共查询到18条相似文献,搜索用时 406 毫秒
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本文使用多组态Dirac-Fock方法计算了类氧钆离子2s22p4,2s2p5,2s22p3s,2s22p33p组态的精细结构能级和激发态的辐射寿命,以及电偶极、磁偶极、电四极跃迁的波长、自发辐射几率、受激辐射几率和振子强度.计算结果可为可能的真空紫外激光器的研制提供必要的理论依据. 相似文献
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用多组态HXR理论方法对KrIV-CdXVI离子4s24p3和4s4p4组态的精细结构能级进行了分析计算。在已有研究工作的基础上,通过对4s24p3和4s4p4组态能级的实验观测值与HXR计算结果之差ΔE沿等电子序列变化规律的分析,找出了ΔE随有效核电荷数Zc变化的规律,预言并计算了PdXIV-CdXVI离子4s24p3和4s4p4组态能级,大部分预言计算值与实验结果的偏差小于100 cm-1。由此还进一步计算了PdXIV-CdXVI子4s24p3-4s4p4跃迁的谱线波长、振子强度和跃迁概率。结果表明:除了4s24p3 2D5/2-4s4p4 2D5/2跃迁的谱线波长(29.992 nm)与实验值相差0.018 nm外,对于其余5条谱线,预言值与实验值的偏差均不超过0.005 nm。 相似文献
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利用基于全相对论框架下的多组态Dirac-Fock理论方法发展起来的程序包GRASP92和新发展的处理辐射跃迁过程的程序REOS99,计算了类镍等电子系列离子(Z=45—95)的基组态3s23p63d101S0以及低激发组态3s23p63d94l,3s23p53d104l和3s3p63d104l(l=s,p,d,f)的能级及其向基态的M1,M2,E2禁戒跃迁概率.通过分析高离化类镍离子在特定的原子序数范围内由于存在能级交叉而产生的强组态相互作用,解释了高离化类镍离子禁戒跃迁概率的反常变化现象,探讨了禁戒跃迁概率受强组态相互作用影响而变化的一般规律. 相似文献
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在考虑组态相互作用的基础上,利用包含相对论修正的Hartree-Fock(HFR)理论对S8+-S13+离子的谱线波长及加权振子强度等有关原子参数进行了系统计算,并与最新的实验观测和其它理论计算结果进行了比较。计算结果表明:S8+-S11+的各个原子态在LS耦合下纯度很高,随着离化度的增大,S12+和S13+离子的部分原子态能级出现混合,组态相互作用逐渐增强。通过对实验结果的分析,识别出32条实验谱线,其中大多数谱线来自S8+-S13+离子的2s22pk-2s2pk+1和2s2pk+1-2s2pk+2(k=0,1,2,3,4)之间的跃迁,理论计算结果与实验谱线波长之间的绝对误差大多数都在实验的有效分辨力以内。 相似文献
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本文对2s1/2-1d3/2壳层原子核(A=30—40)能谱作了系统分析,计算仅限于由2s1/2和1d3/2支壳层产生的情态,但考虑了它们之间的全部组态混合效应。计算是采用多粒子壳模型的Talmi方法,将二体矩阵元当作参数,其值由实验确定。文中详细分析了Si30,Si31,P30,P31,P32,S32,Ar37,Ar38,K38等原子核能谱,理论与实验符合颇好。 相似文献
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利用全相对论组态相互作用理论方法,研究了类铷W37+离子从基组态3s23p63d104s24p64d经过双激发态(3s23p63d104s24p64d)-1nln′l′(n,n′=4,5)的双电子复合过程,得到了该离子在温度为1~5×104 eV范围内的总双电子复合速率系数。分析比较了不同电子激发的双电子复合速率系数,结果表明:4p电子激发的双电子复合速率系数在低温时给出了主要贡献,而3d的贡献在高温时突出。由于强组态相互作用,两电子一光子跃迁对双电子复合速率系数的贡献不可忽略,其中辐射跃迁4p54d5d5f-4p64f5d的贡献是双激发态4p54d5d5f总的双电子复合速率系数的5%。对双电子复合、辐射复合以及三体复合速率系数的比较表明,在所研究的温度范围内双电子复合速率系数最大。 相似文献
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É. Biémont H.-P. Garnir P.-H. Lefèbvre P. Palmeri L. Philippart P. Quinet D. Rostohar C. J. Zeippen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,40(1):91-99
Oscillator strengths have been calculated for the transitions depopulating levels of the 3s23p3, 3s3p4 configurations of K V, of the 3s23p2, 3s3p3 configurations of K VI and of the 3s23p, 3s3p2, 3p3 and 3s3p3d configurations of K VII. A multiconfiguration Dirac-Fock method, incorporating the relativistic two-body Breit
interaction and quantum electrodynamics corrections due to self-energy and vacuum polarization, has been used for the calculations.
The reliability of this approach has been tested by comparison with relativistic Hartree-Fock calculations and also with some
experimental measurements performed by beam-foil spectroscopy at a beam energy of 1.7 MeV. 相似文献
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N. Singh A. K.S. Jha M. Mohan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,38(2):285-291
Breit-Pauli Energy levels, oscillator strengths and transition probabilities
for all the transitions in Cl I between the fine structure levels of
3s2 3p5, 3s2 3p43d, 3s2 3p44s and 3s23p44p states are calculated using extensive configuration interaction (CI) wave functions. We have also determined the lifetimes
of 3s2 3p43d, 3s2 3p44s and 3s2 3p44p levels. The
relativistic effects are included through Breit-Pauli approximation via spin-orbit, Darwin and mass correction terms. Prior
to the calculations of the oscillator strengths and transition probabilities, we fine-tune the CI coefficient using experimental
energies. Our results are compared with experimental and other available theoretical data. The calculated energy levels are
in close agreement with most of the NIST compiled data. We predict new lifetime data for several levels where no other theoretical
and/or experimental results are available, which will form the basis for the
future experimental work.
Electronic supplementary material Online Material 相似文献
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This paper calculates the electron impact excitation rate coefficients from the ground term 2s22p2 3P to the excited terms of the 2s22p2, 2s2p3, 2s22p3s, 2s22p3p, and 2s22p3d configurations of N II. In the calculations, multiconfiguration Dirac--Fork wave functions have been applied to describe the target-ion states and relativistic distorted-wave calculation has been performed to generate fine-structure collision strengths. The collision strengths are then averaged over a Maxwellian distribution of electron velocities in order to generate the effective collision strengths. The calculated rate coefficients are compared with available experimental and theoretical data, and some good agreements are found for the outer shell electron excitations. But for the inner shell electron excitations there are still some differences between the present calculations and available experiments. 相似文献
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A. K.S. Jha P. Jha S. Tyagi M. Mohan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,39(3):391-398
We present relativistic close-coupling photoionization calculations of Al IV
using the Breit-Pauli R-matrix method to obtain photoionization cross-section of Al IV from the ground state and the lowest
two J=0 (even) excited
states. A multi-configuration eigenfunctions expansion of the core Al V is
employed with spectroscopic configurations 2s22p5,
2s2p6,
2s22p43s, 2s22p43p, 2s22p43d and
2s22p44s. We have included, for the first time, the lowest 68
level target states of Al V in the photoionization calculations of Al IV.
Extensive configuration interaction wavefunctions are used to describe both
the initial Al IV states and the final Al V states. Cross-sections are
compared from three level calculations including only 2s2 2p5 2Po
3/2, 1/2 and 2s 2p6
2S1/2 levels of Al
V. The present calculation using the lowest 68 target levels of Al V are
presented for the first time and should provide reasonably complete database
for practical application for photoionization cross-section for Al IV, where
high-energy cross-sections along with near-threshold photoionization cross-section is required. 相似文献
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We have done relativistic calculations for the evaluation of energy levels, oscillator strengths, transition probabilities
and lifetimes for Cr VIII ion. Use has been made of configuration interaction technique by including Briet-Pauli approximation.
The energies of various levels from the ground state to excited levels of 3s3p6, 3s23p43d, 3s23p44s, 3s23p44d of Cr VIII are given in LSJ coupling scheme after fine-tuning and are compared with the experimental results compiled in
the NIST Data Base. Many new lines have been predicted which have not appeared so far in the NIST Data. 相似文献
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We have calculated the excitation energies, oscillator strengths and transition probabilities for electric-dipole-allowed
and intercombination transitions among the 46 LS levels belonging to the configurations 3s
23p
2, 3s3p
3, 3s
23p3d, 3p
4, 3s
23p4s, 3s
23p4p, 3s3p
2(2
S)4s, 3s3p
2(2
P)4s, 3s3p
2(4
P)4s, 3s3p
2(2
D)4s, 3s
23p4d and 3s
23p4f of Si-like Argon. These states are represented by extensive Configuration-Interaction (CI) wavefunctions obtained using the
CIV3 computer code of Hibbert. From our transition probabilities we have also calculated the radiative lifetimes of singlet
and triplet states of Ar V. Our results are compared with other available theoretical calculations and experimental data.
To assess the importance of relativistic effects on our calculated values, we have also carried out calculations in the intermediate-coupling
scheme using the Breit-Pauli Hamiltonian. Small adjustments to the diagonal elements of the Hamiltonian matrices have been
made so that the energy splittings are as close as possible to the experimentally compiled energy values of the National Institute
for standards and Technology (NIST). The energy splitting of 85 fine-structure levels, the oscillator strengths and transition
probabilities for electric-dipole-allowed and intercombination transitions and the lifetimes of some fine-structure levels
are presented and compared with available experimental and other theoretical values. In this calculation, we also predict
new data for several fine-structure levels where no other theoretical and experimental results are available. 相似文献