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The possibility of sulphur determination in uranium matrix by total reflection x-ray fluorescence spectrometry (TXRF) has been studied. Calibration solutions and samples of sulphur in uranium matrix were prepared by mixing uranium in form of a standard uranyl nitrate solution and sulphur in the form of Na2SO4 standard solution, prepared by dissolving Na2SO4 in Milli-Q water. For major element analysis of sulphur, it was determined without separation of uranium whereas for the trace level determinations, uranium was first separated by solvent extraction using 30% tri-n-butyl phosphate (TBP) in dodecane as an extractant. In order to countercheck the TXRF results, a few samples of Rb2U(SO4)3, a chemical assay standard for uranium, were diluted to different dilutions and sulphur content in these solutions were determined. The TXRF determined results for trace determinations of sulphur in these diluted solutions were counterchecked after addition of another uranium solution, so that sulphur is at trace level compared to uranium, separating uranium from these solution mixtures using TBP extraction and determining sulphur in aqueous phase by TXRF. For such TXRF determinations, Co was used as internal standard and W Lα was used as excitation source. The precision and accuracy of the method was assessed for trace and major element determinations and was found to be better than 8% (1σ RSD) and 15% at a concentration level of 1 μg/mL of sulphur measured in solutions whereas for Rb2U(SO4)3, these values were found to be better than 4 and 13%, respectively. 相似文献
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Rosanna Toniolo 《Talanta》2010,80(5):1809-3397
A sensitive and fast responding electrochemical sensor is described for the determination of free and total sulphur dioxide in wines and grape juices which prevents interferences coming from ethanol and other natural components. It consists of a cell provided with a porous gold working electrode supported on one face of an ion-exchange membrane, acting as a solid polymer electrolyte (SPE), which allows gaseous electroactive analytes to be detected. This sensor was used as an amperometric detector for a flow injection system in which controlled volumes of headspace equilibrated with samples were injected. This approach was adopted to make also possible the determination of total SO2, avoiding drawbacks caused by the high relative humidity generated by the sample heating resulting from the neutralization reaction of excess NaOH, whose addition was required to release sulphur dioxide from its combined forms. Factors affecting the detection process were examined and optimised. Under the identified optimal conditions, SO2 detection resulted in sharp peaks which allowed to infer detection limits for a signal-to-noise ratio of 3, referred to liquid samples, of 0.04 and 0.02 mg L−1 for free and total SO2 which were determined at 20 and 35 °C, respectively. Moreover, the responses were found to be characterized by good repeatability (±2% and ±4%, respectively) and linear dependence on the SO2 concentration over a wide range (0.2-500 mg L−1 for both free and total SO2). Finally, the long-term stability of the sensor turned out to be totally satisfactory in that responses changed of ±9% alone even after long periods of continuous use. The application to some commercial wines and grape juices is also presented. 相似文献
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The use of the closed-flow injection system for the direct and repetitive determination of sulphur dioxide (5.0–300 mg lt?1 in young white wines with chemiluminescence detection is described. The chemiluminescence from the oxidation of the disulfitomecurate complex with cerium(IV) in an acidic solution in the presence of riboflavin sulphate. The procedure is simple and reproducible. Results are in good agreement with those obtained by the spcetrophotometric pararosaniline method. 相似文献
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建立了离子体发射光谱仪测定钢中铈元素的方法。为消除共存元素对铈分析游线的光谱干扰,选择Ce413.380nm作为分析线,铈含量在0.005%-0.50%之间工作曲线线性良好。对于含量范围在0.005%-0.10%的铈元素,回收率为85.6%-12.5%,测定结果的相对标准偏差小于9.74%(n=8);对于含量范围在0.10%-0.50%的铈元素,回收率为99.5%-103.0%,测定结果的相对标准偏差小于3.52%(n=8)。该方法适宜钢中含量范围在O.005%-0.50%的铈元素的测定。 相似文献
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建立了镍氢电池正极材料氢氧化亚镍中主成分锌、钴及杂质钙、镁、锰、镉的ICP AES测定方法。选择了仪器最佳工作条件 ,研究了镍基体对被测元素的干扰。方法的回收率为 95 .9%~ 1 0 3% ,RSD为 0 .93%~ 1 8%。 相似文献
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N. MoreiraF. Mendes O. PereiraP. Guedes de Pinho T. HoggI. Vasconcelos 《Analytica chimica acta》2002,458(1):157-167
The influence of nitrogen compounds in grape musts on the content of sulphur compounds of wines was studied. Different vinifications were performed with the addition of methionine (20 mg l−1) and/or cysteine (40 mg l−1) to grape musts before alcoholic fermentation. Six grape musts, with different nitrogen composition, from cultivars of the ‘Vinhos Verdes’ Region, in Portugal, were used. Addition of methionine to grape musts enhanced the content of wines in 3-(methylthio)-1-propanol, acetic acid-3-(methylthio)propyl ester, 3-(methylthio)propionic acid and some unidentified sulphur compounds. Increase of cysteine concentration in musts led to the production of wines with high levels of hydrogen sulphide and cis-2-methyltetrahydro-thiophene-3-OL and also unidentified sulphur compounds; however, the content of 3-(methylthio)propionic acid in the wines decreased considerately with the addition of cysteine to grape musts. This work showed that cultivars from the Vinho Verde Region show different sulphur compound contents. Avesso wines, elaborated from grape musts with low amino acids level, presented the highest total sulphur compounds content. Wines from Azal branco and Alvarinho were characterised by high contents of 4-(methylthio)-1-butanol and 3-(methylthio)propionic acid, respectively. A high content of N-(3-(methylthio) propyl)-acetamide and dimethylsulphone characterise the Loureiro wines. In contrast, Trajadura wines, produced from a must rich in amino acids, presented a low total sulphur compounds content; however, these wines were also characterised by high concentrations of 4-(methylthio)-1-butanol, acetic acid-3-(methylthio)propyl ester and hydrogen sulphide. 相似文献
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ICP-AES法同时测定化妆品中的Hg、As、Pb 总被引:4,自引:0,他引:4
采用高压溶样弹,将样品用硝酸-过氧化氢或高氯酸-过氧化氢溶解后,用ICP-AES法对汞砷铅连续测定。方法的回收率分别为86.0%、96.2%、99.8%,变异系数分别为3.17%、2.51%、2.01%。与原子吸收法比较,无显著差异。应用于市售化妆品检测,结果满意。 相似文献
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The absorption of sulphur dioxide in chloride and bromide containing electrolyte solutions was measured up to ionic strengths of 5 mol/dm3. The thermodynamic equilibrium of the gas phase and the liquid phase was characterized by UV spectroscopy. UV spectra analysis gave strong evidence for SO2X− complexes existing in the solutions. Consequently, these compounds were implemented in the reaction scheme for absorption. 相似文献
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研究了等离子体发射光谱法间接测定药物片剂中扑尔敏的含量。选择了沉淀条件及ICP-AES测定的最佳条件。在PH2-4.5范围内,当四苯硼钠过量时可完全沉淀扑尔敏。硝酸铝可以使沉淀导速如凝而易于过滤,测定滤液中的四苯硼钠计算得扑尔敏的含量。方法的相对标准偏差为2.2%回收率为99%-102%,已用于实际样品的分析。 相似文献
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The determination of sulphur in petroleum products by combustion, concentration of the sulphur dioxide in sodium tetrachtoromercurate solutions and cool flame molecular emission is described. Improvements in burner design and optimization of analytical conditions result in a minimum detectable amount of 6 ng of sulphur. The absorption of sulphur dioxide from air samples and its determination by a similar method gives a detection limit of 1.3 μg SO2 m-3. 相似文献
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Conversion of sulphur compounds in reduced, contaminated sediments that are brought in upland conditions may largely affect the potential mobility of heavy metal contaminants. We applied selected methods for the determination of total sulphur and sulphur fractions in a contaminated sediment in the reduced state and after gradual drying and oxidation during 1 month. Dry ashing, followed by ion chromatographic detection, was reliable for the determination of total sulphur. Good recoveries were obtained in both reference samples and spiked samples. Total sulphur was 14.5±0.6 g kg−1 relative to dry sediment. Wet chemical methods that involve the determination of acid-volatile, Zn–HCl-reducible, chromium-reducible, acetone-soluble and HI-reducible sulphur were used to estimate specific sulphur forms. Results for acetone-soluble sulphur were to high and not consistent with results for other fractions. Major part of sulphur in the sediment (90%) was inorganic. Sulphides were converted partially to sulphate and to intermediary oxidised sulphur compounds upon oxidation of the sediment. The results suggested that the intermediary oxidised sulphur pool in the reduced sediment (2.5 g kg−1) mainly consisted of pyrite, that was not converted during drying and oxidation. No significant changes in organic sulphur were detected. 相似文献
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ICP-AES测定陶瓷器皿中微量溶出铅、镉的研究 总被引:1,自引:0,他引:1
张萍 《广东微量元素科学》2010,17(7):34-36
用4%乙酸溶液萃取分离日用瓷表面微量溶出元素Pb和Cd后,采用电感耦合等离子体原子发射光谱(ICP-AES)法进行了分析,对影响其测量的各种因素进行了较详细的研究,确定了实验的最佳测定条件。结果表明,方法的检出限为0.023(Pb)和0.006μg/L(Cd),回收率为98.0%~104.0%,RSD小于3.5%。该法准确、快速、简便,应用于日用瓷中的微量溶出铅、镉的测定,结果满意。 相似文献
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ICP-OES 法测定高温合金中的多种化学成分 总被引:2,自引:0,他引:2
采用电感耦合等离子体光谱法(ICP-OES)测定了镍基高温合金中的Zr、Mo、W、Ta、Nb、Ti等多种化学成分。选择仪器最佳工作条件,研究了镍基体对被测元素的影响。方法的回收率为95.3%-102%,RSD为0.40%-1.7%。 相似文献