Local structure of Fe-doped In 2 O 3 films investigated by X-ray absorption fine structure spectroscopy

$(\mathrm{In}_{1-x}\mathrm{Fe}_{x})_{2}\mathrm{O}_{3}$ $(x=0.07, 0.09, 0.16, 0.22, 0.31)$ films were deposited on Si (100) substrates by RF-magnetron sputtering technique. The influence of Fe doping on the local structure of films was investigated by X-ray absorption spectroscopy (XAS) at Fe K-edge and L-edge. For the $(\mathrm{In}_{1-x}\mathrm{Fe}_{x})_{2}\mathrm{O}_{3}$ films with $x=0.07, 0.09 \mbox{ and } 0.16$ , Fe ions dissolve into $\mathrm{In}_{2}\mathrm{O}_{3}$ and substitute for $\mathrm{In}^{3+}$ sites with a mixed-valence state ( $\mathrm{Fe}^{2+}/\mathrm{Fe}^{3+}$ ) of Fe ions. However, a secondary phase of Fe metal clusters is formed in the $(\mathrm{In}_{1-x}\mathrm{Fe}_{x})_{2}\mathrm{O}_{3}$ films with $x=0.22 \mbox{ and } 0.31$ . The qualitative analyses of Fe-K edge extended X-ray absorption fine structure (EXAFS) reveal that the Fe–O bond length shortens and the corresponding Debye–Waller factor ( $\sigma^{2}$ ) increases with the increase of Fe concentration, indicating the relaxation of oxygen environment of Fe ions upon substitution. The anomalously large structural disorder and very short Fe–O distance are also observed in the films with high Fe concentration. Linear combination fittings at Fe L-edge further confirm the coexistence of $\mathrm{Fe}^{2+}$ and $\mathrm{Fe}^{3+}$ with a ratio of ${\sim}3:2$ ( $\mathrm{Fe}^{2+}: \mathrm{Fe}^{3+}$ ) for the $(\mathrm{In}_{1-x}\mathrm{Fe}_{x})_{2}\mathrm{O}_{3}$ film with $x=0.16$ . However, a significant fraction ( ${\sim}40~\mbox{at\%}$ ) of the Fe metal clusters is found in the $(\mathrm{In}_{1-x}\mathrm{Fe}_{x})_{2}\mathrm{O}_{3}$ film with $x=0.31$ .     

Mössbauer spectroscopy in the investigation of new mineral–related materials

New materials based on the composition of the mineral schafarzikite, FeSb $_{2}\textit {O}_{4}$ , have been synthesised. $^{57}$ Fe- and $^{121}$ Sb- Mössbauer spectroscopy shows that iron is present as Fe $^{2+}$ and that antimony is present as Sb $^{3+}$ . The presence of Pb $^{2+}$ on the antimony sites in materials of composition FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ induces partial oxidation of Fe $^{2+}_{}$ to Fe $^{3+}$ . The quasi-one-dimensional magnetic structure of schafarzikite is retained in FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ and gives rise to weakly coupled non-magnetic Fe $^{2+}$ ions coexisting with Fe $^{3+}$ ions in a magnetically ordered state. A similar model can be applied to account for the spectra recorded from the compound Co $_{0.5}$ Fe $_{0.5}$ Sb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ .     

Spectroscopic properties of Ho 3 + -doped K–Sr–Al phosphate glasses

Trivalent holmium-doped K–Sr–Al phosphate glasses ( $\mathrm{P}_{2}\mathrm{O}_{5}$ – $\mathrm{K}_{2}\mathrm{O}$ –SrO– $\mathrm{Al}_{2}\mathrm{O}_{3}$ – $\mathrm{Ho}_{2}\mathrm{O}_{3}$ ) were prepared, and their spectroscopic properties have been evaluated using absorption, emission, and excitation measurements. The Judd–Ofelt theory has been used to derive spectral intensities of various absorption bands from measured absorption spectrum of 1.0 mol% $\mathrm{Ho}_{2}\mathrm{O}_{3}$ -doped K–Sr–Al phosphate glass. The Judd–Ofelt intensity parameters ( $\varOmega_{\lambda}$ , $\times10^{-20}~\mathrm{cm}^{2}$ ) have been determined of the order of $\varOmega_{2} = 11.39$ , $\varOmega_{4} = 3.59$ , and $\varOmega_{6} = 2.92$ , which in turn used to derive radiative properties such as radiative transition probability, radiative lifetime, branching ratios, etc. for excited states of $\mathrm{Ho}^{3+}$ ions. The radiative lifetimes for the ${}^{5}F_{4}$ , ${}^{5}S_{2}$ , and ${}^{5}F_{5}$ levels of $\mathrm{Ho}^{3+}$ ions are found to be 169, 296, and 317 μs, respectively. The stimulated emission cross-section for 2.05-μm emission was calculated by the McCumber theory and found to be $9.3\times10^{-2 1}~\mathrm{cm}^{2}$ . The wavelength-dependent gain coefficient with population inversion rate has been evaluated. The results obtained in the titled glasses are discussed systematically and compared with other $\mathrm{Ho}^{3+}$ -doped systems to assess the possibility for visible and infrared device applications.     

Analysis of the \frac{1} {2}^ - and \frac{3} {2}^ - heavy and doubly heavy baryon states with QCD sum rules

In this article, we study the $\frac{1} {2}^ -$ and $\frac{3} {2}^ -$ heavy and doubly heavy baryon states $\Sigma _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi '_Q \left( {\frac{1} {2}^ - } \right)$ , $\Omega _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Omega _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Sigma _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Omega _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ and $\Omega _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ by subtracting the contributions from the corresponding $\frac{1} {2}^ +$ and $\frac{3} {2}^ +$ heavy and doubly heavy baryon states with the QCD sum rules in a systematic way, and make reasonable predictions for their masses.     

Nucleon and {\Delta} Elastic and Transition Form Factors

We present a unified study of nucleon and \({\Delta}\) elastic and transition form factors, and compare predictions made using a framework built upon a Faddeev equation kernel and interaction vertices that possess QCD-like momentum dependence with results obtained using a symmetry-preserving treatment of a vector \({\otimes}\) vector contact-interaction. The comparison emphasises that experiments are sensitive to the momentum dependence of the running couplings and masses in the strong interaction sector of the Standard Model and highlights that the key to describing hadron properties is a veracious expression of dynamical chiral symmetry breaking in the bound-state problem. Amongst the results we describe, the following are of particular interest: \({G_{E}^{p}(Q^{2})/G_{M}^{p}(Q^{2})}\) possesses a zero at Q ² = 9.5 GeV²; any change in the interaction which shifts a zero in the proton ratio to larger Q ² relocates a zero in \({G_{E}^{n}(Q^{2})/G_M^{n}(Q^{2})}\) to smaller Q ²; there is likely a value of momentum transfer above which \({G_{E}^{n} > G_{E}^{p}}\) ; and the presence of strong diquark correlations within the nucleon is sufficient to understand empirical extractions of the flavour-separated form factors. Regarding the \({\Delta(1232)}\) -baryon, we find that, inter alia: the electric monopole form factor exhibits a zero; the electric quadrupole form factor is negative, large in magnitude, and sensitive to the nature and strength of correlations in the \({\Delta(1232)}\) Faddeev amplitude; and the magnetic octupole form factor is negative so long as rest-frame P- and D-wave correlations are included. In connection with the \({N \to \Delta}\) transition, the momentum-dependence of the magnetic transition form factor, \({G_{M}^{*}}\) , matches that of \({G_{M}^{n}}\) once the momentum transfer is high enough to pierce the meson-cloud; and the electric quadrupole ratio is a keen measure of diquark and orbital angular momentum correlations, the zero in which is obscured by meson-cloud effects on the domain currently accessible to experiment. Importantly, within each framework, identical propagators and vertices are sufficient to describe all properties discussed herein. Our analysis and predictions should therefore serve as motivation for measurement of elastic and transition form factors involving the nucleon and its resonances at high photon virtualities using modern electron-beam facilities.     

Regularity for Eigenfunctions of Schr?dinger Operators

We prove a regularity result in weighted Sobolev (or Babu?ka?CKondratiev) spaces for the eigenfunctions of certain Schr?dinger-type operators. Our results apply, in particular, to a non-relativistic Schr?dinger operator of an N-electron atom in the fixed nucleus approximation. More precisely, let ${\mathcal{K}_{a}^{m}(\mathbb{R}^{3N},r_S)}$ be the weighted Sobolev space obtained by blowing up the set of singular points of the potential ${V(x) = \sum_{1 \le j \le N} \frac{b_j}{|x_j|} + \sum_{1 \le i < j \le N} \frac{c_{ij}}{|x_i-x_j|}}$ , ${x \in \mathbb{R}^{3N}}$ , ${b_j, c_{ij} \in \mathbb{R}}$ . If ${u \in L^2(\mathbb{R}^{3N})}$ satisfies ${(-\Delta + V) u = \lambda u}$ in distribution sense, then ${u \in \mathcal{K}_{a}^{m}}$ for all ${m \in \mathbb{Z}_+}$ and all a ?? 0. Our result extends to the case when b _j and c _ij are suitable bounded functions on the blown-up space. In the single-electron, multi-nuclei case, we obtain the same result for all a?<?3/2.     

Blow Up Dynamics for Equivariant Critical Schrödinger Maps

For the Schrödinger map equation \({u_t = u \times \triangle u \, {\rm in} \, \mathbb{R}^{2+1}}\) , with values in S ², we prove for any \({\nu > 1}\) the existence of equivariant finite time blow up solutions of the form \({u(x, t) = \phi(\lambda(t) x) + \zeta(x, t)}\) , where \({\phi}\) is a lowest energy steady state, \({\lambda(t) = t^{-1/2-\nu}}\) and \({\zeta(t)}\) is arbitrary small in \({\dot H^1 \cap \dot H^2}\) .     

Antineutrino science in KamLAND

The primary goal of KamLAND is a search for the oscillation of \({\bar{\nu }}_\mathrm{e}\) ’s emitted from distant power reactors. The long baseline, typically 180 km, enables KamLAND to address the oscillation solution of the “solar neutrino problem” with \({\bar{\nu }}_{e} \) ’s under laboratory conditions. KamLAND found fewer reactor \({\bar{\nu }}_{e} \) events than expected from standard assumptions about \(\overline{\nu }_e\) propagation at more than 9 \(\sigma \) confidence level (C.L.). The observed energy spectrum disagrees with the expected spectral shape at more than 5 \(\sigma \) C.L., and prefers the distortion from neutrino oscillation effects. A three-flavor oscillation analysis of the data from KamLAND and KamLAND + solar neutrino experiments with CPT invariance, yields \(\Delta m_{21}^2 \) = [ \(7.54_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) , \(7.53_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) ], tan \(^{2}\theta _{12}\) = [ \(0.481_{-0.080}^{+0.092} \) , \(0.437_{-0.026}^{+0.029} \) ], and sin \(^{2}\theta _{13}\) = [ \(0.010_{-0.034}^{+0.033} \) , \(0.023_{-0.015}^{+0.015} \) ]. All solutions to the solar neutrino problem except for the large mixing angle region are excluded. KamLAND also demonstrated almost two cycles of the periodic feature expected from neutrino oscillation effects. KamLAND performed the first experimental study of antineutrinos from the Earth’s interior so-called geoneutrinos (geo \({\bar{\nu }}_{e} \) ’s), and succeeded in detecting geo \({\bar{\nu }}_{e} \) ’s produced by the decays of \(^{238}\) U and \(^{232}\) Th within the Earth. Assuming a chondritic Th/U mass ratio, we obtain \(116_{-27}^{+28} {\bar{\nu }}_{e}\) events from \(^{238}\) U and \(^{232}\) Th, corresponding a geo \({\bar{\nu }}_{e}\) flux of \(3.4_{-0.8}^{+0.8}\times \) 10 \(^{6}\) cm \(^{-2}\)  s \(^{-1}\) at the KamLAND location. We evaluate various bulk silicate Earth composition models using the observed geo \({\bar{\nu }}_{e} \) rate.     

Analysis of the vertexes \Xi_{Q}^{*}′QV , \Sigma_{Q}^{*} \Sigma_{Q}^{}V and radiative decays \Xi_{Q}^{*} \rightarrow ′Q \gamma , \Sigma_{Q}^{*} \rightarrow \Sigma_{Q}^{} \gamma

In this article, we study the vertexes $ \Xi_{Q}^{*}$ ′_Q V and $ \Sigma_{Q}^{*}$ $ \Sigma_{Q}^{}$ V with the light-cone QCD sum rules, then assume the vector meson dominance of the intermediate $ \phi$ (1020) , $ \rho$ (770) and $ \omega$ (782) , and calculate the radiative decays $ \Xi_{Q}^{*}$ $ \rightarrow$ ′_Q $ \gamma$ and $ \Sigma_{Q}^{*}$ $ \rightarrow$ $ \Sigma_{Q}^{}$ $ \gamma$ .     

Near Threshold Photoproduction of {K\Sigma} in Four Isospin Channels

Photoproduction of ${K\Sigma}$ on the nucleon in four isospin channels has been investigated near their production thresholds by means of an isobar model. It is shown that in the proton channels ( ${K^+\Sigma^0}$ and ${K^0\Sigma^+}$ channels) the model can nicely reproduce experimental data. Due to the uncertainties in the neutron helicity amplitudes our predictions imply some uncertainties in the observables of the neutron channels ( ${K^+\Sigma^-}$ and ${K^0\Sigma^0}$ channels).     

The Isospin Mixing in the X(3872) Decay Spectrum

The large isospin symmetry breaking found in the X(3872) decay is investigated by looking into the transfer strength from the \({{c}\bar{c}}\) quarkonium to the two-meson states: \({c\bar{c} \rightarrow D^{0}\overline{D}^{*0}, D^{+} D^{*-} , J /\psi\omega, {\rm and} \, J /\psi\rho}\) . The widths of the \({\rho}\) and \({\omega}\) mesons are taken into account in the calculation. It is found that very narrow \({J /\psi\omega}\) and \({J /\psi\rho}\) peaks appear at the \({D^{0}\overline{D}^{*0}}\) threshold. These narrow peaks appear provided that the strength of the \({D^{0}\overline{D}^{*0}}\) component is large around the threshold. The large width of the \({\rho}\) meson enhances the isospin-one component in the transfer strength considerably, which reduces the ratio \({{\rm Br}(X \rightarrow J /\psi\omega)/{\rm Br}(X \rightarrow J /\psi\rho)}\) down to 2.5.     

{\Xi} Hypernucler States Predicted by the New Interaction Model ESC08c

The features of the new interaction model ESC08c in ${\Lambda N}$ , ${\Sigma N}$ and ${\Xi N}$ channels are demonstrated single hyperon potentials ${U_Y(Y=\Lambda, \Sigma, \Xi)}$ in nuclear matter on the basis of the G-matrix theory. (K ^?, K ⁺) productions of ${\Xi}$ hypernuclei are studied with ${\Xi}$ -nucleus folding potentials.     

The NLS Equation in Dimension One with Spatially Concentrated Nonlinearities: the Pointlike Limit

In the present paper, we study the following scaled nonlinear Schrödinger equation (NLS) in one space dimension: $$ i\frac{\rm d}{{\rm d}t}\psi^{\varepsilon}(t)=-\Delta\psi^{\varepsilon}(t) +\frac{1}{\varepsilon}V\left(\frac{x}{\varepsilon} \right)|\psi^{\varepsilon}(t)|^{2\mu}\psi^{\varepsilon}(t)\quad \varepsilon > 0\,\quad V\in L^1(\mathbb{R},(1+|x|){\rm d}x) \cap L^\infty(\mathbb{R}).$$ This equation represents a nonlinear Schrödinger equation with a spatially concentrated nonlinearity. We show that in the limit \({\varepsilon\to 0}\) the weak (integral) dynamics converges in \({H^1(\mathbb{R})}\) to the weak dynamics of the NLS with point-concentrated nonlinearity: $$ i\frac{{\rm d}}{{\rm d}t} \psi(t) =H_{\alpha} \psi(t) .$$ where H _α is the Laplacian with the nonlinear boundary condition at the origin \({\psi'(t,0+)-\psi'(t,0-)=\alpha|\psi(t,0)|^{2\mu}\psi(t,0)}\) and \({\alpha=\int_{\mathbb{R}}V{\rm d}x}\) . The convergence occurs for every \({\mu\in \mathbb{R}^+}\) if V ≥  0 and for every  \({\mu\in (0,1)}\) otherwise. The same result holds true for a nonlinearity with an arbitrary number N of concentration points.     

Radiative and semileptonic B decays involving higher K-resonances in the final states

We study the radiative and semileptonic B decays involving a spin-J resonant $K_{J}^{(*)}$ with parity (?1) ^J for $K_{J}^{*}$ and (?1) ^J+1 for K _J in the final state. Using large energy effective theory (LEET) techniques, we formulate $B\to K_{J}^{(*)}$ transition form factors in the large recoil region in terms of two independent LEET functions $\zeta_{\perp}^{K_{J}^{(*)}}$ and $\zeta_{\parallel}^{K_{J}^{(*)}}$ , the values of which at zero momentum transfer are estimated in the BSW model. According to the QCD counting rules, $\zeta_{\perp,\parallel}^{K_{J}^{(*)}}$ exhibit a dipole dependence in q ². We predict the decay rates for $B\to K_{J}^{(*)}\gamma$ , $B\to K_{J}^{(*)}\ell^{+}\ell^{-}$ and $B\to K_{J}^{(*)}\nu \bar{\nu}$ . The branching fractions for these decays with higher K-resonances in the final state are suppressed due to the smaller phase spaces and the smaller values of $\zeta^{K_{J}^{(*)}}_{\perp,\parallel}$ . Furthermore, if the spin of $K_{J}^{(*)}$ becomes larger, the branching fractions will be further suppressed due to the smaller Clebsch–Gordan coefficients defined by the polarization tensors of the $K_{J}^{(*)}$ . We also calculate the forward–backward asymmetry of the $B\to K_{J}^{(*)}\ell^{+}\ell^{-}$ decay, for which the zero is highly insensitive to the K-resonances in the LEET parametrization.     

Analysis of the {3\over 2}^{+} heavy and doubly heavy baryon states with QCD sum rules

In this article, we study the ${3\over 2}^{+}$ heavy and doubly heavy baryon states $\varXi^{*}_{cc}$ , $\varOmega^{*}_{cc}$ , $\varXi^{*}_{bb}$ , $\varOmega^{*}_{bb}$ , $\varSigma_{c}^{*}$ , $\varXi_{c}^{*}$ , $\varOmega_{c}^{*}$ , $\varSigma_{b}^{*}$ , $\varXi_{b}^{*}$ and $\varOmega_{b}^{*}$ by subtracting the contributions from the corresponding ${3\over 2}^{-}$ heavy and doubly heavy baryon states with the QCD sum rules, and we make reasonable predictions for their masses.     

Study of Σ* Resonances from K − N → πΛ Reactions

In order to know more about some Σ resonances and distinguish various models of hadron structures, an analysis is performed for the reactions K ^? n → π ^? Λ and K ^? p → π ⁰ Λ, using an effective Lagrangian approach. The differential cross sections and Λ polarizations from two experiments are analyzed with the c.m. energy between 1,550 and 1,676 MeV. Our study strongly support the existence of a ${J^P = {1\over 2}^+ \Sigma}$ resonance with mass near 1,633 MeV and width about 120 MeV, which is compatible with the three-star ${\Sigma(1660){1\over 2}^+}$ in PDG. Meanwhile, no evidence is found for the two-star ${\Sigma(1620){1\over 2}^-}$ listed in PDG.     

Comprehensive Bayesian analysis of rare (semi)leptonic and radiative \varvec{B} decays

The available data on \(|\Delta B| = |\Delta S| = 1\) decays are in good agreement with the Standard Model when permitting subleading power corrections of about \(15\,\%\) at large hadronic recoil. Constraining new-physics effects in \(\mathcal {C}_{7}^{\mathrm {}}\) , \(\mathcal {C}_{9}^{\mathrm {}}\) , \(\mathcal {C}_{10}^{\mathrm {}}\) , the data still demand the same size of power corrections as in the Standard Model. In the presence of chirality-flipped operators, all but one of the power corrections reduce substantially. The Bayes factors are in favor of the Standard Model. Using new lattice inputs for \(B\rightarrow K^*\) form factors and under our minimal prior assumption for the power corrections, the favor shifts toward models with chirality-flipped operators. We use the data to further constrain the hadronic form factors in \(B\rightarrow K\) and \(B\rightarrow K^*\) transitions.     

Finite W-Superalgebras and Truncated Super Yangians

Let ${Y_{m|n}^{\ell}}$ be the super Yangian of general linear Lie superalgebra for ${\mathfrak{gl}_{m|n}}$ . Let ${e \in \mathfrak{gl}_{m\ell|n\ell}}$ be a “rectangular” nilpotent element and ${\mathcal{W}_e}$ be the finite W-superalgebra associated to e. We show that ${Y_{m|n}^{\ell}}$ is isomorphic to ${\mathcal{W}_e}$ .     

An Algebraic Construction of Boundary Quantum Field Theory

We build up local, time translation covariant Boundary Quantum Field Theory nets of von Neumann algebras ${\mathcal A_V}$ on the Minkowski half-plane M ₊ starting with a local conformal net ${\mathcal A}$ of von Neumann algebras on ${\mathbb R}$ and an element V of a unitary semigroup ${\mathcal E(\mathcal A)}$ associated with ${\mathcal A}$ . The case V?=?1 reduces to the net ${\mathcal A_+}$ considered by Rehren and one of the authors; if the vacuum character of ${\mathcal A}$ is summable, ${\mathcal A_V}$ is locally isomorphic to ${\mathcal A_+}$ . We discuss the structure of the semigroup ${\mathcal E(\mathcal A)}$ . By using a one-particle version of Borchers theorem and standard subspace analysis, we provide an abstract analog of the Beurling-Lax theorem that allows us to describe, in particular, all unitaries on the one-particle Hilbert space whose second quantization promotion belongs to ${\mathcal E(\mathcal A^{(0)})}$ with ${\mathcal A^{(0)}}$ the U(1)-current net. Each such unitary is attached to a scattering function or, more generally, to a symmetric inner function. We then obtain families of models via any Buchholz-Mack-Todorov extension of ${\mathcal A^{(0)}}$ . A further family of models comes from the Ising model.