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1.
Conclusions On the basis of the rates of their acid hydrolysis, their optical activities, and their IR spectra, it has been established that the glycosides ofAesculus hippocastanum L. are (SK-1) 3--L-arabofuranosyloxy-5,7,4-trihydroxyflavone, (SK-2) 3--L-rhamnofuranosyloxy-5,7,4-trihydroxyflavone, (SK-3) 3--L-arabofuranosyloxy-5,7,3,4-tetrahydroxyflavone, and (SK-4) 3--L-rhamnofuranosyloxy-5,7,3,4-tetrahydroxyflavone.The glycoside SK-3 is identical with avicularin isolated from the leaves ofPsidium quajava [5]. The complete structures of the other three glycosides have been established for the first time.Khimiya Prirodnykh Soedinenii, Vol. 5, No. 1, pp. 5–7, 1969 相似文献
2.
E. V. Levina S. N. Fedorov V. A. Stonik P. V. Andriyashchenko A. I. Kalinovskii V. V. Isakov 《Chemistry of Natural Compounds》1990,26(4):408-411
The previously described cholest-5-ene-3,4,21-triol 3-(sodium sulfate) has been obtained from extracts of the Far Eastern ophiuroidOphiura leptoctenia. Two new sulfated steroid polyols have been isolated from the ophiuroidO.sarsi; cholest-5-ene-3,4,21-triol 3,21-di(sodium sulfate) and cholest-5-ene-2,3,21-triol tri(sodium sulfate). The new polyol 4-acetoxycholest-5-ene-3,21-diol has been identified among the products of the desulfation of this ophiuroid.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Branch, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 483–487, July–August, 1990. 相似文献
3.
I. F. Makarevich 《Chemistry of Natural Compounds》1973,6(5):582-586
Conclusions Two additional cardiac glycosides, glucoerysimoside and glucoerysimosol, have been isolated from the seeds ofCheiranthus allioni Hort. Glucoerysimoside is strophanthidin 3-[O--D-digitoxopyranosyl-(4 1)-O--D-glucopyranosyl-(4 1)--D-glucopyranoside]. Glucoerysimosol is a new cardenolide having the same carbohydrate component, but its aglycone is strophanthidol. From these glycosides a new trisaccharide has been obtained which has been characterized as 4-O--cellobiosyl-D-digitoxose.Khar'kov Scientific-Research Institute of Pharmaceutical Chemistry. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 566–571, September–October, 1970. 相似文献
4.
Chunhai Yang 《Mikrochimica acta》2004,148(1-2):87-92
A single-wall carbon nanotubes (SWNT) film coated glassy carbon electrode (GCE) was fabricated for the direct determination of 4-nitrophenol (4-NP). The electrochemical behaviors of 4-NP at the SWNT-film coated GCE were examined. In 0.1M phosphate buffer with a pH of 5.0, 4-NP yields a very sensitive and well-defined reduction peak at the SWNT-modified GCE. It is found that the SWNT film exhibits obvious electrocatalytic activity towards the reduction of 4-NP since it not only increases the reduction peak current but also lowers the reduction overpotential. Based on this, an electrochemical method was proposed for the direct determination of 4-NP. The reduction peak current varies linearly with the concentration of 4-NP ranging from 1×10–8 to 5×10–6M, and the detection limit is 2.5×10–9M after 3min of open-circuit accumulation. The relative standard deviation at 2×10–7M 4-NP was about 6% (n=10), suggesting excellent reproducibility. This new method was successfully employed to determine 4-NP in several lake water samples. 相似文献
5.
In addition to -sitosterol, cyclosieversigenin, and -sitosterol -D-glucopyranoside, the roots of the plantAstragalus amarus Pall. (Leguminosae) have yielded a new triterpene glycoside of the cycloartane series — cycloaraloside A, which has the structure of 2OR,24S-epoxycycloartane-3,6,16,25-tetraol 3-O--D-glucopyranoside.Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 806–809, November–December, 1989. 相似文献
6.
A new triterpene glycoside has been isolated from the roots ofMedicago sativa L. (family Fabaceae) — medicoside J, and its structure has been established as a medicagenic acid 3-O--D-glucopyranoside 28-O-[O--D-xylopyranosyl-(1 4)-O--L-rhamnopyranosyl-(1 2)--L-arabinopyranoside].Institute of the Chemistry of Plant Substances of the Uzbek Academy of Sciences. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 610–613, September–December, 1986. 相似文献
7.
É. Kh. Bakirov S. S. Yusupova A. Sattikulov A. D. Vdovin V. M. Malikov M. R. Yagudaev 《Chemistry of Natural Compounds》1988,23(4):429-435
The new flavanon lehmannin (I) has been isolated from the roots ofAmmothamnus lehmannii Bunge. On the basis of chemical transformations and with the aid of physicochemical characteristics it has been established that compound (I) has the structure of 2,4,7-trihydroxy-8-(2-isopropenyl-5-methylhex-4-enyl)flavanone. The alkaline cleavage of lehmannin gave ammothamnidin (V). The structure proposed previously for the chalcone ammothamnidin has been corrected. It has been shown that it has the structure of 2,2-4,4-tetrahydroxy-3-(2-isopropenyl-5-methylhex-4- enyl)chalcone. A comparative study of the13C NMR spectra of a number of flavanones has revealed an empirical law permitting the prediction of the presence or absence of substituents (OH and OCH3) at C-2 from the value of the chemical shift of the signal of the C-2 carbon atom.Institute of the Chemistry of Plant Substances of the Uzbek SSR Academy of Sciences, Tashkent. I. P. Pavlov Samarkand State Medical Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 516–524, July–August, 1987. 相似文献
8.
M. I. Isaev 《Chemistry of Natural Compounds》1993,28(5):461-463
The structure of a new cycloartane glycoside, cycloaraloside B, isolated from the roots ofAstragalus amarus Pall. (Leguminosae) has been established on the basis of chemical transformations and spectral characteristics: it is 20R,24S-epoxycycloartane-3,6,16,25-tetraol 3-O-[O--L-rhamnopyranosyl-(12)-(6-O-acetyl--D-glucopyranoside)].Institute of Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 528–531, September–October, 1992. 相似文献
9.
A. A. Savina M. E. Perel'son A. I. Ban'kovskii G. K. Nikonov 《Chemistry of Natural Compounds》1973,6(4):419-422
Conclusions From the roots ofSeseli sessiliflorum Schrenk a new chromone has been isolated for which the structure of 2,2-dimethyl-3-(3-methylthioacryloyloxy)-3,4-dihydropyrano-5,6:6,7-(5-hydroxy-2-methyl) chromone has been proposed. It is the first representative of this group of natural compounds containing sulfur.Khimiya Prirodnykh Soedinenii, Vol. 6, No. 4, pp. 412–415, 1970 相似文献
10.
Conclusions The complete structure of the new C-glycoside, cratenacin, isolated from the leaves ofCrataegus curvisepala (Lindm.) has been determined by chemical and spectral methods; it is 5,7,4-trihydroxyflavone 8-C-[6-O-acetyl--D-glucopyranosyl(4 1)--L-rhamnopyranoside].Khimiya Prirodnykh Soedinenii, Vol. 5, No. 4, pp. 234–236, 1969 相似文献
11.
Summary 1. The synthesis of L-(+)--oleoyl--linoleoyl--glycerylphosphorylethanolamine has been effected.2. During the investigations the following substances were isolated and characterized: L--oleoyl--glycerylphosphoryl-N-phthaloylethanolamine and L---linoleoyl--glycerylphosphoryl-N-phthanoylethanolamine.Khimiya Prirodnykh Soedinenii, Vol. 2, No. 2, pp. 80–83, 1966 相似文献
12.
G. A. Ravdel' N. A. Krit V. A. Oladkina L. A. Shchukina M. M. Shemyakin 《Russian Chemical Bulletin》1965,14(11):1954-1957
Summary Depsipeptides containing -hydroxy -amino acid residues as hydroxy-acid component were synthesized.Communication 11 of the series -Substituted -Amino Acids.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 1987–1992, November 1965 相似文献
13.
24-Ethylcholesta-7, 22E-diene-3,5,6-triol — a natural trihydroxysteroid from the bryozoanMyriapora truncata — has been synthesized from stigmasterol.Institute of Bioorganic Chemistry, Academy of Sciences of the Belorussian SSR, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 664–669, September–October, 1989. 相似文献
14.
The — complexes of metal tetraphenylporphinates with benzene, toluene, and xylenes were characterized by means of thermogravimetry. The ability of metalloporphyrins to form — complexes with certain -donor molecules depends largely on the -acceptor capacity of the macroheterocycle, and on the peculiarities of the metal—porphyrin coordinative linkage. Stoichiometry, energy parameters, and thermal stability of the - complexes of metalloporphyrins with various aromatic ligands are determined to a great extent by the molecular structure of solvents.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp.850–853, May, 1993. 相似文献
15.
Summary Four cardiac glycosides have been isolated from the leaves ofErysimum crepidifolium Rchb. Three of them have been identified as erysimin, erysimoside, and erycordin. The fourth glycoside, which has been named glucostrophalloside, is new, and it consists of strophanthidin 3-O-[4-O--D-glucopyranosyl--D-allomethylopyranoside].Khar'kov Scientific-Research Institute of Pharmaceutical Chemistry. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 611–614, September–October, 1974. 相似文献
16.
V. I. Kalinin S. A. Avilov A. I. Kalinovskii V. A. Stonik Yu. M. Mil'grom Ya. V. Rashkes 《Chemistry of Natural Compounds》1993,28(6):600-603
A minor glycoside — cucumarioside G4 (I) — has been isolated from the total triterpeneglycosides of the holothurianEupentacta fraudatrix, and its structure has been determined by physical and chemical methods as 16-acetoxyholosta-7,23E-diene-3, 25-diol 3-O-(3-O-methyl--D-xylopyranosyl)-(13)-O--D-glucopyranosyl-(14)-O--D-quinovopyransoyl-(12)-(4-O-(sodium sulfato)--D-xylopyranoside)].Deceased.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok. Institute of Chemistry of Plant Substances, Uzbek Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 691–694, November–December, 1992. 相似文献
17.
Summary The structures of the triterpene glycosides leontiside A and leontoside B fromLeontice eversmannii have been established. It has been shown that the leontoside A is hederagenin 3--L-arabopyranoside and leontoside B is hederagenin 3--L-arabopyranosido-4--D-glucopyranoside.Khimiya Prirodnykh Soedinenii, Vol. 3, No. 2, pp. 101–105, 1967 相似文献
18.
L. I. Deryugina 《Chemistry of Natural Compounds》1968,2(5):256-258
Summary 1. A new isoflavone glycoside, astroside, has been isolated fromAstragalus austriacus L.2. Astroside has been characterized as biochanin A-7--D-glucopyranoside, or 5-hydroxy-4-methoxyisoflavone 7--D-glucopyranoside.Khimiya Prirodnykh Soedinenii, Vol. 2, No. 5, pp. 315–319, 1966 相似文献
19.
Conclusions Syntheses are reported for ,-dithioalkyldivinyl ketones, which react with ammonia to give -amino--thioalkyldivinyl ketones.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2414–2415, October, 1988.The authors thank A. M. Kachurin for assistance in taking the spectra. 相似文献
20.
A. É. Timbekova A. L. Vereschagin A. A. Semenov N. K. Abubakirov 《Chemistry of Natural Compounds》1990,26(2):178-183
A new triterpene pentaglycoside — medicoside L — has been isolated from the roots ofMedicago sativa L. (Leguminosae). It has the structure of medicagenic acid 28-O--D-glucopyranoside 3-O-{[O--D-glucopyranosyl-(1 2)][O--L-rhamnopyranosyl-(1 3)]-O--D-glucopyranosyl-(1 2)}--D-glucopyranoside.Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 221–228, March–April, 1990. 相似文献