飞秒激光在透明介质中诱导光学微腔的实验研究

鉴于飞秒激光脉冲持续时间极短且峰值功率极高，将其紧聚焦到透明介质体内部时，易引发双光子效应、碰撞电离、雪崩击穿等一系列非线性过程，在焦点处产生微爆，从而形成微腔结构。提出采用25fs的激光脉冲在透明介质内部诱导形成微腔结构。分析了微腔的能量阈值。结合三维精密位移台，制备了三维微腔点阵。探讨了超短激光脉冲在透明介质内部形成微腔结构的方法与基本实验参数。试验发现：采用更短脉宽的飞秒脉冲时可以降低微腔形成的能量阈值；通过调整飞秒激光功率、脉冲作用次数和光束聚焦情况等因素，可以有效改变微腔的纵深比；在数值孔径较低时因无法实现紧聚焦，故不能形成微腔。     

Influence of boundary conditions on the ordering of elastic dipoles

We consider elastic dipoles in several two-dimensional geometries. Using Cauchy integral techniques and the image method, the state of elastic equilibrium under different boundary conditions can be determined. The results are used to find the ground state of systems of anisotropic dipoles via the simulated annealing method. Only in the case of fixed boundaries the ordering depends on the boundary condition.     

高重复频率激光脉冲光束大小对吸收玻璃损伤特征的影响

针对高重复频率对吸收性滤光片损伤问题,研究了高重复频率(kHz量级)激光脉冲的光束半径大小对吸收玻璃的形貌特征和损伤机理.研究发现在总的激光作用个数、单脉冲能量和脉冲作用频率固定时,吸收玻璃的损伤特性发生很大变化:在光束半径较大时,激光能量分散,主要损伤形貌是熔化破坏;随着光束半径的减小,激光脉冲能量变得集中,热量的累积效果变得明显,逐渐变成熔化破坏和气化破坏;当激光光束半径小到一定程度,则会由于光强过大使得介质表面发生击穿而产生激光等离子体冲击波,同时由于热量沉积的集中使光束作用中心处产生超热液体,当满足相爆炸发生的条件时,气化物、液滴和固体颗粒的混合物会向外飞溅,在损伤凹陷的周围形成气化物、液滴的冷凝区和固体颗粒溅射区. 关键词： 激光诱导损伤 高重复激光脉冲 吸收玻璃 相爆炸     

Driven nonequilibrium lattice systems with shifted periodic boundary conditions

We present the first study of a driven nonequilibrium lattice system in the two-phase region, withshifted periodic boundary conditions, forcing steps into the interface. When the shift corresponds to small angles with respect to the driving field, we find nonanalytic behavior in the (internal) energy of the system, supporting numerical evidence that interface roughness is suppressed by the field. For larger shifts, the competition between the driving field and the boundary induces the breakup of a single strip with tilted interfaces into many narrower strips with aligned interfaces. The size and temperature dependences of the critical angles of such breakup transitions are studied.     

Laser vaporisation of absorbing liquid under transparent cover

Vaporization of absorbing liquid (water) under a transparent solid cover upon exposure to nanosecond pulses of a holmium laser (λ = 2920 nm) is studied using acoustic and optical diagnostics. The features of the optical signal reflected from the liquid–cover interface suggest that a vapor cavity appears at a submicrometer distance from this interface and exists for about one hundred microseconds. An additional acoustic signal appearing after returning the light signal to the initial level is caused by known cavitation effects accompanying vapor cavity fracture and collapse in liquid.     

Phase transformation mechanism of In–Sb–Te through the boundary reaction between InSb and InTe

The boundary reaction between InSb and InTe bilayers shows that In₃Sb₁Te₂ (IST) is formed at the InTe side first due to the diffusion of Sb atoms from InSb to InTe rather than the diffusion of Te atoms from InTe to InSb at the crystallization temperature of IST. The diffusion of Sb atoms into InTe changes the atomic configuration of InTe, which leads to small lattice distortion and a coherent boundary region for the formation of IST crystalline thin films. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

蜂窝结构吸波材料等效电磁参数和吸波特性研究

根据强扰动理论,在长波长近似条件下推导出蜂窝结构吸波材料等效介电常数和等效磁导率的计算公式.电磁参数计算结果表明,蜂窝结构吸波材料等效介电常数和等效磁导率均小于吸收层的介电常数和磁导率,但等效介电常数的降幅更大,从而使等效介电常数更接近于等效磁导率,这正是吸波材料波阻抗匹配设计所需要的.反射率计算结果表明,不同的蜂窝高度,吸收层对应一最优厚度,使蜂窝结构吸波材料的反射率最低.这些结果对于蜂窝结构吸波材料设计具有一定的意义. 关键词： 蜂窝结构吸波材料 等效介电常数 等效磁导率 反射率     

The influence of external boundary conditions on the spherical model of a ferromagnet. I. Magnetization profiles

The spherical model of a ferromagnet is investigated for various (external) boundary conditions. It is shown that, besides the well-known critical point, a second one can be produced by the boundary conditions. Although the main asymptotic of the free energy is analytic at the new critical point, theO(N^1–2/d) asymptotic possesses a singularity here. A natural order parameter of the model has singularities at both critical points. The magnetization profile is studied for the whole range of the model's parameters and at different scales. It is shown that (in an appropriate regime) below the second critical temperature the magnetization profile freezes, that is, becomes temperature independent. Distributions of the single spin variables and some macroscopic observables (including normalized total spin) are studied for the whole temperature range including the critical points.     

透明激光陶瓷散射损耗分析

 为了定量分析激光陶瓷中散射损耗对其透过率的影响,通过建立气孔尺寸分布模型,引入第二相体积比概念,并结合Mie散射、瑞利散射和全散射积分等理论,讨论了激光陶瓷中气孔、晶界第二相和表面粗糙度等引起的散射损耗对激光陶瓷透光性能的影响。研究结果表明：气孔率的大小将明显影响陶瓷透过率,且气孔尺寸分布决定了透过率包络的变化趋势;晶界和表面散射对透过率的影响主要集中在短波长处;在气孔率较低情况下,晶界第二相的存在是导致短波长处透过率急剧降低的主要因素。     

Thermochemical instability of transparent media induced by an absorbing inclusion

The initial stage of thermochemical instability induced by an absorbing inclusion within a transparent matrix, which irradiated by a laser beam, is studied. The instability results in a low threshold (formally non-threshold) optical breakdown of the matrix. It is brought about by the additional absorption of the laser light by the products of the chemical reactions in the matrix. The instability is characterized by a certain induction time when the rate of the chemical reactions is almost steady. When the induction is over, their rate rapidly increases. Theoretical estimate of the induction time are offered. The experimental study of the induction time dependence on the laser-beam intensity confirmed the theoretical estimation.     

透明光学材料中缺陷吸收激光能量引起的热应力与断裂

 利用热弹性理论分析了在光学材料中由于缺陷吸收激光能量引起的温度和热应力分布,并且针对一个简单的裂纹模型分析了热应力产生的应力强度因子,并且给出了一些主要参数对于应力强度因子的影响的规律。     

Laser ablation of absorbing liquids under transparent cover: acoustical and optical monitoring

Phase transition induced with infrared (λ = 2920 nm and λ = 2940 nm) nanosecond laser pulses in strongly absorbing liquids (water, ethanol) under transparent solid cover is investigated with the help of acoustical and optical monitoring. LiNbO₃ transducer is used for registration of pressure pulses generated in irradiated liquids. Optical signals due to scattering and specular reflection of probing optical beams are explored with the schemes involving total internal reflection and interference effects. Combination of these two optical diagnostic methods permits for the first time to show that irradiation of covered liquids leads to vapor cavity formation which is divided from the cover with thin (submicron) liquid film despite the fact that radiation intensity maximum is located just at the liquid–plate boundary. The cavity formation is due to explosive boiling which occurs when the superheated liquid reaches its superheating limit in near critical region. After the first acoustical signal, the second signal is observed with several hundreds microseconds time delay which is caused by the vapor cavity collapse. Some results of optical and acoustical diagnostics in the case of free liquid surface are also presented.     

A parity conserving dimer model with infinitely many absorbing states

We propose and study a model where two aspects are present: parity conservation and infinitely many absorbing states. Whereas steady-state simulations show that the static critical behaviour is not affected by the presence of multiple absorbing configurations, the influence of the initial state associated with the presence of slowly decaying memory effects is clearly displayed in time dependent simulations. We report results of a detailed investigation of the dependence of critical spreading exponents on the initial particle density. Received 13 January 1999 and Received in final form 7 April 1999     

Power spectrum and scattering properties of three-dimensional disordered systems having a variable degree of short-range order

Summary The theory developed in preceding papers, concerning the power spectrum of disordered spatial structures having a variable degree of short-range crystallographic order and long-range directional order, is applied to the study of disordered atomic systems having an average microscopic isotropy. Starting from the general analytical expression of the power spectrum obtained under the assumption of a long-range directional order, the approximated expressions for the spherical structure factorw(k) and the pair distribution functiong(r) are obtained. With respect to other types of calculation, mostly numerical, found in the literature (microcrystalline, DRPHS, random network models) the present approach has the advantage of being mainly analytical and of giving, in general, a better agreement with experiments. Moreover, the possibility to control, through the introduction of suitable nonspherical distribution function, the type of dispersion of the nearest-neighbour atoms of each atom with respect to an ideal lattice allows us to get, through a best-fit analysis of experimental data, a more detailed information on the character of the displacements by which the disorder is generated.

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Riassunto La teoria, sviluppata nei lavori precedenti riguardanti lo spettro di potenza di strutture spaziali disordinate, aventi un grado variabile di ordine cristallografico a corto raggio ed un ordine direzionale a lungo raggio, è applicata allo studio dei sistemi atomici disordinati aventi un'isotropia media dal punto di vista macroscopico. Partendo da un'espressione analitica generale dello spettro di potenza ottenuto con l'ipotesi di un ordine direzionale a lungo raggio, si rieavano espressioni approssimate per il fattore di struttura sfericow(k) e per la funzione di distribuzione a coppieg(r). Rispetto ad altri tipi di calcolo, in gran parte numerici, che si trovano in letteratura (modello monocristallino, DRPHS, ?reticolo casuale?), il presente approccio ha il vantaggio di essere soprattutto analitico e di fornire, in generale, un miglior accordo con l'esperienza. Inoltre le possibilità di controllare, attraverso l'introduzione di opportune funzioni di distribuzione non sferiche, il tipo di dispersione degli atomi prossimi vicini di ciascun atomo rispetto ad un reticolo ideale permette di ottenere, attraverso un'analisi di bestfit dei dati sperimentali, una piú dettagliata informazione sul carattere degli spostamenti atomici con cui il disordine è generato.

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Резюме Теория, развитая в предыдущих статьях, касающихся степенного спектра разупорядоченных пространственных структур, имеющих изменяюшуюся степень ближнего кристаллографического порядка и дальнего ориентационного порядка, применяется к исследованию разупорядоченных атомных систем, обладающих в среднем микроскопической изотропией. Исходя из общего аналитического выражения для степенного спектра, полученного в предположении дальнего ориентационного порядка, выводятся приближенные выражения для сферического струк-турного фактораw(k) и парной функции распределенияg(r). По сравнению с другими типами вычислений, имеющихся в литературе, в большинстве численных, предлагаемый подход обладает рядом преимуществ: является аналитическим и дает лучшее согласие с зкспериментом. Кроме того, возможность контроля, посредством введения соответствующей несферической функции распределения, типа дисперсии ?ближайшего соседа? для каждого атома относительно идеальной решетки, позволяет получить, используя подгонку зкспериментальных данных, более подробную информацию о характере смещений, в результате которых возникает беспорядок.

     

Raman spectroscopic study of oxidation and phase transition in W18O49 nanowires

W₁₈O₄₉ nanowires were synthesized by a high‐temperature physical evaporation technique. The structure, morphology, and composition of the nanowires were characterized by SEM, EMPA, XRD, XPS, and HRTEM techniques. The intrinsic Raman spectrum of W₁₈O₄₉ nanowires was obtained, and the effect of laser power on the change of their structure was also studied. W₁₈O₄₉ nanowires were first oxidized to tungsten trioxide nanowires under irradiation of a certain laser power, and then the tungsten trioxide nanowires underwent a phase transition from monoclinic to orthorhombic with increasing laser power; this phase transition was reversible on turning down the laser power. Copyright © 2006 John Wiley & Sons, Ltd.     

有机双光子吸收材料的研究进展

本文综述了具有优异双光子吸收/双光子荧光性质的有机功能材料的研究工作和成果。近年来,有机材料凭借其出众的性质、丰富的种类、多重功能性以及快速的非线性光学响应引起国际科学和技术界的极大兴趣。文章介绍了测量材料的非线性光学性质和超快响应的实验方法,它们已被广泛应用于有机材料的研究工作,并且取得了重大的进展。本文描述了对偶极、四极、多枝结构、大环结构以及聚合物等有机材料的非线性光学性质和超快光学响应的研究结果。基于有机材料的迷人性质,具有优异非线性光学性质和超快响应的有机材料将会在很多领域显示出巨大的应用潜力。     

激光器与轨道的相对位置对动态加热的影响

通过分析光束入射的角度因子将激光器在地平面上的安放位置进行分类,采用了几何分析和数值模拟的方法,探讨了聚焦激光束在加热运动圆柱体过程中,为了达到一定的加热功率水平和能量水平以取得最好的加热效果而应采取的措施,即应当以激光垂直入射的轨道点为中心,以激光的有效工作时间为取值范围,并参考大气对激光能量的衰减,相对于轨道选取适当的距离进行加热。该研究从理论上说明了激光器与圆柱体运动轨道的相对位置对激光动态加热的影响可以看作一个优化问题,存在最优解,进而对于合理使用激光器进行动态加热具有参考价值。     

基于涡流脉冲相位热成像的金属材料裂纹检测

涡流热成像可以对金属材料表面、近表面缺陷进行快速准确的检测。采用涡流热成像与脉冲相位分析相结合的方法,针对裂纹附近相位谱的分布规律及温度场对相位谱的影响关系问题,分别对带有上表面裂纹和下表面裂纹的45#钢料进行感应加热仿真和实验分析。结果表明,相位谱分布与温度大小无关,只与温度变化趋势有关,相位谱图对不均匀加热有很好的抑制作用,可以扩大裂纹的检测范围,当频率低于12.5 Hz时能够清晰地识别裂纹。结合实验验证了仿真结论的正确性,为下一步利用相位信息实现缺陷的定量检测提供参考。