Diffusional interaction of drops in a liquid

The method of combining asymptotic expansions (with respect to a large Peclet number) is used to investigate the three-dimensional problem of steady-state convective diffusion to the surface of drops, around which flows a laminar stream of a viscous incompressible liquid whose velocity field is assumed to be known from the solution of the corresponding hydrodynamic problem. It is shown that for large Peclet numbers the heat and mass transfer between drops is completely determined by the mutual arrangement of special (starting or ending at the surface of a drop) lines of flow; under these circumstances, in the flow there are chains of drops which have no mutual diffusional effect on one another, and the total diffusional flow to a drop is determined by diffusion to particles located upstream in the same chain. For the case where the distance between the drops in the chain is much leas than P^1/2 (P is the Peclet number), formulas for the distribution of the concentration and the total diffusional flow to the surface of each drop are obtained. It is shown that the total diffusional flow to the surface of a drop approaches zero in inverse proportion to its order number in a chain, which generalizes [1], in which the axisymmetric case is considered. A solution of the diffusional case is obtained for the case where there are critical lines at the surface of the drop. The problem is solved to the end if the singular flow lines are not closed and depart to infinity. With the presence of a region of closed circulation behind the drops, the problem is reduced to an integral equation.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika, Zhidkosti i Gaza, No. 2, pp. 44–56, March–April, 1978.The author thanks Yu. P. Gupalo and Yu. S. Ryazantsev for their interest in the work.     

On the interaction forces between evaporating drops in charged liquid-drop systems

The pairwise hydrodynamic and electrostatic interaction between micrometer-sized water droplets at small distances between them due to their evaporation and the presence of an electric charge on at least one of them is considered. The velocities of the steady-state motion of charged water drops with radii of 1 and 10 μm evaporating in air are calculated. It is shown that at small distances between the drops the joint action of hydrodynamic attraction and polarization interaction, always of attraction type, favor the coalescence of the drops (or drops and solid particles), leading to the displacement of the maximum of the function of drop distribution over size to the region of greater sizes and the gravity sedimentation of large drops. At large distances between the drops, when the short-distance hydrodynamic and polarization attractive forces become smaller than the long-distance Coulomb repulsion forces between likely charged particles, this distance tends to increase. These phenomena give a microphysical explanation to the phenomenon of electrostatic blooming in optically dense smokes and mists.     

Mass transfer from a pulsating drop

The primary difficulty in solving the problem of mass transport through an isolated drop (or bubble) moving in a fluid medium at high Reynolds numbers lies in the extreme complexity of the hydrodynamic pattern of the phenomenon. For sufficiently high velocities a separation of the external flow will occur in the rear portion of the drops and bubbles, which leads to the appearance of a turbulent wake and a sharp increase of the hydrodynamic resistance. Beginning with those dimensions for which the resistance force acting per unit surface of the drop or bubble from the external medium becomes greater than the capillary pressure, the surface of the drops and bubbles begins to deform and pulsate. The local variations of the surface tension, resulting either from the process of convective diffusion or from adsorption of surface-active substances, have a large effect on the hydrodynamics of drops and bubbles (particularly on the deformation of their surface) [1, 2], The presence of vortical, and possibly even turbulent, motion within the drops and bubbles may, under certain conditions [1], lead to their fractionation.Naturally, at the present time such complex hydrodynamics cannot be described by exact quantitative relations. Several authors have attempted to solve this problem approximately within the framework of certain assumptions. In particular [3–6], a theory was developed for the boundary layer on the surface of spherical and ellipsoidal gaseous bubbles moving in a liquid, studies were made [7, 8] of the hydrodynamics of drops located in a gas flow and the conditions were found for which fractionation of such drops takes place. Of considerable practical interest is the development of the theory of mass transfer in pulsating drops and bubbles and finding in explicit form the dependence of the mass transfer coefficients on the hydrodynamic characteristics of these systems. Until this relationship is established, every theory which ignores the effect of hydrodynamics on the mass transfer rate from an individual drop or bubble cannot be considered in any way well-founded. This relates particularly to the theories [9, 10] which consider mass transfer in systems with concentrated streams of drops and bubbles. The present paper is devoted to the study of mass transport through the surface of an isolated drop in an irrotational gas or liquid stream for large Peclet numbers P.In conclusion the authors wish to thank V. G. Levich for his helpful discussions.     

Hydrodynamics of contact of a falling drop with a liquid free surface

A fine structure of the flows developing during primary contact of freely falling drops with a deep quiescent fluid is studied using the macrophotography and high-speed video filming methods. Water drops falling in water, alcohol, and oil, as well as drops of oil, petroleum, and aqueous solutions of salt or alcohol falling in water are investigated. The work is focused on the visualization of the finespray scattering from the primary contact area. The collisions of small droplets with the surface of the submerging drop are first recorded. The direction of the spray and streamer scattering is determined by the surface tension coefficients of the coalescing liquids. The conditions under which the spray droplets collide with the drop surface are determined.     

Self-aeration and turbulence in a stepped channel: Influence of cavity surface roughness

The strong interactions between free-surface flows and atmospheric surroundings may lead to substantial air–water mixing with void fractions ranging from zero in clear-water to 100%. In this study, the air–water flow properties were studied in a large stepped water channel operating at large Reynolds numbers. Interactions between free-surface and cavity recirculation were systematically investigated in the skimming flow regime. Some surface roughness was introduced on the cavity walls and identical experiments were performed with several configurations. Basic results demonstrated some influence of step surface roughness on the flow properties leading to some counter-intuitive finding. The presence of cavity roughness was associated with higher flow velocities and comparatively lower turbulence levels. Distributions of bubble/droplet chords spanned over several orders of magnitude without significant influence of the cavity roughness. The distributions of turbulence levels and bubble count rates showed some correlation and highlighted strong interactions between entrained particles (bubbles, drops) and the flow turbulence.     

Droplet interactions in thermocapillary motion

The dynamics of two spherical droplets, whose movement is driven by variations in interfacial tension caused by a temperature gradient, are analyzed using a method of reflections. Both droplets have the same internal fluid properties but may differ in size, and the configuration of the droplets is arbitrary relative to the direction of the undisturbed temperature gradient. The method of reflections is based on an analysis of the thermal and hydrodynamic disturbances produced by a single droplet placed in an arbitrarily varying temperature field. The results for two-droplet interactions are correct to 0(r⁻⁶) where r is the center-to-center distance between the droplets. For the specific case of bubbles oriented parallel with the undisturbed temperature gradient, my results agree very well with numerical calculations found in the literature. The results for two, identical droplets are used to find the 0(ø) effect on mean droplet velocity of a bounded suspension, where ø is the volume fraction of the droplets. In general, the interactions between droplets moving by thermocapillary effects are much weaker than in the case of sedimentation.     

An experimental study of two-phase flow in simulated reduced-gravity condition: dispersed droplet to slug flow transition and slug flow

The results from an experimental study of reduced-gravity two-phase flows are reported in this paper. The experiments were conducted in simulated reduced-gravity conditions in a ground-based test facility with a circular test section of 25 mm inner diameter. The flow conditions for which data were acquired lie in the dispersed droplet to slug flow transition and slug flow regime. Local data were acquired for 17 different flow conditions at three axial locations. The acquired data complement and extend those discussed in an earlier paper by the authors (Vasavada et al. in, Exp Fluids 43: 53–75, 2007). The radial profiles and axial changes in the local data are analyzed and discussed in this paper. The area-averaged data, in conjunction with the local data, are discussed to highlight important interaction mechanisms occurring between fluid particles, i.e., drops. The data clearly show the effect of progressive coalescence leading to formation of slug drops. Furthermore, the shape of slug drops in reduced-gravity conditions was observed to be different from that in normal-gravity case. The analyses presented here show the presence of drop coalescence mechanisms that lead to the formation of slug drops and transition from dispersed droplet flow to the slug flow regime. The most likely causes of the coalescence mechanism are random collision of drops driven by turbulence eddies in the continuous phase and wake entrainment of smaller drops that follow preceding larger drops in the wake region. Data from flow conditions in which the breakup mechanism due to impact of turbulent eddies on drops illustrate the disintegration mechanism.     

Viscous flow of a suspension of liquid drops in a cylindrical tube

Viscous flow in a circular cylindrical tube containing an infinite line of viscous liquid drops equally spaced along the tube axis is considered under the assumption that a surface tension, sufficiently large, holds the drops in a nearly spherical shape. Three cases are considered: (1) axial translation of the drops, (2) flow of the external fluid past a line of stationary drops, and (3) flow of external fluid and liquid drops under an imposed pressure gradient. Both fluids are taken to be Newtonian and incompressible, and the linearized equations of creeping flow are used.The results show that both drag and pressure drop per sphere increase as the spacing increases at fixed radius and also increase as the radius of the drop increases. The presence of the internal motion reduces the drag and pressure gradients in all cases compared to rigid spheres, particularly for drops approaching the size of the tube.     

Evaluation of FFT-based cross-correlation algorithms for PIV in a periodic grooved channel

The design of a pneumatic droplet generator to produce small (~0.2 mm diameter) water droplets on demand is described. It consists of a cylindrical, liquid-filled chamber with a small nozzle set into its bottom surface, connected to a gas cylinder through a solenoid valve. Rapidly opening and closing the valve sends a pressure pulse to the liquid, ejecting a single droplet through the nozzle. Gas in the chamber escapes through a vent hole so that the pressure drops rapidly and more droplets do not emerge. We photographed droplets as they emerged from the nozzle, and recorded pressure fluctuations in the chamber. We determined the duration of the pressure pulse required to generate a single drop; longer pulses produced satellite drops. The length of the water jet when its tip detached and the diameter of the droplet that formed could be predicted using results from linear stability analysis. The peak pressure in the cavity could be increased by raising the supply pressure, increasing the width of the pressure pulse, or by reducing the size of the pressure relief vent.     

Low-Reynolds-number droplet motion in a square microfluidic channel

In this study, we investigate computationally the low-Reynolds-number droplet motion in a square micro-channel, a problem frequently encountered in microfluidic devices, enhanced oil recovery and coating processes. The droplet deformation and motion are determined via a three-dimensional spectral boundary element method for wall-bounded flows. The effects of the flow rate, viscosity ratio and droplet size on the interfacial dynamics are identified for droplets smaller and larger than the channel size and for a wide range of viscosity ratio. Owing to the stronger hydrodynamic forces in the thin lubrication film between the droplet interface and the solid walls, large droplets exhibit larger deformation and smaller velocity. Under the same average velocity, a droplet in a channel shows a significantly smaller deformation and higher velocity than in a cylindrical tube with the same size, owing to the existence of the corners’ area in the channel which permits flow of the surrounding fluid. A suitable periodic boundary implementation for our spectral element method is developed to study the dynamics of an array of identical droplets moving in the channel. In this case, the droplet deformation and velocity are reduced as their separation decreases; the reduction is influenced by the flow rate, viscosity ratio and more significantly the droplet size.     

Calculation of the rate of coalescence of an emulsion in a turbulent flow

The central moment of the theory describing the merging (coalescence) of the drops of an emulsion is determination of the time of the approach of a drop or a number of drops colliding with a given drop in unit time. In the stage immediately preceding the merging of the drops the forces of the hydrodynamic braking of the approaching drops are found to be considerable. The role of these forces has been analyzed earlier for the case of the capture of small drops by large drops in an oncoming flow in the presence of an external electrical field [1] and for the problem of the Brownian coalescence of drops, taking account of the effect of the electric double layer and of surface forces of interaction [2–4]. The present article considers the approach of drops with turbulent diffusion in an electrical field. Of the greatest interest is the sharp slowing of the approach due to the hydrodynamic interaction of the drops, considerably sharper than in the case of molecular diffusion [2]. As a result, the sharp acceleration of the approach and coalescence of drops with the action of an electrical field on an emulsion in a turbulent flow becomes understandable.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 47–55, May–June, 1976.The authors are grateful to G. I. Barenblatt, A. I. Leonov, V. I. Loginov, and L. P. Smirnov for their evaluation and criticism of the work.     

The fate of soluble and insoluble surfactant monolayers subjected to drop impacts

Surfactant monolayers were formed on a water surface and subjected to water drops falling from a nozzle. Surface tension was measured during these experiments to determine the effect of the drop impacts on the surfactant monolayer. The purpose of this work was to determine whether monolayers can be altered by drop impacts without the formation of a splash. Accordingly, a small fall height was used to avoid drop splashes and concomitant surfactant loss by droplet ejection. The relevance of this work pertains to the fate of surfactant monolayers during rain events. Results are presented for a soluble and insoluble surfactant. The results show that the insoluble monolayer is virtually unaffected by the drops, indicating that the monolayer immediately reforms after the drop impact. The soluble monolayer shows significant changes in measured surface tension during droplet impact when the surfactant concentration is high.     

Dynamics of separation of a single drop in air

The processes of formation of alcohol and water drops, as well as formation of small fragments—satellites, are traced using the high-speed filming. The trajectory of a water drop satellite is nonmonotonic, at first the satellite moves upward against the gravity force, reaches the oscillating residual fluid at the nozzle exit, and then starts to move down. From the satellite, a microdroplet is ejected, which bounces off the residual fluid at the nozzle, returns back to the satellite and merges. In the case of an alcohol drop, no accompanying microdroplet is formed, and the satellite follows a nearballistic trajectory.     

A new mesh relaxation approach and automatic time‐step control method for boundary integral simulations of a viscous drop

We present a numerical methodology for the simulation of a viscous drop under simple shear flows by using the boundary integral method. The present work treats only a single drop in an unbounded fluid‐flow, but the results can be directly applied to studies on the rheology of dilute emulsions, in which the hydrodynamic interactions between two or more drops can be neglected. Singular and non‐singular integral representations of the velocity field are considered. Several aspects of the method are presented, including a new mesh relaxation approach and an automatic time‐step control method. The relaxation strategy is used in order to contain the distortion of the mesh and is performed by using relaxation iterations in a virtual temporal march between each physical time step of the simulation and monitoring the standard deviation of the areas of the elements. The automatic time‐step control method uses a global quantity related to the drop deformation in order to automatically set the temporal integration time step. It is carried out in a way to keep the local integration error less than a given tolerance. This strategy reduces the computational cost of the simulation by dramatically reducing the number of time steps in the temporal integration process. Copyright © 2016 John Wiley & Sons, Ltd.     

Asymptotic model of slow three-dimensional liquid film flow in a space drop catcher

Slow steady-state film flows formed on the inner surface of a drop catcher funnel due to inertial deposition of drops of a dispersed working matter in the spacecraft cooling system are considered. A limiting asymptotic model of slow three-dimensional coolant film flow is constructed assuming that the deposited drops transfer all their mass, momentum, and energy to the film described by the equations of creeping viscous fluid flow in a thin layer of a priori unknown thickness. A first-order quasi-linear partial differential equation for the film thickness is derived. The shape of the film surface is investigated numerically as a function of parameters using the method of characteristics. The range of optimum parameters ensuring the steady-state film flow is found. The limits of existence of the solutions corresponding to the limiting model proposed are investigated.     

Electrokinetic Mixing and Displacement of Charged Droplets in Hydrogels

Mixing in droplets is an essential task in a variety of microfluidic systems. Inspired by electrokinetic mixing, electric field-induced hydrodynamic flow inside a charged droplet embedded in an unbounded polyelectrolyte hydrogel is investigated theoretically. In this study, the polyelectrolyte hydrogel is modeled as a soft, and electrically charged porous solid saturated with a salted Newtonian fluid, and the droplet is considered an incompressible Newtonian fluid. The droplet-hydrogel interface is modeled as a surface, which is located at the plane of shear, with the electrostatic potential \(\zeta \) . The fluid inside the droplet attains a finite velocity owing to hydrodynamic coupling with the electroosmotic flow arising from the droplet and polymer charge. The fluid velocity inside the droplet is linearly proportional to the electroosmotic flow velocity in the charged gel and the electroosmotic flow velocity beyond the electrical double layer of a charged interface. It is found that the polymer boundary condition at the droplet surface and the viscosities of the fluids inside and outside the droplet significantly modulate the interior fluid flow. The ionic strength and the permeability of the polymer network impact the flow differently depending on whether the flow arises from the droplet or polymer charge. Finally, the displacement of a charged droplet embedded in a gel under the influence of an external electric field is undertaken. This work is motivated by experimental attempts, which can register sub-nanometer-scale inclusion displacements in hydrogels, to advance electrical microrheology as a diagnostic tool for probing inclusion-hydrogel interfaces. In the absence of polymer charge, a close connection is found between the electrical response of a charged droplet when it is immobilized in an uncharged incompressible gel and when it is dispersed in a Newtonian electrolyte.     

Interaction phenomena between liquid droplets and hot particles—Captured via high-speed camera

The interaction of evaporating droplets and hot catalyst particles plays a major role in heterogeneously catalysed reactions. The liquid feed is injected into a gas–solid flow and is mixed with the catalyst. The interaction phenomena determine the evaporation time which should be minimised to keep the reactor vessel small. First measurements with a bed of fixed hot FCC-particles (fluid catalytic cracking) and two model fluids have been conducted. The interactions of ethanol and water droplets with the hot bed surface were captured via a high-speed camera. While the ethanol droplet developed a stable steam cushion due to Leidenfrost phenomena, water showed intense interaction and steam explosions which induced repulsion and atomisation of the droplet.     

Viscosity of a Newtonian fluid calculated from the deformation of droplets covered with a surfactant under a linear shear flow

The viscosity of small fluid droplets covered with a surfactant is determined using drop deformation techniques. This method, proposed by Hu and Lips, is here extended to the case of the presence of a surface-active adsorpted at the liquid–liquid interface, to consider more general scenarios. In these experiments, a droplet is sheared by another immiscible fluid of known viscosity, both Newtonian liquids. From the steady-state deformation and retraction mechanisms, the droplet viscosity is calculated using an equation derived from the theories of Taylor and Rallison. Although these theories were expressed for surfactant-free interfaces, they can be applied when a surfactant is present in the system if the sheared droplet reaches reliable steady-state deformations and the surfactant attains its equilibrium adsorption concentration. These determinations are compared to bulk viscosities measured in a rheometer for systems with different viscosity ratios and surfactant concentrations. Very good agreement between both determinations is found for drops more viscous than the continuous phase.     

An experimental study of drop migration in shear flow between concentric cylinders

The phenomenon of migration of liquid drops in Couette flow between concentric cylinders due to non-Newtonian fluid properties and shape deformation has been studied experimentally. The results agree very well with the theory of Chan and Leal, which included the effect of hydrodynamic interaction with the bounding walls, and that of velocity profile curvature in a Couette device. Significant observations that were not reported in previous studies include the migration of a deformable Newtonian drop to an equilibrium position between the centerline and the inner rotor, and the competition between normal stresses and shape deformation effects for the case of a Newtonian drop in a non-Newtonian fluid.     

Pressure drop for flow in channels subjected to strong system rotation

A disc stack centrifuge is an industrial example of a fluid machine in which all the internal flow takes place in a rapidly rotating frame. The present report gives a survey of the experimental and theoretical work performed at Alfa-Laval in order to estimate the pressure drops in the different internal passages in the centrifuge, including both laminar and turbulent flow.For the laminar flow between the discs, a theory has been developed using the concept of a rotating Hele Shaw cell and conformal mapping. The theory is valid in the limit of very small Rossby numbers. For moderately large Rossby numbers, this model overestimates the pressure drop. The linear theory was extended by introducing advecting vortices in a computer model. The vortices cause vertical fluid transport between the Ekman and geostrophic layers by Ekman pumping, an effect which decreases the pressure drop in the disc stack. The linear model and the enhanced model have both been confirmed by experiments.The flow is turbulent in most parts of the centrifuge, except in the disc stack. The theoretical or numerical modelling for rotating turbulent flows is very difficult and no reliable models exist so far. We therefore have to rely on measurements, which show that the pressure is significantly influenced by rotation for Rossby numbers below unity.