The hydrostatic pressure and temperature effects on Raman scattering of a hydrogenic impurity in a disc-shaped quantum dot

Using the perturbation method and the effective-mass approximation, we studied the combined effects of hydrostatic pressure and temperature on Raman scattering in a disc-shaped quantum dot with a parabolic potential in the presence of an electric field. The differential cross-section involved in this process is calculated. Numerical calculations on a typical GaAs quantum dot are performed. The results show that not only the impurity but also the temperature and the hydrostatic pressure have an influence on the differential cross-section of the system.     

Spin-flip Raman laser

The properties of the spin-flip Raman laser (SFR laser) which depend on stimulated Raman scattering from mobile conduction electrons in InSb under an external magnetic field are presented. The essential parameters are derived from a macroscopic treatment of the stimulated Raman effect and the microscopic theory of the scattering cross-section, and are compared with experimental results. Output pulse powers as large as 1 kW have been measured for 10.6 and 5.3 μm excitation radiation and continuous powers of 1 W for continuous excitation with a 5.3 μm pump source. The SFR laser offers some interesting applications in physics and chemistry, since its frequency is proportional to the applied magnetic field and its linewidth can be made smaller than 1 kHz.     

Electron states and electron Raman scattering in semiconductor double cylindrical quantum well wire

The differential cross section for an electron Raman scattering process in a semiconductor GaAs/AlGaAs double quantum well wire is calculated,and expressions for the electronic states are presented.The system is modeled by considering T = 0 K and also with a single parabolic conduction band,which is split into a subband system due to the confinement.The gain and differential cross-section for an electron Raman scattering process are obtained.In addition,the emission spectra for several scattering configurations are discussed,and interpretations of the singularities found in the spectra are given.The electron Raman scattering studied here can be used to provide direct information about the efficiency of the lasers.     

First-order Raman scattering in cylindrical wurtzite nanowire

We have presented a theoretical study on electron resonant Raman scattering (ERRS) process associated with the bulk longitudinal optical (LO), surface optical (SO) and quasi-confined (QC) phonon modes in a free-standing wurtzite nanowire (NW). We consider the Fröhlich electron–phonon interaction in the framework of the dielectric continuum model. Numerical calculations on the GaN material reveal that differential cross-section (DCS) is sensitive to the wire size. The bulk LO and high-frequency quasi-confined (QC₊) phonons make main contributions to the DCS and the impact of the SO phonon can be negligible in the ERRS process. Moreover, scattering intensity of the bulk LO phonon is strongly enhanced as the incident photon energy approaches the energy band-gap of the GaN.     

Raman scattering using vortex light

We re-examine the theory of Raman scattering in cubic crystals. The unconventional vector potential of vortex light leads to new selection rules. We show that in this novel optical process, (a) silent phonon modes become active and (b) scattering tensors change for ordinary Raman active phonon modes. Calculation based on a simplified model shows that the vortex Raman scattering intensity can be comparable with that of ordinary Raman process.     

Electronic Raman scattering in double semi-parabolic quantum wells

The differential cross-section for electronic Raman scattering in double semi-parabolic quantum wells of typical GaAs/AlxGa1-x As is investigated numerically with the effective-mass approximation. The dependence of the differential cross-section on structural parameters such as the barrier width and the well widths is studied. Our results indicate that the electronic Raman scattering is affected by the geometrical size and can be negligible in the symmetric double-well case.     

分子极性对类胡萝卜素共振拉曼光谱的影响

测量了非极性分子β胡萝卜素和极性分子角黄素, 在非极性溶剂CS₂和极性溶 剂1,2二氯乙烷中243–293 K的温度范围内的共振拉曼光谱. 结果表明, 溶质和溶剂的极性对拉曼光谱影响很大. 非极性分子β胡萝卜素在非极性溶剂CS₂中的拉曼散射截面最大, 线宽最窄, 而极性分子角黄素在极性溶剂1,2二氯乙烷中的拉曼散射截面最小, 线宽最大. 用溶剂效应及线性多烯分子的“相干弱阻尼电子-晶格振动”, “有效共轭长度”模型给予了解释.     

Electric field effect on the Raman scattering of a hydrogenic impurity in spherical quantum dot

Using the perturbation method and the effective mass approximation, we studied the combined effects of impurity and external electric field on Raman scattering in a spherical quantum dot with a parabolic potential. Based on the computed energies and wave functions, the differential cross-section involved in this process is investigated, and the selection rules are also calculated. Our results suggest that the scattering intensity is strongly affected by the impurity and external electric field considered in this work.     

双三角量子阱中不对称性及掺杂浓度对电子拉曼散射的影响(英文)

在有效质量近似下,从理论上研究了非对称双三角量子阱的拉曼散射。推导了导带子带间电子跃迁的微分散射截面表达式,以GaAs/AlxGa1-xAs材料为例进行了数值计算。结果表明,散射光谱不仅与掺杂浓度有关,而且与双量子阱的不对称性有关,随着量子阱不对称性的增加或掺杂浓度的减少,散射峰发生了红移。本工作对设计新型微电子和光电子器件有一定的指导意义。     

One phonon-assisted electron Raman scattering in a wurtzite cylindrical quantum well wire

We report the electron resonant Raman scattering (ERRS) process related to the longitudinal optical (LO), interface optical (IO) and quasi-confined (QC) phonons in a cylindrical GaN-AlN quantum well wire (QWW). We present the differential cross-section (DCS) and study the selection rules. Results reveal that the emitted photon frequency decreases with increasing the radius because of the size-selective Raman scattering effect and the built-in electric field. The contribution to the DCS mainly stems from the GaN-type LO (LO1), QC and IO phonons when the wire is thin, but the LO1 and QC phonons are dominant for the thick wire.     

密度泛函理论研究过渡金属对吡啶的拉曼光谱强度的影响

本文采用杂化密度泛函理论计算了过渡金属M -Py分子的基态振动频率和拉曼光谱强度。计算结果表明过渡金属对Py分子的振动频率影响较小 ,但对Py分子的A1 振动模式的拉曼谱强度影响较大。对于A1 对称性的非C -H伸缩振动模 ,吡啶分子环呼吸振动和高频的C -C对称伸缩振动有较大的拉曼散射因子 ,我们还将此结果与典型的SERS活性金属 (铜族金属 )进行了比较     

Energy calculations of 6-mercaptopurine riboside adsorbed on a silver electrode surface using density functional theory

The normal Raman and surface enhanced Raman scattering spectra were obtained for 6-mercaptopurine riboside. The mode of interaction between 6-MPR and an adatom on a silver electrode surface was studied using density functional theory calculations. Two functionals, B3LYP and DVWN, were used in the analysis. The calculations were performed on the ionized and non-ionized forms of 6-MPR, with the silver ions attached to the three possible coordination sites, N1, N3 and N7 of the molecule. The analysis was performed based on the zero-point-energy as well as adsorption and solvation energies. Results of the B3LYP and DVWN calculations were consistent and established that coordination through the N7 of 6-MPR was the most energetically favorable of the three coordination sites. The analysis was unable to determine, with a high degree of accuracy, whether the molecule adsorbs on the surface in its non-ionized or ionized form.     

用染料荧光增益增强弱增益拉曼模式的受激拉曼散射的经典理论

建立了用染料荧光增益增强弱拉曼模式的受激拉曼散射(SRS)的经典理论,详细给出了拉曼增益gR,染料荧光增益gD和总损耗α的表达式,并在其推导过程中对经典理论作了修正,最后得到了荧光增益和受激拉曼增益可以共同使SRS强度的指数部分快速增长的结果,可以很好地解释观察到的实验现象,并为其提供理论依据。     

Vibrational properties of hexagonal boron nitride: inelastic X-ray scattering and ab initio calculations

The phonon dispersion relations of bulk hexagonal boron nitride have been determined from inelastic x-ray scattering measurements and analyzed by ab initio calculations. Experimental data and calculations show an outstanding agreement and reconcile the controversies raised by recent experimental data obtained by electron-energy loss spectroscopy and second-order Raman scattering.     

Electron Raman scattering in single and multilayered spherical quantum dots: Effects of hydrogenic impurity and geometrical size

Based on the effective mass and parabolic one-band approximations, the differential cross-section for the intersubband electron Raman scattering process in a single and multilayered spherical quantum dots is investigated. The influence of an on-center hydrogenic impurity and geometrical parameters such as the well and barrier widths on the differential cross-section is studied. Results show that the number, the position and the magnitude of the peaks of emission spectra, considerably depend on the presence of the hydrogenic impurity as well as geometrical parameters. Results also reveal that the magnitude of the peaks significantly depend on the polarization vectors of incident and scattered lights.     

碳纳米管晶格振动模及拉曼光谱的研究进展

本文介绍了碳纳米管的结构特征和晶格振动模的理论研究 ,综述了不同方法生长的多壁碳纳米管和单壁碳纳米管拉曼光谱的研究进展。另外 ,还简单描述了单壁碳纳米管的应用前景     

噻菌灵在纳米银胶表面吸附的表面增强拉曼光谱研究

噻菌灵(TBZ)属苯并咪唑类杀菌剂,容易在水果、蔬菜及相应的果蔬饮品中形成有毒残留。基于密度泛函理论(DFT)的量子化学计算方法和表面增强拉曼光谱(SERS)技术,从理论和实验角度系统研究了噻菌灵在纳米银胶粒子表面的吸附行为和增强效应。采用柠檬酸钠还原法制备了具有表面增强拉曼散射活性的银纳米溶胶,并对水相的噻菌灵进行了SERS光谱研究。利用TBZ-Ag₄四种吸附模型对噻菌灵与银纳米溶胶的相互作用进行了理论分析。结合FT-Raman光谱和B3LYP/6-311G(d)理论计算的结果,借助Gaussian View5.0程序的图形化功能,对噻菌灵分子的振动模式、FT-Raman振动光谱和SERS光谱进行了系统的指认。研究结果表明：噻菌灵分子的所有原子在同一平面上,属于Cs对称性;其在银纳米溶胶表面具有十分显著的表面增强拉曼活性;分子中的S原子与银胶粒子发生吸附作用,并通过该分子的长轴方向垂直于银纳米银胶表面;可利用SERS光谱方法对痕量的噻菌灵进行快速检测。为研究噻菌灵的特性以及其快速检测提供了理论和实验依据。     

Intense laser field effects on the electron Raman scattering in a strained InGaN/GaN quantum well

The differential cross-section for an intersubband electron Raman scattering process in a strained InGaN/GaN quantum well in the presence of an intense laser field is studied. In the effective-mass approximation, the electronic structure is calculated by taking into account the effects of spontaneous and piezoelectric polarization fields on the confinement potential. Effects of laser field strength, indium composition and the well width on the differential cross-section of the strained quantum well are investigated. Results show that the position and the magnitude of the peaks of emission spectra considerably depend on the laser field strength as well as structural parameters.     

应变对单层砷烯结构拉曼散射的影响

应用密度泛函理论对应变下的单层砷烯拉曼光谱的变化进行研究.由于材料的结构对称性较低，由外部应力诱发的形变不仅可以造成拉曼模式分裂，还可以引发拉曼模式偏移.计算表明：拉曼峰位的变化与应变正相关，建立了应变与峰位移动间的定量关系，为在实验中识别砷烯结构的应变提供依据.     

溶剂折射率对β-胡萝卜素拉曼散射截面的影响

以环己烷的1444 cm^-1拉曼线为内标,采用5145 nm激发光分别测量了β-胡萝卜素的C=C双键（1520 cm^-1）和C—C单键（1155 cm^-1）振动模式下在不同折射率溶剂中的拉曼散射截面,结果表明随溶剂的折射率增加β-胡萝卜素在两种振动模式下拉曼散射截面都增加.利用色散力和共振拉曼理论解释了在不同折射率溶剂中β-胡萝卜素散射截面的差异. 关键词： 拉曼散射截面 β-胡萝卜素 色散力 共振拉曼