无火焰原子吸收光度法连续测定化探样品中铜、铬、钴、镍、铅、镉

本文主要介绍了化探样品相态分析中无火焰原子吸收光度法测定化探样品中的铜、铬、钴、镍、铅、镉的分析方法。近年来，随着地质找矿工作的发展，地球化探人员对相态分析技术越来越感兴趣，在相态分析中，不同相态同一种元素的含量相差很大，给溶液的提取，制备及测定工作带来了很多不便，加之，大量的常量元素的存在尤其是钙、镁、锰、铁等元素极易产生干扰，在水溶态，离子态的分析液中铜、铬、钴、镍、铅、镉的含量又很低，给测试带来了很大难度，在相态的提取过程中，如果做平行、样品分析的话一个样品至少要制备八份溶液，工作量很大，因此，找到一个简单，快捷而又稳定可靠的测试方法是十分必要的，在测定中采用了磷酸为基体改进剂，它不仅可以消除基体的干扰，并可使各种元素测定的精密度得到很大改善。     

Onsager,ice, biomembranes,dimer models and the F-model

Personal recollections give a sampling of some of Onsager's later interests in ice and biomembranes. The author's involvement in these topics led to modeling a particular biomembrane phase transition using dimer models. Recent work is described for a particularly rich dimer model which is isomorphic to the F-model in three kinds of fields (direct, staggered, and quarter). New results for the full three-dimensional phase diagram show (1) how the anomalous OK multicritical point is destroyed by a direct field, and (2) how a new line of critical points must be added to the phase diagram in direct and staggered fields obtained previously by Baxter, due to diverging susceptibilities in the quarter field.     

Energy landscape theory,funnels, specificity,and optimal criterion of biomolecular binding

We study the nature of biomolecular binding. We found that in general there exists several thermodynamic phases: a native binding phase, a non-native phase, and a glass or local trapping phase. The quantitative optimal criterion for the binding specificity is found to be the maximization of the ratio of the binding transition temperature versus the trapping transition temperature, or equivalently the ratio of the energy gap of binding between the native state and the average non-native states versus the dispersion or variance of the non-native states. This leads to a funneled binding energy landscape.     

Pressure-induced structural phase transition in transition metal carbides TMC (TM = Ru,Rh, Pd,Os, Ir,Pt): a DFT study

First-principles calculations based on density functional theory was performed to analyse the structural stability of transition metal carbides TMC (TM = Ru, Rh, Pd, Os, Ir, Pt). It is observed that zinc-blende phase is the most stable one for these carbides. Pressure-induced structural phase transition from zinc blende to NiAs phase is predicted at the pressures of 248.5 GPa, 127 GPa and 142 GPa for OsC, IrC and PtC, respectively. The electronic structure reveals that RuC exhibits a semiconducting behaviour with an energy gap of 0.7056 eV. The high bulk modulus values of these carbides indicate that these metal carbides are super hard materials. The high B/G value predicts that the carbides are ductile in their most stable phase.     

Density-functional calculations of alpha, beta, gamma, delta, delta', and epsilon plutonium

Total energies for the six known polymorphs of plutonium metal have been calculated within spin and orbital polarized density-functional theory as a function of lattice constant. Theoretical equilibrium volumes and bulk moduli correspond well with experimental data and the calculated total energies are consistent with the known phase diagram of Pu. It is shown that a preference for the formation of magnetic moments, increasing through the alpha-->beta-->gamma phases, explains their position in the ambient pressure phase diagram and their anomalous variation of atomic density. A simple model is presented that establishes a relationship between atomic density, crystal symmetry, and magnetic moments which is universally valid for all Pu phases.     

Phase sensitive,all-optical and self-integrated multi-logic AND,OR, XOR,and NOT gates

The design and simulation of all-optical and self-integrated primary logical AND, OR, XOR and NOT gates based on phase sensitivity of spatial optical solitons have been reported. By tuning the phase of incident solitons into a bulky nonlinear Kerr medium and interaction between the phase tuned solitons, the self-integrated logical gates are achieved simultaneously in a 50 μm long distance by one setup. These are the advantages in the application and design of integrated circuits. In addition, the proposed logical gates can be cascaded and the logical AND and XOR gates can simultaneously have two outputs. The simplicity of constructing, simultaneous functions with one setup, the possibility of integrating, high sensitivity and fabrication ease are the advantages of the proposed logical gates and may be a good candidate for the future of integrated photonic computational circuits.     

Shaping of focal field with controllable amplitude,phase, and polarization

We propose a method for configuring the distribution of amplitude, phase, and polarization in the focal region of vector beams. The polarization and phase of incident beam is spatially tailored so that it can produce a focal field that has elaborately prescribed shapes. Our work focuses on the design of a special focus structure with two oval rings, wherein a phase gradient and polarization gradient exist in the inner and outer rings, respectively. The incident light yielding the desired focal field is determined based on an iterative scheme involving vectorial diffraction calculations and fast Fourier transforms. Simulations and experiments demonstrate the generation of a focal field with phase and polarization gradients, which may find applications in optical manipulation.     

Conversion from phase map to coordinate: Comparison among spatial carrier, Fourier transform, and phase shifting methods

For full-field phase measurement methods, many algorithms have been developed to extract a phase map from fringe image(s). Both phase wrapping and unwrapping algorithms have been extensively investigated by many researchers, but few papers can be found on how to calculate the coordinates of surface points from a phase map. This paper focuses on algorithms that show how a phase map can be used to calculate coordinates. Details are given for single image methods such as Fourier transform, spatial carrier methods, and multiple image methods like traditional phase-shifting methods. Algorithms that can be used to convert a phase map to coordinates and some issues related to these conversion algorithms are discussed. An artifact is measured using these phase measurement methods. The results show that using the correct algorithm to convert a phase map to coordinates is a key to obtaining accurate measurement results.     

Mixed state geometric phases, entangled systems, and local unitary transformations

The geometric phase for a pure quantal state undergoing an arbitrary evolution is a "memory" of the geometry of the path in the projective Hilbert space of the system. We find that Uhlmann's geometric phase for a mixed quantal state undergoing unitary evolution depends not only on the geometry of the path of the system alone but also on a constrained bilocal unitary evolution of the purified entangled state. We analyze this in general, illustrate it for the qubit case, and propose an experiment to test this effect. We also show that the mixed state geometric phase proposed recently in the context of interferometry requires unilocal transformations and is therefore essentially a property of the system alone.     

First principles study of the structural,electronic, mechanical and superconducting properties of WX (X=C,N)

The structural, electronic, mechanical and superconducting properties of tungsten carbide (WC) and tungsten nitride (WN) are investigated using first principles calculations based on density functional theory (DFT). The computed ground state properties, such as equilibrium lattice constant and cell volume, are in good agreement with the available experimental data. A pressure induced structural phase transition is observed in both tungsten carbide and nitride, from a tungsten carbide phase (WC) to a zinc blende phase (ZB), and from a zinc blende phase (ZB) to a wurtzite phase (WZ). The electronic structure reveals that these materials are metallic at ambient conditions. The calculated elastic constants obey the Born-Huang criteria, suggesting that they are mechanically stable at normal and high pressure. Also, the superconducting transition temperature is estimated for the WC and WN in stable structures at atmospheric pressure.     

Topology, phase transitions, and the spherical model

The topological hypothesis states that phase transitions should be related to changes in the topology of configuration space. The necessity of such changes has already been demonstrated. We characterize exactly the topology of the configuration space of the short range Berlin-Kac spherical model, for spins lying in hypercubic lattices of dimension d. We find a continuum of changes in the topology and also a finite number of discontinuities in some topological functions. We show, however, that these discontinuities do not coincide with the phase transitions which happen for d > or = 3, and conversely, that no topological discontinuity can be associated with them. This is the first short range, confining potential for which the existence of special topological changes are shown not to be sufficient to infer the occurrence of a phase transition.     

Structural, elastic, phonon and electronic properties of a MnPd alloy

The structural, elastic, phonon and electronic properties of a MnPd alloy have been investigated using the first-principles calculation. The calculated lattice constants and electronic structure agree well with the experimental results. The microscopic mechanism of the diffusionless martensitic transition from the paramagnetic B2 (PM-B2) phase to the antiferromagnetic L10 (AFM-L10) phase through the intermediate paramagnetic L10 (PM-L10 ) phase has been explored theoretically. The obtained negative shear modulus C′= (C11-C12)/2 of the PM-B2 phase is closely related to the instability of the cubic B2 phase with respect to the tetragonal distortions. The calculated phonon dispersions for the PM-L10 and AFM-L10 phases indicate that they are dynamically stable. However, the AFM-L10 phase is energetically most favorable according to the calculated total energy order, so the PM-L10 →AFM-L10 transition is caused by the magnetism rather than the electron-phonon interaction. Additionally, the AFM-L10 state is stabilized through the formation of a pseudo gap located at the Fermi level. The calculated results show that the CuAu-I type structure in the collinear antiferromagnetic state is dynamically and mechanically stable, thus is the low temperature phase.     

The uniaxial brickwork model,exact results,and CVM approximation

A complete phase diagram of the uniaxial brickwork lattice is determined first by using exact results, and then by using the cluster variation method. Both results are in very good agreement, which demonstrates the reliability of the CVM for two-dimensional systems. A well-defined maximum in the exact specific heat and a divergence of the CVM susceptibility provide strong indication for the occurrence of a floating phase.     

Jahn-Teller solitons, structural phase transitions, and phase separation

It is demonstrated that under common conditions a molecular solid subject to Jahn-Teller interactions supports stable Q-ball-like nontopological solitons. Such solitons represent a localized lump of excess electric charge in periodic motion accompanied by a time-dependent shape distortion of a set of adjacent molecules. The motion of the distortion can correspond to a true rotation or to a pseudorotation about the symmetric shape configuration. These solitons are stable for Jahn-Teller coupling strengths below a critical value; however, as the Jahn-Teller coupling approaches this critical value, the size of the soliton diverges signaling an incipient structural phase transition. The soliton phase mimics features commonly attributed to phase separation in complex solids.     

Vibrational spectroscopy at high pressures. Part 50. A Raman scattering study of MSCN (M = K,Rb, Cs,NH4) at high pressures

The phase behaviour of the title compounds was studied at high pressures using Raman spectroscopy. The isostructural materials KSCN and RbSCN show two phase changes (12.5 and 45.5 kbar; 10.5 and 37.5 kbar, respectively) which appear to be second order in type. Structures and transition mechanisms are proposed for each phase. CsSCN has a different orthorhombic structure and shows only one phase change in the range studied, at 23.5 ± 1.5 kbar, which also seems to be second order. The known phase transition in NH₄SCN at 2 kbar has been confirmed, and a new one found at 10 kbar. A monoclinic cell is proposed for the new phase.     

Sample motion-insensitive, full-range, complex, spectral-domain optical-coherence tomography

We present a full-range, complex, spectral-domain optical-coherence-tomography (SD-OCT) system that is based on a double-beam scanning approach. The sample beams of two identical SD-OCT setups are combined collinearly by a bulk optic beam splitter before illuminating the object. The required phase shift for the complex signal reconstruction comes from the phase difference between both interferometers. Because of the double-beam scanning approach, our system is completely insensitive to sample motion. To demonstrate the performance of our setup, we present images of the human optic nerve head in vivo and of a human tooth.     

Dense loops,supersymmetry, and Goldstone phases in two dimensions

Loop models in two dimensions can be related to O(N) models. The low-temperature dense-loops phase of such a model, or of its reformulation using a supergroup as symmetry, can have a Goldstone broken-symmetry phase for N<2. We argue that this phase is generic for -2相似文献   

Scaling analysis of the magnetocaloric effect in Gd5Si2Ge1.9X0.1 (X=Al, Cu, Ga, Mn, Fe, Co)

The field dependence of the magnetic entropy change has been studied for a series of doped Gd₅Si₂Ge₂ alloys, which possess a magnetic phase transition that is either entirely second order or a combination of primarily second-order mixed to a very minor degree with a first-order transition arising from a magneto-structural phase change. By analyzing the field scaling of the refrigerant capacity as well as of the reference temperatures used for constructing a universal scaling curve, a procedure for estimating the values of the critical exponents for the alloys was developed. For the cases where the transition is entirely second order, the results obtained from this procedure are comparable to the values obtained from the Kouvel–Fisher method. For the case of Fe-doped alloys which partially possess a first-order phase change, the Kouvel–Fisher method is inapplicable. However, their critical exponents determined by our developed procedure can be used to estimate the Curie temperature of the orthorhombic majority phase.     

Precise, real-time, every-single-shot, carrier-envelope phase measurement of ultrashort laser pulses

In this Letter we demonstrate a method for real-time determination of the carrier-envelope phase of each and every single ultrashort laser pulse at kilohertz repetition rates. The technique expands upon the recent work of Wittmann and incorporates a stereographic above-threshold laser-induced ionization measurement and electronics optimized to produce a signal corresponding to the carrier-envelope phase within microseconds of the laser interaction, thereby facilitating data-tagging and feedback applications. We achieve a precision of 113 mrad (6.5°) over the entire 2π range.     

Topological lifshitz line, off-specular scattering, and mesoporous materials

Ordered phases formed by surfactants in water solutions, and used in technological processes as templates for the synthesis of mesoporous materials, exhibit topological fluctuations. From the results of the Monte Carlo simulations of the lamellar phase we have established a relation between topological fluctuations and the behavior of the off-specular scattering intensity. We have defined the topological Lifshitz line. At this line the peak position in the off-specular scattering intensity moves from the zero (lamellar phase with fixed topology) to the nonzero value of the scattering wave vector (lamellar phase with fluctuating topology).