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1.
The reaction of cluster Ru6C(CO)17 (1) with nickelocene is studied. Five CO ligands rather than a metal-ligand crown are substituted for two cyclopentadienyl groups to give a new complex Ru6C(5-Cp)2(CO)12 (2). The reaction of cluster1 with entamethylcyclopentadiene leads to new complex Ru6C(-15-CH2C5Me4)(CO)14 (3) containing the cr-bond CH2-Ru, along with an 5-coordinated cyclopentadienyl ring.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1171–1172, June, 1995.  相似文献   

2.
The crystal structure of the -cyclodextrin (-CyD) molecular complex with aspirin (acetylsalicylic acid), salicylic acid, and water, (C42H70O35)2 (C9H8O4)2 (C7H6O3) 23.3H2O, was determined by X-ray structure analysis. The crystal data is space group Pl, a=19.777(5), b=15.247(3), c=15.475(4) Å, =102.63(2)°, =116.96(2)°, =104.12(2)°, V=3729(2) Å3, Dm=1.409(2) g/cm3, DX=1.419 g/cm3, and Z=1. The two -CyDs form a dimer unit with hydrogen bond networks among the secondary hydroxyl groups of both -CyDs. This -CyD dimer includes three guest molecules of two different types in its hydrophobic cavity. Two of them are aspirin, which are separately included in each cavity of the -CyD unit, with their hydrophobic benzene rings protruding into the hydrophobic cavities of the host -CyDs. The remaining guest molecule is the hydrolyzed product of an aspirin, that is salicylic acid, which is sandwiched in the space constructed by the -CyD dimer formation, and is statistically disordered at three sites.  相似文献   

3.
The well-known simple adsorption methods used to evaluate the micropore size distribution from low pressure adsorption isotherms were examined by employing model isotherms for slit-like graphite micropores obtained from nonlocal density functional theory. It was shown that in the range of pore sizes from about 0.4 to 0.9 nm, the Horvath Kawazoe (HK) method satisfactorily reproduces the shape of the micropore size distribution, but the pore sizes are underestimated. In the case of micropores wider than 0.9 nm, the method fails as the formation of the monolayer on the pore walls produces a peak corresponding to 0.6 nm micropores on the HK pore size distribution. Therefore, the HK method indicates the presence of microporosity even for nonporous samples. The Dubinin-Astakhov adsorption isotherms were also examined and it was shown that their application to represent local adsorption isotherms for homogeneous pores is questionable. However, the adsorption potential distributions seem to be promising for micropore analysis.Nomenclature A Adsorption potential kJ/mol - C 1 Constant in Eq. 3 and 4 kJ * nm/mol - C 2 Constant in Eq. 3 and 4 nm3 - C 3 Constant in Eq. 3 and 4 nm9 - C 4 Constant in Eq. 3 and 4 - d Adsorbate molecule diameter nm - d A Adsorbent atom diameter nm - G Change in the Gibbs free energy kJ/mol - J Pore size distribution cm3/(g*nm) - R The universal gas constant = 8.31431 J/(mol * K) - T Absolute temperature K - V Amount adsorbed expressed in cm3 of liquid adsorbate per 1 g of the adsorbent = 0.0015468 * amount adsorbed expressed in cm3 STP/g cm3/g - x Pore width nm - X Differential adsorption potential distribution cm3 * mol/(g*kJ) - Constant defined as nm - p Pressure Pa - p 0 Saturated pressure = 760 torr = 101325 Pa Pa - P c Condensation pressure Pa - Degree of pore filling - S BET BET specific surface area m2/g - S ex External surface area obtained fromt-plot method m2/g - V mi Micropore volume obtained fromt-plot method cm3/g - V 1 Total pore volume cm3/g - E Characteristic energy in the Dubinin-Astakhov equation kJ/mol - n Exponent in the Dubinin-Astakhov equation   相似文献   

4.
The previously known triterpenoid 3-O--L-arabinopyranosides of oleanolic and echinocystic acids and hederagenin, 3-O--D-glucopyranosyl-(12)-O--L-arabinopyranosides of oleanolic acid and hederagenin, in addition to 28-O--L-rhamnopyranosyl-(14)-O--D-glucopyranosyl-(16)-O--D-glucopyranosyl ethers of the 3-O--L-arabinopyranoside of hederagenin, and 3-O--D-glucopyranosyl-(12)-O--L-arabinopyranosides of oleanolic acid and hederagenin, respectively, are isolated from leaves ofFatsia japonica(Araliaceae). The structures of the glycosides are confirmed by chemical methods and 13 C NMR spectroscopy  相似文献   

5.
The method of pulse photolysis has been used to determine termination rate constants of primary peroxy radicals in benzene at 295 K. Radicals CH3O 2 . have been found to decay with the rate constant 2k6=3.7×108 M–1 s–1 and radicals (CH3)3 COOC(CH3)CH2O 2 . with 2k8=1.2×108 M–1 s–1, the rate constant of cross-recombination for both radicals being 2.4×108 M–1 s–1.
295 K: CH3O 2 . 3,7·108 (M·c)–1, (CH3)3COOC(CH3)2CH2O 2 . =qt 1,2·108 (M·c)–1, 2,4·108 (M·c)–1.
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6.
First experiments on the transmutation of long-lived129I and237Np using relativistic protons of 3.7 GeV are described. Relativistic protons generate in extended Pb-targets substancial neutron fluences. These neutrons get moderated in paraffin and are used for transmutation as follows:129I(n,)130I and237Np(n,)238Np. The isotopes130I (T 1/2-12.36 h) and238Np (T 1/2=2.117 d) were identified radiochemically. One can estimate the transmutation cross-section (n,) in the given neutron field as (129I(n,))=(10±2)b and (237Np(n,))=(140±30)b The experiments were carried out in November 1996 at the Synchrophasotron, LHE, Dubna, Russia. The investigation has been performed at the Laboratory of High Energies, JINR, Dubna.  相似文献   

7.
Wettability of Microstructured Hydrophobic Sol-Gel Coatings   总被引:8,自引:0,他引:8  
The formation of appropriate surface patterns on hydrophobic surfaces leads to a general change in their wettability and the contact angle increases substantially. Such coatings are of great technical interest, especially if aqueous media are concerned as in the prevention of ice-adhesion. For this reason various fluorine containing nanocomposite coatings have been developed by sol-gel processing.The morphology of these hydrophobic surfaces has been controlled by varying the content of silica particles regarding size, degree of aggregation, and concentration. The wettability is characterized by the measurement of dynamic contact angles against water. The complete range of different wettability regimes is accessible, i.e. smooth surfaces (both low advancing contact angle and hysteresis between advancing and receding contact angle), surfaces within the Wenzel regime (high advancing contact angle and hysteresis), and superhydrophobic surfaces (high advancing contact angle and low hysteresis). The wettability is correlated with the surface roughness as determined using a profilometer or AFM.The wettability of superhydrophobic surfaces is greatly dependent on the surface tension of the liquid. By comparison of the tiltangle t of a smooth and a superhydrophobic surface, a critical surface tension c is identified, where t (smooth surface) = t (microstructured surface). The microstructured surface provides a better run-off of liquids lg > c 55 mN·m–1.  相似文献   

8.
The results of structural studies of the synthetic analog of the radtkeite mineral Hg3S2Cl1.00I1.00 are analyzed. The crystal structure of the compound has been refined; the unit cell parameters are a m = 16.827(4) , b m = 9.117(1) , c m = 13.165(5) , = 130.17(2)°, V = 1543.3(8) 3, space group C2/m, Z = 8, R = 0.0527. A possible transition a 0 = a m; b 0 = a m + 2c m; c 0 = –b m to the pseudo-orthorhombic F cell previously determined for radtkeite, where one of the angles ( 0 ) is slightly different from 90° (89.55°), has been found. Each sulfur atom in the structure is bonded to three mercury atoms, forming SHg3 umbrellas with distances 2.240(6) –2.474(8) and angles HgSHg 94.7(2)°–102.9(2)°. The SHg3 fragments are linked through Hg vertices to form corrugated [Hg12S8] layers. The halogen atoms lie inside and between the [Hg12S8] layers; the distances are Hg-Cl and Hg-I 2.783(7) , 2.961(7) , and 3.083(4) –3.311(3) , respectively.Original Russian Text Copyright © 2004 by N. V. Pervukhina, S. V. Borisov, S. A. Magarill, D. Yu. Naumov, V. I. Vasiliev, and B. G. NenashevTranslated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 4, pp. 755–758, July–August, 2004.This revised version was published online in April 2005 with a corrected cover date.  相似文献   

9.
The crystal and molecular structure of [Au(C14H22N4)]Br has been determined. Monoclinic crystals, a=12.592(2), b=6.309(1), c=19.628(2) ; =98.00(1)°, V=1544.1(4) 3, Z=4, dcalc=2.251 g/cm3, space group C2/c. The structure consists of virtually planar centrosymmetric [Au(C14H22N4)]+ cations and Br- anions. The coordination sphere of the gold atom involves four nitrogen atoms of the ligands, forming a planar square. The Au–N bond lengths are equal (the mean length is 1.982(7) ). The C–C and C–N bonds inside the -diiminate rings are delocalized. The parameters of the -diiminate rings of the [Au(C14H22N4)]+ cation are compared with the parameters of the related complexes.  相似文献   

10.
Cyclosiversigenin 6-O--L-rhamnopyranoside and 6-O--D-glucopyranoside were isolated fromAstragalus coluteocarpusBoiss. (Leguminosae) andAstragalus dissectusB. Fedtsch. et N. Ivanova, respectively. Cyclosiversigenin 5-O--L-rhamnopyranoside was shown to be an artifact forAstragalus coluteocarpus.Thus, the cyclosiversigenin 6-O--D-glucopyranoside that was isolated from certainAstragalusspecies is hypothesized also to be an artifact. Glycosylation of the 6 -hydroxyl group of cycloartanes by D-glucose and D-xylose, in contrast with other substituents, does not change the low-field position of the PMR signal of the 4-CH 3 group (1.65 2.01 ppm) that is caused by the influence of deuteropyridine directly on the 6 -hydroxyl. Obviously one of the hydroxyls of the -D-glucopyranoside or -D-xylopyranoside residues has the same effect in this instance.  相似文献   

11.
From the kinetic analysis of TPD curves it can be calculated that hydrogen desorption after reduction at lower temperatures can be described by a rate equation of first order, while reduction at higher temperatures provides a second order equation interpreted by a change of the rate-determining step of the complex desorption process.
, , , 2- . , .
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12.
In the present paper the dynamic properties of nonisothermal-nonadiabatic calorimeters have been analysed. In these calorimeters the thermal effect produced is partly accumulated in the calorimetric vessel, and partly transmitted to the shield with constant temperature. The generalized equation of the heat balance and the equation of the dynamics have been given for this type of calorimeter. The dependence between the course of the thermal effectQ in timet as a function of the temperature changes of the calorimeter has been presented. DependencesQ(t)=f[(t)] for a calorimeter with different domain configurations distinguished in it, and with different mutual locations of heat sources and temperature sensor have been given. Practical application of the considerations presented has been given.
Zusammenfassung Die Eigenschaften der sog. nicht-isotherm-nicht-adiabatischen Kalorimeter werden analysiert. In diesen Kalorimetern wird der ausgelöste thermische Effekt teils im Kalorimetergefäß gespeichert und teils dem Konstanttemperaturschild übertragen. Die verallgemeinerte Gleichung des Wärmegleichgewichts und die Gleichung der Dynamik werden für diesen Kalorimetertyp mitgeteilt. Die Abhängigkeit zwischen dem Verlaufe des thermischen EffektesQ in der Zeitt als Funktion der Temperaturänderungen des Kalorimeters werden ebenfalls mitgeteilt. Die AbhängigkeitenQ(t)=f[(t)] werden für ein Kalorimeter mit verschiedenen Bereichskonfigurationen, verschiedenen gegenseitigen Störungen der Wärmequelle und des Temperatursensors angegeben. Es wird auch die praktische Anwendung der beschriebenen Anordnungen gezeigt.

Résumé Les propriétés dynamiques des calorimètres appelés non-isothermes/non-adiabatiques sont examinées dans cet article. Dans ces calorimètres, l'effet thermique étudié est, en partie, accumulée dans la cellule calorimétrique et, en partie, transmis à la gaine à température constante. On donne l'équation générale du bilan thermique et l'équation de la thermocinetique pour ce type de calorimètre. L'évolution de l'effet thermiqueQ pendant le tempst est exprimée en fonction des variations de température du calorimètre en tempst. Les relationsQ(t)=f[(t)] sont données pour un calorimètre avec différentes configurations et différentes altérations mutuelles des sources de chaleur et des détecteurs de température. On donne également une application pratique des considérations présentées.

- . , . . Q t . Q(t)=f[(t)] . .
  相似文献   

13.
Physico-chemical studies of contact solutions based on Pd(II) salts and Fe(NO3)3 for ethylene oxidation to EGMA have been carried out.
- (II) .
  相似文献   

14.
Using pulse radiolysis technique, the one-electron oxidation of vanillin (V-OH) with azide radicals, at pH 6 and 9 resulted in the formation of vanillin phenoxyl radical with k = 6.7 × 107 and 2.5 × 109 dm3 mol-1 s-1, respectively. The transient absorption spectra of the vanillin phenoxyl radical (V-O) formed either at pH 6 or 9, showed a max at 410 nm. At pH 5, the OH radicals seem to form an adduct with vanillin, max at 430 nm and k(OH + V-OH) = 3.3 × 109 dm3 mol-1 s-1, while at pH 9, the OH radical reaction resulted in the formation of vanillin phenoxyl radical with max at 410 nm and k(OH + V-O-) = 6.6 × 109 dm3 mol-1 s-1. The reactivity of NO2radicals with vanillin is lower by orders of magnitude signifying an incomplete reaction. In general, the rate constants for the reaction of OH, N, NO radicals with vanillin were higher at pH 9 than at the lower pH. Its reactivity with other one-electron oxidants like CCl3OO, CHCl2OO and CH radicals and the ability to chemically repair tryptophanyl and guanosyl radicals with k = 1.5 - 4 × 107 dm3 mol-1 s-1 indicate its antioxidative behaviour.  相似文献   

15.
Ion-radical complexes Ti(IV) (O 2 ) are unreactive towards most oxidants except Ce(IV) and Cr2O 7 2– . The one-electron redox potential for the O2 coord./O 2 coord. couple lies between 1 and 1.6 V.
- O 2 Ti(IV) , Ce(IV) Cr2 O 7 2– . - O2 ./O 2 . 1 1,6 .
  相似文献   

16.
The dispersity, calculated from the particle size distribution functions obtained by Small Angle X-ray Scattering (SAXS) measurements, when related to the chemical behavior of Pd/charcoal catalysts in benzene hydrogenation, points out that this reaction is mildly structure-sensitive below the range of 40 Å, whereas no dependence on particle size is observed above this limit.
, , (SAXS), Pd/ , , 40 Å .
  相似文献   

17.
Based on momentum- and position-space analyses of the moment operators for two-electron atoms, it is shown that there exists a family of two-electron wave functions which satisfy a proportionality relation, r/ 1 v /r 12 v =p/ 1 v /p 12 v =2–v/2, between the one and two-electron moments in position and momentum spaces, where v is an arbitrary number for which the moments are well-defined.  相似文献   

18.
The structure and harmonic vibrational frequencies of several weakly bound complexes formed by HF are reported. Theab initio MP2 approach is used with large basis sets for the optimisation of geometries and the determination of harmonic frequencies. COHF and OCHF are examined; both are found to be minima, with the latter being the dominant structure. The linear OCOHF andT shaped OCOFH are studied, but only the linear structure is a minimum. N2OHF has two minima on the surface corresponding to bent NNOHF and linear ONNHF structures.  相似文献   

19.
The pseudobinary systems ACl/CeCl3 (A=Na-Cs) were reinvestigated by means of DTA. The following compounds were found and identified through their X-ray patterns (primarily detected compounds in italics):NaCe 1.67 Cl 6; K3CeCl6, K2CeCl5,KCe 1.67 Cl 6;Rb 3 CeCl 6, Rb2CeCl5,RbCe 2 Cl 7; Cs3CeCl6, Cs2CeCl5,CsCe 2 Cl 7. The compounds A2CeCl5 crystallize with the K2PrCl5 structure. The high-temperature modifications of the compounds A3CeCl6 have the cubic elpasolite structure. The hexagonal unit cell of KCe1.67Cl6 is related to the CeCl3 structure: 0.33 Ce3+ are substituted by one Ks+. The structure of CsCe2Cl7 can be described with a hexagonal subcellZ=4,a=9.72 andc=14.94 Å; however, small superstructure reflexions reduce the symmetry.The thermodynamic functions for the reactionsnACl+CeCl3=A n CeCl n+3(A=K, Rb) were determined by means of e.m.f. measurements.Measurements of the e.m.f.E vs. T yielded the Gibbs enthalpiesG r . The temperature-dependence was found to be linear.The most important result is the formation of the elpasolites (A3CeCl6) and ACe2Cl7.
Zusammenfassung Die pseudobinären Systeme ACl/CeCl3 (A=Na-Cs) wurden mittels Differenzthermoanalyse (DTA) neu untersucht. Folgende Verbindungen wurden gefunden und durch ihre Röntgenbeugungsmuster charakterisiert (erstmalig nachgewiesene Verbindungen sind kursiv):NaCe 1.67 Cl 6; K3CeCl6, K2CeCl5,KCe 1.67 Cl 6;Rb 3 CeCl 6, Rb2CeCl5,RbCe 2 Cl 7; Cs3CeCl6, Cs2CeCl5,CsCe 2 Cl 7. Die Verbindungen A2CeCl5 kristallisieren im K2PrCl5-Typ. Die Hochtemperaturmodifikationen der Verbindungen A3CeCl6 liegen in der kubischen Elpasolith-Struktur vor. Die hexagonale Elementarzelle des KCe1.67Cl6 ist mit der CeCl3-Struktur verwandt: 0,33 Ce3+ sind durch ein K+ ersetzt. Die Struktur des CsCe2Cl7 kann mit einer hexagonalen Pseudozelle beschrieben werden:a=9,72;c=14,94Å;Z=4; schwache Überstrukturreflexe reduzieren jedoch die Symmetrie. Die thermodynamischen Funktionen für die Reaktionen:n ACl + CeCl3=A n CeCl n+3 (A=K, Rb) wurden durch EMK-Messungen bestimmt. Messungen der Abhängigkeit von e. m. f.E gegenT ergaben die Gibbs-EnthalpienG r . Es wurde eine lineare Temperaturabhängigkeit gefunden. Als wichtigstes Resultat ist die Bildung von Elpasoliten (A3CeCl6) und von Verbindungen (ACe2Cl7) anzusehen.

ACl/CeCl3, A . - ( ):NaCe 1.67 Cl 6; K3CeCl6, K2CeCl5,KCe 1.67 Cl 6;Rb 3 CeCl 6, Rb2CeCl5,RbCe 2 Cl 7; Cs3CeCl6, Cs2CeCl5 CsCe 2Cl7. A2CeCl5 K2PrCl5. A3CeCl6 . KCe1.67Cl6 CeCl3, 0,33 Ce3+ . CsCe2Cl7 a=9,72 Å,c=14,94 Å Z=4. , . n ACl + CeCl3=A n CeCl n+3(A=K, Rb) . . . . . .E , G r . ACe2Cl7.


Presented as a poster at the 8th ICTA, Bratislava, 1985.

This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.  相似文献   

20.
Zusammenfassung Gemischt substituierte Disilylamine (RRRSi)2NH lassen sich von NaNH2 zu reaktionsfähigen Natrium-bis-(silyl)-amiden metallieren, aus denen nach Umsetzung mit Organohalogensilanen und anschließender Alkoholyse der verbleibenden Si-Cl-Gruppen gemischt substituierte Trisilylamine (RRRSi)3N mit R=(me), R, R=O(me); R,R=(me), R=O(et); R=(vi), R, R=O(me); R=(me), R=(vi), R=O(ipr) dargestellt werden konnten.33. Mitt.:U. Wannagat, J. Pump undH. Bürger, Mh. Chem.94, 1013 (1963).Auszüge aus den DissertationenH. Bürger, TH Aachen 1962,P. Geymayer, TH Graz 1963, und der DiplomarbeitG. Torper, TH Graz 1962; vgl. auchU. Wannagat undH. Bürger, Angew. Chem.75, 95 (1963).  相似文献   

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