Synthesis，Crystal Structure of N－Salicylidene－o－aminobenzoic Acid Dipyridine Copper（Ⅱ） Monohydrate

Ｓｙｎｔｈｅｓｉｓ，ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＮ－Ｓａｌｉｃｙｌｉｄｅｎｅ－ｏ－ａｍｉｎｏｂｅｎｚｏｉｃＡｃｉｄＤｉｐｙｒｉｄｉｎｅＣｏｐｐｅｒ（Ⅱ）ＭｏｎｏｈｙｄｒａｔｅＬｉＳｈｕ－Ｌａｎ；ＬｉｕＤｅ－Ｘｉｎ；ＭｅｎｇＦａｎ－Ｑｉｎ；Ｚｈ...     

Crystal Structures of O－Vanillin－semicarbazide and Salicylaldehyde－semicarbazide

ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｓｏｆＯ－Ｖａｎｉｌｌｉｎ－ｓｅｍｉｃａｒｂａｚｉｄｅａｎｄＳａｌｉｃｙｌａｌｄｅｈｙｄｅ－ｓｅｍｉｃａｒｂａｚｉｄｅ￥ＬｉＳｈｕ－Ｌａｎ；ＬｉｕＤｅ－Ｘｉｎ；ＺｈｏｕＪｉａｎ－Ｈｕａ；ＭｅｎｇＦａｎ－Ｑｉｎ（Ｄｅｐａ...     

A Mass Spectrometric Study of γ－Amino－group－containing Propyltriethoxysilanes

ＡＭａｓｓＳｐｅｃｔｒｏｍｅｔｒｉｃＳｔｕｄｙｏｆγ－Ａｍｉｎｏ－ｇｒｏｕｐ－ｃｏｎｔａｉｎｉｎｇＰｒｏｐｙｌｔｒｉｅｔｈｏｘｙｓｉｌａｎｅｓＬｉｎＪｉ－Ｍａｏ；ＨｕａｎｇＷｅｎ－Ｔａｏ；ＦａｎｇＬｉ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，Ｓｈ...     

Synthesis and Structure of Di－μ－chlorobis（di－tert－butylcyclopentadienyl） Erbium Chloride

ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆＤｉ－μ－ｃｈｌｏｒｏｂｉｓ（ｄｉ－ｔｅｒｔ－ｂｕｔｙｌｃｙｃｌｏｐｅｎｔａｄｉｅｎｙｌ）ＥｒｂｉｕｍＣｈｌｏｒｉｄｅＲＥＮＪｉｎ－Ｓｏｎｇ；ＳＨＥＮＱｉ；ＨＵＪｉｎｇ－Ｙｕ；ＬＩＮＹｏｎｇ－Ｈｕａ；ＸＩ...     

Synthesis and X－ray Structure Analysis of Bis（carboethoxycyclopentadienyltricarbonylchromium）

ＳｙｎｔｈｅｓｉｓａｎｄＸ－ｒａｙＳｔｒｕｃｔｕｒｅＡｎａｌｙｓｉｓｏｆＢｉｓ（ｃａｒｂｏｅｔｈｏｘｙｃｙｃｌｏｐｅｎｔａｄｉｅｎｙｌｔｒｉｃａｒｂｏｎｙｌｃｈｒｏｍｉｕｍ）ＳｏｎｇＬｉ－Ｃｈｅｎｇ；ＷａｎｇＪｉ－Ｑｕａｎ；ＨｕＱｉｎｇ－Ｍｅｉ（Ｄｅ...     

A New Advance in Preparation of Mo-S(O) Clusters

ＡＮｅｗＡｄｖａｎｃｅｉｎＰｒｅｐａｒａｔｉｏｎｏｆＭｏ－Ｓ（Ｏ）Ｃｌｕｓｔｅｒｓ￥ＹａｏＹｕａｎ－Ｇｅｎ；ＷｕＬｉｎｇ；ＺｈｕＹｏｎｇ－Ｂａｏ；ＬｕＳｈａｏ－Ｆａｎｇ；（ＦｕｊｔａｎＩｎｓｔｉｔｕｔｅｏｆＲｅｓｅａｒｃｈｏｎｔｈｅＳｔｒｕｃｔｕｒｅ...     

Crystal and Molecular Structure of Di－chloro－bis（р－methylphenylbutylsulfide） Palladium（Ⅱ）

ＣｒｙｓｔａｌａｎｄＭｏｌｅｃｕｌａｒＳｔｒｕｃｔｕｒｅｏｆＤｉ－ｃｈｌｏｒｏ－ｂｉｓ（р－ｍｅｔｈｙｌｐｈｅｎｙｌｂｕｔｙｌｓｕｌｆｉｄｅ）Ｐａｌｌａｄｉｕｍ（Ⅱ）￥ＧｕｏＳｏｎｇ－Ｓｈａｎ；ＣｕｉＬｉ；ＷａｎｇＨａｎｇ－Ｚｈａｎｇ；ＱｉａｎＰｕ（...     

Syntheses，Structures and Spectroscopic Properties of Mo（W）－Cu－S－Cluster Compounds with Dialkyldithiocarbamate Ligands

Ｓｙｎｔｈｅｓｅｓ，ＳｔｒｕｃｔｕｒｅｓａｎｄＳｐｅｃｔｒｏｓｃｏｐｉｃＰｒｏｐｅｒｔｉｅｓｏｆＭｏ（Ｗ）－Ｃｕ－Ｓ－ＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓｗｉｔｈＤｉａｌｋｙｌｄｉｔｈｉｏｃａｒｂａｍａｔｅＬｉｇａｎｄｓＣａｏＲｏｎｇ；ＬｅｉＸｉｎ－Ｊｉ...     

Quantum Chemistry Study on Structures of Cluster Ions Nb＿nS_ m~±Generated by Laser Mass Spectra

ＱｕａｎｔｕｍＣｈｅｍｉｓｔｒｙＳｔｕｄｙｏｎＳｔｒｕｃｔｕｒｅｓｏｆＣｌｕｓｔｅｒＩｏｎｓＮｂ＿ｎＳＧｅｎｅｒａｔｅｄｂｙＬａｓｅｒＭａｓｓＳｐｅｃｔｒａＭＡＹａｎ－ｈｕｉ；ＬＩＮＭｅｎｇ－ｈａｉ；ＺＨＥＮＧＬａｎ－ｓｕｎａｎｄＬＩＵＨｏｎｇ－ｌｉ...     

Crystal Structure of Co（S2CPh）3

ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＣｏ（Ｓ_２ＣＰｈ）_３ＬｕＳｈａｏ－Ｆａｎｇ；ＣｈｅｎＨｏｎｇ－Ｂｉｎ；ＨｕａｎｇＸｉａｏ－Ｙｉｎｇ（ＦｕｊｉａｎＩｎｓｔｉｔｕｔｅｏｆＲｅｓｅａｒｃｈｏｎｔｈｅＳｔｒｕｃｔｕｒｅｏｆＭａｔｔｅｒ，Ａｃａｄｅｍｉａ...     

Synthesis and Structure of 4—Nitrobenzaldehyde Thiosemicarbazone

ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ４－ＮｉｔｒｏｂｅｎｚａｌｄｅｈｙｄｅＴｈｉｏｓｅｍｉｃａｒｂａｚｏｎｅＴｉａｎＹｕ－Ｐｅｎｇ；ＤｕａｎＣｈｕｎ－Ｙｉｎｇ；ＬｕＺｈｏｎｇ－Ｌｉｎ；ＹｏｕＸｉａｏ－Ｚｅｎｇ（ＣｏｏｒｄｉｎａｔｉｏｎＣｈｅ...     

Molecular and Crystal Structure of Cinnam ylidene Acetophenone

１　ＩＮＴＲＯＤＵＣＴＩＯＮＣｕｒｒｅｎｔｌｙ，ｃｏｎｓｉｓｔｅｎｔｅｆｆｏｒｔｓｈａｖｅｂｅｅｎｍａｄｅｔｏｔｈｅｉｎｖｅｓｔｉｇａｔｉｏｎｏｆｏｒｇａｎｉｃｎｏｎｌｉｎｅａｒｏｐｔｉｃａｌ（ＮＬＯ）ｍａｔｅｒｉａｌｓ〔１〕．Ｓｏｍｅｏｆｃｉｎｎａｍｙｌｉｄｅｎｅａｃｅｔｏｐｈｅｎｏｎｅｄｅｒｉｖａｔｉｖｅｓｈａｖｅｆａｉｒｌｙｓｔｒｏｎｇｓｅｃｏｎｄｈａｒｍｏｎｉｃｇｅｎｅｒａｔｉｏｎ（ＳＨＧ）ａｎｄｔｈｅｒｅｆｏｒｅａｒｅｐｏｔｅｎｔｉａｌｕｓｅｆｕｌｉｎＮＬＯｆｉｅｌｄｓ．Ｄｕｒｉｎ…     

(C_5H_9C_5H_4)_3NdBrLi(THF)_3和(C_5H_9C_5H_4)_3SmTHF的合成与结构

无水三氯化钕与环戊烷基环戊二烯钠、溴化锂(1:2:1摩尔比)反应,除去不溶物和溶剂后,产物在己烷/四氢呋喃溶剂中冷冻得到兰紫色晶体(C5H9C5H4)3NdBrLi(THF)3(配合物1)。其中心金属Nd3+的配位数为10,以η5与3个环戊二烯基相连,并通过单溴原子桥连锂原子,形成双核结构。该晶体属三斜晶系,P`1空间群。晶体学参数为a=12.048(2)、b=13.498(3)、c=13.831(3);α=104.16(3)、β=104.07(3)、γ=95.96(3); V=2083.3(7)3、Z=2、Dc=1.35Mg/m3、Mr=847.01gmol-1、F(000)=874。无水三氯化钐与环戊烷基环戊二烯钠(1:3)反应,产物在-30oC下的己烷溶剂中结晶得桔红色晶体(C5H9C5H4)3SmTHF(配合物2)。该晶体属正交晶系,Fdd2空间群。晶胞参数a=28.175(5) 、b=46.24(2)、c=9.167(4);V=11943(8)3、Z=16、Dc=1.38Mg/m3、 Mr=622.11 g·mol-1、F(000)=5136。10配位的金属Sm3+与3个环戊二烯基以η5相连,并结合一个四氢呋喃溶剂分子。     

Schiff碱N-氧化吡啶-2-甲醛缩氨基硫脲的晶体结构

合成了标题Ｓｃｈｉｆｆ碱并获得了其单晶,化学式为Ｃ７Ｈ８Ｎ４ＯＳ,Ｍｒ＝ １９６．２３,经Ｘ射线单晶衍射分析,该晶体属于单斜晶系,空间群为Ｃ２／ｃ,晶胞参数： ａ＝ １３．１９８（２）,ｂ＝ ８．０７０（１）,ｃ＝ １６．９９９（２）,β＝ １０２．７６０（１０）°,Ｖ＝ １７６５．８（４）３,Ｚ＝ ８,Ｄｃ＝１．４７６ｇ／ｃｍ ３,μ＝ ０．３３０ｍ ｍ － １,Ｆ（０００）＝ ８１６,在２．４６°＜ θ＜ ２９．００°范围内以ω扫描方式收得独立衍射点２３４７ 个,其中Ｉ＞ ２σ（Ｉ）的可观测点为１６８７ 个。最终偏离因子Ｒ＝０．０３４４,ｗ Ｒ＝ ０．０８４３,（Δ／σ）ｍ ａｘ＝ ０．００１,Ｓ＝ １．０８２。分子为平面构型。与相应配合物的晶体结构进行了比较并讨论了配位前后标题化合物主要的键性质的变化。     

含有Mo--Mo四重键的双钼络合物Mo_2(C_8H_8)_3的合成和晶体结构

Mo_2(C_8H_8)_3是由Mo(CO)_6和环辛四烯在正癸烷中回流而制得。它的晶体属单斜晶系,空间群为P2_1,单胞参数为:a=7.772(3),b=11.964(5),c=10.445(2),β=100.33(2)°,V=955(1)~3,根据Z=2和fw=504.31计算密度Dc=1.75g/cm~3。在Enraf-Nonius CAD4衍射仪上用MoKα射线收集了I>2σ(I)的独立衍射点2393个。晶体结构用直接法(MULTAN)程序解出,所有非氢原子的位置参数和各向异性热振动参数经全矩阵最小二乘法修正,最后的偏离因子R_1(F)=0.030,R_2(F)=0.035。分子中钼—钼的距离为2.293(1),形成了Mo-Mo四重键。Mo_2(C_8H_8)_3存在两种晶型;一是与W_2(C_8H_8)_3同晶;另一是与Cr_2(C_8H_8)_3同晶。     

Synthesis, Structure and Spectral Characterization of a Discrete Binuclear Copper (II) Complex

1　ＩＮＴＲＯＤＵＣＴＩＯＮＲｅｃｅｎｔｌｙ,ｂｒｉｄｇｅｄｂｉｎｕｃｌｅａｒｃｏｍｐｌｅｘｅｓｏｆｆｉｒｓｔｒｏｗｔｒａｎｓｉｔｉｏｎｍｅｔａｌｓｈａｖｅｒｅｃｅｉｖｅｄｍｕｃｈａｔｔｅｎｔｉｏｎｏｎａｃｃｏｕｎｔｏｆｔｈｅｉｒｂｉｏｌｏｇｉｃａｌｒｅｌｅｖａｎｃｅａｎｄｃｏｎｄｅｎｓｅｄｐｈａｓｅｍａｇｎｅｔｉｃｐｒｏｐｅｒｔｉｅｓ[1,2].Ｉｎｔｈｅｓｅｒｅｓｅａｒｃｈｅｓ,ｍａｎｙｂｒｉｄｇｅｄｌｉｇａｎｄｓｗｈｉｃｈｐｌａｙｉｍｐｏｒｔａｎｔｒｏｌｅｓｈａｖｅｂｅｅｎｕｓｅｄａｓｕｓｅｆｕｌ…     

Antitumor Metallothiosemicarbazonate:Synthesis,Crystal Structure,Spectra and Antitumor Studies of Co(Ⅲ) Complex with Thiosemicarbazone Derivative of 2-Benzoylpyridine

The title complex Co(L)2Cl·4H2O I has been achieved via self-assembly by incorporating cobalt into 2-benzoylpyridine thiosemicarbazonate ligand, and characterized by elemental analysis, infrared spectra, mass spectra and single-crystal X-ray diffraction study. The crystal crystallizes in monoclinic, space group P21/n, with a=10.227(3), b=17.363(4), c=17.459(4), β=100.408(4)o, V=3049.2(13)3, Z=4, Mr=677.08, Dc=1.475 g/cm3, μ(MoKα)=0.834 mm-1, F(000)=1400, the final R=0.0747 and wR=0.0896 for 1663 observed reflections with I > 2σ(I). The complex contains one six-coordinated cobalt ion connected by two thiosemicarbazone ligands which act as a tridentate ligand to coordinate with the center metal atoms via two pyridyl nitrogen atoms, two imine nitrogen atoms and two sulfur atoms giving rise to a mononuclear structure. Hydrogen bonds existing in the complex link the different com-ponents to stabilize the crystal structure. The antitumor activity of the title complex was tested against A549 lung cancer cell line. Complex I exhibits antitumor activity.     

Crystal Structure of Nicotinic Acid(3,5-dinitrobenzoic Acid Organic Adduct

The title compound nicotinic acid(3,5-dinitrobenzoic acid(NDNT)has been obtained by the reaction of nicotinic acid with 3,5-dinitrobenzoic acid in deionic water at room temperature.The crystal is of monoclinic,space group P21/n with a=14.053(6),b=5.046(2),c=20.105(8)A,β=103.573(8)°,C13H9N3O8,Mr=335.23,Z=4,V=1385.8(10)A3,Dc=1.607g/cm3,μ(MoKα)=0.137 mm－1,F(000)=688,R=0.0435 and wR=0.0993 for 1239 observed reflections (I>2σ(I)).In the crystals,the asymmetric unit contains one nicotinic acid (C6H5NO2)and one 3,5-dinitrobenzoic acid (C7H4N2O6)molecules which are linked by some hydrogen bonds to form a twenty-membered hydrogen-bonded ring and an extended linear structure.     

CRYSTAL STRUCTURE OF 1-METHYL-6-(E-ETHOXYCAR-BONYLVINYL)-8-BENZOYL-2, 3-DIHYDRO-1H-IMIDAZO[1, 2-a] PYRIDIN-5-ONE

<正> The title compound C20H20N2O4(Mr=352.39)belongs to mono-clinic space group C2/c with a=9.208(4),b=11.714(3),c=32.336(8)A,β=100.83(2)°,V=7146.2(6)A3,Z=16,Dc=1.35 g/cm3,μ(Moka)=1.03 cm-1 and final R=0.06 for 1781 reflections with F≥2.5(F).There are two independent molecules in an asymmetric unit.Neither pyridinone nor phenyl ring is coplanar with the ketonic carbonyl group in the molecule.     

Homochiral laminar europium metal-organic framework with unprecedented giant dielectric anisotropy

Hydrothermal (deuteratothermal) reaction of L-ethyl lactate (Lig-Et) with Eu(ClO(4))(3)6 H(2)O gives colorless block crystals of [Eu(Lig)(2)(X(2)O)(2)][ClO(4)] (1, X=H; 2, X=D) both of which possess a two-dimensional laminar homochiral framework. Single-crystal dielectric measurements reveal that 1 and 2 display a giant dielectric anisotropy approximately exceeding 100 and large isotopic effect with about 54 % enhancement along the a axis. Their ferroelectric features further confirm this respect. Crystal parameters: 1, C(6)H(14)ClO(12)Eu, M(r)=465.58, monoclinic, C(2), a=8.6786(6), b=8.3965(6), c=10.2153(7) A, beta=92.040(1) degrees , V=743.92(9) A(3), Z=2, rho(calcd)=2.079 Mg m(-3), R(1)=0.0508, wR(2)=0.1239, mu=4.448 mm(-1), S=1.043; Flack=0.04(5). 2: C(6)H(10)D(4)ClO(12)Eu, M(r)=469.61, monoclinic, C(2), a=8.689(2), b=8.410(2), c=10.224(3) A, beta=92.057(4) degrees , V=746.7(3) A(3), Z=2, rho(calcd)=2.089 Mg m(-3), R(1)=0.0465, wR(2)=0.1150, mu=4.432 mm(-1), S=1.058; Flack=0.02(5).