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1.
《Colloids and surfaces. B, Biointerfaces》2007,54(2):157-166
Adsorption of the cationic salivary proteins lactoferrin, lactoperoxidase, lysozyme and histatin 5 to pure (hydrophilic) and methylated (hydrophobized) silica surfaces was investigated by in situ ellipsometry. Effects of concentration (≤10 μg ml−1, for lysozyme ≤200 μg ml−1) and dependence of surface wettability, as well as adsorption kinetics and elutability of adsorbed films by buffer and sodium dodecyl sulphate (SDS) solutions were investigated. Results showed that the amounts adsorbed decreased in the order lactoferrin ≥ lactoperoxidase > lysozyme ≥ histatin 5. On hydrophilic silica, the adsorption was most likely driven by electrostatic interactions, which resulted in adsorbed amounts of lactoferrin that indicated the formation of a monolayer with both side-on and end-on adsorbed molecules. For lactoperoxidase the adsorbed amounts were somewhat higher than an end-on monolayer, lysozyme adsorption showed amounts corresponding to a side-on monolayer, and histatin 5 displayed adsorbed amounts in the range of a side-on monolayer. On hydrophobized substrata, the adsorption was also mediated by hydrophobic interactions, which resulted in lower adsorbed amounts of lactoferrin and lactoperoxidase; closer to side-on monolayer coverage. For both lysozyme and histatin 5 the adsorbed amounts were the same as on the hydrophilic silica. The investigated proteins exhibited fast adsorption kinetics, and the initial kinetics indicated mass transport controlled behaviour at low concentrations on both types of substrates. Buffer rinsing and SDS elution indicated that the proteins in general were more tightly bound to the hydrophobized surface compared to hydrophilic silica. Overall, the surface activity of the investigated proteins implicates their importance in the salivary film formation. 相似文献
2.
《Journal of membrane science》2002,196(2):211-220
The separations of amino acids by Donnan dialysis using an ion-exchange membrane were studied. Donnan dialytic experiments were carried out using an anion-exchange membrane, glutamic acid–phenylalanine or glutamic acid–alanine mixed solutions as the feeds, and sodium hydroxide solutions as the stripping ones. The initial concentrations of the two kinds of amino acids in the feed solutions were equal and in the range of 0.5–50 mol m−3. The amino acid fluxes were measured for each feed solution. Above the feed concentration of 10 mol m−3, the glutamic acid flux was over 100 times greater than that of the other amino acid, and it was found that the Donnan dialysis was applicable to the separation of the amino acids. On the other hand, below 10 mol m−3, the amino acid fluxes varied in a complicated manner with the concentration, and below 1 mol m−3 there was little difference between the fluxes of the two amino acids.Furthermore, after soaking the membrane in solutions having the same concentrations as the feed in the Donnan dialysis, uptake of the amino acids into the membrane was also measured. By comparing the experimental results of both the flux and uptake of the amino acids, the reason why the flux varied in a complicated manner with the concentration was discussed. 相似文献
3.
《Arabian Journal of Chemistry》2014,7(6):1140-1147
A polymeric blend has been prepared using urea formaldehyde (UF) and epoxy (DGEBA) resin in 1:1 mass ratio. The thermal degradation of UF/epoxy resin blend (UFE) was investigated by using thermogravimetric analyses (TGA), coupled with FTIR and MS. The results of TGA revealed that the pyrolysis process can be divided into three stages: drying process, fast thermal decomposition and cracking of the sample. There were no solid products except ash content for UFE during combustion at high temperature. The total mass loss during pyrolysis at 775 °C is found to be 97.32%, while 54.14% of the original mass was lost in the second stage between 225 °C and 400 °C. It is observed that the activation energy of the second stage degradation during combustion (6.23 × 10−4 J mol−1) is more than that of pyrolysis (5.89 × 10−4 J mol−1). The emissions of CO2, CO, H2O, HCN, HNCO, and NH3 are identified during thermal degradation of UFE. 相似文献
4.
《Journal of membrane science》2002,207(1):1-16
This work aims to contribute to the characterization of the electrodialysis (ED) of aqueous sulfuric acid–copper sulfate solutions. The presence of impurities such as As and Sb, typical of copper electrorefining electrolytes, is also studied. Results from kinetic studies carried out in ED cells with and without re-circulation are presented. The concentrations were: 3–9 g l−1 copper, 50 g l−1 sulfuric acid, 3 g l−1 arsenic and 0.025 g l−1 antimony; the temperatures, 22 and 44 °C; the transport rates, depending on experimental conditions, 0.2–0.6 mol h−1 m−2of membrane for copper, 0.65–2.8 for sulfate, and 0.016–0.03 for arsenic. A speciation model has been developed and applied in order to interpret the experimental results and the performance of the studied cells has been evaluated. The main conclusion is that ED can be applied to the separation and concentration of chemical species in these systems. 相似文献
5.
《Solid State Sciences》2012,14(2):250-257
CO2 adsorption properties on Mg modified silica mesoporous materials were investigated. By using the methods of co-condensation, dispersion and ion-exchange, Mg2+ was introduced into SBA-15 and MCM-41, and transformed into MgO in the calcination process. The basic MgO can provide active sites to enhance the acidic CO2 adsorption capacity. To improve the amount and the dispersion state of the loading MgO, the optimized modification conditions were also investigated. The XRD and TEM characteristic results, as well as the CO2 adsorption performance showed that the CO2 adsorption capacity not only depended on the pore structures of MCM-41 and SBA-15, but also on the improvement of the dispersion state of MgO by modification. Among various Mg modified silica mesoporous materials, the CO2 adsorption capacity increased from 0.42 mmol g−1 of pure silica SBA-15 to 1.35 mmol g−1 of Mg–Al–SBA-15-I1 by the ion-exchange method enhanced with Al3+ synergism. Moreover, it also increased from 0.67 mmol g−1 of pure silica MCM-41 to 1.32 mmol g−1 of Mg–EDA–MCM-41-D10 by the dispersion method enhanced with the incorporation of ethane diamine. The stability test by 10 CO2 adsorption/desorption cycles showed Mg–urea–MCM-41-D10 possessed quite good recyclability. 相似文献
6.
《Electrochemistry communications》2008,10(5):795-797
Activated carbon fibers (ACFs) with high surface area and highly mesoporous structure for electrochemical double layer capacitors (EDLCs) have been prepared from polyacrylonitrile fibers by NaOH activation. Their unique microstructural features enable the ACFs to present outstanding high specific capacitance in aqueous, non-aqueous and novel ionic liquid electrolytes, i.e. 371 F g−1 in 6 mol L−1 KOH, 213 F g−1 in 1 mol L−1 LiClO4/PC and 188 F g−1 in ionic liquid composed of lithium bis(trifluoromethane sulfonyl)imide (LiN(SO2CF3)2, LiTFSI) and 2-oxazolidinone (C3H5NO2, OZO), suggesting that the ACF is a promising electrode material for high performance EDLCs. 相似文献
7.
《Electrochemistry communications》2007,9(1):65-70
A thionine modified aligned carbon nanotubes (ACNTs) electrode was fabricated and was used to electrochemically determine nitrite. The thionine modified ACNTs electrode exhibited enhanced electrocatalytic behavior to the oxidation of nitrite. The electrochemical mechanism of the thionine/ACNTs electrode towards the oxidation of nitrite was discussed. The thionine modified ACNTs electrode exhibited fast response towards nitrite with a detection limit of 1.12 × 10−6 mol L−1 and a linear range of 3 × 10−6 – 5 × 10−4 mol L−1. The proposed method was successfully applied in the detection of nitrite in real samples. 相似文献
8.
《Arabian Journal of Chemistry》2014,7(5):715-721
A highly sensitive, selective and rapid method for the determination of cobalt based on the rapid reaction of cobalt(II) with 5-(2-benzothiazolylazo)-8-hydroxyquinolene BTAHQ and the solid phase extraction of the Co(II)-BTAHQ complex with C18 membrane disks were developed. In the presence of pH = 6.4 buffer solution and cetylpyridenium chloride (CPC) medium, BTAHQ reacts with cobalt to form a deep violet complex with a molar ratio of 1:1 (cobalt to BTAHQ). This complex was enriched by the solid phase extraction with C18 membrane disks. An enrichment factor of 100 was obtained by elution of the complex from the disks with a minimal amount of isopentyl alcohol. In isopentyl alcohol medium, the molar absorptivity of the complex is 2.42 × 105 L mol−1 cm−1 at 658 nm. Beer’s law is obeyed in the range of 0.01–0.38 μg mL−1 in the measured solution. The relative standard deviation for 11 replicate samples of 0.20 μg mL−1 level is 1.37%. The detection and quantification limits reach 3.1 and 9.7 ng mL−1 in the original samples. This method was applied for the determination of cobalt in biological, water, soil and pharmaceutical preparation samples with good results. 相似文献
9.
《Arabian Journal of Chemistry》2020,13(1):1040-1051
A novel electrochemical platform was designed and prepared for simultaneous determination of p-acetaminophen (AMP) and p-aminophenol (AP) by combining the excellent conductivity and electrocatalytic activities of tetraaminophenyl porphyrin functionalized multi-walled carbon nanotubes (CNTs-CONH-TAPP) and gold nanoparticles (AuNPs). The as-synthesized CNTs-CONH-TAPP composites were characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. The incisive oxidation current responses of AMP and AP at the modified electrode promised a sensitive and selective simultaneous determination of AMP and AP. Under optimized conditions, the peak currents were directly proportional to the concentrations of AMP and AP over the ranges of 4.5–500 μmol L−1 and 0.08–60 μmol L−1, respectively, and the limits of detection were 0.44 μmol L−1 for AMP and 0.025 μmol L−1 for AP(S/N = 3) respectively. The proposed modified electrode showed excellent selectivity, reproducibility and long-term stability and could be applied in simultaneous determination of p-acetaminophen and p-aminophenol in real samples. 相似文献
10.
《Colloids and surfaces. B, Biointerfaces》2010,80(2):480-487
A novel poly(p-xylenolsulfonephthalein) modified glassy carbon electrode was prepared for the simultaneous determination of ascorbic acid (AA), epinephrine (EP) and uric acid (UA). Cyclic voltammetric, chronoamperometric, and differential pulse voltammetric methods were used to investigate the modified electrode for the electrocatalytic oxidation of EP, AA, and UA in aqueous solutions. The separation of the oxidation peak potentials for AA–EP and EP–UA was about 200 and 130 mV, respectively. The calibration curves obtained for AA, EP, and UA were in the ranges of 10–1343, 2–390, and 0.1–560 μmol L−1, respectively. The detection limits (S/N = 3) were 4, 0.1, and 0.08 μmol L−1 for AA, EP and UA, respectively. The diffusion coefficient and the catalytic rate constant for the oxidation of EP at the modified electrode were calculated as 1.40(±0.10) × 10−4 cm2 s−1 and 1.06 × 103 mol−1 L s−1, respectively. The present method was applied to the determination of EP in pharmaceutical and urine samples, AA in commercially available vitamin C tablet, and EP plus UA in urine samples. 相似文献
11.
《Electrochemistry communications》2005,7(6):597-601
A novel chitosan-carboxylated multiwall carbon nanotube modified glassy carbon electrode (MC/GCE) was developed to investigate the oxidation behavior of nitrite using cyclic voltammetry and differential pulse voltammetry modes. The electrochemical mechanism of the MC/GCE towards nitrite was discussed. The MC/GCE exhibited fast response towards nitrite with a detection limit of 1 × 10−7 mol l−1 and a linear range of 5 × 10−7–1 × 10−4 mol l−1. The possible interference from several common ions was tested. The proposed method was successfully applied in the detection of nitrite in real samples. 相似文献
12.
《The Journal of chemical thermodynamics》2007,39(3):455-461
Three members of the lead (II) n-alkanoates (from etanoate to n-butanoate) have been synthesized, purified and studied by d.s.c., X-ray diffraction, and FTIR spectroscopy. Lead (II) acetate, propanoate, and butanoate present only a melting transition at T = (452.6, 398.2, and 346.5) K, with ΔfH = (16.0, 13.1, and 15.6) kJ · mol−1, and ΔfS = (35.3, 32.8, and 45.1) J · mol−1 · K−1, respectively. These temperature data correct to a great extent the historical values reported in the literature. These three members readily quench into a glass state. Their corresponding Tg values are (314.4, 289.0, and 274.9) K, respectively, measured by d.s.c. at a heating rate of 5 K · min−1. 相似文献
13.
《The Journal of chemical thermodynamics》2007,39(3):488-492
The Freundlich and Langmuir isotherms were used to describe the biosorption of Cu(II), Pb(II), and Zn(II) onto the saltbush leaves biomass at 297 K and pH 5.0. The correlation coefficients (R2) obtained from the Freundlich model were 0.9798, 0.9575, and 0.9963 for Cu, Pb, and Zn, respectively, while for the Langmuir model the R2 values for the same metals were 0.0001, 0.1380, and 0.0088, respectively. This suggests that saltbush leaves biomass sorbed the three metals following the Freundlich model (R2 > 0.9575). The KF values obtained from the Freundlich model (175.5 · 10−2, 10.5 · 10−2, and 6.32 · 10−2 mol · g−1 for Pb, Zn, and Cu, respectively), suggest that the metal binding affinity was in the order Pb > Zn > Cu. The experimental values of the maximal adsorption capacities of saltbush leaves biomass were 0.13 · 10−2, 0.05 · 10−2, and 0.107 · 10−2 mol · g−1 for Pb, Zn, and Cu, respectively. The negative ΔG∘ values for Pb and the positive values for Cu and Zn indicate that the Pb biosorption by saltbush biomass was a spontaneous process. 相似文献
14.
《Journal of membrane science》2006,268(1):13-19
Tetrahydrofuran (THF) is a strong aprotic solvent, commonly used in the pharmaceuticals industry due to its broad solvency for both polar and non-polar compounds. THF and water form a homogeneous azeotrope at 5.3 wt.% water thus simple distillation is not feasible to dehydrate THF below this concentration. Pervaporation offers a solution since it is not governed by vapour–liquid equilibria. However many polymer-based pervaporation membranes are cast utilizing THF as the casting solvent and so these membranes have a tendency to swell excessively in its presence. This results in poor separation performance and poor long-term stability and thus renders these membranes unsuitable for THF dehydration.In this study, a new membrane available from CM Celfa, CMC-VP-31 has been tested for the dehydration of THF. The membrane shows excellent performance when dehydrating THF with a flux of over 4 kg m−2 h−1 when dehydrating THF containing 10 wt.% water at 55 °C dropping to 0.12 kg m−2 h−1 at a water content of 0.3 wt.%. The permeances of water and THF in the membrane were calculated to be 11.76 × 10−6 and 7.36 × 10−8 mol m−2 s−1 Pa−1, respectively, at 25 °C and found to decrease in the membrane with increasing temperature to values of 6.71 × 10−6 and 1.63 × 10−8 mol m−2 s−1 Pa−1 at 55 °C. The flux and separation factor were both found to increase with an increase in temperature thus favouring the operation of CMC-VP-31 at high temperatures to optimize separation performance. 相似文献
15.
《The Journal of chemical thermodynamics》2003,35(7):1161-1169
Excess molar volumes VmE of binary mixtures of 2,2,2-trifluoroethanol with water, or acetone, or methanol, or ethanol, or 1-alcholos, or 1,4-difluorobenzene, or 4-fluorotoluene or α,α,α-trifluorotoluene were measured in a vibrating tube densimeter at temperature 298.15 K and pressure of 101 kPa. The VmE extrema are: 1.540 cm3 · mol−1 for (2,2,2-trifluoroethanol + 1-heptanol); 1.452 cm3 · mol−1 for (2,2,2-trifluoroethanol + 1-hexanol); 1.238 cm3 · mol−1 for (2,2,2-trifluoroethanol + 1-butanol); 0.821 cm3 · mol−1 for (2,2,2-trifluoroethanol + 4-fluorotoluene); 0.817 cm3 · mol−1 for (2,2,2-trifluoroethanol + ethanol); 0.647 cm3 · mol−1 for (2,2,2-trifluoroethanol + methanol); 0.618 cm3 · mol−1 for (2,2,2-trifluoroethanol + acetone); 0.605 cm3 · mol−1 for (2,2,2-trifluoroethanol + α,α,α-trifluorotoluene); 0.485 cm3 · mol−1 for (2,2,2-trifluoroethanol + 1,4-difluorobenzene); and −0.656 cm3 · mol−1 for (2,2,2-trifluoroethanol + water). The limiting excess partial molar volumes are estimated. 相似文献
16.
《The Journal of chemical thermodynamics》2006,38(3):211-223
The high-temperature heat capacity of zirconia was directly measured by differential scanning calorimetry between T = (1050 and 1700) K and derived from the heat content measured by transposed temperature drop calorimetry between T = (970 and 1770) K, including the monoclinic–tetragonal (m–t) phase transition region. The enthalpy and entropy of the m–t phase transition are (5.43 ± 0.31) kJ · mol−1 and (3.69 ± 0.21) J · K−1 · mol−1, respectively. Values of thermodynamic functions are provided from room temperature to 2000 K. 相似文献
17.
《Radiation Physics and Chemistry》1999,53(2):171-176
Pulse radiolytic reduction of bovine serum albumin (BSA) and lysozyme by CO⨪2 radical in presence of polyvinyl alcohol (PVA) has been studied. At pH 6.8 in presence of 2% (w/v) PVA, reduction of BSA and lysozyme (both at 1×10−4 mol dm−3) give an additional transient peak at 390 nm along with the usual 420 nm peak. The bimolecular rate constants for the reaction of CO⨪2 radical at pH 6.8±0.2 with BSA are 2.7×108 and 7.13×108 dm3 mol−1 s−1 at 420 nm and 390 nm respectively. The same for lysozyme are 3.2×108 and 5.6×108 dm3 mol−1 s−1 at 420 nm and 390 nm, respectively. Dimethyl disulfide also gives 390 nm and 420 nm peaks in this system upon reduction with CO⨪2 radical. The 390 nm peak is ascribed to the sulfenium radical (RSS(H)R). Studies on the variation of pH suggests the protonation of RSSR⨪ radical (420 nm) to form RSS(H)R radical (390 nm) in this viscous media. The decay of RSS(H)R radical occurs via formation of RS radical and RS(H)S(H)R, the final product being RSH in both cases. 相似文献
18.
《Journal of Analytical and Applied Pyrolysis》2009,84(2):145-150
The thermal behavior of 4-amino-1,2,4-triazol-5-one (ATO) was studied under non-isothermal condition by DSC method in a sealed cell of stainless steel. The melting enthalpy and melting entropy of ATO are 21.34 ± 0.49 kJ mol−1 and 46.54 ± 0.30 J mol−1 K−1, respectively. The kinetic parameters were obtained from the analysis of DSC curves by Kissinger method, Ozawa method, the differential method and the integral method. The main exothermic decomposition reaction mechanism of ATO is classified as nucleation and growth, and the kinetic parameters of the reaction are Ea = 119.50 kJ mol−1 and A = 109.03 s−1. The gas products and condensed phase products of the thermal decomposition of ATO were studied on two simultaneous devices of the fast thermolysis reaction cell (gas reaction cell) in situ in conjunction with rapid scan transform infrared spectroscopy (RSFT-IR) and the solid reaction cell in situ. The heat of formation (HOF) for ATO was evaluated by G3 theory. The detonation velocity (D) and detonation pressure (P) were estimated by using the well-known Kamlet–Jacobs equation, based on the theoretical HOF and the determined crystal density. 相似文献
19.
《Electrochemistry communications》2007,9(10):2606-2610
Nano-sized nickel ferrite (NiFe2O4) was prepared by hydrothermal method at low temperature. The crystalline phase, morphology and specific surface area (BET) of the resultant samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and nitrogen physical adsorption, respectively. The particle sizes of the resulting NiFe2O4 samples were in the range of 5–15 nm. The electrochemical performance of NiFe2O4 nanoparticles as the anodic material in lithium ion batteries was tested. It was found that the first discharge capacity of the anode made from NiFe2O4 nanoparticles could reach a very high value of 1314 mAh g−1, while the discharge capacity decreased to 790.8 mAh g−1 and 709.0 mAh g−1 at a current density of 0.2 mA cm−2 after 2 and 3 cycles, respectively. The BET surface area is up to 111.4 m2 g−1. The reaction mechanism between lithium and nickel ferrite was also discussed based on the results of cycle voltammetry (CV) experiments. 相似文献
20.
《The Journal of chemical thermodynamics》2006,38(2):152-157
Vapour pressures of water over saturated solutions of cesium chloride, cesium bromide, cesium nitrate, cesium sulfate, cesium formate, and cesium oxalate were determined as a function of temperature. These vapour pressures were used to evaluate the water activities, osmotic coefficients and molar enthalpies of vapourization. Molar enthalpies of solution of cesium chloride, ΔsolHm(T = 295.73 K; m = 0.0622 mol · kg−1) = (17.83 ± 0.50) kJ · mol−1; cesium bromide, ΔsolHm(T = 293.99 K; m = 0.0238 mol · kg−1) = (26.91 ± 0.59) kJ · mol−1; cesium nitrate, ΔsolHm(T = 294.68 K; m = 0.0258 mol · kg−1) = (37.1 ± 2.3) kJ · mol−1; cesium sulfate, ΔsolHm(T = 296.43 K; m = 0.0284 mol · kg−1) = (16.94 ± 0.43) kJ · mol−1; cesium formate, ΔsolHm(T = 295.64 K; m = 0.0283 mol · kg−1) = (11.10 ± 0.26) kJ · mol−1 and ΔsolHm(T = 292.64 K; m = 0.0577 mol · kg−1) = (11.56 ± 0.56) kJ · mol−1; and cesium oxalate, ΔsolHm(T = 291.34 K; m = 0.0143 mol · kg−1) = (22.07 ± 0.16) kJ · mol−1 were determined calorimetrically. The purity of the chemicals was generally greater than 0.99 mass fraction, except for HCOOCs and (COOCs)2 where purities were approximately 0.95 and 0.97 mass fraction, respectively. The uncertainties are one standard deviations. 相似文献