Construction of kernels of the nonlinear collision integral in the Boltzmann equation using laplace transformation

It is shown that the relation between kernels L _l (v, v ₁) of the linear collision integral and kernels G _l,0 ^l (v, v ₁, v ₂) of the nonlinear collision integral can be reduced to the Laplace transformation. Analytic expressions for nonlinear kernels G _0,0 ⁺⁰ (v, v ₁, v ₂) and G _1,0 ⁺¹ (v, v ₁, v ₂) are determined for hard spheres and pseudo-Maxwellian molecules.     

Nonfactorization and the decaysD s +→φπ +,φρ + andφl + ν l

Using the experimentally measured values ofx=A ₂(0)/A ₁(0) andy=V(0)/A ₁(0) and the measured ratiosR _st=Γ(D _s ⁺ →φl ⁺ ν _l)/Γ(D _ins ⁺ →φπ ⁺) andR _h=Γ(D _s ⁺ →φρ ⁺)/Γ(D _s ⁺ →φπ ⁺), we present evidence for significant nonfactorization contribution in the decay amplitude forD _s ⁺ →φπ ⁺. We analyze the role of nonfactorization inD _s ⁺ →φρ ⁺ and conclude that present data onR _h are consistent with factorization inD _s ⁺ →φρ ⁺. A measurement of polarization inD _s ⁺ →φρ ⁺ would greatly assist our analysis.     

On the energy dependence of the yield of doubly charged negative ions during the capture of free electrons by C60(CF3)12 trifluoromethylfullerene molecules

Peaks of C₆₀(CF₃) _n ^2? doubly charged negative ions (n = 6–12) have been observed in the mass spectra of the resonance electron capture by trifluoromethylfullerene C₆₀(CF₃)₁₂ molecules. It has been established that these ions are formed owing to the attachment of two free isoenergetic electrons. The autodetachment of an extra electron has been detected for the doubly charged molecular ions (n = 12). It has been established from the observation of the delayed fragmentation of the most abundant ions with n = 8 and 10 that the doubly charged negative ions, like their singly charged analogs, are metastable with respect to the separation of the CF₃ fragment(s). The yield of doubly charged negative ions has been obtained as a function of the electron energy. By comparing them with the analogous dependences for the singly charged ions, the specific features have been revealed which were associated with the presence of the repulsive Coulomb barrier and the regular effect of the doubled energy of two additional electrons on the energy dependence of the dissociative decay of the doubly charged negative ions. The absolute cross section for the formation of the C₆₀(CF₃) ₁₀ ^2? ions has been measured. At the energy of their yield maximum near the 5 eV, it is ～1 × 10^?19 cm².     

Light-induced EPR spectra of reaction centers fromRhodobacter sphaeroides at 80 K: Evidence for reduction of QB by B branch electron transfer in native reaction centers

Photosynthetic reaction centers (RCs) fromRhodobacter sphaeroides capture solar energy by electron transfer from primary donor D to quinone acceptor Q_B through the active A branch of electron acceptors. The light-induced electron paramagnetic resonance (EPR) spectrum from native RCs that had Fe²⁺ replaced by Zn²⁺ was investigated at cryogenic temperature (80 K, 35 GHz). In addition to the light-induced signal due to the formation of D^+.Q _A ^?. observed previously, a small fraction (ca. 5%) of the signal displayed very different characteristics. The signal was absent in RCs in which the Q_B was displaced by the inhibitor stigmatellin. Its decay time (τ=6 s) was the same as observed for D^+.Q _B ^?. in mutant RCs lacking Q_A, which is significantly slower than for D^+.Q _A ^?. (τ=30 ms). Its EPR spectrum was identical to that of D^+.Q _B ^?. . The quantum efficiency for forming the major component of the signal was the same as that found for mutant RCs lacking Q_A (?=0.2%) and was temperature independent. These results are explained by direct photochemical reduction of Q_B via B branch electron transfer in a small fraction of native RCs.     

Lebensdauer- und Hyperfeinstrukturmessungen an einigen angeregten Zuständen der Konfiguration 4d 9 5p im Pd I-Spektrum mit der Level-crossing-Methode

Lifetimes and hfs coupling constants of some excited states of the 4d ⁹ 5p configuration of Pd I have been determined in a level crossing experiment by observing the field dependence of the polarization of the fluorescence radiation in a magnetic field. From the halfwidths of the measured zero field level crossing signals one obtains the mean lifetimes of the following fine structure states:τ(³P ₁ ⁰ )=(7.46±0.32)nsec;τ(³ P ₂ ⁰ )=(6.9±0.76)nsecτ(³P ₁ ⁰ )=(4.99±0.35)nsec;τ(³ D ₁ ⁰ )=(4.89±0.40)nsecτ((³D ₃ ⁰ )=(6.99±0.49)nsec;τ(³ F ₄ ⁰ )=(7.09±0.46)nsec.Δm=2 crossing signals were detected in the³ P ₁ ⁰ ,³D ₃ ⁰ and³F ₄ ⁰ -states of the odd isotope¹⁰⁵Pd. A detailed analysis of the experimental curves yields the hfs coupling constantsA andB of these states:A(³P ₁ ⁰ )=?(133±2) Mc/sec;B(³ P ₁ ⁰ )=(140±30) Mc/secA(³D ₃ ⁰ )=?(120±10) Mc/sec;B(³ D ₃ ⁰ )=?(660±100) Mc/secA(³F ₄ ⁰ )=?(87±2) Mc/sec;B(³ F ₄ ⁰ )=?(330±30) Mc/sec. A theoretical calculation of the hfs constants is given on the basis of reduced matrix elements. Within the limit of the errors these values agree with the experimental ones. The nuclear electric quadrupole moment deduced from the measuredB values isQ (¹⁰⁵Pd)=(0.8±0.3)·10^?24 cm² (without corrections).     

Electron-vibrational energy exchange in collisions of electronically excited N2(A 3Σ u + ) molecules with Zn(X 1 S) atoms

The interaction matrix between the N₂ molecule in the X ¹Σ _g ⁺ and A ³Σ _u ⁺ states and the Zn atom in the ¹ S and ³ P states calculated earlier by the asymptotic method was used to find the rate constants for the electron-vibrational energy exchange N₂(A ³Σ _u ⁺ , v) + Zn(¹ S) → N₂(X ¹Σ ₈ ⁺ , v′) + Zn(³ P). The calculations were performed by the transition state method, and the probabilities of transitions between intersecting electron-vibrational terms of the system in motion along the reaction coordinate were determined by the Landau-Zener equation. The calculated electron excitation transfer constants between N₂(A ³Σ _u ⁺ , v = 1, 0) and Zn(¹ S) over the temperature range 300–900 K were on the order of 10^?11?10^?12 cm³/s.     

Ionization and dissociative ionization of methane molecules

A technique for mass-spectrometric investigation of the yield of positive ions produced by direct and electron-impact dissociative ionization of methane molecules is described, and respective experimental data are presented. Doubly charged C ₂ ⁺ , CH ₃ ²⁺ , and CH ₄ ²⁺ ions, as well as singly charged D ₂ ⁺ , CD ₃ ⁺ , and CD ₄ ⁺ ions, are detected in the mass spectrum of a methane molecule at electron energy U _e = 90 eV for the first time. From ionization efficiency curves, the ionization energy of the parent molecule and the appearance energy of fragment ions are determined. The ionization energy of the CH₄ molecule is found to be 12.62 ± 0.20 eV. Electron-molecular reactions that may take place when a low-energy electron beam interacts with a methane molecule are analyzed. The ionization process and the formation of methane molecule fragments are studied.     

Hyperfeinstrukturaufspaltung und Lebensdauer des 72 P 3/2-Terms von Rb85 und Rb87

The hyperfine structure splitting of the 7² P _3/2 state of Rb⁸⁵ and Rb⁸⁷ has been measured with optical double resonance. The following hfs interaction constants have been obtained: Rb⁸⁵:A _7p ⁸⁵ =3.71(1) MHz;B _7p ⁸⁵ =3.68 (8)MHz. Rb⁸⁷:A _7p ⁸⁷ =12.57(1) MHz;B _7p ⁸⁷ =1.71 (3)MHz. These values yield quadrupole moments ofQ _7p,hfs ⁸⁵ =+0.316(7) barn andQ _7p,hfs ⁸⁷ =+0.147(2)barn which are reduced by application of the Sternheimer correction toQ _7p ⁸⁵ =+0.267(6) barn andQ _7p ⁸⁷ =+0.124(2) barn. The averaged ratio of the uncorrected values of Q_hfs in the 5p and 7p ² P _3/2 stake isQ _5p,hfs/Q _7p,hfs=1.07(3). This has to be compared with the correction factors for polarization of the core of electrons by the nuclear quadrupole moment (1?R)_5p/(1?R)_7p=1.07. The agreement between the measured and calculated ratio indicates a net antishielding of the nuclear quadrupole moments of rubidium by the core of electrons as has been predicted bySternheimer. The lifetime of the 7² P _3/2 state of the RbI-spectrum is:τ(7² P _3/2, Rb)=2.4(2)·10^?7 sec.     

Structural analysis of three-spin systems of photosystem II by PELDOR

The pulsed electron electron double resonance (PELDOR) pulse sequence is applied to a three-spin system consisting of three radicals (Y _D ^· , Y _Z ^· and Q _A ^? ) generated in spinach PS II. The distance between Y_Z and Q_A has been determined to be 3.4 nm with the previously derived distances of the other radical pairs, 2.9 nm for Y _D ^· -Y _Z ^· and 3.9 nm for Y _D ^· -Q _A ^? . This distance has been derived from the Y _Z ^· -Q _A ^? radical pair trapped in Y_D-less mutants ofChlamydomonas reinhardtii. Furthermore the method was applied to the Y _D ^· -Q _A ^? -Chl _Z ⁺ system to find the unknown distance between Q_A and Chl_Z. The derived distance was 3.4 nm. A triangular configuration was found in the membrane system that gives the relative positions of the electron transfer components.     

Higgs bosons and neutrinos in the left-right model

The left-right asymmetric model featuring the bidoublet and two triplets of Higgs fields is investigated. It was established that, from an analysis of the reaction l ^?γ → W ^?ν_l, it is possible to deduce not only information about the properties of the singly charged Higgs bosons $\tilde \delta ^{( - )} $ and h ^(?) but also an answer to the question of whether the neutrino is a Majorana or a Dirac particle. The processes $f_i \bar f_j \to \Delta _1^{( - - )} \tilde \delta ^{( + )} $ and e^?μ^? → Δ _1,2 ^(—) γ leading to the production of doubly charged Higgs bosons are investigated. It is shown that information about the properties of singly charged Higgs bosons can also be obtained by studying the ultrahighenergy cosmic neutrinos from the reaction e ^?ν _e →μ^?ν_μ.     

Exact results for two-dimensional coarsening

We consider the statistics of the areas enclosed by domain boundaries (‘hulls’) during the curvature-driven coarsening dynamics of a two-dimensional nonconserved scalar field from a disordered initial state. We show that the number of hulls per unit area, n _h (A, t)dA, with enclosed area in the range (A,A + dA), is described, for large time t, by the scaling form n _h (A, t) = 2c _h /(A + λ _h t)², demonstrating the validity of dynamical scaling in this system. Here $ c_h = {1 \mathord{\left/ {\vphantom {1 8}} \right. \kern-0em} 8}\pi \sqrt 3 $ is a universal constant associated with the enclosed area distribution of percolation hulls at the percolation threshold, and λ _h is a material parameter. The distribution of domain areas, n _d (A, t), is apparently very similar to that of hull areas up to very large values of A/λ _h t. Identical forms are obtained for coarsening from a critical initial state, but with c _h replaced by c _h /2. The similarity of the two distributions (of areas enclosed by hulls, and of domain areas) is accounted for by the smallness of c _h . By applying a ‘mean-field’ type of approximation we obtain the form n _d (A, t) ? 2c _d [λ _d (t+t ₀)] ^τ?2/[A+λ _d (t+t ₀)] ^τ , where t ₀ is a microscopic timescale and τ = 187/91 ? 2.055, for a disordered initial state, and a similar result for a critical initial state but with c _d → c _d /2 and τ → τ _c = 379/187 ? 2.027. We also find that c _d = c _h + O(c _h ² ) and λ _d = λ _h (1 + O(c _h )). These predictions are checked by extensive numerical simulations and found to be in good agreement with the data.     

Relativistic calculations of ground states of single-electron diatomic molecular ions

We have performed relativistic calculations of ground-state energies for a series of single-electron homonuclear dimers A ₂ ^(2Z?1)+ with nucleus charge Z = 1, 2, 10, 20, 30, 40, 50, 60, 70, 80, 90, 92, and 100 and internuclear distances R = 2/Z. The work involves the Born-Oppenheimer approximation and the single-electron two-center Dirac Hamiltonian, which describes the interaction between an electron and two immovable point charges. Analysis of the convergence process and comparison with data presented in other works for H ₂ ⁺ and Th ₂ ¹⁷⁹⁺ dimers shows that the relative error of the obtained results is on the order of 10^?11–10^?12. High-accuracy values of ground-state energies for some dimers other than Z = 1 and 90 have been obtained in this work for the first time.     

Interaction of Zn atoms in the 1 S and 3 P states with N2 molecules in the X 1Σ g + and A 3Σ u + states at moderate distances between the atom and molecule

An asymptotic method was used to derive analytical expressions for the matrix elements of interaction between the N₂ molecule in the X ¹Σ _g ⁺ and A ³Σ _u ⁺ electronic states and the Zn atom in the ¹ S and ³ P states. Quadrupole-quadrupole, dispersion, and exchange interactions were taken into consideration. The character of the set of diabatic vibronic potential energy surfaces of the system suggests that the energy transfer in the process N₂(A ³Σ _u ⁺ ) + Zn(¹ S) → N₂(X ¹Σ _g ⁺ ) + Zn(³ P) may prove to be rather effective.     

Determination of the positions of impurity centers in a dislocation core in a NaCl crystal from magnetoplasticity spectra

The spectra of the mean free paths l(ν) of edge dislocations have been studied in NaCl crystals exposed in the electron paramagnetic resonance scheme to the crossed magnetic fields: the Earth’s field (50 μT) and the pump field (2.5 μT, 5–440 kHz). The spectra have been measured for a series of angles θ = 0°–5° of rotation of the sample around its edge [100] with respect to the Earth’s field. The fine structure of the spectra contains a series of peaks whose resonance frequencies are described by the empirical expression v _i ^± = Asin(θ ± Δθ _i ) ≈ A(θ ± Δθ _i ). The parameters Δθ _i are independent of the angle θ within the experimental errors. Within the model of “frozen” magnetic moments associated with impurity center Ca⁺-Cl⁰, the angles Δθ _i characterize the deviation of the axis of the center from the 〈100〉 direction in the core of a dislocation. These angles can be expressed in terms of the spectra obtained: Δθ _i = (? _i ⁺ ? v _i ^? )/2A. The computer simulation of the edge dislocation core provides the set of the angles Δθ _i close to the measured values. The spin-lattice relaxation time of the center on dislocation has been estimated from the low-frequency edge of the spectrum l(ν) as τ _{s ? l} ～ 10^?4 s.     

The primary and secondary acceptors in bacterial photosynthesis III. Characterization of the quinone radicals Q A − ⋅ and Q B − ⋅ by EPR and ENDOR

Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) techniques were used to investigate the electronic structure of the primary (Q _A ^?? ) and secondary (Q _B ^?? ) ubiquinone electron acceptors in reaction centers (RCs) of the photosynthetic bacteriumRhodobacter sphaeroides. To reduce the EPR linewidth, the high-spin Fe²⁺ present in native RCs was replaced by diamagnetic Zn²⁺. Experiments were performed both on frozen solutions and single crystals at microwave frequencies of 9, 35 and 94 GHz. Differences in the EPR/ENDOR spectra were observed for Q _A ^?? and Q _B ^?? , which are attributed to different environments of the quinones in the RC. The differences exhibited themselves in: (i) the g-tensors, (ii) the¹⁷O and¹³C hyperfine coupling (hfc) constants of the quinones labeled at the carbonyl group, (iii) the¹H-hfcs of the quinone ring and (iv) the exchangeable protons hydrogen bonded to the carbonyl oxygens. From these results and from H/D exchange experiments, the following conclusions were drawn: both Q _A ^?? and Q _B ^?? have at least two hydrogen bonds of different strengths to the carbonyl oxygens. The hydrogen bonds for Q _A ^?? are stronger and more asymmetric than for Q _B ^?? . For Q _A ^?? the stronger bond (to O₄) was assigned to His(M219) and the weaker (to O₁) to Ala(M260). For Q _B ^?? the stronger bond (to O₄) was assigned to His(L190), with several weaker bonds (to O₁) to Ser(L223), Ile(224) and Gly(L225). From the temperature dependence of the hfcs of the exchangeable protons some dynamic properties of the RC were deduced. Hfcs with more distant nitrogens were observed by electron spin echo envelope modulation (ESEEM). For Q _A ^?? they were assigned to N_δ of His(M219) and to the peptide backbone nitrogen of Ala(M260) and for Q _B ^?? to N_δ of His(L190). These interactions indicate the extent of the electron wave function, which is important for the understanding of the electron transfer mechanism. Based on the magnetic resonance results, the function of the quinone acceptors in the reaction center is discussed.     

Virasoro type Lie algebras and deformations

The first and second cohomologies of Cartan Type Lie algebras with coefficients in irreducible tensor modules are calculated. The spaceH ¹(L, U) is interpreted as a space of deformations of (L, U)-modules.H ²(L, L)≠0 ifL=S ₂,S ₂ ⁺ orL=H _n ,H _n ⁺ . Lie algebra of divergenceless vector fieldsS ₂ ⁺ has only one nontrivial local deformation. The two-sided simple hamiltonian algebraH _n has 2n ²+n new local deformations in addition to Moyal cocycle. The Lie algebrasL=W _n (n>3),S _n?1(n>2),H _n (n>1),K _n+1(n>1) have 3, 1, 1, 3 nonisomorphic tensor modules with irreducible bases and nonzero 1-cohomologies; respectively, the corresponding numbers for 2-cohomologies are 9, 6, 7 and 9.     

g-factors of the ground state rotational band of158Dy

Theg-factors of the four lowest states of the ground state rotational band of¹⁵⁸Dy have been determined asg(2 ₁ ⁺ )=+0.362(23),g(4 ₁ ^su+ )=+0.340(20),g(6 ₁ ^su+ )=+0.207(36) andg(8 ₁ ^su+ )=+0.21(11). Theg-factors of the 2⁺ and 4⁺ states were measured by the IPAC method with radioactive samples of 2.4 h¹⁵⁸Er in external magnetic fields. To investigate the higher states, for the first time an on-line γ—γ IPAC experiment was performed with the reaction¹⁵⁶Gd(α, 2n)¹⁵⁸Dy by use of the static hyperfine field of DyGd.     

Microscopic foundation of the interacting boson model in thes d-shell nuclei

Starting from an isospin invariant shell-model hamiltonian, we describe a method for deriving microscopically the IBM-hamiltonian appropriate to lights d-shell nuclei. The key ingredients of our approach are:a) the Belyaev-Zelevinsky-Marshalek (BZM) bosonization procedure;b) two successive unitary transformations that extract the “maximally decoupled” collective bosons with angular momentaJ=0(s _ππ ⁺ ,s _νν ⁺ ,s _πν ⁺ ) andJ =2(d _ππ ⁺ ,d _νν ⁺ ,d _πν ⁺ (T=0),d _πν ⁺ (T=1)). The method is applied to obtain the low-energy spectra and the electron scattering form factors for the 0 ₁ ⁺ →2 ₁ ⁺ transitions in²⁰Ne and²⁴Mg. Good agreement with the exact shell-model results is achieved. The inclusion of proton-neutron bosons (s _πν ⁺ ,d _πν ⁺ (T=1),d _πν ⁺ (T=0)), as well as the renormalization of boson parameters due to the non-collective degrees of freedom, are shown to play a crucial role.