A theoretical study of the spectra of ketones,acids, and esters

The long-wave * transitions and weak n * transitions are discussed for several compounds of practical importance. Wave functions are presented for aliphatic ketones, acids, and esters.     

A new approach to the problem of the anomalous magnetic moment of the electron

A heuristic model for deriving the anomalous magnetic moment of the electron is presented. A term /2 – 0.327(/)² is deduced, in better agreement with experiment than is the QED derivation of /2 – 0.328(/)². The result is strengthened by the recent non-QED account of the Lamb shift by Yu and Sachs.     

Spin-orbit coupling in the chlorobenzene molecule

The possible ways of drawing of the intensity of the S₀ T* transition in the chlorobenzene molecule are investigated. The effective spin-orbit coupling of either S* or S* states with the T* state leads to the out-of-plane polarized component of phosphorescence in the chlorobenzene. The in-plane polarized component cannot be explained by the mechanism under consideration — by drawing of intensity of the S₀ S₀* transitions through spin-orbit coupling of first order.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 134–138, August, 1974.     

The inelastic reactions πp→λ(⌆) K with allowance for the contribution of branch cuts

The method of complex angular moments is used to analyze the experimental data on the inelastic reactions p ()K, taking into account branch cuts in the j-plane in the eikonal approximation. An optical model for the backward scattering is considered. Agreement with experiment is obtained in the region of small angles for the reactions (⁰)K⁰. In the case of ^–P K⁰(^–K⁺) processes, agreement is obtained with the experimental results for large (180) scattering angles.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 26–30, August, 1972.     

Genetic optimization of modulation characteristics for two twisted nematic liquid crystal spatial light modulators

A single twisted nematic liquid crystal spatial light modulator may suffer from coupled amplitude modulation and a phase modulation capability of less than 2, although almost all panels can achieve . Two twisted nematic liquid crystal panels can be combined in an optical system to produce a total phase modulation of at least 2, and a minimal coupled amplitude modulation. A genetic algorithm is used to optimize the combined modulation characteristics of two liquid crystal panels in a multiplicative architecture. Simulation results and experimental verification are presented which show a substantial reduction in the combined amplitude modulation, and a total phase modulation of 2.     

Scalar mesons in ππ and K¯K scattering

The s-wave pion scattering amplitude is analysed with the aim to clarify the mass spectrum of scalar mesons and to find evidence of lightest glueball. The S-matrix and K¯K coupled channel formalism is used. The existence of scalar mesons S^* and is implied by the data. The production K¯K and the elastic K¯KK¯K coupled amplitudes are predicted from the scattering data. The couplings c f S^* to and K¯K states are determined.     

Three-pion resonances

We investigate the continuum three-pion problem within a relativistic three-body model that takes into account the S andP waves. The dynamical input of the two-body subsystem is given by separable potentials, which yield a good fit to the scattering data and resonance parameters up to a two-body invariant mass of 900MeV. We introduce a parameter expressing the ambiguity in the reduction of a fully relativistic theory to a three-dimensional one. The masses and widths of the ,a ₁(1260), and (1300) mesons, which decay predominantly into three pions, are reasonably well described by our model. Theh ₁(1170) meson, however, which also decays into three pions, cannot be explained as a three-pion resonance. Some Argand diagrams are shown in those channels where resonances exist.     

Photophysical Behavior of β-Carboline-3-Carboxylic Acid N-Methylamide

The solvent and temperature effect of fluorescence and phosphorescence and its polarization characteristics for -carboline-3-carboxylic acid N-methylamide were studied. From the results obtained it is concluded that the first excited singlet state changes from the * type in a polar solvent (EPA) to the n* type in a nonpolar solvent (MC) and that the lowest singlet excited states (* type and n* type) interact by vibronic coupling. In the nonpolar solvent (MC) the lowest singlet excited states are very close in energy and consequently the vibronic coupling is stronger. It has been found that the 0–0 band of the phosphorescence emission in EPA is polarized out of plane, using the excitations corresponding to absorptions into the first and second excited * singlet states. This fact and the order of lifetime measured indicate an emitting triplet that is *. The origin of this polarization is very likely mixing as a result of spin–orbit coupling. However, the vibrational structures and changing polarization outside the 0–0 band indicate that second-order effects involving spin–orbit coupling and vibronic interactions are important and the mixing scheme appears to be and . The proximity effect can qualitatively explain the absence of phosphorescence and the stronger vibronic interaction between the n* and the * states of -carboline-3-carboxylic acid .N-methylamide in a hydrocarbon solvent (MC).     

Wedge-screw dispiration in smectic liquid crystals with antiferroelectric order

Using the approximative expression for the elastic energy density of the antiferroelectric (AF) liquid crystal the elastic self-energy of (, b)-wedge-screw dispiration is estimated. Then the elastic interaction between (, b)-wedge-screw dispiration and (2)-wedge dischnation in AF liquid crystals is investigated. The attraction of dislocation part of dispiration with (2)-wedge disclination can lead to the formation of (3)-wedge-screw dispiration. When (2)-wedge disclination is trapped by (2d)-screw dislocation the resulting (2, 2d)-dispiration can dissociate into a pair of two (, d)-dispirations.The authors express their thanks to Professors A. Fukuda, H. Takezoe, Dr. Y. Takanishi and to Dr. K. Miyachi for discussions concerning their experimental observations of (3, d)-wedge-screw dispirations and (, d)-twist-edge dispirations in AF structures. This work was supported by the grant No. 19062 from Acad. Sci. Cz. R. and also benefited by the grant No.: 202/93/155 from the Grant Agency of the Czech Republic.     

π0 → γγ in the Spinor Strong Interaction Theory

An expression for the decay rate (⁰ ) has been derived in the frameworkof the spinor strong interaction theory, a first-principles strong interaction theoryproposed some years ago as an alternative to low-energy QCD. The startingpoint is the SO(3) gauge-invariant action for two quark mesons which has beensuccessful in accounting for confinement, ^{+ +} , e⁺, and ⁰ e⁺, nonexistenceof the Higgs boson, and other low-energy mesonic phenomena. The quasi-four-quarkmeson equations developed for the decay of a vector meson into twopseudoscalar mesons V PP has been taken over here to apply to P(⁰) VV(^{+ –}) (plus ⁺ and ^– which annihilate each other). This mechanismin principle agrees with that of the assumption of vector meson dominance inthe literature. It, together with the effect of form factors, arises naturally in theformalism and need not be assumed. Equations for the perturbed vector mesonwave functions cannot be simply solved and an assumption has been made toobtain an estimate of their magnitude. Together with a constant associated withthe strong coupling obtained earlier from V() PP(K⁺K^–), the estimated decayrate is 19.2 eV, in order-of-magnitude agreement with data (7.74 eV).     

The π+ d → pp reaction at intermediate energies

Conclusion The joint efforts of the laboratories with intermediate energies accelerators at ANL, KEK, LANL, LNPI, Saclay, SIN and TRIUMF produced a rather definite picture of the ⁺pp reaction in the isobar region. However the problem of anomalies for the square-root branch point due to the production of isobar in the intermediate state have not been resolved so far. The poles obtained in different phenomenological analyses could be just the effective parametrization of these cuts (see e.g. [13]). Anyway, some singularities are definitely necessary to describe the data.The experimental data in regions s < 2·05 GeV and s < 2·25 GeV are clearly insufficient. Further accumulation of the data in these regions is necessary. Polarized deuteron data are badly needed in the whole kinematical range [13]. Besides as it was mentioned before it is necessary to measure accurately cross sections of other inelastic reactions which are important for the investigation (observation?) of dibaryonsNN N, NN andd N, NN [21]. It would be of interest also to measure cross sections of non quasi two-particle channels likeNN N, 2N andd N, 2N [22]. (In the case ofNN scattering quasi two-particle channels are known to dominate in a wide energy range.)Presented at the symposium Mesons and Light Nuclei, Bechyn, Czechoslovakia, May 27–June 1, 1985.I am grateful to L. A. Kondratyuk, M. G. Ryskin and M. I. Strikman for valuable discussions of the considered problems.     

Bounds to the differential cross-section for the processes p¯p→π+ −

Using scattering data, the integrated cross-section for p¯p^+–, and unitarity, we derive upper bounds to the differential cross-section for p¯p^{+ –}. Comparison with experimental data shows that in general the bounds are several times larger than the measured value, but that at certain points this factor is only about two or three.Presented at the Symposium on Hadron-Hadron Scattering at High Energies, Liblice, Czechoslovakia, June 16–21, 1975.I would like to thank Dr. A. K.Common for useful discussions and collaboration in the early stages of this work.     

Semiclassical theory of the scattering of π-mesons by nucleons in the case of strong coupling. Part I

The scattering cross section of the reaction + N N + , + N N + is calculated by the semiclassical method. It is predicted that the latter reaction occurs through N** resonance. The mass of this resonance, the spin, and isospin are found. The zero approximation with respect to the coupling constant between the - and -mesons is considered.     

A finite size analysis of the structure factor in the antiferromagnetic Heisenberg (AFH) model

From a finite size analysis we extract the structure factorS(p, N=) of the one dimensional AFH-model in the groundstate: The gross structure is well described byL (p) = –ln(1– ^p ). The fine structure which only contributes a few percent reveals a pronounced non-linear behavior inL(p) with a maximum atp=0.20 and a minimum atp=0.82.     

Calculation of Ratios of μ and π Masses to the e Mass for a Simplified Model with a Square-Well Potential

In the present paper, the feasibility of constructing a model of elementary and particles based on the Poincaré model of the electron [1] is examined with allowance for schemes of particle decay. The muon and pion in stopped states are considered as spherical resonators for virtual neutrino quanta excited inside an elastic lepton shell; the number of these quanta is determined by the scheme of the corresponding particle decay. In the model, the muon differs from the electron by two additional quanta of the neutrino field. The e, , and masses are calculated with the help of a single parameter. The ratio of and e masses is about (6c/e ²)^2/3, and the ratio of ° and e masses is (3/2)^2/3. The calculated e, , and ° masses are in the 0.547:105.71:134.963 ratios, which is in good agreement with the available experimental data. The calculated electromagnetic radius of the charged pion (±) = 0.5f is close to that calculated from the experimental data. The neutrino mass _e is found to be m( _e ) 0.02 eV.     

Weakly model dependent pion form factor with physically interpretable parameters

Conclusion We have constructed the pion form factor model satisfying fundamental principles, providing some freedom for the asymptotic behaviour and depending only on the adjustable parameters with a definite physical interpretation. The explicit incorporation of the pion form factor left-hand cut from the second Riemann sheet into a model was carried out for the first time. As a result we have described (contrary to the previous attempts [18, 19]) the pion form factor data from the range of momenta –9·770 GeV² t 9·579 GeV² and data on theP-wave isovector phase shift in the elastic region simultaneously with the adjustable parameters acquiring very reasonable values. The asymptotic behaviour was enforced by the data to be consistent with the naive quark model prediction. The calculated values of the pion charge radius as well as theP-wave isovector scattering length coincide with the world averaged values. With regard to these positive features of our pion form factor model it can be employed for the reliable calculation (via unitarity) of theP-wave isovector scattering partial amplitude outside the physical region, which could be useful in a saturation of various sum rules in scattering physics.     

Study of the πn → π<Superscript>{-}</Superscript>π<Superscript>{-}</Superscript>p reaction at 430 MeV energy

The total cross-section for the ^{-}n ^{-}{-}p reaction has been measured at a pion kinetic energy of 430MeV in a deuterium bubble chamber. The cross-section value was found to be 0.197±0.016mb that is much smaller than the predictions of the chiral perturbation theory. The differential spectra are compared with calculations made in the framework of the model of Bolokhov et al. 13.60.LeMeson production [:AND:]13.85.LgTotal cross-sections     

A study in the coupled πNN-NN system and the question of dinucleon resonances

Conclusions We have presented soms of our preliminary results on the coupled NN-NN problem. The overall result obtained so far is rather encouraging and we are currently making the model more sophisticated in order to be able to make more quantitative arguments which may hopefully serve somehow to clarify the dibaryon resonance problems. To end we would like to emphasize that since all the channels (viz.d d, d NN, NN NN, etc.) are unitarily coupled, one cannot arbitrarily change some input parameters to attain a better fit in one of the channels alone: all the channels are closely linked, which serves as a very strong constraint to the input. In near future we wish to extend our model to calculate processes with three-body final statesWork supported in part by Bundesministerium für Forschung und Technologie.Invited talk at the symposium Mesons and Light Nuclei, Liblice, Czechoslovakia, June 1981.I am grateful to my collaborators, Y. Avishai, C. Fayard, G. -H. Lamot and S. Nahabetian for numerous discussions.     

An interpretation of the conditions for the existence of Shockley surface states

A study is made of the Shockley surface states in a linear chain of equal atoms, joined by alternately strong bonds. If the simple MO LCAO method is used, which considers the exchange integrals between nearest neighbours and next nearest neighbours, we get the surface states for a semi-infinite chain if the stronger bond is interrupted. The connection between Shockley and Tamm surface states is shown and the hypothesis is put forward that the condition for the existence of Shockley surface states has a generally simple physical interpretation, the validity of which is proved on the models of a semi-infinite crystal studied up to now.

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