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高浓度臭氧化学分析法 总被引:2,自引:0,他引:2
根据文献[1]用KI溶液吸收O_3,然后滴定溶液中产生的I_2。在建立方法过程中,我们发现按文献[1]的条件操作时,对同一样品,分析结果差别很大。当O_3被0.5mol/L浓度的碘化 相似文献
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测定可逆反应动力学参数的一种新方法 总被引:2,自引:1,他引:1
提出了测定一级可逆反应速率常数的新方法,用以测定稀土的偶氮胂Ⅲ络合物与CyDTA交换反应的速率常数,并详细讨论了测定速率常数时动力学数据的选取原则。 相似文献
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计算9.6微米臭氧带冷却率的一种新方法 总被引:1,自引:0,他引:1
本文用一种新的计算方法,计算了9.6微米O_3带的冷却率.经过与逐线积分结果的比较,证明了这种新的算法可以精确处理目前红外辐射传输计算中尚未获得圆满解决的频率积分、角度积分以及非均匀路径等问题.新算法在计算时间方面也是比较节省的.同时,文中还表明了通常的带模式方法中所使用的CG近似、漫射因子近似等,对9.6微米O_3带基本上是不适用的。 相似文献
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食品中二氧化硫的含量测定 ,采用的是国家标准GB5 0 0 9.34 96盐酸副玫瑰苯胺法[1 ] ,但该法在实际运用中却存在着许多不足之处 ,如SO2 的吸收剂采用的是剧毒四氯汞钠试剂 ,且该试剂配制好后需放置过夜后过滤才可使用 ;而显色剂盐酸副玫瑰苯胺溶液的配制也较为麻烦 ,需时较长 ;更为严重的是 ,该法在未扣除有色试样背景干扰的情况下 ,对有色试样采取直接取样进行分析 ,这就给测定结果带来了较大的误差 ,特别是测定诸如赤砂糖这类颜色较深的物质中SO2 含量时 ,其较深的背景严重干扰测定 ,且测定结果往往还因其取样量的不同而不同 ,这就… 相似文献
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一种测定食品中微量铁的新方法 总被引:1,自引:0,他引:1
提出了一种用分光光度法测定食品中微量铁的新方法,即在微酸性条件下,铁与邻硝基苯基荧光酮、表面活性剂CPC形成蓝色的三元络合物。该法简便、体系稳定、灵敏度高,用于测定茶叶、大豆中的微量铁,取得满意结果。 相似文献
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在有色冶金、电池等行业的技术难题都与其使用的原料——工业级氯化铵中钾钠离子和其它的碱金属、碱土金属离子的含量过高有关。如用工业级氯化铵生产仲钨酸铵时,只能生产1级、2级的粗放型产品,而难以生产国际上十分抢手的零级产品。如果能将工业级氯化铵中的碱金属含量降到xxμg·g-1,则为生产出零级仲钨酸铵创造了有利条件。眺山化工厂的主要产品为碳酸钾,其副产品为 相似文献
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The determination of low concentrations of inorganic anions in water samples of high salinity is one of the most difficult
tasks in analytical chemistry. There is, however, an increasing demand for the exact and reliable determination of nutrients
even at very low concentration levels in environmental samples of complex composition. We therefore present the development,
quality control and application of an easy and rugged method that makes possible the determination of trace amounts of nitrate
in solutions with high concentrations of chloride (>30 000 mg L−1) and a hundred-fold excess of bromide ions, based on ion chromatography with UV detection at λ = 210 nm. While chloride ions
show no absorbance at this wavelength, a bromide concentration >1500 μg L−1 severely interferes with nitrate determination at the trace level. On the contrary, at nitrate concentrations of >500 μg L−1, this bromide interference becomes negligible. Consequently, to overcome the impact of bromide on the trace level determination
of nitrate, all samples are spiked with a definite volume of a nitrate standard solution to obtain an overall nitrate concentration
of >500 μg L−1 which allows the exact and reliable determination of nitrate concentrations down to 25 μg L−1. We will report the successful application of the method to samples of high salinity. 相似文献
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Ivana Cesarino Fernando C. Moraes Sergio A. S. Machado Juliano PassarettiFilho Arnaldo A. Cardoso 《Electroanalysis》2011,23(6):1512-1517
A new electrochemical methodology has been developed for the detection of ozone using multiwalled carbon nanotubes (MWCNT). The method presented here is based on the reaction of ozone with indigo blue dye producing anthranilic acid (ATN). The electrochemical profile of ATN on an electrode of glassy carbon (GC) modified with MWCNT showed an oxidation peak potential at 750 mV vs. Ag/AgCl. An analytical method was developed using differential pulse voltammetry (DPV) to determine ATN in a range of 50–400 nmol L?1, with a detection limit of 9.7 nmol L?1. Ozonated water samples were successfully analyzed by GC/MWCNT electrode and the recovery procedure yielded values between of 96.5 and 102.3 %. 相似文献
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L. A. Obvintseva T. B. Sharova A. K. Avetisov I. P. Sukhareva 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2018,92(6):1099-1106
Prospects for the use of semiconductor resistive sensors in studies of the heterogeneous destruction of ozone at low concentrations (5–400 μg/m3) were shown. The influence of various factors (sensor temperature, gas flow rate, ozone concentration) on the results of ozone concentration measurements with sensors of various types was studied. Methods for forming a sensitive layer of In2O3(3% Fe2O3) sensors with specified parameters of calibration curves were proposed. The optimum conditions for the operation of sensors in a flow mode were formulated. The results of the study of heterogeneous destruction of ozone on microfiber polymer and natural disperse (sand, coals) materials obtained by the developed method were presented. 相似文献
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采用火焰原子吸收光谱法测定了高纯碳酸锂中多种杂质元素(包括锌、钠、铅、钾、铁、钙及镁)的含量。结果表明:测定上述各元素的相对标准偏差(n=9)在1.9%~4.4%之间。各元素的工作曲线具有良好的线性关系,相关系数在0.9943至0.9998之间。用标准加入法做回收试验,测得平均回收率在98.3%至101.0%之间。 相似文献
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1引言Valienam ine((1S,2S,3S,4R)-1-氨基-5-(羟甲基)环己-5-烯-2,3,4-三元醇),分子式C7H13NO4,是一种由假单孢菌降解井冈霉素获得的假氨基糖,可通过阿卡波糖或井冈霉素水解来制备。它不仅能够有效治疗糖尿病及高血糖所导致的肥胖症,而且还能治疗艾滋病等其它疾病,所以对其的研究和开发已引起全世界生物医学领域的广泛关注。Valienam ine的检测方法主要有糖化酶检测法、紫外分光光度法、质谱法和薄层扫描法等,这些方法都存在难于定量或定量不准确、检测不方便的缺陷。有人用p-硝基氟苯与Valienam ine反应衍生生成N-p-硝基苯-Valienam … 相似文献
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血清中阿斯匹林和水杨酸浓度的快速高效液相色谱法测定 总被引:3,自引:0,他引:3
A fast method for determining concentrations of aspirin and salicylic acid in serum using reversedphase high performance liquid chromatography with Spherisorb C18 column,MeOH i H2O: n-BuOH : H3PO4 (300:200 :10 :0. 5,volume ratio) eluent and UV-237 detector was eatablished. The linear range of the method is 1-20μg/mL (r=0. 9996)for aspirin and 2 30μg/mL (r=0. 9981) for salicylic acid. The averagerecoveries are 96. 0 %-106. 0% and 92. 0%-119.5% ,respectively. 相似文献
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The determination of the individual conversion rate of each monomer in a radical copolymerization allows the absolute concentration of each kind of growing radical to be derived, provided the reactivity ratios and the homopropagation rate constants are known. The procedure is applied to the following binary copolymerizations: styrene-methyl methacrylate, vinyl chloride-vinyl acetate, acrylonitrile-vinyl acetate, and acrylonitrile-vinyl chloride. In the two latter cases, the anomalous behavior, probably caused by the internal cyclization reaction involving CN bonds, is well evidenced. 相似文献
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《液相色谱法及相关技术杂志》2012,35(9):1291-1303
Abstract Ranitidine hydrochloride is a highly potent H2 receptor antagonist of value in the treatment of peptic ulceration. A method is described for the determination of ranitidine in biological fluids. The drug is extracted from plasma prior to determination by reverse phase high performance liquid chromatography. The method is sensitive enough to determine 10ng ranitidine per ml in plasma. The h.p.l.c. method has been automated so that analysis can be carried out without attention over a 24 hour period. The automated h.p.l.c. method has been used for studying the pharmacokinetics of oral and intravenous doses of ranitidine hydrochloride administered to man. 相似文献