Two Dimensional 1HNMR Studies on 2′5′-Dideoxyadenosylcobalamin

The ¹HNMR spectrum of 2′,5′-dideoxyadenosylcobalamin, a Coenzyme B₁₂(5′-deoxyadenosylcobalamin) analogue, has been assigned by 2D COSY. Its proton coupling constants have also been measured by J-resolved experiment. The comparison between the analogue and Coenzyme B¹² was made.     

The decays of theρ′1 andω′1 mesons

New measurements of the reactione ⁺ e ^– confirm previous evidence for the decay₁ and provide a strong constraint on the mass of the₁. The results from a detailed analysis of these data are compared with those from a corresponding analysis of new data on the reactione ⁺ e ^–. It is shown that in accord with expectation. This identification of a strong₁ decay supports a previous claim that the₁ and theC(1480), observed in the channel, cannot be different manifestations of the same particle.     

In-Medium η′ Mass Reduction

In this talk, we present the reduction of the mass of η′-meson at finite temperature which leads to the enhancement of η′ contributions to the dilepton spectra from relativistic heavy ion collisions. QCD low energy theorem, together with the Witten–Veneziano formula, provides the relation of the η′ mass with gluon condensates.     

Pulsed ESR on the organic ion radical salt: 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-[TCNQ]2

We present firstT _1e ^?1 andT _2e ^?1 measurements on the organic ion radical salt 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)₂ as function of temperature and of orientation. The electronic spin diffusion constant could be determined directly by the electron spin echo field gradient technique:D (300 K)=0.03±0.02 cm²/sec. Pulsed ESR experiments have — in comparison to conventional cw-ESR — the advantage to monitor viaT _1e ^?1 andT _2e ^?1 the spectral density of dynamical processes at different frequencies. This is shown in a general manner on 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)₂. Between 300 and 60 K,T _1e ^?1 andT _2e ^?1 are close in amplitude and have a similar temperature dependence. At 60 K their degeneracy is lifted, yielding a quantitative value for the effective spin exchange between localized spinsτ _ex ^?1 sec^?1 and via the absolute value of the relaxation an average distance of the localized centers of about 12 Å. The dynamical data as evaluated above cannot be correlated with the conductivity, clearly indicating that the conduction electrons are a minority, not being monitored by the ESR-experiments.     

Morse 势中矩阵元Xνν′、Pνν′的计算

矩阵元ＸＶＶ’和ＰＶＶ’在有关量子力学问题中有相关重要的应用，本文利用广义拉盖尔多项式的正交性和分部积分的方法，推导Ｍｏｒｓｅ势中ＸＶＶ’、ＰＶＶ’的计算公式。     

1,1′-和1,2′-二萘甲酮结构的光谱分析

本文用红外光谱仪 (FTIR)、紫外分光光度计 (UV)对在无水AlCl3 存在下萘与草酰氯反应合成的1 ,1′ 和 1 ,2′ 二萘甲酮的结构进行了研究。结果表明 ,1 ,1′ 和 1 ,2′ 二萘甲酮结构 (对称性 )上的差别表现出FTIR、UV光谱图上的明显不同。     

N.M.R. spectra of the XnAA′ Xn′ type

The method described previously for the calculation of the X spectrum for spin systems of of the X_nAA′X_n′ type is extended by means of magnetic equivalence factoring to cases in which the long-range coupling constant J_x is non-zero. This coupling is treated as a first-order perturbation to the energy levels obtained when J_x =0, and it is found that J_x may be measured directly from the separations between easily identified lines in the spectrum. A detailed account of the X ₃ AA′X ₃′ system is given, and the N.M.R. spectrum of fluoro-N,N′-dimethyl-1,3,2,4-diazadiphosphetidine is analysed. The spectral parameters obtained are discussed. A computer programme which calculates the spectra of systems involving magnetic equivalence is used to examine the validity of the approximations in the method.     

B →πη（′）, η（′）η（′） decays and NLO contributions in the pQCD approach＊

By employing the perturbative QCD （pQCD） factorization approach, we calculate the full leading and the partial next-to-leading order （NLO） contributions to the seven B →πη（′） and η（′）η（′） decays. For B^＋→ π＋η（′） decays, the pQCD predictions for their decay rates agree very well with the data after the inclusion of the small NLO contributions. For neutral decays, the pQCD predictions are also consistent with the experimental upper limits and can be tested by the LHC experiments. The measured value of dir .Acp^dir（π＋η）= 19±7% can also be accommodated by the pQCD approach.     

′2004中国平板显示学术会议

“′2 0 0 4中国平板显示学术会议”定于 2 0 0 4年 1 0月在上海召开。本次会议的主题为 :“新视野———平板显示” ,会议将云集国内外一流专家 ,力争办成全国最大规模和最高水平的平板显示技术交流大会。会议期间将邀请国际著名显示技术专家、学者演讲并进行技术交流 ,同时举办新产品、新技术展示。 主办单位 :国家和上海市有关行业协会、学会 ; 承办单位 :上海广电股份有限公司欢迎国内外从事平板显示相关行业的科研、工程技术、产品开发、技术推广以及教学的同仁踊跃投稿并参加大会。征文范围 :′2 0 0 4中国平板显示学术会议覆盖显示科…     

d′ production in heavy-ion collisions

The production of d′ dibaryons in heavy-ion collisions due to the elementary process NN → d′π is considered. The NN → d′π cross section is estimated using the vacuum d′ width Γ_d′ ≈ 0.5 MeV extracted from data on the double charge exchange reactions on nuclei. The d′ production rate per single collision of heavy ions is estimated at an incident beam energy of 1 A GeV within the framework of the Quantum Molecular Dynamics transport model. We suggest to analyse the invariant mass spectrum of the NNπ system in order to search for an abundance of events with the invariant mass of the d′ dibaryon. The d′ peak is found to exceed the statistical fluctuations of the background at a 6σ level for 2 × 10⁵ · A central collisions of heavy ions with the atomic number A.     

4,4′-二氨基-2,2′-联吡啶的合成及光谱性质

设计出一种简便、有效、安全的4,4′-二氨基-2,2′-联吡啶的超声波合成方法,利用红外光谱、核磁共振氢谱和熔点的测试对产物进行了表征,并测试了产物的紫外-可见吸收光谱和荧光光谱。最终产物的收率有了较大提高。     

EPR investigations of Cu(II) complexes with 5′-CMP and 5′-GMP

Electron paramagnetic resonance investigation of the Cu(II) complexes with guanosine-5′-monophosphate (5′-GMP) and cytidine-5′-monophosphate (5′-CMP) shows the affinity of the Cu(II) ion to interact with the base and the phosphate group. The different modes of the coordination of the metal ion at the nucleotide and the water molecules lead to octahedral species, distorted by dynamical Jahn-Teller effect (g₀ = 2.106) for the Cu(II)-5′-CMP complex and rhombically distorted (g₁ = 2.358, g₂ = 2.126, g₃ = 2.068) or tetragonally distorted (g_∥^′ = 2.299, g_⊥^′ = 2.126) for the Cu(II)-5′ -GMP complex. The compound with 5′-CMP presents also a more stable in time square-planar species (g_∥ = 2.265, A_∥ = 162 G, g_⊥ = 2.076). The local symmetry changes in aqueous solution by coordination of water molecules.     

Calculated conversion rate of E′4 centers into E′2 centers in alpha quartz

Recent cluster calculations by Rudha et al. [1] are used to obtain a pseudo-Jahn-Teller adiabatic energy profile for the interconversion between E′₄ centers and E′₂ centers based on the structural models proposed therein. Reasonable values are obtained for the underlying parameters which lends some further support to the models. A reaction rate method is next used to compute the temperature dependence of the conversion rate in either direction, as well as of the rate for reorientational flopping of Fowler's E′₁ center. Thermally-activated tunneling is found to be the main factor controlling the conversions in most of the temperature range of any practical interest.     

Low voltage red phosphorescent organic light-emitting devices with triphenylphosphine oxide and 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl electron transport layers

We have developed red phosphorescent organic light-emitting devices operating at low voltages by using triphenylphosphine oxide (Ph₃PO) and 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl (DPVBi) electron transport layers. 4,4′-bis(N-carbazolyl)-1,1′-biphenyl (CBP) and tris-(1-phenylisoquinolinolato-C²,N) iridium(III) [Ir(piq)₃] were used as host and guest materials, respectively. Small voltage drops across the electron transport layers and direct injection of holes from 4,4′,4″-tris[N-(2-naphthyl)-N-phenyl-amino]-triphenylamine (2-TNATA) hole transport layer into the Ir(piq)₃ guests are responsible for the high current density at low voltage, resulting in a high luminance of 1000 cd/m² at low voltages of 2.8–3.0 V in devices with a structure of ITO/2-TNATA/CBP:Ir(piq)₃/DPVBi/Ph₃PO/LiF/Al.     

′92 SPIE 37届年会简介

国际光学工程学会(SPIE)第37届年会于1992年7月19日至24日在美国西海岸城市圣迭戈(San biego)会议中心召开。我有幸参加了这次规模浩大的光学及光电子学领域的盛会,现将大会情况作简单介绍。 ′92 SPIE年会上交流内容非常广泛。大会设有“先进探测器及探测系统”、“X射线光学”、“偏振与天文学”、“海洋光学”、“光学器件设计与定标”、“仪器设计”、“干涉测量法及光子学仪器制造”、“光学材料”、“侦察系统”、“数学图象处理”以及“信息处理”等11个主会场,下设49个分会场分别进行交流。其中“信息处理”有8个分会场,参会文章最多。     

Simulation of BEPCⅡ′s BPM

Considering the effect of photoelectron, BEPCⅡ′s beam position monitor (BPM) uses antechamber structure. The cut-off frequency of TE mode is maybe lower than the BPM signal processing frequency 500MHz. The power of TE mode will result in beam position measurement error. With monitoring the antechamber's TE mode power amplitude and calculating the transmission of TE mode power to BPM's electrodes, we can calculate the error of position measurement caused by TE mode. We found that the error is beyond the acceptance when the cut-off frequency of TE₁₀ mode is lower than 500MHz. By changing the slot length, the cut-off frequency is higher than 500MHz and the error could be accepted. At last the effect of the wakefield to the beam has been simulated and the longitudinal impedance of wakefield has been calculated.     

Inclusive (e,e′ N), (e,e′ NN), (e,e′ π), …v reactions in nuclei

We study the inclusive (e, e′ N), (e, e′ NN), (e, e′ π), (e, e′ πN) reactions in nuclei using a Monte Carlo simulation method to treat the multichannel problem of the final state. The input consists of reaction probabilities for the different steps evaluated using microscopical many body methods. We obtain a good agreement with experiment in some channels where there is data and make predictions for other channels which are presently under investigation in several electron laboratories. The comparison of the theoretical results with experiment for several kinematical conditions and diverse channels can serve to learn about different physical processes occurring in the reaction. The potential of this theoretical tool to make prospections for possible experiments, aiming at pinning down certain reaction probabilities, is also emphasized.     

η and η′ Physics at MAMI

Decays of the η and the η′ represent a significant portion of the scientific program with the Crystal Ball at MAMI. This review summarizes the current status of the program and discusses some recent results, such as the slope parameter of the η → 3π⁰ Dalitz plot, the matrix element of η → π⁰γγ and the invariant mass of e ⁺ e ⁻γ from the η → e ⁺ e ⁻γ Dalitz decay. Possible future measurements are discussed.     

String creation and heterotic-type I′ duality

The BPS spectrum of type I′ string theory in a generic background is derived using the duality with the nine-dimensional heterotic string theory with Wilson lines. It is shown that the corresponding mass formula has a natural interpretation in terms of type I′, and it is demonstrated that the relevant states in type I′ preserve supersymmetry. By considering certain BPS states for different Wilson lines an independent confirmation of the string creation phenomenon in the DOD8 system is found. We also comment on the non-perturbative realization of gauge enhancement in type I′, and on the predictions for the quantum mechanics of type I′ DO-branes.