共查询到20条相似文献,搜索用时 281 毫秒
1.
A. M.?Ramalho M. M.?Conceio V. J.?Fernandes Jr. J. C.?Machado L. E. B.?Soledade A. G.?Souza 《Journal of Thermal Analysis and Calorimetry》2005,79(2):319-322
Summary Solid-state M-4-MeO-Bz compounds, where M stands for bivalent Mn, Co, Ni, Cu and Zn and 4-MeO-Bz is 4-methoxybenzoate, have been synthesized. Simultaneous thermogravimetry-differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffractometry, infrared spectroscopy, elemental analysis and complexometry were used to characterize and to study the thermal behaviour of these compounds. The results led to have information about the composition, dehydration, thermal stability and thermal decomposition of the isolated compounds. 相似文献
2.
F. S. Alves L. H. Bembo F. J. Caires E. Y. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2013,113(2):739-744
Solid-state heavier lanthanides fumarates compounds have been synthesized, and the compounds were characterized by employing simultaneous thermogravimetry and differential thermal analysis (TG–DTA), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), TG coupled to FTIR, elemental analysis, and complexometry. On heating, the dehydration occurs in a single and two consecutive steps and the thermal decomposition of the anhydrous compounds occurs in consecutive and/or overlapping steps, with formation of the respective oxides: Tb4O7 and Ln2O3 (Ln=Dy to Lu). The results also led to information about composition, thermal behavior, and the type of coordination of the isolated compounds. 相似文献
3.
Chomič J. Györyová K. Szunyogová E. Kováéová J. 《Journal of Thermal Analysis and Calorimetry》2004,76(1):33-41
Five new complex compounds of general formula Zn(Hsal)2·L2·nH2O (where Hsal=OHC6H4COO-, L=thiourea (tu), nicotinamide (nam), caffeine (caf), theobromine (tbr), n=2-4), were prepared and characterized by chemical analysis, IR spectroscopy and studied by methods of thermal analysis (TG/DTG,
DTA). It was found that the thermal decomposition of hydrated compounds starts with the release of water molecules. During
the thermal decomposition of anhydrous compounds the release of organic ligands take place followed by the decomposition of
salicylate anion. Zinc oxide was found as the final product of the thermal decomposition heated up to 800°C. RTG powder diffraction
method, IR spectra and chemical analysis were used for the determination of products of the thermal decomposition.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
4.
Elena Maria Mosoarca Sasca Viorel Livia Avram Ramona Tudose Otilia Costisor 《Journal of Thermal Analysis and Calorimetry》2008,94(2):361-365
The thermal decomposition in air and in nitrogen atmosphere of binuclear complex compounds of Cu(II) and Co(II) containing the Mannich base N,N′-tetra(4-antipyrylmethyl)-1,2 diaminoethane (TAMEN) as a ligand, Cu2(TAMEN)Cl4 and Co2(TAMEN)Cl4, were investigated. X-ray powder diffractometry, infrared spectroscopy and simultaneous thermogravimetry-differential thermal analysis (TG-DTA), have been used to characterize and to study the thermal behavior of these compounds. The results provided information concerning the stoichiometry, crystallinity, thermal stability and decomposition mechanism of the compounds. 相似文献
5.
E. Schnitzler G. Bannach O. Treu-Filho C. T. Carvalho M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2011,106(3):643-649
Solid-state compounds of general formula ThL4·nH2O, where L represents 2-methoxybenzylidenepyruvate and 2-methoxycynamylidenepyruvate, were synthesized. Complexometric titrations
with EDTA, thermogravimetry (TG), differential thermal analysis (DTA), X-ray powder diffractometry, elemental analysis (EA),
and infrared spectroscopy have been employed to characterize and to study the thermal behavior of these compounds in dynamic
air atmosphere. The results led to informations about the composition, dehydration, crystallinity, and thermal decomposition
of the isolated compounds. The performed molecular calculations in this study were done using the Gaussian 03 routine. Theoretical
calculations help in interpretations of FT-IR spectra supplying structural and physicochemical parameters. 相似文献
6.
Viorel Sasca Elena Maria Mosoarca Livia Avram Ramona Tudose Otilia Costisor 《Journal of Thermal Analysis and Calorimetry》2008,94(2):355-360
The thermal decomposition of Mannich base N,N′-tetra(4-antipyrylmethyl)-1,2-diaminoethane (TAMEN), and its Ni(II), binuclear
complex, Ni2(TAMEN)Cl4, in air and in nitrogen atmosphere, were investigated. X-ray powder diffractometry, infrared spectroscopy and simultaneous
thermogravimetry-differential thermal analysis (TG-DTA), have been used to characterize and to study the thermal behavior
of these compounds. The results provided information concerning the stoichiometry, crystallinity, thermal stability and decomposition
mechanism of the compound. 相似文献
7.
N. S. Fernandes M. A. S. Carvalho Filho C. B. Melios M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2000,59(3):663-668
Solid-state compounds Ln-4Cl-BP, where Ln represents lighter trivalent lanthanides and 4Cl-BP is 4-chlorobenzylidenepyruvate, were prepared. Thermogravimetry, derivative
thermogravimetry (TG and DTG), differential scanning calorimetry (DSC) and other methods of analysis were used to characterize
and to study the thermal behaviour of these compounds.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
8.
Katarína Győryová J. Chomič Erika Szunyogová Lenka Piknová V. Zeleňák Zuzana Vargová 《Journal of Thermal Analysis and Calorimetry》2006,84(3):727-732
Three
new complex compounds of general formula Zn{4-ClC6H3-2-(OH)COO}2⋅L2⋅nH2O
(where L=thiourea (tu), nicotinamide (nam),
caffeine (caf), n=2,3), were prepared and
characterized by chemical analysis, IR spectroscopy and their thermal properties
were studied by TG/DTG, DTA methods. It was found that the thermal decomposition
of hydrated compounds starts with the release of water molecules. During the
thermal decomposition of anhydrous compounds the release of organic ligands
take place followed by the decomposition of salicylate anion. Zinc oxide was
found as the final product of the thermal decomposition performed up to 650°C.
RTG powder diffraction method, IR spectra and chemical analysis were used
for the determination of products of the thermal decomposition. 相似文献
9.
M. Kobelnik E. Schnitzler M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2008,91(3):891-895
Solid-state M-2-MeO-BP compounds, where M represents bivalent Mn, Fe, Co, Ni, Cu, Zn and 2-MeO-BP is 2-methoxybenzylidenepyruvate have been synthesized. Simultaneous
thermogravimetry-differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffractometry,
infrared spectroscopy, elemental analysis and complexometry were used to characterize and to study the thermal stability and
thermal decomposition of these compounds. The results led to information about the composition, dehydration, crystallinity
and thermal decomposition of the isolated compounds. 相似文献
10.
B. Ambrozini P. R. Dametto A. B. Siqueira C. T. Carvalho M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2009,97(2):761-764
Solid state Ln–L compounds, where Ln stands for light trivalent lanthanides (L–Gd) and L is tartrate, have been synthesized.
Thermogravimetry and differential thermal analysis (TG/DTA), differential scanning calorimetry (DSC), X-ray powder diffractometry,
elemental analysis and complexometry were used to characterize and to study the thermal behaviour of these compounds. The
results led to information about the composition, dehydration and thermal decomposition of the isolated compounds. 相似文献
11.
J. R. Locatelli E. C. Rodrigues A. B. Siqueira E. Y. Ionashiro G. Bannach M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2007,90(3):737-746
Solid-state Ln(Bz)3·H2O compounds where Ln stands for trivalent yttrium or lanthanides and Bz is benzoate have been synthesized. Simultaneous thermogravimetry-differential
thermal analysis (TG-DTA), X-ray powder diffractometry, infrared spectroscopy and chemical analysis were used to characterize
and to study the thermal behaviour of these compounds. The results led to information about the composition, dehydration,
thermal stability and thermal decomposition of the isolated compounds. 相似文献
12.
《无机化学与普通化学杂志》2018,644(11):512-517
Five energetic salts of 3,6‐bishydrazino‐1,2,4,5‐tetrazine (BHT), namely (BHT)2(NTO)3 ( 3 ), (BHT)(BTT) · 2H2O ( 4 ), (BHT)(DNP)2 ( 5 ), (BHT)(NATr)2 ( 6 ), and (BHT)(FOX‐7)2 ( 7 ), were synthesized and fully characterized by elemental analysis, FT‐IR, and mass spectra. The crystal structures of salts 3 and 4 were obtained and determined. Sensitivities towards outside stimuli and thermal behaviors of all the compounds were investigated, besides, thermodynamics of both 3 and 4 were calculated as well. The compounds 3 – 7 exhibit splendid thermal stabilities and satisfactory sensitivities simultaneously. Notably, unlike the previously known layered packing, compound 4 was found to adopt an unusual layered crystal packing with arch layers alternately arranged upward or downward. It may play an important role in contributing to its superior thermal stability (350 °C), providing an enlightening thinking to design new highly thermal stable energetic materials. 相似文献
13.
ZHOU Jie WU Shaojie ZHANG Wenhui LIU Qmg YANG Bin REN Yinghui MA Haixia ZHAO Fengqi HU Rongzu 《高等学校化学研究》2019,35(3):403-409
Three energetic ion salts of 3,6-bis[(1H-1,2,3,4-tetrazol-5-yl)-amino]-1,2,4,5-tetrazine(BTATz), namely, methylamine salt(compound 1), ethylenediamine salt(compound 2), and diethylamine salt(compound 3), were synthesized and characterized by elemental analysis, Fourier transform infrared spectrometry, NMR spectroscopy, and ^13C NMR spectroscopy. The crystal structure of compound 1 was determined by single-crystal X-ray crystallography, and structural analysis revealed that it belonged to the monoclinic system with P21/c space group. In addition, the thermal behavior of the three compounds was studied by differential scanning calorimetry and thermogravimetry techniques. The thermal decomposition peak temperatures of the compounds were 574.89, 545.60, and 606.72 K, indicating that the three ion salts exhibited good thermal stability. Tlie kinetic mechanism equations of the main decomposition process and the entropy of activation(△S^≠), enthalpy of activation(△H^≠), and Gibbs free energy of activation(△G^≠) of the three compounds were also obtained. Moreover, the thermal safety of the compounds was evaluated by the values of the self^accelerated decomposition temperature(Tsadt)5 thermal ignition temperature(TTIT), and critical temperature of thermal explosion(7b). The results showed that all the compounds demonstrated good thermal safety, and the thermal safety of compound 3 was better than that of the others. 相似文献
14.
M. L. S. De Melo N. A. Santos R. Rosenhaim A. G. Souza P. F. Athayde Filho 《Journal of Thermal Analysis and Calorimetry》2011,105(3):831-836
Solid state Ln2–L3 compounds, where Ln stands for light trivalent lanthanides (lanthanum to gadolinium), except promethium, and L is folate
(C19H17N7O6), have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning
calorimetry (DSC), X-ray powder diffractometry, infrared spectroscopy (FTIR), TG coupled to FTIR, elemental analysis and complexometry
were used to characterize and to study the thermal behaviour of these compounds. The results provided information concerning
the stoichiometry, crystallinity, ligand’s denticity, thermal stability, thermal behaviour and identification of the gaseous
products evolved during the thermal decomposition of these compounds. 相似文献
15.
B. Ambrozini P. R. Dametto M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2011,105(3):867-871
Solid state Ln2-L3 compounds, where Ln stands for heavy trivalent lanthanides (terbium to lutetium) and yttrium, and L is tartrate [(C4H4O6)?2] have been synthesized. Simultaneous thermogravimetry and differential thermal analysis, differential scanning calorimetry, X-ray powder diffractometry, infrared spectroscopy, elemental analysis and complexometry were used to characterize and to study the thermal behaviour of these compounds. The results provided information concerning the stoichiometry, crystallinity, ligand??s denticity, thermal stability and thermal behaviour of these compounds. 相似文献
16.
G. Bannach A. B. Siqueira E. Y. Ionashiro E. C. Rodrigues M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2007,90(3):873-879
Solid-state M-2-Cl-BP, where M stands for Mn, Fe, Co, Ni, Cu, Zn and Pb and 2-Cl-BP is 2-chlorobenzylidenepyruvate, have been synthesized. Thermogravimetry
and derivative thermogravimetry (TG/DTG), simultaneous thermogravimetry and differential thermal analysis (TG-DTA), X-ray
powder diffractometry, infrared spectroscopy, elemental analysis, and complexometry were used to characterize and to study
the thermal behaviour of these compounds. The results led to information about the composition, dehydration, thermal stability
and thermal decomposition of the isolated compounds. 相似文献
17.
A. C. Gigante F. J. Caires D. J. C. Gomes L. S. Lima O. Treu-Filho M. Pivatto M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2014,115(1):127-135
Solid-state compounds of yttrium and lanthanide chelates of ethylenediaminetetraacetic acid have been synthesized. Simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC), theoretical and experimental infrared spectroscopy (FTIR), elemental analysis, complexometry and TG-DSC coupled to FTIR were used to characterize and to study the thermal decomposition of these compounds. The results provided information about the composition, dehydration, thermal stability, thermal decomposition and identification of gaseous products evolved during the thermal decomposition of these compounds. The theoretical and experimental spectroscopic data suggest the possible modes of coordination of the ligand with the lanthanum and terbium metal ions. 相似文献
18.
The title compounds 9-ethyl-1,3,6,8-tetra-p-tolyl-9H-carbazole (1) and 9-ethyl-1,3,6,8-tetrakis-(4-fluoro-phenyl)-9H-carbazole (2) were synthesized and characterized by single-crystal X-ray diffraction. Thereinto, the crystal structures of compounds 1 and 2 were composed by asymmetry units. The ratio of compounds 1 and 2 to the solvent molecule cyclohexane (CYH) is 4/3. X-ray analysis reveals that the 1,3,6,8-phenyl groups are distorted at large angles relative to the planar carbazole ring. Furthermore, the luminescent and thermal properties of 1 and 2 have also been investigated. It can be seen that thermal stability of compound 1 with p-tolyl is better than that of 2 with 4-fluoro-phenyl. Fluorescence spectra analysis showed that compounds 1 and 2 have strong UV emission. 相似文献
19.
Caira MR le Roex T Nassimbeni LR Ripmeester JA Weber E 《Organic & biomolecular chemistry》2004,2(16):2299-2304
The structures of the inclusion compounds formed by the host H = 9,9'-(biphenyl-4,4'-diyl)bis(fluoren-9-ol) with N,N-dimethylacetamide (H.2DMA and H.4DMA), 1,4-dioxane (H.3DIOX), methyl ethyl ketone (H.2MEK), as well as that of the apohost have been elucidated. The compounds were characterised by thermal analysis and solid state NMR, and the kinetics of desorption of H.4DMA, H.2DMA and H.3DIOX have been examined. 相似文献
20.
Effect of metal compounds on the thermal degradation behaviors of poly(3-hydroxybutyric acid) (P(3HB)), poly(4-hydroxybutyric acid) (P(4HB)), and poly(?-caprolactone) (PCL) was investigated by means of thermogravimetric and pyrolysis-gas chromatograph mass spectrometric analyses. Na and Ca compounds accelerated a random chain scission of P(3HB) molecules resulting in a decrease of thermal degradation temperature, whereas the contribution of Zn, Sn, Al compounds to the thermal degradation of P(3HB) was very small. In contrast to P(3HB), Zn, Sn and Al compounds induced the thermal degradation of PCL at lower temperature range by catalyzing the selective unzipping depolymerization from ω-hydroxyl chain end. Transesterification reaction of PCL molecules could be facilitated by the presence of Ca compound, while the gravimetric change was detected at almost identical temperature region regardless of the content of Ca compound. According to the lactonizing characteristic of monomer unit, the thermal degradation of P(4HB) progressed by the cyclic rupture via unzipping reaction from the ω-hydroxyl chain end or/and random intramolecular transesterification at the main chain with a release of γ-butyrolactone as volatile product. Each of metal compounds used in this study was effective to catalyze the cyclic rupture of P(4HB) molecules, and the degradation rate was accelerated by the presence of metal compounds. 相似文献