脉冲控制量子系统的哈密顿量约化

探索了脉冲控制的含近简并能级的有限维量子系统的哈密顿量的约化．由一个非简并基态能级和几个近简并激发态能级组成的量子系统被一个短脉冲控制,目标是控制所有激发态的布居数之和．考虑了两个可以看成等价二能级系统的例子,当脉冲强度比较弱时,得到了原始系统和约化系统的简单关系;当脉冲强度比较强时,对于只含一个频率的脉冲,一阶近似的关系也是存在的．     

Active mode locking of continuous-wave doubly and singly resonant optical parametric oscillators

We report on what we believe to be the first active mode locking of near-degenerate, doubly and singly resonant cw-pumped optical parametric oscillators (OPOs). We show experimentally that a steady-state regime of short pulses is reached in a few tens of microseconds under cw pumping. The oscillation buildup dynamics of both OPOs is also explored, evidencing an unusual transient behavior in the mode-locking process.     

ZnGeP2 parametric oscillator pumped by a linewidth-narrowed parametric 2 microm source

A tandem optical parametric oscillator (OPO) is used to convert radiation from 1.064 microm to the mid-infrared. Spectral bandwidth narrowing close to 80 times compared with a conventional cavity was achieved by using a bulk Bragg grating as an outcoupler in a near-degenerate periodically poled KTiOPO(4) OPO. The narrowed 2,008 nm radiation was subsequently used for pumping the ZnGeP(2) OPO, which was tunable between 3.3 and 5.2 microm. Pulse energies of 170 microJ and pump depletion close to 70% were obtained in the ZnGeP(2) OPO. To our knowledge this is the first time the output from a near-degenerate type I PPKTP OPO has been used for ZnGeP(2) OPO pumping.     

Obtaining high refractive index with vanishing absorption via spontaneously generated coherence and incoherent pumping

A three-level ∧-model atomic system with incoherent pumping is proposed to achieve high refractive index without absorption. In this kind of model, two lower levels are near-degenerate levels. It is found that high refractive index accompanied by vanishing absorption can be always accomplished by adjusting some related parameters. Although probe field is very weak, the SGC effect is prominent in the presence of incoherent pumping.     

On the finesse of a phase-conjugate Fabry-Perot resonator using nearly-degenerate four-wave mixing

We consider a Fabry-Perot cavity in which one of the mirrors is a phase-conjugate mirror (PCM) using near-degenerate four-wave mixing. We show that when taking pump depletion into account, the divergence in finesse of the resonator predicted by linear theories for a resonator round trip gain approaching unity is eliminated. The saturation of the finesse as a function of pump intensity leads to a new kind of bistability in the transmission characteristics of the system.     

An E.S.R. study of some alkyl substituted benzene anion radicals : an experimental evaluation of the extent of vibronic interaction

E.S.R. studies of the proton hyperfine splitting in the anion radicals of benzene, toluene, ethylbenzene, iso-propylbenzene, t-butylbenzene, and p-xylene show that it is strongly dependent upon temperature. In the case of the monoalkylbenzenides there are two contributions to this observed temperature dependence. First, there is a rapid thermal averaging over two near-degenerate states which have different spin-density distributions. The energy separations between these two near-degenerate states have been measured for the above series of monoalkylbenzenides and are reported here. It is also possible to measure experimentally the spin-density distributions for the two states between which the averaging takes place. With this information one can obtain an experimental estimate of the extent of vibronic interaction which occurs in these systems. Such estimates are presented here and compared with those obtained theoretically. The second source of the strong temperature dependence of the proton hfs lies in the temperature dependence of the sigma-pi interaction parameter, Q _H. The sigma-pi interaction parameter has been studied as a function of temperature for all members of the above series and the results reported. Finally, restricted rotation of the iso-propyl group in the anion radical of iso-propylbenzenide was observed and the barrier to rotation has been measured.     

High pressure stabilization and emergent forms of PbH4

A wide decomposition pressure range of 132 GPa is predicted for PbH4 above which it emerges in very different forms compared with its group-14 congeners. This triply Born-Oppenheimer system is a nonmolecular, three-dimensional, metallic alloy, despite a prominent layered structure. A significant number of enthalpically near-degenerate structures, with exceedingly small energy barriers for distortions, and characteristic instabilities in the phonon spectra suggest that even at very high pressures PbH4 may exhibit both metallic and liquidlike properties and sublattice or even full melting.     

Phase-dependent inversionless gain in a four-level atomic system with a closed interaction loop

A four-level atomic system with a closed interaction loop connected by two coherent driving fields and a microwave field is investigated. The results show that inversionless gain can be achieved on a higher frequency transition outside the closed interaction loop, and the gain behaviour can be modulated by the phase of the closed loop as well as the amplitude of the microwave field. The phase sensitivity property in such a scheme is similar to that in an analogous configuration with spontaneously generated coherence, but it is beyond the rigorous condition of near-degenerate levels with non-orthogonal dipole moments. Therefore this scheme is much more convenient in experimental realization.     

Stable operation of a cw optical parametric oscillator near the signal-idler degeneracy

The frequency stability of a cw optical parametric oscillator (cw OPO) near the signal-idler degeneracy has been studied. The strong tendency of a near-degenerate OPO to mode hop has been suppressed by using a bulk Bragg grating as a spectral filter in the OPO cavity. An experimental demonstration of stable parametric oscillation in a single longitudinal mode of the OPO cavity is reported, together with the capability of tuning the signal-idler difference frequency from 1 to 4 THz. The OPO has potential use in cw terahertz generation.     

2-μm singly resonant optical parameter oscillator

We experimentally realize a singly resonant optical parameter oscillator （OPO） which operates at the degenerate point of KTiOPOa （KTP） crystal. A thin film plate polarizer （TFP） is used as the output coupler to obtain linearly polarized 2.12 μm laser. A maximum output power of 2.2 W at 2.12 μm is obtained from a near-degenerate, type-II KTP OPO by utilizing a Q-switched diode-pumped Nd：YAG laser operating at 5 kHz.     

Collisions of ultracold trapped cesium Feshbach molecules

We study collisions in an optically trapped, pure sample of ultracold Cs₂ molecules in various internal states. The molecular gas is created by Feshbach association from a near-degenerate atomic gas, with adjustable temperatures in the nanokelvin range. We identify several narrow loss resonances, which point to the coupling to more complex molecular states and may be interpreted as Feshbach resonances in dimerdimer interactions. Moreover, in some molecular states we observe a surprising temperature dependence in collisional loss. This shows that the situation cannot be understood in terms of the usual simple threshold behavior for inelastic two-body collisions. We interpret this observation as further evidence for a more complex molecular structure beyond the well-understood dimer physics.     

Highly efficient second-harmonic generation in buried waveguides formed by annealed and reverse proton exchange in periodically poled lithium niobate

Efficient three-wave mixing devices have numerous applications, including wavelength conversion, dispersion compensation, and all-optical switching. Second-harmonic generation (SHG) is a useful diagnostic for near-degenerate operation of these devices. With buried waveguides formed in periodically poled lithium niobate by annealed and reverse proton exchange, we demonstrate what is believed to be the highest normalized conversion efficiency (150%/W cm(2)) for SHG in the 1550-nm communications band reported to date.     

基于光纤环形腔光数据包循环复制的实验研究

通过实验研究了利用不同分光比耦合器构成的光纤环形腔实现光数据包循环复制的效果,并理论分析了影响复制效果的结构因素。耦合器分光比、光纤环形腔中的损耗和噪声对复制效果有不同的影响。光纤环形腔中光放大器、滤波器的加入,以及光脉冲直流基座的降低,可以明显改善输出的幅值和复制序列长度。但实验显示,接近等幅复制的光放大会引起光纤环形腔的自激。在这一情况下,在输出端增加饱和半导体光放大器（SOA）可提高复制信号的识别效果。     

利用棱镜减小自衍射信号光角色散的研究

自衍射效应在飞秒激光领域有非常重要的应用,如提高飞秒脉冲的时域对比度、作为自参考光谱干涉脉冲测量法的参考光、作为频率分辨光学开关法的信号光等.然而,具有较宽光谱带宽的飞秒激光在自衍射效应过程中产生的信号光存在明显的角色散,这给自衍射效应的应用带来不利影响.本文研究发现通过在自衍射效应的一个光路中加入等腰直角棱镜,当到棱镜的入射角为23fi时可以明显地减小飞秒激光脉冲自衍射信号的角色散.这就为以后将自衍射效应更好的应用到飞秒激光脉冲的研究提供了有用的参考.     

Generation of high-energy few-cycle laser pulses by using the ionization-induced self-compression effect

A mechanism behind the ionization-induced self-compression effect for ultrashort laser pulses propagating in gas-filled capillaries is proposed. It is shown that as a result of excitation of the nonlinear-plasma waveguide laser pulses producing gas ionization can be self-compressed to few-cycle duration. This effect is used for high-energy laser pulses and its scalability to J-level energies is demonstrated.     

Shaping of few-cycle laser pulses via a subwavelength structure

We theoretically investigate the propagation of few-cycle laser pulses in resonant two-level dense media with a sub- wavelength structure, which is described by the full Maxwell-Bloch equations without the frame of slowly varying envelope and rotating wave approximations. The input pulses can be shaped into shorter ones with a single or less than one optical cycle. The effect of the parameters of the subwavelength structure and laser pulses is studied. Our study shows that the media with a subwavelength structure can significantly shape the few-cycle pulses into a subcycle pulse, even for the case of chirp pulses as input fields. This suggests that such subwavelength structures have potential application in the shaping of few-cycle laser pulses.     

Electronic structure of amino acids and ureas

The outer electronic levels of glycine, alanine, glycine ethyl ester, urea, and thiourea have been investigated by means of photoelectron spectroscopy using He I (584 Å) and He II (304 Å) radiation and CNDO/2 molecular orbital calculations. In the amino acids the molecular orbital (MO) ordering ha been found to be [σ core and carbonyl π > a″(O) a′(O) > a″(N)] with a first ionization potential of ～8.8 eV. Glycine and alanine are foun to exist as the undissociated amino carboxylic acids rather than zwitterions in the high temperature vapor. In urea the three lowest energy molecular o are near-degenerate [σ(4b₁) ～ π(1a₂) ～ π(2b₂)] while in thiourea only the two lowest energy MO's are near-degenerate [π(1a₂ σ(4b₁) ～ π(2b₂)]. The first ionization potentials of urea and thiourea are 9.7 and 7.9 eV respectively.     

Peculiarities of the inverse Faraday effect induced in iron garnet films by femtosecond laser pulses

The inverse Faraday effect in iron garnet films subjected to femtosecond laser pulses is experimentally investigated. It is found that the magnitude of the observed effect depends nonlinearly on the energy of the optical pump pulses, which is in contradiction with the notion that the inverse Faraday effect is linear with respect to the pump energy. Thus, for pump pulses with a central wavelength of 650 nm and an energy density of 1 mJ/cm², the deviation from a linear dependence is as large as 50%. Analysis of the experimental data demonstrates that the observed behavior is explained by the fact that the optically induced normal component of the magnetization is determined, apart from the field resulting from the inverse Faraday effect, by a decrease in the magnitude of the precessing magnetization under the influence of the femtosecond electromagnetic field.     

High efficiency double-pass-pumped 2 μm periodically poled MgO:LiNbO3 optical parametric oscillator

A high efficiency near-degenerate periodically poled MgO:LiNbO₃ optical parametric oscillator pumped by a nanosecond Nd:YVO₄ laser is demonstrated. Under a 1.064 ??m pump power of 7.2 W, an output power of 5.3 W with an optical-to-optical conversion efficiency of 74% and a slope efficiency of 82% in the 2 ??m region is obtained in a double-pass-pumped doubly resonant geometry at 20 kHz repetition rate.     

The electronic spectra of benzene and its conjugated isomers: A full perturbative CI approach

The lower transition energies of benzene and its conjugated planar isomers: fulvene, dimethylene-cyclobutene, and trimethylene cyclopropane, have been calculated by the CIPSI method, a full second-order perturbation treatment using multiconfigurational wavefunctions constructed by an iterative CI process between near-degenerate configurations and simple determinants for the remaining configurations. Oscillator strengths are computed for electric-dipole allowed transitions. This study shows that the theoretical π-π^* transitions given by a minimal atomic basis set are too high by about 0.5 eV in the case of covalent excited states and by 1–2 eV in the case of ionic states. It suggests that the effect of σ-π correlation may be as important as the more or less diffuse character of the π orbitals as concerns the agreement with experiment. Ground-state properties (total energies and stability, dipole moments) are also discussed.