Oscillatory Marangoni convection around the air bubble in a vertical surfactant stratificationConvection de Marangoni oscillante autour d'une bulle d'air dans une stratification verticale surfactante

The solutocapillary Marangoni convection around a gas bubble in the inhomogeneous binary mixture of miscible fluids with a vertical surfactant concentration gradient was studied experimentally. A new phenomenon, the oscillatory instability of the surfactant mass transfer, near the bubble boundary, was detected and investigated. The interpretation of this effect as an interaction between the surfactant adsorption at the bubble free surface and solutocapillary and buoyancy convective mechanisms is proposed. The experimental data on oscillation period in relation to bubble dimensions, time, liquid layer thickness, physico-chemical fluid parameters and concentration gradients are presented and discussed. To cite this article: K. Kostarev et al., C. R. Mecanique 332 (2004).     

Numerical and experimental study of the heat transfer and fluid flow by thermocapillary convection around gas bubbles

 At liquid–gas or liquid–liquid interfaces thermocapillary or Marangoni convection develops in the presence of a temperature or concentration gradient along the interface. This convection was not paid much attention up to now, because under terrestrial conditions it is superimposed by the strong buoyancy convection. In a microgravity environment, however, it is the remaining mode of natural convection. During boiling in microgravity it was observed at subcooled conditions. Therefore the question arises about its contribution to the heat transfer. Thus the thermocapillary convection was intensively studied at single gas bubbles in various liquids both experimentally and numerically. Inside a temperature gradient chamber, the overall heat transfer around single bubbles of different volume was measured with calorimetry and the liquid flow with PIV and LDV. In parallel to the experiment, a 2-dimensional mathematical model was worked out and the coupled heat transfer and fluid flow was simulated with a CV-FEM method both under earth gravity level and under microgravity. The results are described in terms of the dimensionless Nusselt-, Peclet-, Marangoni-, Bond- and Prandtl-number. Received on 23 August 1999     

Dissolved gas effects on thermocapillary convection during boiling in reduced gravity environments

The mechanisms by which thermocapillary convection arises during boiling of nominally pure fluids in low-g environments are currently not known. It has recently been suggested that small amounts of dissolved gas within the bulk liquid can accumulate within the vapor bubble, forming localized concentration gradients that results in a temperature gradient to form along the liquid–vapor interface that drives thermocapillary convection. This hypothesis was tested by boiling > 99.3% pure n-perfluorohexane with and without noncondensible gas in a low-g environment using a 7.0 × 7.0 mm² microheater array to measure time and space resolved heat transfer at various wall superheats. The thermocapillary convection around the primary bubble that formed in the gassy fluid was found to be much weaker than in the degassed fluid, and the primary bubble diameter was much larger in the gassy fluid due to the accumulation of noncondensible gas within the bubble. The results suggest that the accumulation of noncondensible gas in the bubble can result in temperature variations along the interface but due to the increased vapor/gas bubble size, the driving thermocapillary temperature gradient along the interface is significantly reduced and result in much weaker thermocapillary flow. The highest CHF values in a reduced gravity environment (19 W/cm²) occurred when the fluid was highly subcooled and degassed.     

Convective mass transfer across fluid interfaces in straight angular pores

Steady convective mass transfer to or from fluid interfaces in pores of angular cross-section is theoretically investigated. This situation is relevant to a variety of mass transport process in porous media, including the fate of residual non-aqueous phase liquid ganglia and gas bubbles. The model incorporates the essential physics of capillarity and solute mass transfer by convection and diffusion in corner fluid filaments. The geometry of the corner filaments, characterized by the fluid–fluid contact angle, the corner half-angle and the interface meniscus curvature, is accounted for. Boundary conditions of zero surface shear (‘perfect-slip’) and infinite surface shear (‘no-slip’) at the fluid–fluid interface are considered. The governing equations for laminar flow within the corner filament and convective diffusion to or from the fluid–fluid interface are solved using finite-element methods. Flow computations are verified by comparing the dimensionless resistance factor and hydraulic conductance of corner filaments against recent numerical solutions by Patzek and Kristensen (J. Colloid Interface Sci 236, 305–317 2001). Novel results are obtained for the average effluent concentration as a function of flow geometry and pore-scale Peclet number. These results are correlated to a characteristic corner length and local pore-scale Peclet number using empirical equations appropriate for implementation in pore network models. Finally, a previously published “2D-slit” approximation to the problem at hand is checked and found to be in considerable error.     

Experimental study of Marangoni bubble migration in normal gravity

Marangoni convection, whether thermal or solutal, is known to have a profound impact on many technological processes involving gas inclusions in a liquid phase. Evidently, similar phenomena may arise both in thermocapillary and solutocapillary situations, due to similarity of the motion driving mechanisms. However, the fact that the characteristic times of heat and surfactant diffusion generally differ by several orders of magnitude lends singularity to the behavior of Marangoni convection in inhomogeneous mixtures. Moreover, in the solutocapillary case one can meet the action of some additional effects associated with dissolution of the surfactant in a liquid, its adsorption at the interface and evaporation into a gas phase. This paper presents a comparative analysis of the results of ground experiments studying the behavior of air bubbles in a liquid under the action of thermocapillary and solutocapillary forces. The use of original experimental techniques makes it possible to eliminate the influence of gravity effects. A new Marangoni phenomenon—solutocapillary bubble migration—was detected and investigated. The results of studying thermal and concentration convective flows and bubble motion, in relation to bubble size, time, liquid layer thickness and fluids properties, are presented and discussed.     

Convective self-oscillations near an air-bubble surface in a horizontal rectangular channel

The concentration convection in an isothermal fluid near an air bubble clamped between the vertical walls of a horizontal channel with a rectangular cross-section is studied experimentally and numerically. The channel is filled with an aqueous solution of a surfactant with a nonuniform concentration. As a result of the competition between the gravitational convection in the cavity volume and the Marangoni convection near the bubble surface, an oscillation flow regime is established. This regime is observed experimentally over several hours. In the numerical experiment, the oscillations are obtained in the presence of an initial horizontal surfactant concentration gradient. Against the background of gravitational convection, short bursts of Marangoni convection with ten times greater intensity are observed. The convective flow patterns and the oscillation periods obtained experimentally and numerically are in fairly good agreement.     

Effect of the adsorption-desorption process intensity on solutal convection near a drop in a horizontal channel

The interaction between gravity convection and Marangoni convection in a horizontal rectangular channel filled with a liquid containing a surfactant and a drop of another liquid is numerically investigated. For large Schmidt numbers the occurring oscillatory regime of solutal convection is analyzed. In the model with a surface phase the effect of the adsorption and desorption processes on the convective flow structure is determined. The corresponding initial and boundary value problem is solved using a difference method.     

Viscosity of a Newtonian fluid calculated from the deformation of droplets covered with a surfactant under a linear shear flow

The viscosity of small fluid droplets covered with a surfactant is determined using drop deformation techniques. This method, proposed by Hu and Lips, is here extended to the case of the presence of a surface-active adsorpted at the liquid–liquid interface, to consider more general scenarios. In these experiments, a droplet is sheared by another immiscible fluid of known viscosity, both Newtonian liquids. From the steady-state deformation and retraction mechanisms, the droplet viscosity is calculated using an equation derived from the theories of Taylor and Rallison. Although these theories were expressed for surfactant-free interfaces, they can be applied when a surfactant is present in the system if the sheared droplet reaches reliable steady-state deformations and the surfactant attains its equilibrium adsorption concentration. These determinations are compared to bulk viscosities measured in a rheometer for systems with different viscosity ratios and surfactant concentrations. Very good agreement between both determinations is found for drops more viscous than the continuous phase.     

An investigation on near wall transport characteristics in an adiabatic upward gas–liquid two-phase slug flow

The near-wall transport characteristics, inclusive of mass transfer coefficient and wall shear stress, which have a great effect on gas–liquid two-phase flow induced internal corrosion of low alloy pipelines in vertical upward oil and gas mixing transport, have been both mechanistically and experimentally investigated in this paper. Based on the analyses on the hydrodynamic characteristics of an upward slug unit, the mass transfer in the near wall can be divided into four zones, Taylor bubble nose zone, falling liquid film zone, Taylor bubble wake zone and the remaining liquid slug zone; the wall shear stress can be divided into two zones, the positive wall shear stress zone associated with the falling liquid film and the negative wall shear stress zone associated with the liquid slug. Based on the conventional mass transfer and wall shear stress characteristics formulas of single phase liquid full-pipe turbulent flow, corrected normalized mass transfer coefficient formula and wall shear stress formula are proposed. The calculated results are in good agreement with the experimental data. The shear stress and the mass transfer coefficient in the near wall zone are increased with the increase of superficial gas velocity and decreased with the increase of superficial liquid velocity. The mass transfer coefficients in the falling liquid film zone and the wake zone of leading Taylor bubble are lager than those in the Taylor bubble nose zone and the remaining liquid slug zone, and the wall shear stress associated falling liquid film is larger than that associated the liquid slug. The mass transfer coefficient is within 10⁻³ m/s, and the wall shear stress below 10³ Pa. It can be concluded that the alternate wall shear stress due to upward gas–liquid slug flow is considered to be the major cause of the corrosion production film fatigue cracking.     

Effects of Chemical Reaction and Double Dispersion on Non-Darcy Free Convection Heat and Mass Transfer

In this article, the effects of chemical reaction and double dispersion on non-Darcy free convection heat and mass transfer from semi-infinite, impermeable vertical wall in a fluid saturated porous medium are investigated. The Forchheimer extension (non-Darcy term) is considered in the flow equations, while the chemical reaction power–law term is considered in the concentration equation. The first order chemical reaction (n = 1) was used as an example of calculations. The Darcy and non-Darcy flow, temperature and concentration fields in this study are observed to be governed by complex interactions among dispersion and natural convection mechanisms. The governing set of partial differential equations were non-dimensionalized and reduced to a set of ordinary differential equations for which Runge–Kutta-based numerical technique were implemented. Numerical results for the detail of the velocity, temperature, and concentration profiles as well as heat transfer rates (Nusselt number) and mass transfer rates (Sherwood number) are presented in graphs.     

A Non-isothermal Pore Network Drying Model with Gravity Effect

The concept of immiscible displacement as an invasion percolation (IP) process driven by heat and mass transfer is used in a pore network model for convective drying of capillary porous media. The coupling between heat and mass transfer occurs at the liquid–gas interface through temperature-dependent equilibrium vapor pressure and surface tension as well as the phase change enthalpy (in evaporation and condensation). The interfacial effects due to capillary forces and gravity are combined in an invasion potential; viscous forces are neglected. Simulation results show stabilized invasion patterns and finite drying front width by the influence of gravity.     

Effect of absorbate concentration level on dissolving translating bubble collapse governed by simultaneous heat and mass transfer

 We studied gas absorption from a rising spherical bubble when the concentration level of the absorbate in the absorbent is finite (finite dilution of absorbate approximation). It is showed that in the case of finite dilution the lateral convective term in the equation of mass transfer of the absorbate must be taken into account. It is found that the rate mass transfer and the rate of bubble collapse increases with the increase of the absorbate concentration level. Isothermal and nonisothermal absorptions are considered whereby the latter is described by coupled equations of mass and heat transfer. It is showed that the rate of mass transfer and the rate of bubble collapse decreases when the heat of absorption increases. Received on 28 May 1999     

Nonlinear regimes of convection of an elasticoviscous fluid in a closed cavity heated from below

The two-dimensional thermal convection of a elasticoviscous fluid in a horizontal cylinder with a square cross-section heated from below is investigated. For describing the rheological properties of the fluid the Oldroyd model with the upper convective derivative is used. The investigation is carried out numerically using the finite-difference method. The instability limits of mechanical equilibrium with respect to monotonic and oscillatory perturbations are determined. Supercritical convection regimes are investigated numerically. Perm. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 4, pp. 5–11, July–August, 2000. This work was carried out with financial support from the Program of State Financial Support for Leading Science Schools (grant No. 96-15-96084).     

The Effect of Double Dispersion on Natural Convection Heat and Mass Transfer in a Non-Newtonian Fluid Saturated Non-Darcy Porous Medium

The effect of power law index parameter of the non-Newtonian fluid on free convection heat and mass transfer from a vertical wall is analyzed by considering double dispersion in a non-Darcy porous medium with constant wall temperature and concentration conditions. The Ostwald–de Waele power law model is used to characterize the non-Newtonian fluid behavior. In this case a similarity solution is possible. The variation of heat and mass transfer coefficients with the governing parameters such as power law index, thermal and solutal dispersion parameters, inertia parameter, buoyancy ratio, and the Lewis number is discussed for a wide range of values of these parameters.     

Mass transfer from a pulsating drop

The primary difficulty in solving the problem of mass transport through an isolated drop (or bubble) moving in a fluid medium at high Reynolds numbers lies in the extreme complexity of the hydrodynamic pattern of the phenomenon. For sufficiently high velocities a separation of the external flow will occur in the rear portion of the drops and bubbles, which leads to the appearance of a turbulent wake and a sharp increase of the hydrodynamic resistance. Beginning with those dimensions for which the resistance force acting per unit surface of the drop or bubble from the external medium becomes greater than the capillary pressure, the surface of the drops and bubbles begins to deform and pulsate. The local variations of the surface tension, resulting either from the process of convective diffusion or from adsorption of surface-active substances, have a large effect on the hydrodynamics of drops and bubbles (particularly on the deformation of their surface) [1, 2], The presence of vortical, and possibly even turbulent, motion within the drops and bubbles may, under certain conditions [1], lead to their fractionation.Naturally, at the present time such complex hydrodynamics cannot be described by exact quantitative relations. Several authors have attempted to solve this problem approximately within the framework of certain assumptions. In particular [3–6], a theory was developed for the boundary layer on the surface of spherical and ellipsoidal gaseous bubbles moving in a liquid, studies were made [7, 8] of the hydrodynamics of drops located in a gas flow and the conditions were found for which fractionation of such drops takes place. Of considerable practical interest is the development of the theory of mass transfer in pulsating drops and bubbles and finding in explicit form the dependence of the mass transfer coefficients on the hydrodynamic characteristics of these systems. Until this relationship is established, every theory which ignores the effect of hydrodynamics on the mass transfer rate from an individual drop or bubble cannot be considered in any way well-founded. This relates particularly to the theories [9, 10] which consider mass transfer in systems with concentrated streams of drops and bubbles. The present paper is devoted to the study of mass transport through the surface of an isolated drop in an irrotational gas or liquid stream for large Peclet numbers P.In conclusion the authors wish to thank V. G. Levich for his helpful discussions.     

Free convection heat and mass transfer with Hall current, Joule heating and thermal diffusion

A boundary layer analysis has been presented to study the combined effects of viscous dissipation, Joule heating, transpiration, heat source, thermal diffusion and Hall current on the hydromagnetic free convection and mass transfer flow of an electrically conducting, viscous, homogeneous, incompressible fluid past an infinite vertical porous plate. The governing partial differential equations of the hydromagnetic free convective boundary layer flow are reduced to non-linear ordinary differential equations and solutions for primary velocity, secondary velocity, temperature and concentration field are obtained for large suction. The expressions for the skin-friction, the heat transfer and the mass transfer are also derived. The results of the study are discussed through graphs and tables for different numerical values of the parameters entered into the equations governing the flow.     

Visualization of gas–liquid mass transfer and wake structure of rising bubbles using pH-sensitive PLIF

A planar laser-induced fluorescence (PLIF) technique for visualizing gas–liquid mass transfer and wake structure of rising gas bubbles is described. The method uses an aqueous solution of the pH-sensitive dye Naphthofluorescein and CO₂ as a tracer gas. It features a high spatial resolution and frame rates of up to 500 Hz, providing the ability to capture cinematographic image sequences. By steering the laser beam with a set of two programmable scanning mirrors, sequences of three-dimensional LIF images can be recorded. The technique is applied to freely rising bubbles with diameters between 0.5 and 5 mm, which perform rectilinear, oscillatory or irregular motions. The resulting PLIF image sequences reveal the evolution of characteristic patterns in the near and far wake of the bubbles and prove the potential of the technique to provide new and detailed insights into the spatio-temporal dynamics of mass transfer of rising gas bubbles. The image sequences further allow the estimation of bubble size and rise velocity. The analysis of bubble rise velocities in the Naphthofluorescein solution indicates that surfactant-contaminated conditions are encountered.     

Stability of triple diffusive convection in a viscoelastic fluid-saturated porous layer

The triple diffusive convection in an Oldroyd-B fluid-saturated porous layer is investigated by performing linear and weakly nonlinear stability analyses. The condition for the onset of stationary and oscillatory is derived analytically. Contrary to the observed phenomenon in Newtonian fluids, the presence of viscoelasticity of the fluid is to degenerate the quasiperiodic bifurcation from the steady quiescent state. Under certain conditions, it is found that disconnected closed convex oscillatory neutral curves occur, indicating the requirement of three critical values of the thermal Darcy-Rayleigh number to identify the linear instability criteria instead of the usual single value, which is a novel result enunciated from the present study for an Oldroyd-B fluid saturating a porous medium. The similarities and differences of linear instability characteristics of Oldroyd-B, Maxwell, and Newtonian fluids are also highlighted. The stability of oscillatory finite amplitude convection is discussed by deriving a cubic Landau equation, and the convective heat and mass transfer are analyzed for different values of physical parameters.     

Linear and nonlinear stability analysis of binary Maxwell fluid convection in a porous medium

The stability analysis of the quiescent state in a Maxwell fluid-saturated densely packed porous medium subject to vertical concentration and temperature gradients is presented. A single phase model with local thermal equilibrium between the porous matrix and the Maxwell fluid is assumed. The critical Darcy–Rayleigh numbers and the corresponding wave numbers for the onset of stationary and oscillatory convection are determined. A Lorenz like system is obtained for weakly nonlinear stability analysis.     

The Onset and Nonlinear Regimes of Convection in a Two-Layer System of Fluid and Porous Medium Saturated by the Fluid

The onset of convection and its nonlinear regimes in a heated from below two-layer system consisting of a horizontal pure fluid layer and porous medium saturated by the same fluid is studied under the conditions of static gravitational field. The problem is solved numerically by the finite-difference method. The competition between the long-wave and short-wave convective modes at various ratios of the porous layer to the fluid layer thicknesses is analyzed. The data on the nature of convective motion excitation and flow structure transformation are obtained for the range of the Rayleigh numbers up to quintuple supercriticality. It has been found that in the case of a thick porous layer the steady-state convective regime occurring after the establishment of the mechanical equilibrium becomes unstable and gives way to the oscillatory regime at some value of the Rayleigh number. As the Rayleigh number grows further the oscillatory regime of convection is again replaced by the steady-state convective regime.