Finite element technique to solve the elastic strain for Leonov fluid flow

The finite element method is used to find the elastic strain (and thus the stress) for given velocity fields of the Leonov model fluid. With a simple linearization technique and the Galerkin formulation, the quasi-linear coupled first-order hyperbolic differential equations together with a non-linear equality constraint are solved over the entire domain based on a weighted residual scheme. The proposed numerical scheme has yielded efficient and accurate convective integrations for both the planar channel and the diverging radial flows for the Leonov model fluid. Only the strain in the inflow plane is required to be prescribed as the boundary conditions. In application, it can be conveniently incorporated in an existing finite element algorithm to simulate the Leonov viscoelastic fluid flow with more complex geometry in which the velocity field is not known a priori and an iterative procedure is needed.     

Multiscale simulation of viscoelastic free surface flows

A micro–macro approach based on combining the Brownian configuration fields (BCF) method [M.A. Hulsen, A.P.G. van Heel, B.H.A.A. van den Brule, Simulation of viscoelastic flow using Brownian configuration fields, J. Non-Newtonian Fluid Mech. 70 (1997) 79–101] with an Arbitrary Lagrangian–Eulerian (ALE) Galerkin finite element method, using elliptic mesh generation equations coupled with time-dependent conservation equations, is applied to study slot coating flows of polymer solutions. The polymer molecules are represented by dumbbells with both linear and non-linear springs; hydrodynamic interactions between beads are incorporated. Calculations with infinitely extensible (Hookean) and pre-averaged finitely extensible (FENE-P) dumbbell models are performed and compared with equivalent closed-form macroscopic models in a conformation tensor based formulation [M. Pasquali, L.E. Scriven, Free surface flows of polymer solutions with models based on the conformation tensor, J. Non-Newtonian Fluid Mech. 108 (2002) 363–409]. The BCF equation for linear dumbbell models is solved using a fully implicit time integration scheme which is found to be more stable than the explicit Euler scheme used previously to compute complex flows. We find excellent agreement between the results of the BCF based formulation and the macroscopic conformation tensor based formulation. The computations using the BCF approach are stable at much higher Weissenberg numbers, (where λ is the characteristic relaxation time of polymer, and is the characteristic rate of strain) compared to the purely macroscopic conformation tensor based approach, which fail beyond a maximum Wi. A novel computational algorithm is introduced to compute complex flows with non-linear microscopic constitutive models (i.e. non-linear FENE dumbbells and dumbbells with hydrodynamic interactions) for which no closed-form constitutive equations exist. This algorithm is fast and computationally efficient when compared to both an explicit scheme and a fully implicit scheme involving the solution of the non-linear equations with Newton’s method for each configuration field.     

Efficient simulation of nonlinear viscoelastic fluid flows

This paper presents a new and efficient method for computing the flow of a non-Newtonian fluid. The approach is based on two independent concepts:Time-dependent simulation of viscoelastic flow: A new decoupled algorithm, presented in P. Saramito, Simulation numérique d'ecoulements de fluides viscoélastiques par éléments finis incompressibles et une méthode de directions alternées; applications, Thèse de l'Institut National Polytechnique de Grenoble, 1990 and P. Saramito, Numerical simulation of viscoelastic fluid flows using incompressible finite element method and a θ-method, Math. Modelling Num. Anal., 35 (1994) 1–35, enables us to split the major difficulties of this problem, and to solve it more efficiently. Moreover, this scheme is of order two in time, and can be used to obtain stationary flows in an efficient way.Conservative finite element method: this method combines the incompressible Raviart Thomas element, the discontinuous Lesaint-Raviart element, and a finite volume element method. It satisfies exactly the mass conservation law, and leads to an optimal size for the nonlinear system in terms of the total degree of freedom versus the mesh size.We apply our numerical procedure to the Phan-Thien-Tanner model with a classical benchmark: the four to one abrupt contraction. The numerical solutions exhibit good behavior, especially near the singularity, in the vicinity of the re-entrant corner. The numerical experiments present the main features of such flows: vortex development and overshooting of the velocity profile along the axis of symmetry in the entry region.     

Coupled thermo-mechanical modelling of bulk-metallic glasses: Theory, finite-element simulations and experimental verification

A three-dimensional, finite-deformation-based constitutive model to describe the behavior of metallic glasses in the supercooled liquid region has been developed. By formulating the theory using the principles of thermodynamics and the concept of micro-force balance [Gurtin, M., 2000. On the plasticity of single crystals: free energy, microforces, plastic-strain gradients. J. Mech. Phys. Solids 48, 989-1036], a kinetic equation for the free volume concentration is derived by augmenting the Helmholtz free energy used for a conventional metallic alloy with a flow-defect free energy which depends on the free volume concentration and its spatial gradient. The developed constitutive model has also been implemented in the commercially available finite-element program ABAQUS/Explicit (2005) by writing a user-material subroutine. The constitutive parameters/functions in the model were calibrated by fitting the constitutive model to the experimental simple compression stress-strain curves conducted under a variety of strain-rates at a temperature in the supercooled liquid region [Lu, J., Ravichandran, G., Johnson, W., 2003. Deformation behavior of the Zr-Ti-Cu-Ni-Be bulk metallic glass over a wide range of strain-rates and temperatures. Acta Mater. 51, 3429-3443].With the model calibrated, the constitutive model was able to reproduce the simple compression stress-strain curves for jump-in-strain-rate experiments to good accuracy. Furthermore stress-strain responses for simple compression experiments conducted at different ambient temperatures within the supercooled liquid region were also accurately reproduced by the constitutive model. Finally, shear localization studies also show that the constitutive model can reasonably well predict the orientation of shear bands for compression experiments conducted at temperatures within the supercooled liquid region [Wang, G., Shen, J., Sun, J., Lu, Z., Stachurski, Z., Zhou, B., 2005. Compressive fracture characteristics of a Zr-based bulk metallic glass at high test temperatures. Mater. Sci. Eng. A 398, 82-87].     

Forward roll coating flows of viscoelastic liquids

Roll coating is distinguished by the use of one or more gaps between rotating cylinders to meter and apply a liquid layer to a substrate. Except at low speed, the two-dimensional film splitting flow that occurs in forward roll coating is unstable; a three-dimensional steady flow sets in, resulting in more or less regular stripes in the machine direction. For Newtonian liquids, the stability of the two-dimensional flow is determined by the competition of capillary and viscous forces: the onset of meniscus nonuniformity is marked by a critical value of the capillary number. Although most of the liquids coated industrially are non-Newtonian polymeric solutions and dispersions, most of the theoretical analyses of film splitting flows relied on the Newtonian model. Non-Newtonian behavior can drastically change the nature of the flow near the free surface; when minute amounts of flexible polymer are present, the onset of the three-dimensional instability occurs at much lower speeds than in the Newtonian case.Forward roll coating flow is analyzed here with two differential constitutive models, the Oldroyd-B and the FENE-P equations. The results show that the elastic stresses change the flow near the film splitting meniscus by reducing and eventually eliminating the recirculation present at low capillary number. When the recirculation disappears, the difference of the tangential and normal stresses (i.e., the hoop stress) at the free surface becomes positive and grows dramatically with fluid elasticity, which explains how viscoelasticity destabilizes the flow in terms of the analysis of Graham [M.D. Graham, Interfacial hoop stress and instability of viscoelastic free surface flows, Phys. Fluids 15 (2003) 1702–1710].     

Numerical study around the corotational Maxwell model for the viscoelastic fluid flows

We present numerical results for the FEM (finite element method) presented in [Comput. Methods Appl. Mech. Engrg. 191 (2002) 5045–5065]. This method is devoted to the approximation of fluid flows obeying the Oldroyd model. A particularity of this method, is to take into account the purely viscoelastic case, the so-called Maxwell model, important in practice. Numerical results are given for a fluid flowing in an abrupt plane 4 to 1 contraction. We use the corotational Maxwell model as benchmark in the choice of our computations. Results are also given for the upper convected Maxwell model. Interesting effects appear on the velocity profile: a phenomenon of quasi slip at the downstream wall.     

Inelastic constitutive equations for complex flows

A new class of inelastic constitutive equations is presented and discussed. In addition to the rate-of-strain tensor, the stress is assumed to depend also on the relative-rate-of-rotation tensor, a frame-indifferent quantity that brings information about the nature of the flow. The material functions predicted by these constitutive equations are given for simple shear and uniaxial extension. A special case of these equations takes the Newtonian form, except that the viscosity is a function of the invariants of both kinematic tensors on which the stress depends. This simple constitutive equation has potential applications in liquid flow process simulations, since it combines simplicity with the capability of responding independently to shear and extension, as real liquids seem to do. Finally, possible forms for the new viscosity function are discussed.     

On the fully developed tube flow of a class of non-linear viscoelastic fluids

The fully developed pipe flow of a class of non-linear viscoelastic fluids is investigated. Analytical expressions are derived for the stress components, the friction factor and the velocity field. The friction factor which depends on the Deborah and Reynolds numbers is substantially smaller than the corresponding value for the Newtonian flow field with implications concerning the volume flow rate. We show that non-affine models in the class of constitutive equations considered such as Johnson-Segalman and some versions of the Phan-Thien-Tanner models are not representative of physically realistic flow fields for all Deborah numbers. For a fixed value of the slippage factor they predict physically admissible flow fields only for a limited range of Deborah numbers smaller than a critical Deborah number. The latter is a function of the slippage.     

Purely elastic flow asymmetries in flow-focusing devices

The flow of a viscoelastic fluid through a microfluidic flow-focusing device is investigated numerically with a finite-volume code using the upper-convected Maxwell (UCM) and Phan-Thien–Tanner (PTT) models. The conceived device is shaped much like a conventional planar “cross-slot” except for comprising three inlets and one exit arm. Strong viscoelastic effects are observed as a consequence of the high deformation rates. In fact, purely elastic instabilities that are entirely absent in the corresponding Newtonian fluid flow are seen to occur as the Deborah number (De) is increased above a critical threshold. From two-dimensional numerical simulations we are able to distinguish two types of instability, one in which the flow becomes asymmetric but remains steady, and a subsequent instability at higher De in which the flow becomes unsteady, oscillating in time. For the UCM model, the effects of the geometric parameters of the device (e.g. the relative width of the entrance branches, WR) and of the ratio of inlet average velocities (VR) on the onset of asymmetry are systematically examined. We observe that for high velocity ratios, the critical Deborah number is independent of VR (e.g. De_c ≈ 0.33 for WR = 1), but depends non-monotonically on the relative width of the entrance branches. Using the PTT model we are able to demonstrate that the extensional viscosity and the corresponding very large stresses are decisive for the onset of the steady-flow asymmetry.     

On the relevance of Continuum Damage Mechanics as applied to the Mullins effect in elastomers

The present paper reports and rationalizes the use of Continuum Damage Mechanics (CDM) to describe the Mullins effect in elastomers. Thermodynamics of rubber-like hyperelastic materials with isotropic damage is considered. Since it is demonstrated that stress-softening is not strictly speaking a damage phenomenon, the limitations of the CDM approach are highlighted. Moreover, connections with two-network-based constitutive models proposed by other authors are exhibited through the choice of both the damage criterion and the measure of deformation. Experimental data are used to establish the evolution equation of the stress-softening variable, and the choice of the maximum deformation endured previously by the material as the damage criterion is revealed as questionable. Nevertheless, the present model agrees qualitatively well with experiments except to reproduce the strain-hardening phenomenon that takes place as reloading paths rejoin the primary loading path. Finally, the numerical implementation highlights the influence of loading paths on material response and thereby demonstrates the importance of considering the Mullins effect in industrial design.     

Highly parallel time integration of viscoelastic flows

A highly parallel time integration method is presented for calculating viscoelastic flows with the DEVSS-G/DG finite element discretization. The method is a synthesis of an operator splitting time integration method that decouples the calculation of the polymeric stress by solution of a hyperbolic constitutive equation from the evolution of the velocity and pressure fields by solution of a generalized Stokes problem. Both steps are performed in parallel. The discontinuous finite element discretization of the hyperbolic constitutive equation leads to highly-parallel element-by-element calculation of the stress at each time step. The Stokes-like problem is solved by using the BiCGStab Krylov iterative method implemented with the block complement and additive levels method (BCALM) preconditioner. The solution method is demonstrated for the calculation of two-dimensional (2D) flow of an Oldroyd-B fluid around an isolated cylinder confined between two parallel plates. These calculations use extremely fine finite elements and expose new features of the solution structure.     

On the shear and bending of a degrading polymer beam

In this paper we develop a model, within a general framework that has been developed to describe the response of dissipative systems, for the strain induced degradation of polymeric solids, due to scission. The theory can be generalized to include degradation due to ultraviolet radiation, oxygen diffusion etc., by incorporating an appropriate form for the rate of dissipation associated with these processes. We study the simple shear and pure bending of such degrading polymer beams.     

Numerical simulation method for viscoelastic flows with free surfaces—fringe element generation method

To simulate filling flow in injection moulding for viscoelastic fluids, a numerical method, based on a finite element method and a finite volume method, has been developed for incompressible isothermal viscoelastic flow with moving free surfaces. The advantages of this method are, first, good applicability to arbitrarily shaped mould geometries and, second, accurate treatment for boundary conditions on the free surface. Typical filling flows are simulated, namely filling flow into a 1:4 expansion cavity with and without an obstacle. Numerical results predict the position of weld lines and air-traps. The method also indicates the effects of elongational flow on molecular orientation.     

A note on unsteady flows of a viscoelastic fluid with the fractional Maxwell model between two parallel plates

The fractional calculus approach in the constitutive relationship model of viscoelastic fluid is introduced. A generalized Maxwell model with the fractional calculus was considered. Exact solutions of some unsteady flows of a viscoelastic fluid between two parallel plates are obtained by using the theory of Laplace transform and Fourier transform for fractional calculus. The flows generated by impulsively started motions of one of the plates are examined. The flows generated by periodic oscillations of one of the plates are also studied.     

Velocity overshoots in gradual contraction flows

This study reports the results of a systematic numerical investigation, using the upper-convected Maxwell (UCM) and Phan-Thien–Tanner (PTT) models, of viscoelastic fluid flow through three-dimensional gradual planar contractions of various contraction ratios with the aim of investigating experimental observations of extremely large near-wall velocity overshoots in similar geometries [R.J. Poole, M.P. Escudier, P.J. Oliveira, Laminar flow of a viscoelastic shear-thinning liquid through a plane sudden expansion preceded by a gradual contraction, Proc. Roy. Soc. Lond. Ser. A 461 (2005) 3827]. We are able to obtain good qualitative agreement with the experiments, even using the UCM model in creeping-flow conditions, showing that neither inertia, second normal-stress difference nor shear-thinning effects are required for the phenomenon to be observed. Guided by the numerical results we propose a simple explanation for the occurrence of the velocity overshoots and the conditions under which they arise.     

Bifurcation phenomena in viscoelastic flows through a symmetric 1:4 expansion

In this work we present an investigation of viscoelastic flow in a planar sudden expansion with expansion ratio D/d = 4. We apply the modified FENE–CR constitutive model based on the non-linear finite extensibility dumbbells (FENE) model. The governing equations were solved using a finite volume method with the high-resolution CUBISTA scheme utilised for the discretisation of the convective terms in the stress and momentum equations. Our interest here is to investigate two-dimensional steady-state solutions where, above a critical Reynolds number, stable asymmetric flow states are known to occur. We report a systematic parametric investigation, clarifying the roles of Reynolds number (0.01 < Re < 100), Weissenberg number (0 < We < 100) and the solvent viscosity ratio (0.3 < β < 1). For most simulations the extensibility parameter of the FENE model was kept constant, at a value L² = 100, but some exploration of its effect in the range 100–500 shows a rather minor influence. The results given comprise flow patterns, streamlines and vortex sizes and intensities, and pressure and velocity distributions along the centreline (i.e. y = 0). For the Newtonian case, in agreement with previous studies, a bifurcation to asymmetric flow was observed for Reynolds numbers greater than about 36. In contrast viscoelasticity was found to stabilise the flow; setting β = 0.5 and We = 2 as typical values, resulted in symmetric flow up to a Reynolds number of about 46. We analyse these two cases in particular detail.     

A new decoupled finite element algorithm for viscoelastic flow. Part 2: Convergence properties of the algorithm

We present the results of some numerical experiments which were carried out in order to investigate the general characteristics of the algorithm described in Part I of this paper.     

Explicit algebraic stress modelling of homogeneous and inhomogeneous flows

Capability of the explicit algebraic stress models to predict homogeneous and inhomogeneous shear flows are examined. The importance of the explicit solution of the production to dissipation ratio is first highlighted by examining the algebraic stress models performance at purely irrotational strain conditions. Turbulent recirculating flows within sudden expanding pipes are further simulated with explicit algebraic stress model and anisotropic eddy viscosity model. Both models predict better stress–strain interactions, showing reasonable shear layer developments. The anisotropic stress field are also accurately predicted by the models, though the anisotropic eddy viscosity model of Craft et al. returns marginally better results. Copyright © 2005 John Wiley & Sons, Ltd.     

On the modeling of fluidity loss phenomena in Couette and Poiseuille flows of elastic liquids

Some effects of the possible relaxation transition from viscoelastic liquid state to highly elastic solid state were theoretically and numerically investigated in the shear situations, within the approach proposed in papers [1, 2, 5, 16]. It was found that for a single Maxwellian model the constitutive equations developed in [1, 2, 5] are not valid at elevated shear stresses. Some new aspects of the possible rheological behavior of elastic liquids in subcritical (before transition) and supercritical (after transition) regimes were demonstrated. The mechanism of fluidity loss studied in this paper could serve as a possible trigger mechanism for the melt flow instabilities.