? and N,N,N′,N′-tetramethyl-para-phenylenediamine (TMPD), a fast charge transfer was observed at the p-BDD/electrolyte interface. For the [Fe(CN)6]3? redox probe, the heterogeneous electron-transfer rate constant (k 0) value obtained for p-BDD was 10.9 times higher than that obtained using a f-BDD electrode. Moreover, the p-BDD electrodes also gave a smaller peak potential separation, ΔE p, and larger analytical signal magnitude for different biomolecules, such as dopamine (DA), acetaminophen (AC), and epinephrine (EP). These set of results demonstrated that the p-BDD electrode is a suitable candidate for applications in electroanalytical chemistry. 相似文献
15.
Bruno R. L. Ferraz Demetrius Profeti Luciene P. R. Profeti 《Journal of Solid State Electrochemistry》2018,22(2):339-346
This paper reported a simple method for sulfanilamide determination by redox process electroanalysis of oxidation products (SFDox) formed in situ on glassy carbon electrode. The CV experiments showed a reversible process after applied E acc = + 1.06 V and t acc = 1 s, in 0.1 mol L?1 BRBS (pH = 2.0) at 50 mV s?1. Different voltammetric scan rates (from 10 to 450 mV s?1) suggested that the redox peaks of SFDox on the glassy carbon electrode (GCE) is an adsorption-controlled process. Square-wave voltammetry (SWV) method optimized conditions showed a linear response to SFD from 3.00 to 250.0 μmol L?1 (R = 0.998) with a limit of detection of 0.638 μmol L?1 and limit of quantification of 2.0 μmol L?1. The developed the SWV method was successfully used in the determination of SFD pharmaceutical formulation and human serum. The SFD quantification results in pharmaceutical obtained by SWV-GCE were comparable to those found by official analytical protocols. 相似文献
16.
Y. Z. Song J. J. Song T. T. Zhao C. Y. Chen M. He J. Du 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(6):1185-1191
Density functional theory was employed for calculation of HS(CH2)mSH (m = 1–8) and its derivatives at B3LYP method at 6-31++g (d,p) level. Using eigenvalues of LUMO and HOMO for HS(CH2)mSH, the standard electrode potentials were estimated by a stepwise multiple regression techniques (MLR), and obtained as E° = 1.500 + 7.167 × 10–3 HOMO–0.229 LUMO with high correlation coefficients of 0.973 and F values of 43.973. 相似文献
17.
Tao-Tao Pang Xu-Yan Zhang Yong-Bing Xue 《Journal of inclusion phenomena and macrocyclic chemistry》2017,87(3-4):275-282
Cyclic voltammetry was used to detect p-sulfonated calix[n]arenas (SCnA) how to immobilize on gold surface. P-sulfonated calix[n]arenes not only increased the specific surface area of the modified electrode, but also improved the enrichment ability of tyrosine. This led to a significant increase in peak current, and improved the sensitivity of tyrosine determination on the p-sulfonated calix[n]arenes-modified electrode. The modified electrode showed good catalytic ability of l-tyrosine oxidation reaction. The peak current of l-tyrosine increased and the oxidation peak potential shifted negatively with cavity size of the SCnA-modified electrode, which indicated that the catalytic ability of the modified electrode to l-tyrosine oxidation reaction was also enhanced. For the tyrosine guest molecule, the order of electrochemical activity and magnitude of catalytic ability of the oxidation reaction of the three modified gold electrodes was as follows: SC4A?>?SC6A?>?SC8A. The electrode had high selectivity and stability for the determination of tyrosine, with a wide linear range, low detection limit and high sensitivity at different concentrations under different pH values. This resulted in an accurate, fast, sensitive electrochemical method for the determination of tyrosine. The sensor was used for the determination of tyrosine in human urine with satisfactory results. 相似文献
18.
Marcia Viltres Portales Ana R. Lazo Fraga Alicia M. Díaz García Osmany García-Zaldívar Aimé Peláiz Barranco Miguel A. Aguilar Frutis 《Journal of Solid State Electrochemistry》2018,22(2):471-478
The transducer of solid-state electrodes based on an epoxy-graphite composite was modified by two different methods, such as direct mixed and layer deposition of graphene (commercial and synthesized by electrochemical exfoliation of graphite). The modified electrodes were characterized by cyclic voltammetry and impedance spectroscopy. Also, scanning electron microscopy (SEM) was carried out to acquire information concerning the morphology of the composite electrode. Voltammetric measurements, in presence of [Fe(CN)6]3? as electroactive standard, determined a quasi-reversible electrochemical behavior under linear diffusion control. Electronic transference for modified and unmodified electrodes was compared. Solid-state electrode modified by inclusion of synthesized graphene showed a better electronic transference at electrode surface, due to the lower potential difference between anodic and cathodic peaks (ΔE = 125 mV) with respect to unmodified electrode (ΔE = 160 mV). Impedance spectroscopy characterization of electrode bodies in solid-state it was revealed a higher electronic conductivity and a supercapacitive behavior for the modified composites (values of intrinsic capacitances in the order of nanofarads) due to inclusions of graphite and graphene in the epoxy matrix. These inclusions were verified through SEM microscopy. The electronic conductivity and the supercapacitive character contributed both to the enhancement of electronic transference at electrode surface. 相似文献
19.
20.
V. K. Laurinavichyute S. E. Bakhtenkova O. A. Drozhzhin S. M. Kazakov E. V. Antipov 《Russian Journal of Electrochemistry》2016,52(11):1048-1056
Iron selenide (FexSey) thin films were electrodeposited on a glassy carbon electrode (GCE) surface under constant potential and pulse potential modes. The deposition mechanism was investigated using cyclic voltammetry. Electrochemical processes at room temperature are accompanied by adsorption of selenium on the electrode surface and complicated by chemical reactions in the solution bulk. Several approaches to control the film stoichiometry were applied: varying of electrodeposition potential; the use of elevated temperatures (60–80°C) to decrease the electrode passivation and electrodissolution of interfering elements under pulse mode. The composition of FexSey thin films was analyzed using an energy dispersive X-rays (EDX) analysis. 相似文献