Removal of low-concentration benzene in indoor air with plasma-MnO2 catalysis system

Non-thermal plasma (NTP) and combined plasma-MnO₂ catalytic (CPMC) air cleaners were tested for removal of low-concentration benzene in air. Both air cleaners were made of stainless steel needle matrix plate and used DC corona discharger. The effects of discharge power and relative humidity (RH) on benzene removal efficiency were investigated in a closed chamber. The intermediate products produced in purification processes were analyzed using gas chromatography-mass spectrometer (GC-MS). The concentrations of discharge byproducts and CO₂ selectivity produced in both processes were also compared. It was found that the benzene removal efficiency increased with discharge power in both systems; With the increase of RH in air, benzene removal efficiency firstly increased and then decreased in NTP while it gradually decreased in CPMC. For a fixed discharge power of 9 W and RH of 20% in CPMC, the conversion of benzene increased from 82.9% to 89.6%, the CO₂ selectivity increased from 38% to 80%, the concentration of O₃ decreased from 25.3 ppm to 1.3 ppm, and NO₂ formation decreased from 234 ppm to 25.7 ppm, compared with NTP.     

Experimental investigations and modelling studies of ozone producing corona discharges

The ozone generation by negative corona discharge in coaxial cylindrical system of electrodes have been studied experimentally in Ar+O₂ and N₂+O₂ mixtures. Both in argon and nitrogen mixtures with oxygen the monotonous decrease in ozone concentration [O₃] was observed at decreasing oxygen content in mixtures and the constant input energy density η. The rate coefficients for the ozone generation and ozone decomposition were obtained by fitting experimentally measured data [O₃]=f(η) with Vasiljev-Eremin formula. The calculated rate coefficient for ozone generation in N₂+O₂ mixtures at low content of oxygen (below 20%) was found considerably higher than that in Ar+O₂ mixtures. Increase in the rate coefficients for ozone generation and decomposition was observed with decreasing content of oxygen in both mixtures. The experimental results are in qualitative agreement with the simple model incorporating five main chemical processes in mechanism of ozone generation. The research was partially supported by Slovak Grant Agency under project 1/765920 The UK EPSRC (Grant GM/98944) and NATO Joint Project PST CLG 976544.     

Upconversion Based Tunable White-Light Generation in Ln:Y<Subscript>2</Subscript>O<Subscript>3</Subscript> Nanocrystalline Phosphor (Ln = Tm/Er/Yb)

We report the generation of efficient white light based on upconversion (UC) in Tm³⁺/Er³⁺/Yb³⁺:Y₂O₃ nanocrystalline phosphor synthesized by simple and cost effective solution combustion technique on 976 nm laser excitation. The calculated color coordinates (using 1931 CIE standard) for samples annealed at different temperatures vary from (0.16, 0.30) to (0.32, 0.33) with dopant concentration, annealing temperature and the pump power; thus providing a wide color tunability including the white one. White emission is observed even at a very low laser power (60 mW). The maximum upconversion efficiency obtained for white emission is 2.79% with the color coordinates (0.30, 0.32) at laser power of 420 mW which is quite close to the standard white color coordinates.     

Properties of oxide nanopowders prepared by target evaporation with a pulse-periodic co2 laser

The design and characteristics of a setup for producing metal oxide nanopowders with an output of up to 20 g/h are discussed. The grain mean size in the powders is 15 nm, and the radiation power consumption is 30—40 (W h)/g. Y₂O₃-stabilized ZrO₂ (YSZ) and Al₂O₃ + YSZ nanopowders are prepared by target evaporation with a pulse-periodic CO₂ laser, followed by vapor condensation in an air stream. The mean power, peak power, and efficiency of the pulse-periodic CO₂ laser, excited by a combined discharge, are, respectively, 1 kW, 10 kW, and ≈10%. Data for the powder specific surface, grain shape, and grain size distribution, as well as results of X-ray phase and structure analysis, are reported.     

Optical characterization of atmospheric‐pressure plasma needle

The atmospheric‐pressure plasma needle is a promising source that can be used efficiently for different industrial applications. A radio frequency (RF) (13.56 MHz) generator was used to generate a He–O₂/Ar mixture plasma. The ground‐state oxygen atomic density [O] was calculated as a function of discharge parameters by “actinometry”. The Ar‐I (2p₁ → 1s₂) line at 750 nm and the O‐I (³P → ³S) line at 844 nm were used to estimate the [O] atomic density. The rotational temperature T _R of He–O₂/Ar mixture was measured from the rotational levels of the “first negative system” (FNS) by using the “Boltzmann plot”. The effect of discharge parameters on the atomic oxygen density [O] and the gas temperature was monitored. These results show that [O] density increases with RF power and O₂ concentration, but decreases with the gas flow rate. Whereas the gas temperature increases with increase in the input RF power, it decreases with increase in the gas flow rate and O₂ concentration in the mixture. Since the [O] atomic density contributes to plasma‐based biomedical applications, the proposed optimum conditions for plasma‐based decontamination of heat‐sensitive materials in the present study are 0.6% oxygen, 500 sccm flow rate, and 26 W RF power.     

The effect of CCl2F2 on ozone generation from oxygen

The production of ozone by negative corona discharge from O₂ + CCl₂F₂ (CFC12) mixtures is experimentally investigated at two pressures of gaseous mixture of 800 and 900 mbar in the CCl₂F₂ concentration range of (0–7)%. The efficiency of ozone generation is remarkably reduced with increasing content of CCl₂F₂ in the mixture with oxygen. The effect is more apparent at lower pressure of gaseous mixture. In order to identify the most likely process responsible for the inhibition of ozone production a discussion of the chemical kinetics of various processes is presented. This research was carried out with financial support from the Slovak Grant Agency for the project under the No. 1/5184/98 and the Action Austria-Slovakia project under the number 25s19.     

Ozone generation in oxygen-fed wire-to-cylinder ozonizer: effect of CH2Cl2, CHCl3 and CCl4 diluents

The inhibition effect of methylene chloride CH₂Cl₂, chloroform CHCl₃ and carbon tetrachloride CCl₄ on the ozone generation process from oxygen by negative corona discharge was experimentally investigated. The experiments were performed in a system of coaxial cylindrical electrodes at total gas pressure of 900 mbar and ambient temperature of gaseous mixtures. The rate of ozone generation as well as ozone concentration apparently decreases with a rising number of substituted chlorine atoms in the methane molecule at constant specific energy consumption dissipated in the discharge and at constant concentration of gaseous impurities in oxygen. In addition to experimental results, the paper presents theoretical considerations aimed at identifying the main process responsible for inhibition of ozone generation. The consumption of considerable fraction of oxygen atoms by CH _x Cl _y–1 radicals formed in discharge, is likely the most important mechanism responsible for the deleterious effect of such compounds on the efficiency of ozone production.     

Detection of oxygen atoms in a high pressure surfatron microwave discharge via two-photon four-wave mixing

3 P_J) oxygen atoms are detected in a high pressure surface wave discharge driven at 2.45 GHz via two-photon resonant degenerate four-wave mixing spectroscopy (TP-DFWM) in the forward folded BOX configuration. The nonlinear optical signal provides a direct measure of the relative oxygen atom concentration with high spatial resolution inside the discharge up to pressures of 1 bar and without distortions due to linear absorption or saturation effects. The axial distribution of oxygen atom concentration is observed to depend sensitively on total pressure and gas flux. For total gas pressures up to 600 mbar both in case of a mixture of 10% O₂/He and 10% O₂/Ar the concentration of oxygen atoms increases linearly with pressure. At higher pressures an increase with larger slope is observed for 10% O₂/Ar, while the concentration remains constant for 10% O₂/He. This is interpreted by an increase of the three-body recombination rate in O₂/He mixtures. Received: 26 July 1996/Revised version: 15 November 1996     

Ozone Synthesis in an Electric Discharge between Ferroelectric Electrodes at Atmospheric Pressure

This paper deals with studies of the ozone synthesis by means of an ac discharge (50 Hz) between two parallel ferroelectric plates under radial oxygen flow conditions at atmospheric pressure. Bariumtitanate based ceramic with ? ∽ 6000 was used as ferroelectric material. An important feature of this kind of the discharge is the fact that the operating voltage is well one order of magnitude smaller than that of the silent discharge usually used for the O₃ production. Examples of I — U characteristics are discussed. The absorption of light at 253.7 nm wavelength was used to determine [O₃] within and downstream of the discharge as function of the O₂ flow rate. These results have been examined in terms of a kinetic investigation of the O₃ synthesis based on the so-called plug flow model including the particle balance equations of electrons, O atoms, O₂ and O₃ molecules, respectively. Thus, the measured decrease of [O₃] with increasing flow rate can be explained by the increasing influence of the loss of O₃ by convection on the particle balance of O₃. Furthermore it is shown that inside the plasma reactor [O₃] increases with the radius r. Therefore the data for measured spatial average of [O₃] inside the discharge are lower than that of [O₃] in the flowing afterglow. The last values are identical with that of [O₃] at the exit of the discharge.     

Continuous-wave Nd:GdVO<Subscript>4</Subscript>/LBO laser at 541.5 nm under diode pumping into the emitting level

We report a green laser at 541.5 nm generation by intracavity frequency doubling of a continuous wave (cw) laser operation of a 1083 nm Nd:GdVO₄ laser under 880 nm diode pumping into the emitting level ⁴ F _3/2. A LiB₃O₅ (LBO) crystal, cut for critical type I phase matching at room temperature is used for second harmonic generation of the laser. At an incident pump power of 17.8 W, as high as 2.52 W of cw output power at 541.5 nm is achieved. The optical-to-optical conversion efficiency is up to 14.2%, and the fluctuation of the green output power was better than 3.6% in the given 30 min.     

Plasma-chemical processes in the active medium of a CO laser

The concentrations of plasma-chemical products (C, O, CO₂, C₂, and C₃O₂) were measured under conditions typical of the active medium of an electrical discharge CO laser. The dependence of the concentration of C₃O₂ molecules on the experimental conditions was studied. A reaction scheme responsible for the concentration of C₃O₂ molecules formed in the discharge was proposed.     

Optical characteristics of cylindrical exciplex and excimer lamps excited by microwave radiation

The object of investigation is the optical characteristics of Br₂, Cl₂, XeBr, and XeCl excilamps excited by microwave radiation. The power of the microwave discharge is determined from a pressure jump in the bulb of the lamp. Conditions for the effective generation of XeCl* and XeBr* exciplexes in cylindrical lamps are found. The efficiency of generation of these exciplexes equals 7.2 and 7.8%, respectively.     

Relaxing Phenomena in Negative Corona Discharge: New Aspects

Two theories, explaining the time dependence of the negative corona discharge current in air, are confronted with new experimental results. The influence of the ozone concentration on the discharge current was experimentally confirmed in dry air and in mixtures of nitrogen with oxygen. Assuming that only the dissociative electron attachment to ozone molecule is a process being responsible for a reduction of the electron component in the total mean discharge current, the mean value of the electron attachment rate constant k = (3 - 5.5) × 10^?9 cm^?3 s^?1 was derived from the measured dependence of the discharge current on the ozone concentration. The calculated value of the rate constant k corresponds to the dissociative attachment of electron to ozone molecule via process e + O₃ → products (O^? or O^?₂ negative ions).     

Reduced Graphene Oxide decorated with Manganese Cobalt Oxide as Multifunctional Material for Mechanically Rechargeable and Hybrid Zinc–Air Batteries

Spinel MnCo₂O₄ nanoparticles on nitrogen‐doped reduced graphene oxide (MnCo₂O₄/NGr) are synthesized for advanced zinc–air batteries with remarkable cyclic efficiency and stability. The synthesized MnCo₂O₄/NGr exhibits good oxygen‐reduction reaction (ORR) activity with half‐wave potential E _1/2 of 0.85 V (vs reversible hydrogen electrode (RHE)), comparable to commercial Pt/C with E _1/2 of 0.88 V (vs RHE) along with superior oxygen electrode activity ΔE = 0.91 V for the ORR/OER (oxygen‐evolution reaction) in alkaline media. Durability tests confirm that MnCo₂O₄/NGr is more stable than Pt/C in alkaline environment. MnCo₂O₄/NGr functions with stable discharge profile of 1.2 V at 20 mA cm^?2, large discharge capacity of 707 mAh g^?1_Zn at 40 mA cm^?2 and a high energy density of 813 Wh kg^?1_Zn in a mechanically rechargeable zinc–air battery. The electrically rechargeable MnCo₂O₄/NGr zinc–air battery displays hybrid behavior with both Faradaic and oxygen redox charge–discharge characteristics, operating at higher voltage and providing higher power density and excellent cyclic efficiency of 86% for over 100 cycles compared to Pt/C with efficiency of around 60%. Moreover, hybrid zinc–air battery operates with a stable and energy efficient profile at different current densities.     

Compact high conversion efficiency Nd:YAG/LBO green laser using unstable V cavity

We demonstrated a 36.9 W green laser with an intra-cavity second harmonic generation. A compact unstable V type cavity was adopted to compress the whole cavity configuration. The type I phase-matching LiB₃O₅ was used as the nonlinear crystal in the second harmonic generation. The 36.9 W average power and 38 ns pulse width of 532 nm green laser was obtained at a repetition rate of 10.3 kHz, corresponding to a peak power of 94 kW. The optical to optical conversion efficiency from diode to green and from IR to green laser was about 19.8 and 82%, the whole cavity length is about 300 mm. To the best of our knowledge, this is the shortest cavity configuration of side pump green system with output power higher than 30 W and IR to green conversion efficiency larger than 80%. The output fluctuation of this system was less than 3% in 2 h.     

Continuous wave Nd:LuVO<Subscript>4</Subscript>-LBO blue laser under direct 888 nm diode laser pumping

We report the efficient blue laser at 458 nm generation by intracavity frequency doubling of a continuous wave (CW) laser operation of a diode pumped Nd:LuVO₄ laser on the ⁴ F _3/2 → ⁴ I _9/2 transition at 916 nm. An LiB₃O₅ (LBO) crystal, cut for critical type I phase matching at room temperature is used for second harmonic generation of the laser. At an incident pump power of 18.2 W, as high as 1.73 W of continuous wave (CW) output power at 458 nm is achieved. The optical-to-optical conversion efficiency is up to 9.5%, and the fluctuation of the red output power was better than 3.5% in the given 30 min.     

5.3 W deep-blue light generation by intra-cavity frequency doubling of Nd:GdVO4

We report the efficient compacted deep-blue laser at 456 nm generation by intra-cavity frequency doubling of a continuous-wave (cw) laser operation of a diode-pumped Nd:GdVO₄ laser on the ⁴ F _3/2→⁴ I _9/2 transition at 912 nm. The different long LiB₃O₅ (LBO) crystals, cut for critical type I phase matching at room temperature, are used for second harmonic generation (shg) of the laser. At an incident pump power of 30 W, up to 5.3 W of cw output power at 456 nm is achieved with 15-mm-long LBO (3.8 W with 10 mm-long LBO). The conversion efficiency is 17.7% from pump diode input to second harmonic wave output.PACS 42.70.Hj; 42.55.Xi; 42.65.Ky     

High power nano-LiMn2O4 cathode materials with high-rate pulse discharge capability for lithium-ion batteries

Nano-LiMn 2 O 4 cathode materials with nano-sized particles are synthesized via a citric acid assisted sol-gel route.The structure,the morphology and the electrochemical properties of the nano-LiMn 2 O 4 are investigated.Compared with the micro-sized LiMn 2 O 4,the nano-LiMn 2 O 4 possesses a high initial capacity (120 mAh/g) at a discharge rate of 0.2 C (29.6 mA/g).The nano-LiMn 2 O 4 also has a good high-rate discharge capability,retaining 91% of its capacity at a discharge rate of 10 C and 73% at a discharge rate of 40 C.In particular,the nano-LiMn 2 O 4 shows an excellent high-rate pulse discharge capability.The cut-off voltage at the end of 50-ms pulse discharge with a discharge rate of 80 C is above 3.40 V,and the voltage returns to over 4.10 V after the pulse discharge.These results show that the prepared nano-LiMn 2 O 4 could be a potential cathode material for the power sources with the capability to deliver very high-rate pulse currents.     

The role of electrolyte in governing the performance of protonic solid state battery

The solid-state proton conductor, P₂O₅.5H₂O, is found very difficult to handle due to presence of a very high content of moisture and corrosive nature. The addition of Al₂O₃ and SiO₂ into P₂O₅.5H₂O, forming composite electrolytes, obviates said drawback. The Zn + ZnSO₄ used as an anode to prepare cells with different cathode viz. I₂, MnO₂, PbO₂, and V₆O₁₃ characterized under different conditions. Open circuit voltage, discharge current and discharge time, on load voltage, discharge capacity, power density, and energy density are evaluated from discharge properties. Protonically conducting composite 70(P₂O₅.5H₂O)/30[(92SiO₂)/08(Al₂O₃)] is found to be the optimum combination with the optimized 50Zn/50ZnSO₄ as anode and 40MnO₂/60 graphite as cathode from secondary battery view point. Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006     

Conversion of nitrogen oxides in N2:O2:CO2 and N2:O2:CO2:NO2 mixtures subjected to a dc corona discharge

This paper concerns the influence of a direct current (dc) corona discharge on production and reduction of NO, NO₂ and N₂O in N₂:O₂:CO₂ and N₂:O₂:CO₂:NO₂ mixtures. The corona discharge was generated in a needle-to-plate reactor. The positively polarized electrode consisted of 7 needles. The grounded electrode was a stainless steel plate. The gas flow rate through the reactor was varied from 28 to 110 cm³/s. The time-averaged discharge current ranged from 0 to 6 mA. It was found that in the N₂:O₂:CO₂ mixture the corona discharge produced NO, NO₂ and N₂O. In the N₂:O₂:CO₂:NO₂ mixture the reduction of NO₂ was between 6–56%, depending on the concentration of O₂, gas flow rate and corona discharge current. The NO₂ reduction was accompanied by production of NO and N₂O. The results show that efficient reduction of nitrogen oxides by a corona discharge cannot be expected in the mixtures containing N₂ and O₂ if reducing additives are not employed.