Crank-angle resolved imaging of biacetyl laser-induced fluorescence in an optical internal combustion engine

The use of a frequency-tripled, diode-pumped Nd:YAG laser in combination with a CMOS camera lens-coupled to a three-stage image intensifier allowed the visualization of the fuel distribution with crank angle resolution for hundreds of consecutive engine cycles. Biacetyl, doped into iso-octane, was excited at rates of 12 kHz with 100 ns pulses. Pulse energies are high enough to allow single-pulse imaging of the vapor-phase fuel distribution for motored and fired operation in an optical engine. The repetition rate of the setup is adequate to resolve critical steps in the development of the fuel cloud around the spark plug of a direct-injection gasoline engine.PACS 42.62.Fi; 33.50.Dq; 82.33.Vx     

Quantitative high-speed burned gas temperature measurements in internal combustion engines using sodium and potassium fluorescence

When sodium- and potassium-containing fuel additives are used in internal combustion engines, the bright fluorescence that sodium and potassium atoms emit in the burned gas zone offers a large potential for spectroscopic combustion analysis. To utilize this potential quantitatively, it is crucial to fully understand all physical and chemical processes involved. This includes (1) the temperature dependence of the fluorescence intensity due to gas-phase collisions, (2) the pressure, temperature and equivalence ratio effects on thermodynamic equilibria in the burned gas zone and (3) pressure and temperature-dependent line shapes for quantitative correction of fluorescence reabsorption. High-speed imaging of sodium and potassium fluorescence in a spark-ignited, direct injection, single-cylinder research engine was conducted under well-controlled homogeneous operating conditions at equivalence ratios ranging from 0.71 to 1.43, cylinder pressure from 3 to 15 bar and burned gas temperatures from 1,700 to 2,600 K. This study demonstrates that the influence of pressure, temperature and equivalence ratio on the fluorescence signals of sodium and potassium is understood quantitatively and establishes the potentials and limitations of this tool for burned gas temperature measurements with high temporal and two-dimensional spatial resolution in a homogeneously operated internal combustion engine.     

Investigations on mufflers for internal combustion engines

This paper deals with experimental studies on reactive types of muffler—and their combinations with absorption types—in order to determine their noise attenuation characteristics. Tests were carried out on a test rig, with a loudspeaker as the input source, as well as on a four cylinder diesel engine. The frequency spectra of attenuation levels, obtained experimentally, were compared with corresponding theoretical predictions. In addition, the effect on the performance of the engine itself was studied.The results showed, in general, a fairly good agreement between experimental results from test rig and theoretical predictions in the frequency range for which the latter is valid. The attenuation levels obtained from the mufflers fitted on the engine were, in general, lower. The effect on the performance of the engine was marginal. It was seen that the combination mufflers offer a good solution when high noise attenuation is desired.     

An analysis of the in-cylinder soots generated from the main- and post-injection combustion in diesel engines

In modern diesel engines, the exhaust soot primarily comes from the main-injection combustion and post-injection combustion. Therefore, to reduce the diesel soot emissions, it is essential to better understand the soots generated from the main-injection combustion (main-soot) and from the post-injection combustion (post-soot). This work focused on the properties of the main-soot and post-soot during the combustion process, including the primary particle size, nanostructure and soot mass. The in-cylinder soot samples were obtained using a self-developed total cylinder sampling system, and the primary particle size and nanostructure were determined using high-resolution transmission electron microscopy. The isolation of the post-soot was achieved by adding dimethyl ether to the intake gas instead of the real main-injection to create a simulated main-injection combustion environment for post-soot formation. Combustion analysis and numerical simulation results showed that the simulated combustion environment for post-soot formation generated by the DME combustion was very similar to that generated by the real main-injection combustion. During the combustion process, although the main-soot and post-soot exhibit similar variations in the primary particle size, the maximum primary particle size of the post-soot is smaller than that of the main-soot (23.38 nm for the main-soot and 20.51 nm for the post-soot). The main-soot and post-soot show almost the same trends in the nanostructure, as characterized by the fringe length, separation and tortuosity, throughout the combustion process. The introduction of the post-injection accelerates the reduction of the primary particle size of the main-soot and the increase in the structural order of the main-soot. Because a large number of the main-soot particles are oxidized during the post-injection combustion, the post-soot accounts for a considerable proportion in the engine-out soot (i.e., 42%).     

Two-dimensional visualization of the flame front in an internal combustion engine by laser-induced fluorescence of OH radicals

Two-dimensional laser-induced fluorescence (2D-LIF) imaging of OH radicals, excited at 308 nm, has been employed to visualize the flame front in an internal combustion engine burning air/propane mixtures. Light sheet thicknesses down to 70 m have been attained for excitation. Hydroxyl radicals were detected up to pressures of 7.5 bar at engine speeds of 500 rpm. An upper limit of 300 m for the flame front thickness was obtained from line intensity profiles.     

Influence of the in-cylinder flow on cycle-to-cycle variations in lean combustion DISI engines measured by high-speed scanning-PIV

In this study, the influence of the three-dimensional (3D) in-cylinder flow on engine's cycle-to-cycle variations (CCV) in a spray-guided direct-injection spark-ignition engine is investigated. The engine is operated at homogeneous lean air–fuel mixture which enhances the sensitivity to CCV due to reduced laminar flame speed. To compensate this, intake velocity is increased by a tumble-flap (TF) in the intake-port. To address the 3D-nature of the temporal evolution of the instantaneous in-cylinder flow for different TF-positions, time-resolved scanning particle image velocimetry (Scanning-PIV) is applied to the engine. The required scan-frequency is provided by an acousto-optical-deflector (AOD) to measure the flow field quasi-simultaneously in the central tumble-plane and both mid-valve-planes. The three planes are 18?mm displaced from each other to capture the variability of the large-scale tumble vortex. The in-cylinder flow measurements are combined with combustion analyses by the in-cylinder pressure-trace and the detection of the location of ignition through the evaluation of the luminous spark-plasma. A correlation-map analysis is conducted to identify coherent flow features responsible for CCV of the combustion parameters. This reveals a strong dependency of the spark position to variations of an upward directed flow pointing onto the spark plug. The variations of the upward flow are due to strong CCV of the bended tumble-axis position. An increased tumble motion caused by the TF results in favorable flow conditions by stabilizing the tumble-axis in the middle of the cylinder which decreases the CCV of the spark position significantly. Further correlation analysis including the combustion process exhibits that flow-structures moving the spark and early flame kernel towards the cylinder center reduces the crank angle of 5% heat release and the combustion duration considerably.     

Quantitative laser-induced fluorescence: Some recent developments in combustion diagnostics

This report summarizes several recent applications of quantitative laser-induced fluorescence techniques for the determination of species concentrations and temperature in combustion processes. Several lines of further development are discussed.     

Delayed observation of laser-induced fluorescence for imaging of tumors

We report on a technique to improve fluorescence images of superficially growing tumors marked with photosensitizers. Exploiting the longer fluorescence decay times of porphyrin-based photosensitizers compared to average decay times of tissue autofluorescence, delayed detection of laser-induced fluorescence allows to suppress the autofluorescence background. The feasibility of delayed fluorescence imaging of tumors has been demonstrated in-vitro. It follows from an analysis of delayed fluorescence spectra that autofluorescence background falling into the photosensitizer fluorescence band can be reduced by up to one order of magnitude.     

Ultrahigh-frame-rate nitric oxide planar laser-induced fluorescence imaging

We demonstrate the ability to generate ultrahigh frequency burst sequences of deep UV at 226 nm by mixing the optical parametric oscillator signal output at 622 nm with third harmonic at 355 nm from a pulse burst laser system. We obtained 226 nm burst sequences with uniform burst envelopes, and the average pulse energy is approximately 0.5 mJ. Nitric oxide planar laser-induced fluorescence image sequences at ultrahigh (100 kHz) frame rates have been obtained.     

Volume-resolved flame chemiluminescence and laser-induced fluorescence imaging

There is significant need for optical diagnostic techniques to measure instantaneous volumetric vector and scalar distributions in fluid flows and combustion processes. This is especially true for investigations where only limited optical access is available, such as in internal combustion engines, furnaces, flow reactors, etc. While techniques such as tomographic PIV for velocity measurement have emerged and reached a good level of maturity, instantaneous 3D measurements of scalar quantities are not available at the same level. Recently, developments in light field technology have progressed to a degree where implementation into scientific 3D imaging becomes feasible. Others have already demonstrated the utility of light field technology toward imaging high-contrast particles for PIV and for imaging flames when treated as single-surface objects. Here, the applicability and shortcomings of current commercially available light field technology toward volumetric imaging of translucent scalar distributions and flames are investigated. Results are presented from imaging canonical chemiluminescent and laser-induced fluorescent systems. While the current light field technology is able to qualitatively determine the position of surfaces by locating high-contrast features, the correlation-based reconstruction algorithm is unable to fully reconstruct the imaged objects for quantitative diagnostics. Current analysis algorithms are based on high-contrast correlation schemes, and new tools, possibly based on tomographic concepts, will have to be implemented to reconstruct the full 3D structure of translucent objects for quantitative analysis.     

Local fuel concentration measurements in internal combustion engines using spark-emission spectroscopy

Spectrally resolved visible and ultraviolet emissions are investigated as a basis for wide-range, individual-cycle measurement of the local fuel concentration in spark-ignition engines. The 388-nm CN emission intensity, normalized by the spark-discharge energy during the observation interval (typically 150 μs at the start of the glow discharge), is found to be the most useful measure of fuel concentration when data are required over a wide range. Calibration data for homogeneous propane–air and isooctane–air mixtures over a wide range of cylinder gas conditions at the time of ignition collapse to a single curve when the fuel concentration is expressed in terms of the number density of carbon atoms. The carbon number densities measured in this study correspond to fuel–air equivalence-ratios in the range 0–3 at 95% throttle conditions. Random and systematic errors are 10% or less. Applied to an engine in which liquid fuel is injected directly into the cylinder, the technique reveals substantial cyclic fluctuations in the fuel concentration at the spark gap for early fuel injection (intended to produce a homogeneous fuel–air mixture in the combustion chamber) and large fuel-concentration fluctuations for late fuel injection (which produces a highly stratified mixture). The results also show that for stratified operation with a fixed fuel-injection timing, a spark timing that is later than optimum leads to incomplete combustion in many cycles due to fuel–air ratios that are too lean for good ignition and rapid flame development. Received: 6 November 2001 / Revised version: 6 May 2002 / Published online: 25 September 2002 RID="*" ID="*"Corresponding author. Fax: +1-586/986 0176, E-mail: todd.fansler@gm.com     

Experimental investigation of in-duct insertion loss of catalysts in internal combustion engines

Acoustic performance characteristics of catalysts in the exhaust system are important in the development of predictive tools for the breathing system of internal combustion engines. To understand the wave attenuation behavior of these elements with firing engines, dynamometer experiments are conducted on a 3.0L V-6 engine with two different exhaust systems: one with the catalysts on the cross-over pipe, and the other that replaces the catalysts with equal length straight pipes. The instantaneous crank-angle resolved pressure data are acquired at wide open throttle and 500 rpm intervals over the operating range of the engine (from 1000 to 5000 rpm) at various locations in both exhaust systems. The effect of the catalyst is then isolated and discussed in terms of insertion loss at critical locations in the exhaust system. The analysis is presented both in terms of time-domain and order-domain. The predictive capability of a finite-difference based time-domain nonlinear approach is also demonstrated as applied to large amplitude waves in the exhaust system of firing engines.     

Calibration of imaging laser-induced fluorescence measurements in highly absorbing flames

It has been described earlier that imaging measurements of laser-induced fluorescence (LIF) in flames can be calibrated to number densities with an integrated absorption measurement provided the integrated absorption is small. In this paper a method is presented that extends the technique to flames with substantial absorption, improves the number density determination and allows the experimental parameters to be chosen more freely. The method is based on an iterative computer procedure that reconstructs the 1-D spatially resolved absorption profile from laser measurements of the 1-D spatially resolved LIF and the integrated absorption of the laser beam. The technique is experimentally demonstrated by measurements of OH number densities in atmospheric flames. It is potentially a single-pulse method. Other applications of the iterative procedure are mentioned.     

Oxygen-distribution imaging with a novel two-tracer laser-induced fluorescence technique

We introduce a new technique for imaging oxygen concentrations in fuel/air mixtures that takes advantage of the different responses of toluene and 3-pentanone to collisional quenching by molecular oxygen. Since laser-induced fluorescence signals from both tracers upon excitation at 248 nm are spectrally well separated, simultaneous detection is possible. The technique is first applied to instantaneous imaging in turbulent mixing processes of interacting seeded air and nitrogen flows. Received: 1 August 2001 / Revised version: 29 October 2001 / Published online: 29 November 2001     

The application of a raman-shifted tunable KrF excimer laser for laser-induced fluorescence combustion diagnostics

Four wavelength extensions have been investigated by stimulated Raman scattering in hydrogen or deuterium gas of the 248 nm fundamental output of a narrow-band tunable KrF excimer laser. They have been used to acquire laser-induced fluorescence spectra of NO and OH in flames at atmospheric pressure. NO is detected in relatively high rotational states within the -band electronic system at 225 nm. OH was excited at 291.5 nm in the (1–0), at 313 nm in the (1–1) and at 268.5 nm in the predissociative (3–1) band of the ²–² electronic band system, respectively. Prospects of 2D imaging for concentration and temperature measurements in flames using these wavelength extensions are discussed.     

Investigation of droplet combustion in strained counterflow diffusion flames using planar laser-induced fluorescence

Experimental investigation of an isolated droplet burning in a convective flow is reported. Acetone droplets were injected in a steady laminar diffusion counterflow flame operating with methane. Planar laser-induced fluorescence measurements applied to OH radical and acetone was used to measure the spatial distribution of fuel vapour and the structure of the flame front around the droplet. High-magnification optics was used in order to image flow areas with a ratio of 1:1.2. The different combustion regimes of an isolated droplet could be observed from the configuration of the envelope flame to that of the boundary-layer flame, and occurrence of these regimes was found to depend on the droplet Reynolds number. Experimental results were compared with 1D numerical simulations using detailed chemistry for the configuration of the envelope flame. Good agreement was obtained for the radial profile of both OH radical and fuel vapour. Influence of droplet dynamics on the counterflow flame front was also investigated. Results show that the flame front could be strongly distorted by the droplet crossing. In particular, droplets with high velocity led to local extinction of the flame front whereas droplets with low velocity could ignite within the flame front and burn on the oxidiser side. PACS 33.50.-j; 42.62.-b; 47.55.D-; 47.70.Pq; 47.80.Jk     

基于激光诱导叶绿素荧光寿命成像技术的植物荧光特性研究

针对植物荧光遥感探测中信号易受干扰的问题, 提出了一种用于评估植物生长状况及环境监测的荧光寿命成像技术. 采用凹透镜对355 nm波长的激光扩束, 再照射植物激发叶绿素荧光, 由增强型电荷耦合器件接收荧光信号. 采用时间分辨测量法, 连续用相同激光脉冲照射植物以激发相同的荧光信号, 同时不断改变激光脉冲触发探测器启动的延时时间, 从而能够得到完整的离散荧光信号分布图像. 对植物特定位置点产生的离散荧光信号进行拟合, 再运用一种改进型的迭代解卷积法可反演高精度的荧光寿命; 进而反演图像各点的荧光寿命以生成植物的荧光寿命分布图. 该方法所绘制的荧光寿命图比荧光强度图能更准确地反映植物内部的叶绿素含量, 并对活体植物叶绿素荧光寿命的物理特性进行了初步研究, 证明叶绿素荧光寿命与植物生理状态存在一定关联; 并且叶绿素荧光寿命与活体植物所处环境存在着复杂的关系. 未来将与生物物理学家们合作, 继续探寻叶绿素荧光寿命与植物生存环境的关系.     

Single-shot laser-induced fluorescence imaging of formaldehyde with XeF excimer excitation

Single-shot formaldehyde laser-induced fluorescence (LIF) imaging measurements in a technical scale turbulent flame have been obtained using XeF excimer laser excitation in the ?¹A₂-˜X¹A₁ transition at 353.2 nm. Measurements have been carried out in a 150 kW natural gas swirl burner where formaldehyde distribution fields have the potential, in combination with OH concentration fields, to visualize the heat release distribution and therefore give an optimal visualization of flame-front positions. The extended areas where formaldehyde was detected in the swirl flame indicates the presence of low temperature chemistry in preheated gas pockets before ignition. Received: 31 January 2000 / Revised version: 2 March 2000 / Published online: 5 April 2000     

Temperature imaging with single- and dual-wavelength acetone planar laser-induced fluorescence

Two sensitive techniques for temperature imaging by use of acetone planar laser-induced fluorescence, applicable at temperatures up to 1000 K, are introduced and demonstrated. Photophysics data on the wavelength-dependent temperature variation of acetone fluorescence permit the implementation of a single-wavelength technique in environments with constant pressure and constant acetone mole fraction, and a dual-wavelength method can be applied in flows with mixing and (or) chemical reaction. Preliminary imaging results are presented for acetone-air flow over a heated cylinder (single-wavelength strategy) and for a heated laminar jet (dual-wavelength strategy).