High-Temperature Sulphidation of Fe-Cr Alloys

Scales resulted from a sulphidation of Fe _100?x Cr _x alloys (x ≤ 26) at 1073K in the atmosphere of H ₂/H ₂ S with the partial pressure of sulphur of 10^?8 atm were investigated by means of transmission and conversion electron Mössbauer spectroscopies, X-ray diffraction, electron microscopy and microprobe analysis. Although crystallographically single-phase, the scales were revealed to be composed of FeS (x ≤ 10) and Fe _1?x Cr _x S (x > 10).     

The Electronic and Magnetic Structure of Iron–Interstitial Metalloid Alloys

We have studied the Fe-X (X=B, C and N) systems, represented by clusters of atoms, using the discrete variational method. The calculated properties at the cluster's central site are compared with experimental and other theoretical results. The local magnetic, contact magnetic hyperfine field and contact charge density at the central site were calculated for different locations of impurities in bct, fcc and for intermediate structures. The calculated properties for N impurities are somehow different from those obtained for B and C impurities. The reasons behind the large average magnetic moment at Fe site in Fe-N systems were not convincingly clarified, however, distinctive features related to these systems are pointed out. This revised version was published online in August 2006 with corrections to the Cover Date.     

Moessbauer Study of Magnetic Structure in Fe-Based Nanocrystalline Alloys for MI Effect

The magneto-impedance effect in Fe-based nanocrystalline Fe₇₃Cu₁Nb_1.5Mo₂Si_13.5B₉ alloys has been observed. The results showed that the field dependence of the MI ratio was strongly influenced by the transverse magnetic structure in samples, which was demonstrated by Moessbauer spectroscopy. This revised version was published online in August 2006 with corrections to the Cover Date.     

Interface Microstructures of Si3N4/Fe and Fe-Cr Alloys Joints

Interfaces of solid state bonded Si₃N₄ceramics with Fe and Fe-(5, 10, 15 wt%)Cr alloy interlayers inArgon for 1 h at 1100°, 1200° and 1300°C have beencharacterized by electron probe microanalysis (EPMA) and transmissionelectron microscopy (TEM). Smooth interfaces with no evidence ofreactions products resulted when bonding at 1100°C. However, theinteraction between the ceramic and the metal increased at higherbonding temperatures and Cr-contents. In all samples Si and N fromthe ceramic dissolve and diffuse in the metal interlayer, whereas thesintering additives of the ceramic remain inactive.Low Cr-content (5%) interlayers resulted in the formationof an interfacial zone composed of two sublayer structures; adjacentto the ceramic was a thin one containing the sintering aids ofSi₃N₄ and fine precipitates of Fe₃Si and -Fe₄N in a bcc-Fe matrix. The second was thicker and includedfine Fe₃Si,-Fe₄N and-Fe₂N precipitates in abcc-Fe matrix. The bond region with high Cr-content interlayersincluded three sublayer structures. The first one next to the ceramicwas a bcc-Fe matrix containing sintering aids, fine dispersedFe₃Si and-Fe₄N, and CrN. The secondsublayer was similar but without any segregants from the ceramic. Thethird one, finally had a lamellae structure of Cr₂N/bcc-Fe and the Fe matrix contained also-Fe₄N.The interactionbetween the ceramic and the metal interlayer is believed to becontrolled by the solution rate of N in the alloy foils.     

Influence of Nonstoichiometry on the Magnetic Properties of CeFe2:Mn Alloys

JETP Letters - Experimental dependences of the spontaneous magnetic moment per 3d atom on the impurity concentration for doped CeFe2:Mn alloys are surprising. The concentration dependences of the...     

Molecular-Dynamics Method for the Simulation of Grain-Boundary Migration

A molecular-dynamics method for the simulation of the intrinsicmigration behavior of individual, flat grain boundaries is introducedand validated. A constant driving force for grain-boundary migrationis generated by imposing an anisotropic elastic strain on a bicrystalsuch that the elastic-energy densities in its two halves aredifferent. For the model case of a large-planar-unit-cell, high-angle(001) twist boundary in Cu we show that an elastic strain of1%–4% is sufficient to drive thecontinuous, viscous movement of the boundary at temperatures wellbelow the melting point. The driving forces thus generated (at thehigh end of the experimentally accessible range) enable aquantitative evaluation of the migration process during the timeframe of 10^-9 s typically accessible bymolecular-dynamics simulation. For this model high-angle grainboundary we demonstrate that (a) the drift velocity is, indeed,proportional to the applied driving force thus enabling us todetermine the boundary mobility, (b) the activation energy forgrain-boundary migration is distinctly lower than that forgrain-boundary self-diffusion or even self-diffusion in the melt and(c) in agreement with earlier simulations the migration mechanisminvolves the collective reshuffling during local disordering(melting) of small groups of atoms and subsequentresolidification onto the other crystal.     

Inherent Structure Approach to the Study of Glass-Forming Liquids

The inherent structure approach, wherein thermodynamic and structural changes in glass-forming liquids are analyzed in terms of local potential energy minima that the liquid samples, has recently been applied extensively to the study of thermodynamic aspects of glass-forming liquids. The evaluation of the configurational entropy, which arises from the multiplicity of local energy minima, plays a central role in such analyses. Results are presented here concerning the calculation of configurational entropy based on computer simulations of a model liquid; and the application of the inherent structure formalism to the study of the glass transition locus, and the fragility of glass-forming liquids.     

Thermodynamic and Magnetic Properties of the Two-Dimensional Anisotropic Ising Model with Competing Interactions

Physics of the Solid State - The two-dimensional anisotropic Ising model with competing interactions is studied on a square lattice by Monte Carlo methods using the Wang–Landau algorithm. The...     

Magnetic cluster expansion simulation and experimental study of high temperature magnetic properties of Fe-Cr alloys

We present a combined experimental and computational study of high temperature magnetic properties of Fe-Cr alloys with chromium content up to about 20?at.%. The magnetic cluster expansion method is applied to model the magnetic properties of random Fe-Cr alloys, and in particular the Curie transition temperature, as a function of alloy composition. We find that at low (3-6?at.%) Cr content the Curie temperature increases with the increase of Cr concentration. It is maximum at approximately 6?at.% Cr and then decreases for higher Cr content. The same feature is found in thermo-magnetic measurements performed on model Fe-Cr alloys, where a 5?at.% Cr alloy has a higher Curie temperature than pure Fe. The Curie temperatures of 10 and 15?at.% Cr alloys are found to be lower than the Curie temperature of pure Fe.     

Magnetic Properties of Amorphous and Nanocrystalline Fe-Zr-B-Al Alloys

We have investigated the influence of aluminium substitution for iron on the magnetic properties of amorphous and nanocrystalline Fe_88-x Zr₇B₅Al _x alloys (x = 0, 1, 3, 5, 7 and 9 at.%). Thermomagnetic curves show an increase of Curie and crystallization temperature of amorphous phase with the increase of the content of aluminium in the alloy. The increase of aluminium content up to 3 at.% Al does not cause the decrease of a saturation magnetization in the as-quenched sample. In addition, magnetostriction of the annealed alloys has been studied. Also, the increase of aluminium content in the alloy causes an increase of the magnetostriction constant.     

Magnetic Moments of Single-Crystal Tb–Sm Alloys

In the present paper, the magnetic properties of Tb_1–xSm_x alloys with different samarium contents are investigated along the <11 [`2]\overline 2 0 > (b), < 10 [`1]\overline 1 0 \gt; (a), and <0001> (c) crystallographic directions in magnetic fields up to 50 kOe in the temperature interval 4.2–400 K. It is demonstrated that small additions of the light rare-earth samarium metal to the heavy rare-earth terbium metal increase the specific magnetization and the effective magnetic moments.     

An Infinitesimal Deformation Approach to the Crystallographic Theory of the Martensite Phase Transformation: Application to Au-Cd,Fe-Ni AND In-Tl Alloys

Using the infinitesimal deformation approach, a crystallographic analysis of the austenite-martensite transformation from the cubic to orthorhombic phase - which predicts crystallographic parameters such as habit plane, orientation relationship between austenite and martensite, rotation matrix and total shape deformation matrix - is derived from a knowledge of the crystal structures of the initial and final phase only. The numerical values coming from orientation relationships obtained for Au-47.5 Cd Fe-Ni and In--Tl alloys are compared with predictions of the phenomenological crystallographic theory, infinitesimal deformation approach and experimental data.     

Abelian Bosonization Approach,to a Magnetic Impurity Model

Abelian bosonization is applied to a magnetic impurity model, the so-called Wolff impurity model. The resulting bosonized version of the model can be solved exactly. We calculate the local dynamic spin and charge density-density correlations of the conduction electrons, and show that a quasi-particle peak in the spin-density excitations appears and becomes sharp significantly as the local interaction U grows up. The local static spin and charge susceptibilities and specific heat of the interacting electrons are also obtained, explicitly displaying a local Fermi liquid behavior.     

Magnetic Properties of Soft Magnetic Alloys 5BDSR and 82K3HSR

Russian Physics Journal - The paper explores the size and morphology of microparticles of soft magnetic alloys 5BDSR and 82K3HSR and nanoparticles first obtained from these alloys using pulsed...     

An Investigation of Phase Diagrams of Decomposing Magnetic Alloys

The interaction of phase decomposition and magnetic ordering processes in an A–B alloy of an arbitrary structure is studied theoretically. The decomposition and magnetization temperatures are calculated. The phase diagrams are constructed and compared with experiment on Fe–Cr, Fe–Co, and Pt–Co alloys.     

Magnetic Phase Transitions to an Incommensurate Magnetic Structure in FeGe2 Compound

Physics of the Solid State - A symmetry analysis of possible magnetic structures in an incommensurate magnetic phase in FeGe2 compound, resulted from phase transitions from the paramagnetic phase,...     

Xenon-ion Induced Magnetic and Structural Modifications of Ferromagnetic Alloys

Thin polycrystalline films of permalloy (Ni₇₉Fe₂₁) and permendur (Co₅₀Fe₅₀) have been irradiated with Xe-ions to fluences of 10¹⁴–10¹⁶ ions/cm². Ion-induced structural and magnetic modifications have been measured by grazing angle X-ray diffraction, Rutherford backscattering and magneto-optical Kerr effect. In the case of permendur, the Xe-ion implantation first reduced the coercivity, because of stress relaxation, while higher ion fluences increased the coercivity due to pinning centers generated in the film. The ion irradiation aligned the in-plane easy axis of the magnetization along the direction of the external magnetic field during implantation. Phase shifts obtained from magnetic force microscopy confirmed these modifications. The effects of Xe-ion irradiation in permalloy films are much weaker and underline the importance of magnetostriction in the variation of the coercivity and anisotropy.     

Magnetic Behavior of Nanocrystalline FeNbCrBCu Alloys at Elevated Temperatures

The magnetic behavior of nanocrystalline Fe_73.5Nb_4.5Cr₅B₁₆Cu₁ alloys is investigated in a series of specimens with different volume fractions of crystalline phase. It is shown that the Curie temperature of amorphous phase firstly decreases after structural relaxation in amorphous state and then rapidly increases during the first stages of crystallization. The strikingly different behavior of coercivity at elevated temperatures is observed for the samples with low and high volume fractions of nanocrystalline particles.