Rheological aging and rejuvenation in solid friction contacts

We study the low-velocity (0.1-100 μm s^-1) frictional properties of interfaces between a rough glassy polymer and smooth silanized glass, a configuration which gives direct access to the rheology of the adhesive joints in which shear localizes. We show that these joints exhibit the full phenomenology expected for confined quasi-2D soft glasses: they strengthen logarithmically when aging at rest, and weaken (rejuvenate) when sliding. Rejuvenation is found to saturate at large velocities. Moreover, aging at rest is shown to be strongly accelerated when waiting under finite stress below the static threshold. Received 20 February 2002 and Received in final form 16 May 2002     

Non-Amontons behavior of friction in single contacts

We report on the frictional properties of a single contact between a glassy polymer lens and a flat silica substrate covered either by a disordered or by a self-assembled alkylsilane monolayer. We find that, in contrast to a widely spread belief, the Amontons proportionality between frictional and normal stresses does not hold. Besides, we observe that the velocity dependence of the sliding stress is strongly sensitive to the structure of the silane layer. Analysis of the frictional rheology observed on both disordered and self-assembled monolayers suggests that dissipation is controlled by the plasticity of a glass-like interfacial layer in the former case, and by pinning of polymer chains on the substrate in the latter one.     

Nonlinear dynamics of mechanical systems with friction contacts: Coupled static and dynamic Multi-Harmonic Balance Method and multiple solutions

Real applications in structural mechanics where the dynamic behavior is linear are rare. Usually, structures are made of components assembled together by means of joints whose behavior maybe highly nonlinear. Depending on the amount of excitation, joints can dramatically change the dynamic behavior of the whole system, and the modeling of this type of constraint is therefore crucial for a correct prediction of the amount of vibration.     

Tuning of nanotube mechanical resonances by electric field pulling

We show here that field emission (FE) can be used to directly observe the vibration resonances nu(R) of carbon nanotubes (CNTs) and that the tension created by the applied field allows the tuning of these resonances by up to a factor of 10. The resonances are observable by the changes they create in the FE pattern or the emitted FE current. The tuning is shown to be linear in voltage and to follow from the basic physics of stretched strings. The method allows one to study the mechanical properties of individual multiwall carbon nanotubes within an ensemble and follow their evolution as the CNTs are modified. The tuning and detection should be useful for nanometric resonant devices.     

Contrasting friction and diffusion in molecularly thin confined films

We study, using fluorescence correlation spectroscopy, translational diffusion in molecularly thin liquids confined within a surface forces apparatus. The diffusion coefficient decreases exponentially from the edges towards the center of the Hertzian contact and further suggests the presence of a small number of distinct diffusion processes. This holds alike a crystallizable fluid (OMCTS) and a glass-former (1,2-propane diol), both of which displayed static friction. We conclude that friction, the average of an ensemble of molecules, masked massively heterogeneous molecular mobility.     

A model for the characterization of friction contacts in turbine blades

Stresses produced by the forced vibrations can lead to a significant reduction of the life of turbo engine blades. To predict the vibration amplitudes of this components an accurate dynamic analysis is necessary. The forced response calculation of these dynamic systems is strongly affected by the presence of the contact interfaces (i.e., underplatform dampers, shrouds, root joints). Different contact models are available in literature. These models make use of contact parameters, contact stiffness and friction coefficient to evaluate the damping and stiffness related to the contact interfaces. In this paper a model is proposed to characterize friction contact of non-spherical contact geometries obeying the Coulomb friction law with constant friction coefficient and constant normal load. The hysteresis curves of the oscillating tangential contact forces vs. relative tangential displacements and the dissipated energy at the contact are obtained for different contact geometries. The developed model is suitable to be implemented in numerical solvers for the calculation of the forced response of turbine blades with embedded friction contacts.     

Defects mediated diffusion in Pt/Co/Pt multilayers induced by dense electronic excitations

Present study compares the effects of 200 MeV Ag¹⁵⁺ and 100 MeV O⁷⁺ ion irradiations on the structural, interfacial mixing and magnetic properties of annealed Pt/Co/Pt layers fabricated by DC magnetron sputtering. X-ray diffraction analysis shows that ion irradiations coupled with post annealing results in the formation of the face centred tetragonal L1₀ CoPt phase. Irradiation using 200 MeV Ag¹⁵⁺ ions having higher ionizing energy transfer to the film was found to be more efficient in causing structural phase transition as compared with that using 100 MeV energy O⁷⁺ ions having lower ionizing energy transfer at similar fluence. Rutherford back scattering analysis reveals the role of defect mediated inter-atomic diffusion in tailoring the alloy composition of the film irradiated by different energetic ions. A broad magnetic switching field distribution for O⁷⁺ ion irradiated films compared to Ag¹⁵⁺ ion irradiation was evident from the magnetic measurements. The contribution of alloy composition to switching field distribution has been discussed in details. Above results showed that the electronic energy loss and fluence dependent defects, generated by irradiation, played an important role in tuning the structural, atomic diffusion and magnetic reversal properties of Pt/Co/Pt.     

Probing the microscopic structure of bound states in quantum point contacts

Using an approach that allows us to probe the electronic structure of strongly pinched-off quantum point contacts (QPCs), we provide evidence for the formation of self-consistently realized bound states (BSs) in these structures. Our approach exploits the resonant interaction between closely coupled QPCs, and demonstrates that the BSs may give rise to a robust confinement of single spins, which show clear Zeeman splitting in a magnetic field.     

Driven localized excitations in the acoustic spectrum of small nonlinear macroscopic and microscopic lattices

Both bright and dark traveling, locked, intrinsic localized modes (ILMs) have been generated with a spatially uniform driver at a frequency in the acoustic spectrum of a nonlinear micromechanical cantilever array. Complementary numerical simulations show that a minimum density of modes, hence array size, is required for the formation of such locked smoothly running excitations. Additional simulations on a small 1D antiferromagnetic spin system are used to illustrate that such uniformly driven running ILMs should be a generic feature of a nanoscale atomic lattice.     

Simultaneous formation of contacts and diffusion barriers for VLSI by rapid thermal silicidation of TiW

The formation of (Ti_xW_1–x)Si₂/(Ti_xW_1–x)N, by rapid thermal processing of Ti_xW_1–x on Si in an N₂ ambient is investigated. An activation energy of 1.7 eV is obtained for silicide formation. A distinct snow-ploughing of As atoms is observed during silicide formation whereas the interfacial B concentration decreases with increasing silicide formation temperature. The diffusion barrier properties of the (Ti_xW_1–x)Si₂/(Ti_xWi_1–x)N stack in contact with Al is investigated upon post-metal annealing. No interaction between the layers is found for temperatures as high as 475°C after 60 min. The improved thermal stability of the (Ti_xW_1–x)N layer in contact with Al is attributed to nitrogen blocking of the grain boundaries.     

Growth rates and electrical conductivity of microscopic ohmic contacts fabricated by laser chemical vapor deposition of platinum

The laser chemical vapor deposition of platinum from its bishexafluoroacetylacetonate derivative is studied with a cw argon ion laser at 458 and 514 nm. The height, the width, as well as the electrical conductivity of the deposited stripes are reported as a function of the vapor pressure of the metalorganic precurser, the laser intensity, and the writing speed.     

Combining macroscopic and microscopic diffusion studies in zeolites using NMR techniques

In this study the zero length column (ZLC) technique is extended to the case where the decay of the adsorbed phase concentration is observed directly by nuclear magnetic resonance (NMR). An adsorption-desorption apparatus compatible with a 400-MHz NMR spectrometer was developed. It operates with nitrogen or helium as the inert purge gas. The column of the adsorbent material is placed in the sensitive region of the superconducting magnet and the rf coil of the NMR spectrometer. The time scales of the adsorption and desorption processes depend on concentration, temperature and crystal shape and are found to be in the range of 1-10 min. From the desorption branch, the non-equilibrium ZLC-NMR measurements yield intracrystalline diffusion coefficients in the range of 10(-13) to 10(-11) m2/s for different alkanes in silicalite-1. These values are always found to be smaller than the values measured by pulsed field gradient NMR under equilibrium condition indicating that there must be additional transport resistance at the external surface of these silicalite-1 zeolite crystals.     

Absorption of zero Lamb waves in an elastic layer by mechanical resonators with friction

The propagation of zero Lamb waves in a plate with mechanical resonators attached to its surfaces is studied. It is shown that, in a plate that is single-mode for symmetric (antisymmetric) waves, the zero symmetric (antisymmetric) Lamb wave can be absorbed by mechanical resonators with a certain friction. The single-mode (for symmetric or antisymmetric waves) plate can be not thin compared to the wavelength of the transverse wave.     

Effects of electron correlations,dynamical screening and plasmon excitations on muon diffusion in metals

An investigation is made of the effects of electron-electron interaction on muon diffusion in metals. It is shown that electron-electron correlation plays an important role in the motion of muons. The equation-of-motion method is used to calculate the correlation function. It is shown that electron correlations effectively reduce the muon hopping rate at low temperatures. It is also shown that the effect of dynamic screening increases the hopping rate. We found that due to plasmon excitation, the hopping rate is reduced by a factor which can be as larger as one to two orders of magnitude.     

Nature of mechanical instabilities and their effect on kinetic friction

It has long been recognized that kinetic friction F(k) between two solids must be due to instabilities, sudden "pops" of certain degrees of freedom. Here, such pops are studied with a focus on boundary lubrication. The pops' characteristics and consequently the friction-velocity relationship depend qualitatively on dimensionality, commensurability, and details of the lubricant wall interaction. It is found that F(k) should be small between commensurate surfaces. F(k) is large for incommensurate surfaces, unless the lubricant's motion is confined to 1D. The effects of thermal noise are discussed and computer simulations are employed to show the relevance of the predictions to less idealized models.