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1.
A series of fluorinated poly(amide imide)s were prepared from 1,4‐bis(2′‐trifluoromethyl‐4′‐trimellitimidophenoxy)benzene and various aromatic diamines [3,3′,5,5′‐tetramethyl‐4,4′‐diaminediphenylmethane, α,α‐bis(4‐amino‐3,5‐dimethyl phenyl)‐3′‐trifluoromethylphenylmethane, 1,4‐bis(4′‐amino‐2′‐trifluoromethylphenoxy)benzene, 4‐(3′‐trifluoromethylphenyl)‐2,6‐bis(3′‐aminophenyl)pyridine, and 1,1‐bis(4′‐aminophenyl)‐1‐(3′‐trifluoromethylphenyl)‐2,2,2‐trifluoroethane]. The fluorinated poly(amide imide)s, prepared by a one‐step polycondensation procedure, had good solubility both in strong aprotic solvents, such as N‐methyl‐2‐pyrrolidinone, dimethylacetamide, dimethylformamide, dimethyl sulfoxide, and cyclopentanone, and in common organic solvents, such as tetrahydrofuran and m‐cresol. Strong and flexible polymer films with tensile strengths of 84–99 MPa and ultimate elongation values of 6–9% were prepared by the casting of polymer solutions onto glass substrates, followed by thermal baking. The poly(amide imide) films exhibited high thermal stability, with glass‐transition temperatures of 257–266 °C and initial thermal decomposition temperatures of greater than 540 °C. The polymer films also had good dielectric properties, with dielectric constants of 3.26–3.52 and dissipation factors of 3.0–7.7 × 10?3, and acceptable electrical insulating properties. The balance of excellent solubility and thermal stability associated with good mechanical and electrical properties made the poly(amide imide)s potential candidates for practical applications in the microelectronics industry and other related fields. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1831–1840, 2003  相似文献   

2.
Novel π‐conjugating polymers based on dibenzothiophene were synthesized with a novel dibenzothiophene derivative, 2,8‐bis(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)dibenzothiophene ( 1 ), prepared from dibenzothiophene. The Suzuki coupling polycondensation of 1 with 2,7‐dibromo‐9,9‐dioctylfluorene, 3,6‐dibromo‐9‐octylcarbazole, or 1,4‐dibromo‐2,5‐dioctyloxybenzene afforded the corresponding dibenzothiophene‐based polymers. The measurements of photoluminescence indicated that all these polymers exhibited blue emission in solution. The copolymer containing dibenzothiophene and 9,9‐dioctylfluorene units exhibited higher thermal stability than poly[(9,9‐dioctylfluorene‐2,7‐diyl)], although the quantum yield of copolymer was lower than that of poly[(9,9‐dioctylfluorene‐2,7‐diyl)]. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1521–1526, 2003  相似文献   

3.
Novel poly(tetramethyl‐1,3‐silphenylenesiloxane) derivative with phenol moiety in the main chain, that is, poly(tetramethyl‐5‐hydroxy‐1,3‐silphenylenesiloxane) ( P1 ), was synthesized and the thermal properties were investigated by differential scanning calorimetry (DSC) and thermogravimetry (TG). P1 was obtained via deprotective hydrogenation of poly(tetramethyl‐5‐benzyloxy‐1,3‐silphenylenesiloxane) ( Pre‐P1 ) catalyzed by 10% palladium on charcoal as well as via direct polycondensation of 3,5‐bis(dimethylhydroxysilyl)phenol ( M2 ). Pre‐P1 was obtained by polycondensation of 1,3‐bis(dimethylhydroxysilyl)‐5‐benzyloxybenzene ( M1 ), catalyzed by 1,1,3,3‐tetramethylguanidinium 2‐ethylhexoate. M1 was prepared by the Grignard reaction using chlorodimethylsilane and 1,3‐dibromo‐5‐benzyloxybenzene followed by the hydrolysis catalyzed by 5% palladium on charcoal. M2 was prepared by deprotective hydrogenation of M1 catalyzed by 10% palladium on charcoal. The obtained P1 was soluble in common organic solvents such as tetrahydrofuran, chloroform, dichloromethane, toluene, and so forth as well as in highly polar solvents as ethanol and methanol in which poly(tetramethyl‐1,3‐silphenylenesiloxane) is insoluble. The glass transition temperature (Tg) of P1 was determined to be 40 °C from DSC, which was much higher than that of poly(tetramethyl‐1,3‐silphenylenesiloxane) (?52 °C), indicating that the intermolecular and/or intramolecular hydrogen bondings based on hydroxyl groups restricted the mobility of the main chain. The temperature at 5% weight loss (Td5) of P1 (393 °C) determined by TG was lower than that of poly(tetramethyl‐1,3‐silphenylenesiloxane) (ca. 500 °C), indicating that the phenol moieties decline the thermal stability; however, the obtained P1 would promise to be a new reactive‐polymer with phenolic–hydroxyl moieties to develop new functional materials. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 692–701, 2008  相似文献   

4.
A new symmetrical diamine monomer containing a triaryl imidazole pendant group was successfully synthesized by the nucleophilic substitution of hydroquinone with the synthesized 2‐(2‐chloro‐5‐nitrophenyl)‐4, 5‐diphenyl‐1H‐imidazole (I). A series of novel polyamides were prepared from the diamine monomer and various aliphatic and aromatic dicarboxylic acids via phosphorylation polyamidation. These polyamides are readily soluble in many organic solvents; their inherent viscosities ranged from 0.68 to 0.89 dl/g and gave tough and flexible films by solution‐casting. They had useful levels of thermal stability associated with relatively high Tgs (186–278°C), 10% weight loss temperatures in the range of 355–482°C, and char yields at 600°C in air up to 67%. All the polyamides have fluorescence emission in dilute (0.2 g/dl) DMAc solution with maxima at 425–495 nm and with the quantum yields in the range 14–28%. The chemiluminescence activity of polyamides was also studied in the presence of peroxyoxalate. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

5.
A set of new aromatic poly(ether amide)s containing benzimidazole groups and ethylene oxide sequences of different lengths were synthesized and characterized. The new polymers were prepared from two benzimidazole diamines, 2‐(4‐aminophenyl)‐5‐aminobenzimidazole and 2‐(3‐aminophenyl)‐5‐aminobenzimidazole, and various oligo(ethylene oxide)dibenzoyl chlorides. They exhibited good solubility in polar aprotic solvents and glass‐transition temperatures in the range of 125–300 °C (the longer the ethylene oxide spacer was, the lower the glass‐transition temperature was). The new polyamides were essentially amorphous, as observed by X‐ray diffraction measurements and confirmed by differential scanning calorimetry measurements, by means of which no melting endotherm was observed in any case. The decomposition temperatures, as revealed by thermogravimetric analysis in nitrogen, were about 400 °C for all of them, regardless of the length of the ethylene oxide content or the phenylene ring orientation (meta or para) of the diamine moiety. The number of ethylene oxide linkages per repeat unit also determined the water uptake. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1414–1423, 2006  相似文献   

6.
In this work, three alipharomatic polyesters—poly(propylene terephthalate) (PPT), poly(propylene isophthalate) (PPI), and poly(propylene naphthalate) (PPN)—were prepared and studied with the aliphatic diol 1,3‐propanediol and the corresponding aromatic diacids. Their synthesis was performed by the two‐stage melt polycondensation method in a glass batch reactor. The thermal characterization of these polyesters was carried out with different thermal techniques such as simultaneous thermogravimetry/differential thermal analysis, thermomechanical analysis (TMA), and dynamic thermomechanical analysis. From the recorded values for the glass‐transition temperature (Tg) and melting temperature with all the aforementioned techniques, it could be said that they were in good agreement. According to the thermogravimetric results, PPT and PPI showed about the same thermal stability, whereas PPN seemed to be somewhere more thermostable. Remarkably, a transition existed immediately after Tg that was realized by the first derivative of TMA, and it was characterized as a midrange transition. For all polyesters, the average coefficient of linear thermal expansion was calculated with TMA. The secondary relaxations Tβ and Tγ, recorded with dynamic mechanical thermal analysis, were mainly affected by the kinds of monomers. Concerning the mechanical properties, PPN had the highest tensile strength at break, whereas PPT had the highest elongation at break. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3998–4011, 2005  相似文献   

7.
The synthesis of aromatic poly(ether imide)s containing spirobifluorene units in the polymer backbone is described. 2,2′‐Bis(3,4‐dicarboxyphenoxy)‐9,9′‐spirobifluorene dianhydride, which was used as a new monomer, was synthesized with 2,2′‐dihydroxy‐9,9′‐spirobifluorene as the starting material. In the spiro‐segment, the rings of the connected bifluorene were orthogonally arranged. This bis(ether anhydride) monomer was employed in reactions with a variety of aromatic diamines to furnish poly(ether imide)s, involving an initial ring‐opening polycondensation and subsequent chemically induced cyclodehydration. Excellent solubility in common organic solvents at room temperature, good optical transparency, and high thermal stability are the prominent characteristic features of these new polymers, which can be attributed to the presence of spiro‐fused orthogonal bifluorene segments along the polymer chain. The glass‐transition temperatures of the polyimides were 240–293 °C, and the 5% weight‐loss temperatures were greater than 500 °C. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 40: 262–268, 2002  相似文献   

8.
A series of new aliphatic polyesters derived from 1,12‐dodecanedioic acid and different diols with an even number of methylene units have been studied to assess the effect of the chemical structure on the final thermal properties of the materials. The polyesters have high thermal stability and are fast crystallizing polymers, with crystallization rate similar to that of polyethylene (PE). This behavior is connected to the fact that long aliphatic chains assume conformational characteristics very similar to that of PE. However, the polyester prepared from ethanediol shows a peculiar behavior (for example, double melting peak, melting and crystallization temperatures, which do not fit the trend of those of the other samples and ringed spherulites) owing to a probable different conformation, deviating from the all‐trans planar typical of PE. In the isothermal crystallization studies, a bell‐shape trend has been found for the crystallization rate as a function of the number of ? (CH2)? units in the diol. The high crystallization rate of the sample with long ? (CH2)? sequences has been attributed to the high chain flexibility and, thus, high mobility in the molten state and ease of chain folding. By reducing the aliphatic sequence length, instead, implications of the structural characteristics of the samples are probably involved. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1053–1067, 2007  相似文献   

9.
Aromatic polyamides based on a novel bis(ether‐carboxylic acid) were synthesized by the direct phosphorylation condensation method. 1,4‐Bis(4‐carboxyphenoxy)‐2,5‐di‐tert‐butylbenzene was combined with various diamines containing flexible linkages and side substituents to render a set of eight novel aromatic polyamides. The polymers were produced with high yields and moderate to high inherent viscosities (0.49–1.32 dL/g) that corresponded to weight‐average and number‐average molecular weights (by gel permeation chromatography) of 31,000–80,000 and 19,000–50,000, respectively. Except for a single example, the polyamides were essentially amorphous and soluble in a variety of common solvents such as cyclohexanone, dioxane, and tetrahydrofuran. They showed glass‐transition temperatures of 250–295 °C (by differential scanning calorimetry) and 10% weight loss temperatures above 460 °C, as revealed by thermogravimetric analysis in nitrogen. Polymer films, obtained by casting from N,N‐dimethylacetamide solutions, exhibited good mechanical properties, with tensile strengths of 83–111 MPa and tensile moduli of 2.0–2.2 GPa. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 475–485, 2001  相似文献   

10.
A novel fluorinated aromatic diamine, 1,1‐bis(4‐amino‐3,5‐dimethylphenyl)‐1‐(3,5‐ditrifluoromethylphenyl)‐2,2,2‐trifluoroethane (9FMA), was synthesized by the coupling reaction of 3′,5′‐ditrifluoromethyl‐2,2,2‐trifluoroacetophenone with 2,6‐dimethylaniline under the catalysis of 2,6‐dimethylaniline hydrochloride. A series of fluorinated aromatic polyimides were synthesized from 9FMA and various aromatic dianhydrides, including pyromellitic dianhydride, 3,3′4,4′‐biphenyl tetracarboxylic dianhydride, 4,4′‐oxydiphthalic anhydride, 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride (BTDA), and 4,4′‐hexafluoroisopropylidene diphthalic anhydride, via a high‐temperature, one‐stage imidization process. The inherent viscosities of the polyimides ranged from 0.37 to 0.74 dL/g. All the polyimides were quickly soluble in many low‐boiling‐point organic solvents such as tetrahydrofuran, chloroform, and acetone as well as some polar organic solvents such as N‐methyl‐2‐pyrrolidinone, N,N′‐dimethylacetamide, and N,N′‐dimethylformamide. Freestanding fluorinated polyimide films could be prepared and exhibited good thermal stability with glass‐transition temperatures of 298–334 °C and outstanding mechanical properties with tensile strengths of 69–102 MPa and elongations at break of 3.3–9.9%. Moreover, the polyimide films possessed low dielectric constants of 2.70–3.09 and low moisture absorption (<0.58%). The films also exhibited good optical transparency with a cutoff wavelength of 303–351 nm. One polyimide (9FMA/BTDA) also exhibited an intrinsic negative photosensitivity, and a fine pattern could be obtained with a resolution of 5 μm after exposure at the i‐line (365‐nm) wavelength. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2665–2674, 2006  相似文献   

11.
A novel fluorinated aromatic dianhydride, 4,4′‐[2,2,2‐trifluoro‐1‐(3‐trifluoromethyl‐phenyl)ethylidene]diphthalic anhydride (TFDA) was synthesized by coupling of 3′‐trifluoromethyl‐2,2,2‐trifluoroacetophenone with o‐xylene under the catalysis of trifluoromethanesulfonic acid, followed by oxidation of KMnO4 and dehydration. A series of fluorinated aromatic polyimides derived from the novel fluorinated aromatic dianhydride TFDA with various aromatic diamines, such as p‐phenylenediamine (p‐PDA), 4,4′‐oxydianiline (ODA), 1,4‐bis(4‐aminophenoxy)benzene (p‐APB), 1,3‐bis(4‐amino‐phenoxy)benzene (m‐APB), 4‐(4‐aminophenoxy)‐3‐trifluoromethylphenylamine (3FODA) and 1,4‐bis(4‐amino‐2‐trifluoromethylphenoxy)benzene (6FAPB), were prepared by polycondensation procedure. All the fluorinated polyimides were soluble in many polar organic solvents such as NMP, DMAc, DMF, and m‐cresol, as well as some of low boiling point organic solvents such as CHCl3, THF, and acetone. Homogeneous and stable polyimide solutions with solid content as high as 35–40 wt % could be achieved, which were prepared by strong and flexible polyimide films or coatings. The polymer films have good thermal stability with the glass transition temperature of 232–322 °C, the temperature at 5% weight loss of 500–530 °C in nitrogen, and have outstanding mechanical properties with the tensile strengths of 80.5–133.2 MPa as well as elongations at breakage of 7.1–12.6%. It was also found that the polyimide films derived from TFDA and fluorinated aromatic diamines possess low dielectric constants of 2.75–3.02, a low dissipation factor in the range of 1.27–4.50 × 10?3, and low moisture absorptions <1.3%. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4143–4152, 2004  相似文献   

12.
A series of new polyimides were prepared via the polycondensation of (3‐amino‐2,4,6‐trimethylphenyl)‐(3′‐aminophenyl)methanone and aromatic dianhydrides, that is, 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA), 4,4′‐oxydiphthalic anhydride, 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride, and 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluoropropane dianhydride. The structures of the polyimides were characterized by Fourier transform infrared and NMR measurements. The properties were evaluated by solubility tests, ultraviolet–visible analysis, differential scanning calorimetry, and thermogravimetric analysis. The two different meta‐position‐located amino groups with respect to the carbonyl bridge in the diamine monomer provided it with an unsymmetrical structure. This led to a restriction on the close packing of the resulting polymer chains and reduced interchain interactions, which contributed to the solubility increase. All the polyimides except that derived from BPDA had good solubility in strong aprotic solvents, such as N‐methyl‐2‐pyrrolidinone, N,N′‐dimethylacetamide, N,N‐dimethylformamide, and dimethyl sulfone, and in common organic solvents, such as cyclohexanone and chloroform. In addition, these polyimides exhibited high glass‐transition values and excellent thermal properties, with an initial thermal decomposition temperature above 470 °C and glass‐transition temperatures in the range of 280–320 °C. The polyimide films also exhibited good transparency in the visible‐light region, with transmittance higher than 80% at 450 nm and a cutoff wavelength lower than 370 nm. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1291–1298, 2006  相似文献   

13.
Poly‐2,3bis[(2‐hydroxy‐3‐methoxyphenyl)methylene]diamino pyridine (PHMPMDAP) that a new Schiff base polymer has been synthesized and characterized by spectroscopy, elemental, and thermal analyses techniques. This azomethine polymer was found to form complexes readily with Cu(II), Zn(II), Co(II), Pb(II), and Fe(II). From IR and UV‐Vis studies, the phenolic oxygen and imine nitrogen of the ligand were found to be the coordination sites. Thermogravimetric analysis (TGA) data indicate the polymer to be more stable than the monomer. The structure of the polymer obtained was confirmed by FT‐IR, UV‐Vis, 13C‐NMR, and 1H‐NMR. Characterization was undertaken by TGA, size exclusion chromatography (SEC), and solubility tests. Also, electrical conductivities of PHMPMDAP and polymer–metal complexes are measured by four probe technique. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

14.
Novel polyesters from 2,5‐furandicarboxylic acid or 2,5‐dimethyl‐furandicarboxylate and 2,3‐butanediol have been synthesized via bulk polycondensation catalyzed by titanium (IV) n‐butoxide, tin (IV) ethylhexanoate, or zirconium (IV) butoxide. The polymers were analyzed by size exclusion chromatography, nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy (FTIR), matrix‐assisted laser ionization‐desorption time‐of‐flight mass spectrometry, electrospray ionization time‐of‐flight mass spectrometry, electrospray ionization quadruple time‐of‐flight mass spectroscopy, thermogravimetric analysis, and differential scanning calorimetry. Fully bio‐based polyesters with number average molecular weights ranging from 2 to 7 kg/mol were obtained which can be suitable for coating applications. The analysis of their thermal properties proved that these polyesters are thermally stable up to 270–300 °C, whereas their glass transition temperature (Tg) values were found between 70 and 110 °C. Furthermore, a material was prepared with a molecular weight of 13 kg/mol, with a Tg of 113 °C. This high Tg would make this material possibly suitable for hot‐fill applications. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013  相似文献   

15.
The nonlinear optical property of new polyester has been studied via second harmonic generation (SHG). The values of electro‐optic coefficients, d33 and d31, of the poled polymer film were 3.15 × 10 ?7 and 1.5 × 10?7 esu, respectively. Thermal behavior of this polyester was studied through thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). 4‐di‐(2′‐hydroxyethoxy)‐4‐diphenyl‐hydrazonomethyl was synthesized from the reaction of 3,4‐dihydroxy‐4‐diphenyl‐hydrazonomethyl with 2–chloro–1‐ethanol in a 1:2 mole ratio and subsequently reacted with terephthaloyl chloride (TPC) in the presence of pyridine, as catalyst, to produce the new nonlinear polyester. The chemical structures of the resulting monomers and polymer were characterized by CHN analysis, 1H‐NMR, FT‐IR, and UV–Vis spectroscopy. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

16.
A series of random copolymers poly(3‐ethynylthiophene)‐copoly(2‐(4‐decyloxyphenyl)‐5‐(4‐ethynylphenyl)‐1,3,4‐oxadiazole) with different oxadiazole content ( P2 – P4 ) and homopolymer poly(3‐ethynylthiophene) ( P1 ) as well as poly(2‐(4‐decyloxyphenyl)‐5‐(4‐ethynylphenyl)‐1,3,4‐oxadiazole) ( P5 ) were prepared. The copolymers ( P2 – P4 ) are completely soluble in common organic solvents. The structures and properties of all polymers were characterized and evaluated by FTIR, 1H NMR, 13C NMR, TGA, UV, PL, GPC, and nonlinear optical (NLO) analyses. The incorporation of diaryl‐oxadiazole into polyacetylene‐containing thiophene significantly endows copolymers with higher thermal stability, which may origin from the synergetic effect of the “jacket effect” of diaryl‐oxadiazole units and the effect of retarding or eliminating a few 6π‐electrocycliaztion proceeds of oxadiazole‐containing polyacetylene due to the hindrance of thiophene units. When the copolymer ( P3 ) posses more regular alternating thiophene pendants and oxadiazole pendants arrangement along the polymer backbone, it shows good thermal stability (Td up to 388 °C) and larger third‐order nonlinear optical susceptibility (χ(3) up to 11.0 × 10?11 esu). © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010  相似文献   

17.
As distinguished from the conventional preparation of poly(aryl ether ketone)s utilizing 4,4′‐difluorobenzophenone, a novel synthetic method of high molecular weight poly(phthalazinone ether ketone) derived from 4,4′‐dichlorobenzophenone was studied. Reaction conditions to get high molecular weight polymer were investigated in details. Experimentally, sulfolane was chosen as the reaction media and high molecular weight polymer could be obtained in 7–8 hr at 210°C. The cyclic oligomers in the polymer product reduced to below 3.0% when the concentration of the reactant is 1.6–1.7 g/ml. Fourier transform infrared (FT‐IR), 1H NMR, and elemental analysis were used to confirm the structure of the obtained polymer. The amorphous polymer showed reasonable solubility in selective solvent, such as chloroform and N‐methyl‐2‐pyrrolidone, and tough, flexible, and transparent thin film can be readily prepared from their N‐methyl‐2‐pyrrolidone solution. The obtained polymer showed high glass transition temperature (Tg) up to 261°C detected by differential scanning calorimetry (DSC), and the temperature of 5% weight loss under nitrogen higher than 500°C detected by thermal gravimetric analysis (TGA), indicating its excellent thermal stability. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

18.
New well‐defined brush polypyromellitimides with n‐octyloxy and n‐dodecyloxy side chains were prepared by two‐step polycondensations of 3,6‐di(n‐alkyloxy)pyromellitic dianhydrides with various conventional aromatic diamines. Their structures and properties were investigated and compared with those of polyimides without the side chains. The alkyloxylated poly(amic acid)s had inherent viscosities of 0.45–1.09 dL/g. The polyimides showed enhanced solubility in organic solvents and had layered structures in the solid state. As the side‐chain length increased from n‐octyloxy to n‐dodecyloxy, the extent of layered structure formation increased, whereas the glass‐transition temperature and thermal resistance decreased. As for the liquid‐crystal (LC) aligning ability measured with 4‐n‐pentyl‐4′‐cyanobiphenyl on rubbed thin‐film surfaces, all the side‐chain polyimides revealed homogeneous LC alignment parallel to the rubbing direction with distinctively higher pretilt angles than those of the polyimides without the side chains. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3130–3142, 2004  相似文献   

19.
The synthesis of a new bis(ether carboxylic acid), 2,2′‐bis(4‐carboxyphenoxy)‐9,9′‐spirobifluorene, in which two orthogonally arranged carboxyphenoxyfluorene entities are connected through an sp3 carbon atom (the spiro center), is reported. The direct phosphorylation polycondensation of this diacid monomer with various aromatic diamines yields aromatic polyamides containing 9,9′‐spirobifluorene moieties in the main chain. The presence of the spiro segment restricts the close packing of the polymer chains and decreases interchain interactions, resulting in amorphous polyamides with enhanced solubility, and high glass‐transition temperatures and good thermal stability are maintained through controlled segmental mobility. The glass‐transition temperatures of these polyamides are in the range of 234–306 °C, with 10% weight losses occurring at temperatures above 530 °C. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1160–1166, 2003  相似文献   

20.
A new triphenylamine‐containing aromatic dicarboxylic acid, N,N′‐bis(4‐carboxyphenyl)‐N,N′‐diphenyl‐1,4‐phenylenediamine, was synthesized by the condensation of N,N′‐diphenyl‐1,4‐phenylenediamine with 4‐fluorobenzonitrile, followed by the alkaline hydrolysis of the intermediate dinitrile compound. A series of novel triphenylamine‐based aromatic poly(amine amide)s with inherent viscosities of 0.50–1.02 dL/g were prepared from the diacid and various aromatic diamines by direct phosphorylation polycondensation. All the poly(amine amide)s were amorphous in nature, as evidenced by X‐ray diffractograms. Most of the poly(amine amide)s were quite soluble in a variety of organic solvents and could be solution‐cast into transparent, tough, and flexible films with good mechanical properties. They had useful levels of thermal stability associated with glass‐transition temperatures up to 280 °C, 10% weight‐loss temperatures in excess of 575 °C, and char yields at 800 °C in nitrogen higher than 60%. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 94–105, 2003  相似文献   

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