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杭州老虎洞窑古陶瓷成分的化学计量学研究 总被引:1,自引:0,他引:1
用支持向量机算法研究了与杭州老虎洞古陶瓷有关的两个断源、断代问题。作为化学计量学的~种新型分类算法,支持向量机在小样本问题上表现出良好的泛化能力,与特征选择方法结合,可以有效处理样本少,特征多的问题。本研究综合利用支持向量机、特征选择算法和其它化学计量学算法研究了杭州凤凰山麓万松岭附近的古窑遗址和“传世哥窑”的断源、断代问题,证明老虎洞窑与郊坛下窑产品截然不同,万松岭附近地面收集瓷片样本是老虎洞窑宋代地层的瓷片滑落所致,而“传世哥窑”样品可能是老虎洞窑元代时的产品。实验表明:支持向量机算法与化学分析相结合可以成为研究古陶瓷断源和断代问题的一种新方法。 相似文献
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一种工业废料用于催化气化的尝试 总被引:2,自引:1,他引:1
筛选工业废料用于煤炭催化气化,以求解决回收催化剂的难题。所用水泥窑灰对丹东无烟煤和黄县褐煤均有较好的催化活性,可以大大提高碳的转化率,缩短气化时间。达到相同转化率时,用它催化可比无催化的反应温度降低约100℃。水泥窑灰中主要活性组分为K_2SO_4和CaCO_3。动力学测试表明,添加窑灰与不添加窑灰的气化反应均属一级反应。 相似文献
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乌鸡白凤丸及乌骨鸡、土鸡中微量元素的分析 总被引:3,自引:0,他引:3
采用原子吸收法分析了乌鸡白凤丸,泰和乌骨鸡和土鸡的某些无机元素含量并进行了对照研究。结果表明,乌鸡白凤丸的南方方中无机元素含量比北方方丰富,有更好的养血,补血功效,但北方方也有其特点。 相似文献
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Y. Q. Wang S. L. Feng X. Q. Feng Y. Lei L. Cheng Q. Xu Z. X. Zhuo D. X. Xue 《Journal of Radioanalytical and Nuclear Chemistry》2007,272(3):541-543
Yaozhou Kiln at Lidipo and Shangdian are two independent porcelain kiln groups of Yaozhou kiln series in Shanxi Province.
Both of them were consisted of some individual porcelain kilns. The samples of 20 pieces of porcelain sherds produced in Shangdian
and 43 pieces of porcelain sherds made in Lidipo sites which produced in Kin Dynasty (1115–1234 A.D.) have been collected.
The main chemical compositions in body were determined by X-ray fluorescence (XRF). The contents of trace elements were measured
using neutron activation analysis (NAA). Principal component analysis (PCA) and stepwise discriminant analysis were used to
study the provenance characteristic of these samples. The results indicated that the main components and trace elements in
the specimen can be used to reveal the provenance characteristic. 相似文献
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Hongyu Zhang Zhiwen Zhao Dawei Yang Sheng Wang Wenyu Guo 《Journal of Radioanalytical and Nuclear Chemistry》2009,279(1):307-312
Dangyangyu kiln was an important civil porcelain production place in the North China during the Song Dynasty. In order to
find out the source of raw materials of the porcelain body and glaze and their classification relationship so as to correctly
distinguish them, we have used XRF to determine the major chemical elements of some porcelain samples with light brown and
samples with black flower on a white background. Dynamic fuzzy cluster analysis was applied to the data. Results indicate
that the origin of raw materials of light brown porcelain body samples is comparatively more concentrated, while that of the
porcelain with black flower on a white background is scattered about. The origin of the body materials of those two kinds
of porcelain samples is obviously different. The origin of raw materials of light brown porcelain samples is comparatively
concentrated and stable, while that of the porcelain with black flower on a white background is scattered about, moreover,
the origin of glaze raw materials and the formula of the two kinds are obviously different. The origin and formula of the
light brown porcelain with white glaze in the interior are close to those of the white glaze of porcelain with black flower
on a white background, but they are not entirely identical. 相似文献
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Jihao Zhu Songlin Feng Dongyu Fan Xiangqian Feng Qing Xu Huishan Quan Yueming Shen Zhenxi Zhuo Wenjiang Zhang 《Journal of Radioanalytical and Nuclear Chemistry》2007,272(3):545-549
Chemical composition is an important information of studying the provenance character of ancient pottery and porcelain. The
ancient celadon samples produced in Later Tang (850–907 A.D.) to Former Southern Song (1127–1279 A.D.) have been analyzed
with NAA. Its provenance characteristic was compared with that of Hongzhou Kiln of Jiangxi Province and Yaozhou Kiln of Shanxi
Province in this paper. The experimental data were studied with statistic methods. The results indicated that the chemical
compositions of ancient porcelain body samples made in three kilns were different. The difference is able to be identified.
The porcelain body materials of both Silongkou Yue Kiln and Hongzhou Kiln were similar. The samples of Yaozhou kiln in north
of China existed obvious difference. 相似文献
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HF (hydrogen fluoride) emission control is one of the critical environmental parameters in the firing of ceramic materials at peak temperatures higher than 1000 °C. In this study, in-stack concentrations of HF were monitored on-line with laser-based equipment during the fast firing of ceramic tiles in continuous industrial roller hearth kilns under standard kiln operating conditions.Three different ceramic tile compositions: porous red-body wall tiles, red-body stoneware tiles, and porcelain tiles were fired in industrial kilns customarily used to manufacture these types of tiles, modifying the heating rate and tile dry bulk density. The in-stack concentrations of HF can be explained on the basis of tile HF adsorption and emission processes in the kiln preheating and firing zones, analysed in previous studies.The methodology used in this study has significant advantages for industrial studies compared with previous methodologies based primarily on laboratory-scale studies and analysis of solid material. The main advantages are: (a) rapid response, allowing abrupt changes in the HF emission to be studied; and (b) direct measurement of the in-stack concentration of HF, which is the most common parameter used as a legal limit for industrial emission control.The study shows that tile HF adsorption in the preheating zone is very important. It also shows that HF stack emissions can vary significantly in continuous kilns depending on whether glazed or unglazed tiles are produced, or important changes occur in production (such as gaps in the kiln feed). The results indicate, furthermore, that HF stack emissions do not decrease significantly when realistic changes are made in industrial operating conditions if these industrial kilns are run at peak temperatures above 1100 °C. The most important reduction in in-stack concentrations of HF is observed when glazed ceramic tiles are fired, so further research in this field can be made in order to reduce HF emissions. 相似文献
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应用能量色散X射线荧光光谱法测定了16个金元时期钧窑瓷器胎、釉样品的化学组成。由结果可知:金元钧瓷胎具有低硅高铝的北方瓷器特点,釉则多为钙碱釉。金元时期样品与北宋时期钧窑瓷器胎釉化学组成比较,金元时期钧窑样品的化学组成变化较大,从因子分析散点图可见,北宋钧官窑样品化学组成变化不大;金元钧窑与北宋钧民窑样品制作工艺上存在继承和发展的关系,但金元时期对原料选择和配方的控制已不如北宋时期严格,反映出金元时期的钧窑已处于衰落阶段。 相似文献
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Angela Traini Lorena C. Giannossa P. Ubbrìaco Annarosa Mangone Maria D. De Filippis R. Laviano 《Journal of Thermal Analysis and Calorimetry》2008,92(1):337-344
Two kilns, one of which collapsed during firing cycle together with its entire pottery load, have been excavated at the Egnazia
site in Southern Italy.
To understand the reason for the collapse, ‘Broad Line’ typology pottery finds were analysed by complementary analytical techniques.
Analytical results not only suggest as cause of collapse sudden overheating in kiln due to uncontrolled increases in temperature,
but also indicate a good technological cycle from the recovery of raw materials to the manufacturing and firing process, which
tends to disprove the common assumption of non-professional production. 相似文献
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A. Bhattacharya 《Journal of Thermal Analysis and Calorimetry》1993,40(1):141-149
TG and DTA studies on laboratory cement raw mixes and raw dolomite have been extensively reported in the literature. This paper discusses four aspects. (1) Calcination kinetics of raw mix by isothermal TG and calculation of rate constants to derive activation energy by Arrhenius plots. (2) Quantification by TG of minerals in Indian laterites. The amount of goethite appears to influence burnability of raw mix. (3) Determination of practical heat of clinker formation from DTA studies and establishment of enthalpy temperature relationship of raw mix for heat transfer studies in rotary kilns. (4) Prediction of material temperature profile in a dolomite kiln from DTA studies of raw dolomite. 相似文献
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Summary In this study a high-performance liquid chromatography method was developed for the determination of procyanidin dimers B1,
B2, B3, B4 and procyanidin trimers C1 and T2 in white wine using fluorescence detection. This method allowed analysis of white
wine with no prior treatment. Limits of quantification were form 12 μg.L−1 to 16 μg.L−1. Reproductibility data for replicate analysis was measured and the CV was less than 4.5%. This method was used for the determination
of these compounds in six French white wines. 相似文献
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以掺杂合成高岭石为研究对象,讨论了铁含量与合成高岭石白度之间的关系,并对目标物进行了X射线衍射和差热分析等表征,探讨了铁在合成高岭石中的存在状态. 相似文献