CHD/sub 2/OH optically pumped by a waveguide CO/sub 2/ laser: new far-infrared laser lines from the CD/sub 2/ wagging vibrational mode

For the first time, a wide tunability waveguide CO/sub 2/ laser was used to pump the CHD/sub 2/OH molecule for the generation of new FIR laser lines with a large offset. Optoacoustic signals associated with the infrared absorbing transitions of the CD/sub 2/ wagging vibrational mode served as a guide for finding new laser lines. All lines were characterized in wavelength, relative polarization, intensity, optimum pressure of operation, and precise offset measurements.     

Measurement of far-infrared laser frequencies from optically pumped CHD/sub 2/OH

A three-laser heterodyne system was used to frequency measure 11 previously observed optically pumped far-infrared (FIR) laser emissions of CHD/sub 2/OH. These newly measured frequencies have fractional uncertainties of /spl plusmn/2/spl times/10/sup -7/ and correspond to laser wavelengths ranging from 47.8 to 238.0 /spl mu/m. The pump laser offset frequency was measured for 15 CHD/sub 2/OH FIR laser emissions.     

Optical pumping of CHD/sub 2/OH and CH/sub 2/DOH methanol isotopomers by means of a new pulsed CO/sub 2/ laser: characterization of new far-infrared laser emissions

We have reinvestigated CHD/sub 2/OH and CH/sub 2/DOH methanol isotopomers as sources of far-infrared laser radiation using the optical pumping technique. A new waveguide pulsed CO/sub 2/ laser was used, that delivers high peak powers also in the 10-HP CO/sub 2/ band and has allowed us to observe 19 new far-infrared emissions from CHD/sub 2/OH and 8 new far-infrared emissions from CH/sub 2/DOH. Each of them is characterized in wavelength, pump offset from the center of the exciting CO/sub 2/ line, relative polarization, optimum operating pressure and intensity.     

New FIR Laser Lines from CHD2OH Methanol

We have investigated CHD₂OH methanol as source of far-infrared (FIR) laser radiation using the optical pumping technique. Our new waveguide pulsed CO₂ laser, with peak powers as high as some kW, has allowed us to observe 12 new lines. Each of them is characterized in wavelength, relative polarization, intensity, optimum operating pressure and pump offset from the center of the exciting CO₂ line.     

Measurements and assignments of new large offset CD3OH FIR laser lines

By using an acoustooptic modulator we extend the 300 MHz tunability of a waveguide CO₂ laser to 480 MHz. The CD₃OH was optically pumped by the 10R(32), 10R(34), and 10R(36) CO₂ laser lines, and 17 new FIR laser lines were discovered. The Stark effect on previously known FIR laser lines was investigated, and some tentative FIR laser lines assignments are suggested.     

Observation and characterization of new FIR laser lines from formicacid

We report the observation and characterization of seven new far-infrared (FIR) laser lines from H¹²COOH and H¹³COOH in the range 232.2 to 746.6 μm optically pumped by a wide-tunability waveguide CO₂ laser. Their absorption frequency is outside of the tuning range of a conventional CO₂ pump laser     

New optically pumped FIR laser lines in CD3OH

In this work we report laser action in 69 new FIR laser lines in CD₃OH optically pumped by a regular cw CO₂ laser. We have performed measurements of laser wavelength, optimum pressure of the gas, relative polarization and intensity on all lines, including some previously known.     

Frequencies of cw FIR laser lines from optically pumped CH2F2

The frequencies of 48 optically pumped cw FIR CH₂F₂ laser lines have been measured relative to stabilized CO₂ lasers. Uncertainties are estimated to be about 5 parts in 10⁷.     

Observation of new FIR superradiant lines from optically pumped D2O

Four new laser lines from optically pumped D2O vapor are reported at wavelengths of 235 μm, 280 μm, 97 μm, and 98 μm, the latter having a quantum conversion efficiency of 38 percent.     

New FIR laser lines and frequency measurements for optically pumped CD3OH

Twenty new cw FIR laser lines in CD₃OH, optically pumped by a CO₂ laser, are reported. The frequencies of 39 of the stronger laser lines were measured relative to stabilized CO₂ lasers with a fractional uncertainty, as determined by the reproducibility of the FIR frequency itself, of 2 parts in 10⁷.     

Wavelengths for new CH3OH laser lines

Using a grating-tuned CO₂-TEA laser to pump CH₃OH in a metallic-wave-guide resonator, submillimeter laser emissions have been produced by pumping with 36 lines in the 9.4μm CO₂ band and with 23 lines in the 10.6μm band. Several dozen new SMM laser lines were observed. Wavelengths accurate to within ～0.1% are given for 12 previously unmeasured lines between 34μm and 225μm.     

The optically pumped hydrazine FIR laser: Assignments and new laser lines

Strong far-infrared (FIR) lasing action has been observed in hydrazine optically pumped with isotopic CO2lasers and the N2O laser. The wavelengths of 13 new laser lines have been determined. The results of a recent infrared-microwave double resonance study of hydrazine have been used to assign the transitions involved in the production of five of these new lines and nine of the previously observed laser lines.     

13CD3OH and12CD3OH optically pumped by a13CO2 laser: Observations and assignments of FIR laser lines

In this work we report the first observation of FIR laser lines from¹³CD₃OH pumped by the¹³CO₂ isotope laser. Using the same pump we have also found 3 new lines from¹²CD₃OH. Tentative assignments for the absorption and emission transitions of the observed lines are also proposed.     

New far-infrared laser lines from CH/sub 3/OD methanol deuterated isotope

We report on a study of the CH/sub 3/OD molecule in a search for new far-infrared (FIR) laser lines. For optical pumping of large offset vibrational absorption transitions, a continuous-wave waveguide CO/sub 2/ laser with 300 MHz tunability around each line was used for the first time. As a consequence, 17 new far-infrared laser emissions were observed. For these lines, we also present data on wavelength, intensity, offset, relative polarization, and optimum operation pressure.     

FIR laser lines of CH3OH pumped by CO2laser sequence lines

We report on the utilization of a sequence band CO2laser as the pumping source for new FIR laser lines of CH3OH.     

Operating characteristics of CW CO/sub 2/-N/sub 2/O laser

The authors have obtained the emission characteristics of a CW CO/sub 2/-N/sub 2/O laser. The CO/sub 2/ laser lines and N/sub 2/O laser lines vary according to the applied condition. Thus the operating conditions are interpreted.<>     

13CD3OD optically pumped by a waveguide CO2 laser: new FIR laser lines

A waveguide CO₂ laser of wide tunability was used to pump infrared transitions of the ¹³CD₃OD C-O stretching vibrational mode. The optoacoustic signal associated with the absorbing transitions served as a guide to search for new laser lines. We could observe 36 new far-infrared laser lines ranging from 57 to 1192 μm. All lines were characterized in wavelength, relative polarization, intensity, optimum pressure of operation, and precise offset measurements     

Characterization of new FIR laser lines from CD3-rockingand asymmetric CD3 deformation modes of 13CD3OD

In this paper, we report new optically pumped far-infrared (FIR) laser lines from the in-plane CD₃-rocking and asymmetric CD ₃ deformation absorption vibrational bands of ¹³CD ₃OD. A waveguide CO₂ laser of wide tunability (290 MHz) was used as the pump source, and a Fabry-Perot open cavity as the FIR laser resonator. Optoacoustic absorption spectrum was used as a guide to search for new FIR laser lines. We could observe 13 new laser lines in the range 103-491 μm. The lines were characterized according to wavelength, relative polarization, relative intensity, and optimum working pressure. The transferred lamb-dip technique was used to measure the frequency absorption transition for both new and previously reported laser lines     

New CH2F2 FIR laser lines pumped by a tunable WG CO2 laser

8 new large offset FIR laser lines of CH₂F₂ have been discovered by pumping with a high tunability waveguide CW CO₂ laser. Optoacoustic measurements of CH₂F₂ have also been performed and the pump offsets of the new and of previously known lines have been measured and checked. Some assignments are proposed and a few assignments found in literature are checked     

CO/sub 2/ laser processing of alumina (Al/sub 2/O/sub 3/) printed circuit board substrates

We report the results of an investigation of the laser-material interaction processes involved in laser drilling of alumina, through the use of an enhanced peak power (2.5 kW) CO/sub 2/ laser and novel temporal pulse formats. Peak power was varied from 30 W to 2 kW for pulses of constant energy to observe the effect produced on scribe depth. High-speed videography of hole formation has been combined with microscopic analysis to investigate the key processes involved in laser processing of alumina. Plasma screening was observed for short, high peak power laser pulses, and optimal scribing was achieved in the weakly plasma absorbing regime. A new processing technique for scribing alumina has been developed, which exploits the fast response of the laser to produce novel temporal pulse shapes, which can be modified to generate cleaner holes. Scribe speeds of up to 280 mm/spl middot/s/sup -1/ were obtained for scribe holes >200 /spl mu/m deep and 150 /spl mu/m apart, with no material plugging the hole, in 0.635-mm-thick 96% alumina.