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1.
Summary The titration of ferrous iron in presence of fluoride ions in acid medium gives fleeting end points and erroneous results. A method is deviced to overcome this difficulty by oxidising the ferrous with an excess of KMnO4 in alkaline medium. After mixing the reactants the excess of KMnO4 is reduced by an excess of Hg2 2+ ions in presence of H2SO4 and fluoride. The remaining mercurous is then titrated with standard KMnO4 solution.Part III: Issa, I. M., and M. Hamdy: Z. analyt. Chem. 174, 418 (1960).  相似文献   

2.
Summary Quadrivalent selenium can be determined with fair accuracy by mixing with an excess of KMnO4 in the presence of 25–75 ml of 2% NaF solution and 4–7 ml of 9 N sulfuric acid. After leaving the reaction mixture for 10–30 minutes the excess KMnO4 is estimated by one of the following procedures: A) Titration of the excess KMnO4 with monovalent mercury, B) Adding an excess of Hg2 2+ solution to react with the excess KMnO4 followed by titrating the excess mercurous with KMnO4 solution.Part I: Issa, I. M., and M. Hamdy, Z. analyt. Chem. 172, 94 (1980).  相似文献   

3.
Summary Manganate solutions prepared by the reduction of permanganate with formic acid in 1 M NaOH are fairly stable in a concentration of 0.015 M in presence of 1 M NaOH. They can be titrated successfuly with arsenite in the presence of telluric acid but not in its absence owing to the sluggishness of the reaction. Titration of arsenite with manganate yields always lower results deviating by 0.77% from the theoretical values in presence of telluric acid and 0.1–0.2 M NaOH. Much earlier end points with errors amounting to – 17 or – 38% are obtained in the absence of telluric acid.This work was started during 1957. Since that time the reactions of manganate with arsenite, tellurite, bivalent manganese and hydrogen peroxide were studied in our laboratory. While this work was prepared for publication den Boef et al. published their first investigation in the same line in 1959.  相似文献   

4.
Summary Trivalent chromium and quadrivalent vanadium can be determined with fair accuracy by a method consisting in mixing either with an excess of KMnO4 in the presence of 0.3 to 1.8 M alkali hydroxide. After leaving the mixture for 5 min, the solution is acidified with sulphuric acid and mixed with 50 to 75 ml of 2% NaF solution. An excess of monovalent mercury Hg2 2+ solution is then added, the solution heated to 40° C and then titrated with KMnO4 solution in the presence of Cu2+ ions to conceal the pink manganic fluoride colour.Part II: Issa, I. M., and M. Hamdy: Z. analyt. Chem. 172, 162 (1960).  相似文献   

5.
The complexation reaction between Tl+, Ag+ and Pb2+ cations with 2,6-di(furyl-2yl)-4-(4-methoxy phenyl)pyridine as a new synthesis ligand in acetonitrile (ACN)–H2O and methanol (MeOH)–H2O binary solutions has been studied at different temperatures using conductometric method. The conductometric data show that the stoichiometry of the complexes is 1: 1 [M: L] and the stability constant of complexes changes with the binary solutions identity. Also, the structure of the resulting 1: 1 complexes was optimized using the LanL2dz basis set at the B3LYP level of theory using GAUSSIAN03 software. The results show that the change of logKf for (DFMP.Pb)2+ and (DFMP.Ag)+ complexes with the mole ratio of acetonitrile and for (DFMP.Ag)+ and (DFMP.Tl)+ complexes with the mole ratio of methanol have a linear behavior, while the change of logKf of (DFMP.Tl)+complex in ACN–H2O binary solutions (with a minimum in XACN = 0.5) and (DFMP.Ag)+ complex in MeOH–H2O binary solutions (with a minimum in XMeOH = 0.75) show a non-linear behavior. The selectivity order of DFMP ligand for these cations in mol % CAN = 25 and 75 obtain Tl+ > Pb2+ > Ag+ but in mol % CAN = 50, the selectivity order observe Pb2+ > Tl+ > Ag+. Also, this selectivity sequence of DFMP in MeOH–H2O (mol % MeOH = 75 and 100) and (mol % MeOH = 50) is obtained Pb2+ > Ag+ and Tl+ > Ag+ > Pb2+ respectively. The values of thermodynamic parameters show that these values are influenced by the nature and the composition of binary solution. In all cases, the resulting complexes are enthalpy stabilized and entropy destabilized. The TΔSC° versus ΔHC° plot of all obtained thermodynamic data shows a fairly good linear correlation which indicates the existence of enthalpy-entropy compensation in the complexation reactions.  相似文献   

6.
Zusammenfassung Am Beispiel von Silberhalogenidfällungen werden Möglichkeiten aufgezeigt, die adsorptive Mitfällung von Spurenelementen durch Konkurrenzreaktionen zu beeinflussen.Entgegen älteren Literaturangaben wurde eine Verringerung der Spurenadsorption durch Aciditätserhöhung bis zu 7 M salpetersauren Lösungen nicht beobachtet.Die von Silberhalogenid-Niederschlägen in Gegenwart überschüssigen Halogenids normalerweise weitgehend adsorbierten Kationenspuren Bi3+, Cd2+, Hg+, Pb2+, Pd2+, Tl+ und Tl3+ werden dann nicht mitgefällt, wenn sie bei der Matrixfällung in genügend stabile undissoziierte Moleküle oder in Komplexanionen übergeführt werden. Als Komplexbildner wirkt bei Cd2+, Hg2+, Pd2+, Tl+ und Tl3+ schon das im Überschuß vorhandene Bromid, während überschüssiges Jodid die Elemente Bi3+, Cd2+, Hg2+ und Pd2+ komplexiert. Mit Ausnahme von Tl+ können alle diese Ionen in neutraler Lösung auch mit ÄDTA maskiert und in Lösung gehalten werden, wobei die bekannte pH-Funktion der Komplexbildungskonstanten eine gezielte Selektivierung der Spurenanreicherung möglich macht. Solange die Probelösung bei der Fällungsreaktion noch Silber im Überschuß enthält, werden die ÄDTA-Komplexe zahlreicher Kationen zunächst adsorptiv mitgefällt, nach Überschreiten des Äquivalenzpunktes jedoch wieder desorbiert.Durch Belegen der aktiven Oberfläche der Silberhalogenid-Mederschläge mit stark adsorbierbaren Ionen kann die Mitfällung der übrigen Elemente verhindert werden. Die Untersuchungen ergaben die folgende Reihe in der Stärke der Adsorption von Kationen an AgCl: Tl+>Pb2+>(Hg2+; Pd2+)>Tl3+>Bi3+>Cd2+.
Enrichment of trace elements by precipitation of the main componentIII. Investigations of the influence on trace adsorption at silver halogenide precipitates
The co-precipitation of trace elements by adsorption can be influenced by competetive reactions. This is demonstrated with silver halogenide precipitations. Opposed to former literature a diminution of trace adsorption by raising the acidity could not be observed up to 7 M solutions of nitric acid. Cation traces as Bi3+, Cd2+, Hg2+, Pb2+, Pd2+, Tl+, and Tl3+, which are normally adsorbed by silver halogenide precipitates in presence of surplus halogenids, are not co-precipitated if they are transformed into sufficiently stable undissociated molecules or complex anions.As complexing agent the surplus bromide acts with Cd2+, Hg2+, Pd2+, Tl+, and Tl3+; the surplus iodide with Bi3+, Cd2+, Hg2+, and Pd2+. With the exception of Tl+ all of these ions can be masked by EDTE in neutral medium and kept in solution. The known pH-function of the stability constants permits an aimed selection of the elements to be enriched. As long as the solution still contains a silver surplus during the precipitation, the EDTE complexes of numerous cations are co-precipitated at first, however desorbed after exceeding the equivalence point. Depositing of strongly adsorbable ions at the active surface of the silver halogenide precipitates prevents the co-precipitation of other elements. The strength of adsorption at silver chloride is given by the following order of cations: Tl+ > Pb2+ >(Hg2+; Pd2+)>Tl3+>Bi3+>Cd2+.


II. Mitt.: diese Z. 235, 235 (1968).

Herrn Professor Dr. E. Asmus zum 60. Geburtstag gewidmet.

Wir danken Herrn J. Lohmar für die experimentelle Mitarbeit. Der Fa. E. Merck AG, Darmstadt, sei auch an dieser Stelle für die Überlassung reinsten Silbernitrats gedankt.  相似文献   

7.
Owing to the instability of hydrogen peroxide in alkaline solutions, direct oxidation with KmnO4 did not yield accurate results.The back titration of KmnO4 in the presence of IN NaOH and Ba+2 ions also gave inaccurate results. The reaction could not be checked at the manganate state. However, in the presence of 2N NaOH and telluric acid quantitative data were obtained, which is not the case if telluric acid is absent.Another advantageous method is the oxidation of hydrogen peroxide with excess KmnO4 in the presence of 1N NaOH and telluric acid, followed by back titrating excess oxidant with monovalent thallium.  相似文献   

8.
Although the cyclo‐P6 complex [(Cp*Mo)2(μ,η66‐P6)] ( 1 ) was reported 30 years ago, little is known about its chemistry. Herein, we report a high‐yielding synthesis of 1 , the complex 2 , which contains an unprecedented cyclo‐P10 ligand, and the reactivity of 1 towards the “naked” cations Cu+, Ag+, and Tl+. Besides the formation of the single oxidation products 3 a,b which have a bisallylic distorted cyclo‐P6 middle deck, the [M( 1 )2]+ complexes are described which show distorted square‐planar (M=Cu( 4 a ), Ag( 4 b )) or distorted tetrahedral coordinated (M=Cu( 5 )) M+ cations. The choice of solvent enabled control over the reaction outcome for Cu+, as proved by powder XRD and supported by DFT calculations. The reaction with Tl+ affords a layered two‐dimensional coordination network in the solid state.  相似文献   

9.
The reproducible synthesis of the unusual ionic aluminum compound [Tl3F2Al(OR)3]+[Al(OR)4] ( 1 ) is reported. In the reaction of Li[Al(OR)4] [R = C(H)(CF3)2] with TlF the initially desired Tl[Al(OR)4] only formed with an exact 1:1 stoichiometry, while an excess of TlF led to [Tl3F2Al(OR)3]+[Al(OR)4] ( 1 ). Additionally the x‐ray single crystal structure of the byproduct [(R‐OH)TlAl(OR)3(μ‐F)]2 ( 2 ) was determined. Compounds 1 and 2 were characterized by X‐ray single crystal structure determinations and 1 also by NMR spectroscopy and an elemental analysis. In 1 the [Tl3F2Al(OR)3]+ cation forms a trigonal bipyramid with a pentacoordinate aluminum atom. Three Tl+ cations cover the [F2Al(OR)3]2— dianion core and the charge of the resulting [Tl3F2Al(OR)3]+ cation is compensated by a weakly coordinating [Al(OR)4] anion. Compound 2 contains a centrosymmetric [Al(OR)3(μ‐F)]22— dianion core with pentacoordinate aluminum atoms building a distorted edge sharing double trigonal bipyramid. The [Al(OR)3(μ‐F)]22— dianion coordinates two [Tl(R‐OH)]+ cations giving the non charged molecular [(R‐OH)TlAl(OR)3(μ‐F)]2 ( 2 ). Based on BP86/SVP (DFT‐) and lattice enthalpy calculations a pathway of the reaction was proposed to rationalize the formation of the [M3F2Al(OR)3]+ cation upon reaction of Li[Al(OR)4] with MF for M = Tl but not for M = Cs (cf. Cs+ and Tl+ have very similar ionic radii). Using a suitable BorñHaber cycle and in agreement with the experiment, the enthalpies of the reaction of 2 M[Al(OR)4] with 2 MF giving [M3F2Al(OR)3]+[Al(OR)4] and MOR were shown to be favorable for M = Tl by 127 kJ/mol but endothermic for the formation of the hypothetical [Cs3F2Al(OR)3]+[Al(OR)4] by 95 kJ/mol. It is suggested that in the reaction leading to 1 initially Tl[Al(OR)4] is formed, followed by an abstraction of TlOR and Al(OR)3. The latter very strong Lewis acid reacts subsequently with an excess of TlF yielding 1 .  相似文献   

10.
The strong oxidising capacity of thallium(III) dominates its reaction with solutions of dithizone (H2Dz) in organic solvents. When carbon tetrachloride is used as solvent, the unstable thallium(III) complex Tl(HDz)3 is found in the organic phase but it very quickly disproportionates to the thallium(I) complex [Tl(HDz)], and bis-1,5-diphenylformazan-3-yl-disulphide. This reaction is notably faster in chloroform, in which thallium(I) dithizonate is the first identifiable product. In contact with an acidic aqueous phase, thallium(I) dithizonate is reverted to regenerate dithizone in the organic phase and Tl+ ions appear in the aqueous phase. Organic solutions of the disulphide disproportionate spontaneously by first-order kinetics to give an equimolar mixture of dithizone and the mesoionic compound, 2,3-diphenyl-2,3-dihydrotetrazolium-5-thiolate: this change is much slower in carbon tetrachloride than in the more polar chloroform and is catalysed by both Tl+ and Tl3+. If thallium(III) is present in excess, the mesoionic compound is the principal oxidation product of the dithizone although a dication may also be formed. The mesoionic compound does not react with thallium(I) but forms a water-soluble 2:1 complex with thallium(III); partition of this complex into the organic phase is uninfluenced by chloride ions. Because of the large number of competing reactions, the composition of the reaction mixture at any stage of the reaction between thallium(III) and dithizone depends on the relative concentrations of the components, the order in which they are brought together, the time elapsed after mixing, the pH of the aqueous phase, and the nature of the organic solvent.  相似文献   

11.
Summary It is demonstrated that magnesium can be titrated with EGTA in the presence of CaEDTA complex. On the basis of this substitution reaction, calcium and magnesium are successively titrated with EGTA, if an appropriate amount of CaEDTA is added after having reached the end point for calcium. Both end points are indicated amperometrically using a thallium oxide anode. The method has been tested for analysis of tap and mineral water. Larger amounts of manganese(II) render the calcium result too high. Moreover, the indication of both end points is affected by the electrode position of an inactive MnO2-layer onto the Tl2O3-layer. Reducing agents destroy the Tl2O3-layer. These interferences can be overcome by addition of an appropriate amount of manganate(VII) to the sample.
Sukzessive Substitutionstitration von Calcium und Magnesium mit ÄGTA, indiziert mit der Thalliumoxidelektrode
Zusammenfassung Magnesium kann mit ÄGTA in Gegenwart des CaÄDTA-Komplexes titriert werden. Auf der Grundlage dieser Substitutionstitration können Calcium und Magnesium nacheinander mit ÄGTA titriert werden, wenn nach dem Endpunkt für Calcium eine ausreichende Menge CaÄDTA zugesetzt wird. Beide Endpunkte werden amperometrisch mit Hilfe einer Thalliumoxidelektrode angezeigt. Die Methode wurde an Leitungswasser und Mineralwasser geprüft. Größere Mengen Mangan(II) bewirken zu hohe Calciumwerte. Darüber hinaus wird die Indikation beider Endpunkte dadurch beeinträchtigt, daß sich eine inaktive MnO2-Schicht auf der Tl2O3-Schicht elektrolytisch abscheidet. Reduzierende Stoffe zerstören die Tl2O3-Schicht. Diese Störungen können durch Zugabe von Permanganat vermieden werden.
  相似文献   

12.
In absence of Ba+2 ions arsenite reduces KMnO4 in alkaline medium to MnO2 without the appearance of an inflection at the manganate state. Reduction could be checked at the manganate in presence of 1N NaOH and Ba+2 equal to 3 times that equivalent to MnO4-2 and arsenate, and when dilute arsenite solutions are applied viz.0.02N In absence of Ba+2 ions the end-points are attained later than the MnO2 stage except in 2–3N NaOH. In presence of telluric acid good results are obtained at all alkalinities whence reduction is checked at Mn+4.As+3 could be estimated also by mixing with KMnO4 either in the presence of Ba+2 ions + 1N NaOH or in absence of Ba+2 ions + I.5–3N NaOH and back-titrating the excess oxidant with monovalent thallium.  相似文献   

13.
Summary Lead was estimated as Bismuthiol II complex of composition (C8H5N2S3)2Pb by precipitating it from its chloride or nitrate solution in presence of a mineral acid, acetic acid, tartrate or cyanide. The estimation is quantitative up to a maximumph of about 6.5. The lead-Bismuthiol II complex is stable up to about 311° C and the conversion factor is 0.315. The method affords a complete separation of lead from alkalis and alkaline earths, Be2+, Mg2+, Zn2+, Mn2+, Co2+, Ni2+, Fe2+, Fe3+, Cr3+, Al3+, rare earths, Ti4+, Zr4+, Th4+, UO2 2+, Pd2+, As3+, Sb3+, Cl, SO4 2–, PO4 3–, AsO4 3–, MoO4 2– and WO4 2–. Among the sulphide group members Ag+, Au3+, Hg+, Hg2+, Tl+, Tl3+, Cd2+ and platinum metals, except Pd2+, interfere while oxidising agents decompose the excess reagent. Bi3+, Cu2+ and Sn2+, do not interfere up to a maximum limit of 30 mg, 50 mg, and 250 mg respectively.Part I: see Z. analyt. Chem. 154, 262 (1957).  相似文献   

14.
From extraction experiments and γ-activity measurements, the extraction constants corresponding to the general equilibrium M+(aq) + 1·Cs+(nb) \rightleftarrows \rightleftarrows 1·M+(nb) + Cs+(aq) taking part in the two-phase water–nitrobenzene system (1 = hexaarylbenzene-based receptor; M+ = H3O+, NH4 +, Ag+, K+, Rb+, Tl+; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complex species in nitrobenzene saturated with water were calculated; they were found to increase in the series of Rb+ < K+ < Ag+, Tl+ < H3O+, NH4 +.  相似文献   

15.
From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the equilibrium M +(aq) + 1 · Na+ (nb) ⇄ 1 · M + (nb) + Na+ (aq) taking place in the two-phase water-nitrobenzene system (M + = Li+, H3O+, NH4 +, Ag+, K+, Rb+, Tl+, Cs+; 1 = tetraphenyl p-tert-butylcalix[4]arene tetraketone; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the 1 · M + complexes in water saturated nitrobenzene were calculated; they were found to increase in the order Cs+ < Rb+ < Tl+ < K+ < NH4 + < Ag+ < H3O+ < Li+. Correspondence: Emanuel Makrlík, Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic.  相似文献   

16.
Pulse radiolysis of an aqueous solution of mono-valent thallium ion and mixed solutions of Tl+/Ag+ in the presence of various amino polycarboxylic acids such as trans-1,2-diaminocyclohexane-N,N,N′,N′-tetraacetic acid (DCTA), diethylenetriaminepentaacetic acid (DTPA), N-(2-hydroxyethyl)ethylenediaminetriacetic acid (HEDTA) and triethylenetetraminehexaacetic acid (TTHA) has been carried out. Abnormal valence states of Tl ions were generated. It is concluded that DCTA, DTPA, HEDTA and TTHA decrease the redox potential of Tl ions in aqueous solutions. It was observed that the electron transfer from complexed Tl2+ to Ag+ varied in the range 7.5 × 108 to 1.0 × 109, depending on the type of complexing ligand. Electron transfer from Tl2+ to Ag+ lead to the formation of silver atoms, which agglomerate further to form silver colloid.  相似文献   

17.
The complexation reactions between 7,10,13-triaza-1-thia-4,16-dioxa-20,24-dimethyl-2,3;17,18-dibenzo-cyclooctadecane-6,14-dione ( TTD ) and 7,10,13-triaza-1-sulfoxo-4,16-dioxa-20,24-dimethyl-2,3;17,18-dibenzo-cyclooctadecane-6,14-dione ( TSD ) macrocycles with Ag+, Cd2+, Cu2+, Pb2+, Sr2+, Tl+, and Zn2+ ions have been studied in ethanol and methanol solutions at 25°C. The complexes formed between macrocycles ( TTD ) and ( TSD ) with these metals cations had a stiochiometry of 1:1 and 1:2, respectively. The stability constants of the resulting complexes were determined and found to decrease in the order Cu2+ > Zn2+ > Ag+ > Tl+ > Cd2+ > Pb2+ > Sr2+ with macrocycle ( TTD ) and Tl+ > Zn2+ > Cd2+ > Pb2+ > Cu2+ > Ag+ > Sr2+ with macrocycle ( TSD ).  相似文献   

18.
Pb+2 (~37-0.6mg) and Tl+ (45-0.9 mg) can bc estimated by mixing with KmnO4 in presence of Ba+2 ions and INNaOH. The excess KmnO4 is then titrated with formic acid.A mixture of Pb+2 and Tl+ is oxidized simultaneously with KMn04 in 0.1N NaOH. Pb+2 interferes also when precipitated as sulphate or tellurate. In presence of SO4-2 and telluric acid, thallium can be titrated only when its concentration is not less than 30 mg, below which lead seriously interferes. Tl+ can be accurately determined in the filtrate from the PbS04 precipitate.  相似文献   

19.
    
Zusammenfassung Die gegenseitige Verdrängung aus innerkomplexen Metall-Diäthyldithiocarbaminaten, die in CCl4 gelöst sind, durch Metallionen in wäßriger Phase wurde für folgende Kationen quantitativ untersucht: Hg2+, Pd2+, Ag+, Cu2+, Tl3+, Ni2+, Bi3+, Pb2+, Co3+ bzw. Co2+, Cd2+, Tl+, Zn2+, In3+, Sb3+, Fe3+, Te4+, Mn3+ bzw. Mn2+. Es sind dies die Elemente, die aus alkalischen Lösungen quantitativ als Diäthyldithiocarbaminate mit organischen Lösungsmitteln extrahiert werden können. Die Verdrängungsversuche wurden bei pH 8,5 bzw. 11 bei Abwesenheit von Komplexbildnern durchgeführt.V. Mitteilung: H. Bode, Z. anorg. allg. Chem. 289, 207–218 (1957).Unsere Arbeit wurde durch Gaben der Deutschen Forschungsgemeinschaft gefördert, wofür auch an dieser Stelle gedankt sei.  相似文献   

20.
Summary Copper has been determined gravimetrically as its bis-salicylaldehyde-ethylenediamine complex of the composition C16H14O2N2 · Cu, dried at 100–120° C. The complex is completely precipitated in theph range of 10.5–13.5, adjusted with ammonia or caustic alkali. It is stable in presence of excess ammonia, 0.1 N alkali, ammonium salts and complexing agents as tartrate, citrate, sodium-thiosulphate, fluoride, thiourea, triethanolamine and EDTA. In presence of tartrate and ammonia the ions of alkali metals, alkaline earths, Ag+, Tl+, Tl3+, Pb2+, Cd2+, Co2+, Mn2+, Pd2+, Al3+, Cr3+, La3+, Ce3+, Au3+, Pt4+, Ti4+, Zr4+, Th4+, UO2 2+ and anions as VO3 , MoO4 2–, WO4 2–, CrO4 2–, PO4 3–, AsO4 3– do not interfere. Ni2+ and Hg2+ are masked by tartrate, EDTA and ammonia; As3+, Sb3+ and Sn2+ are separated using fluoride as the complexing agent; at an alkalinity of 0.1 N caustic alkali in presence of tartrate As3+, Sb3+, Sn2+, Bi3+, Zn2+ and Fe3+ are separated. Fe3+ can also be separated using triethanolamine as the masking agent at aph of about 13.0. Copper can be separated from almost all the ions, thus affording a highly selective method for the determination of copper.
Zusammenfassung Es wird eine gravimetrische Methode zur Bestimmung von Kupfer beschrieben, die auf der Bildung des Bis-salicylaldehyd-äthylendiaminkomplexes beruht. Dieser hat die Zusammensetzung C16H14O2N2 · Cu. Die Fällung wird imph-Bereich 10,5–13,5 (mit Ammoniak oder Alkalilauge eingestellt) vorgenommen und der Niederschlag bei 100°–120° C getrocknet. Der Komplex ist beständig in Gegenwart von überschüssigem Ammoniak, 0,1 n Alkali, Ammoniumsalzen sowie Tartrat, Citrat, Natriumthiosulfat, Fluorid, Thioharnstoff, Triäthanolamin und ÄDTA. In Gegenwart von Tartrat und Ammoniak stören nicht: Alkalien, Erdalkalien, Ag+, Tl+, Tl3+, Pb2+, Cd2+, Co2+, Mn2+, Pd2+, Al3+, Cr3+, La3+, Ce3+, Au3+, Pt4+, Ti4+, Zr4+, Th4+, UO2 2+ sowie VO3 , MoO4 2–, WO4 2–, CrO4 2–, PO4 3– und AsO4 3+. Ni2+ und Hg2+ können mit Tartrat, ÄDTA und Ammoniak maskiert werden, As3+, Sb3+ und Sn2+ mit Fluorid. In 0,1 n ätzalkalischer Lösung in Gegenwart von Tartrat können As3+, Sb3+, Sn2+, Bi3+, Zn2+ und Fe3+ abgetrennt werden. Fe3+ kann ebenfalls mit Triäthanolamin beiph 13,0 maskiert werden. Das beschriebene Verfahren erlaubt somit eine Abtrennung des Kupfers von fast allen anderen Ionen.


Part I: Singh, B. R., and S. Kumar: Z. analyt. Chem. 185, 211 (1962).  相似文献   

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