Surface tension modelling of liquid Cd–Sn–Zn alloys

The thermodynamic model in conjunction with Butler equation and the geometric models were used for the surface tension calculation of Cd–Sn–Zn liquid alloys. Good agreement was found between the experimental data for limiting binaries and model calculations performed with Butler model. In the case of ternary alloys, the surface tension variation with Cd content is better reproduced in the case of alloys lying on vertical sections defined by high Sn to Zn molar fraction ratio. The calculated surface tension is in relatively good agreement with the available experimental data. In addition, the surface segregation of liquid ternary Cd–Sn–Zn and constituent binaries has also been calculated.     

Thermophysical properties of Cu–In–Sn liquid Pb-free alloys: viscosity and surface tension

The viscosity of a few Cu–In–Sn liquid alloys has been investigated by a number of geometric (Muggianu, Kohler, Toop) and physical thermodynamic models (Kozlov–Romanov–Petrov, Budai–Benko–Kaptay, Schick et al.) and GSM for the cross section (z/y = 1/3) in Pb-free liquid alloy Cu_x–In_y–Sn_z at 1073 K. Moreover, the surface tensions of the same liquid alloys have been investigated by a number of geometric models and the Butler model for the cross section Cu_x–In_y–Sn_z (z/(y + z) = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1) at the same temperature. The best agreement of the surface tensions was obtained in the Kohler model for x_Cu = 10 at % and the Butler model for x_Cu = 20 at % and x_Cu = 30 at.%, respectively. The best agreement among chosen geometric and physical models and experiment for these selected sections Cu₈₀In₁₅Sn₅, Cu₇₅In₁₅Sn₁₀, Cu₅₅In₇Sn₃₈, Cu₃₃In₅₀Sn₁₇ and Cu₂₆In₅₅Sn₁₉ at 1073 K was obtained for the Budai–Benkö–Kaptay model.     

Density and surface tension of diluted Sn–In alloys

The results from measuring the density and surface tension of Sn–In melts via the sessile drop method in a helium atmosphere and at a residual gas pressure of 0.01 Pa are presented. The density polytherms of all samples are linear with negative temperature coefficients. In the range of 550–750°C, the surface tension falls linearly as the temperature rises.     

Electrical resistivity of liquid Bi–Sb alloys

The electrical resistivities of liquid Bi–Sb alloys have been measured by DC four-probe method within Bi-rich composition through a wide temperature range. The distinct anomaly of a hump shape was observed on resistivity–temperature (ρndash;T) curves for liquid Bi–Sb alloys on heating at the relatively high temperatures. These anomalies have revealed the temperature-induced liquid–liquid phase transition in Bi–Sb melts. The DSC results for BiSb20wt% alloy further prove the existence of liquid–liquid transition. Measuring the ρ–T curves first on heating and then on cooling we have found that on cooling the ρ–T curve remained linear. It means that the postulated liquid–liquid transition may be irreversible.     

Determination of surface tension of liquid ternary Ni–Cu–Fe and sub-binary alloys

Experimental data in the literature are almost limited to determine the thermophysical properties of multicomponent complex alloys, especially due to the inability of laboratories to achieve the desired ideal conditions, due to the difficulty of protection from oxidation at high temperatures and other contamination at high temperatures, due to time and cost in laboratory studies. Due to these reasons, the theoretical data obtained in this subject is of great importance. In this study, a series of geometric and physical models, such as Chou’s general solution model (GSM), Muggianu’s Model, Kohler’s Model, Toop’s Model, Hillert’s Model, Guggenheim’s Model, Butler’s Model, Egry’s Model and ideal solution model for quasi-binary alloy system for Section A: Ni_{0.4(1 – x)}Cu_xFe_{0.6(1 – x)}. and Section B: (Ni_xCu_0.2Fe_{0.8 – x}) are used to calculate the surface tension-composition and surface tension-temperature curves of the Cu-Fe-Ni ternary liquid system are plotted. The data for this process is evaluated by means of an extended Redlich-Kister-Muggianu polynomial fit to the experimental values of the surface tensions of the binary liquid alloy systems. The obtained results for these models are also compared with the available data in the literature and relatively good agreements are observed. In addition, the surface segregation having important key factor in determining surface tension of the liquid alloy Ni-Fe-Cu has also been investigated in this work.     

Surface tension of hydrocarbon chains at the liquid–vapour interface

Molecular dynamics simulations were performed at constant temperature to obtain the surface tension of hydrocarbon chains at the liquid–vapour interface. The Ewald sum was used to calculate the dispersion forces of the Lennard–Jones potential to take into account the full interaction. The NERD and TraPPE_UA flexible force field models were used to simulate molecules from ethane to hexadecane along the coexistence curve. The simulation results for the TraPPE_UA model are in good agreement with experimental data, whereas the NERD model predicts slightly higher values.     

Volumetric properties of near-eutectic liquid Li–Pb alloys

The density and the thermal expansion of liquid lithium–lead alloys with Pb content of 83.0 and 84.3 at. % was measured using gamma-ray attenuation technique over the temperature range from liquidus to 1000 K. The density change during solid–liquid phase transition was directly measured for the first time for Li15.7Pb84.3 alloy. A comparison of the obtained results with literature data has been carried out.     

Surface tension estimation of high temperature melts of the binary alloys Ag–Au

Abstract

Surface tension calculation of the binary alloys Ag–Au at the temperature of 1381 K, where Ag and Au have similar electronic structures and their atomic radii are comparable, are carried out in this study using several equations over entire composition range of Au. Apparently, the deviations from ideality of the bulk solutions, such as activities of Ag and Au are small and the maximum excess Gibbs free energy of mixing of the liquid phase is for instance ?4500 J/mol at X_Au = 0.5. Besides, the results obtained in Ag–Au alloys that at a constant temperature the surface tension increases with increasing composition while the surface tension decreases as the temperature increases for entire composition range of Au. Although data about surface tension of the Ag–Au alloy are limited, it was possible to make a comparison for the calculated results for the surface tension in this study with the available experimental data. Taken together, the average standard error analysis that especially the improved Guggenheim model in the other models gives the best agreement along with the experimental results at temperature 1383 K although almost all models are mutually in agreement with the other one.     

Interaction between solid nickel and a tin–indium eutectic melt,and the nature of eutectic alloys

Structural transformations during reactions between nickel and an indium–tin eutectic melt are studied via the diffraction of high-energy synchrotron radiation. It is shown that InNi intermetallic compound is the first to form after melting. No phases belonging to a Ni–Sn system are observed. A hypothesis concerning the nanocluster structure of the eutectic melt is proposed: Structural formations with forbidden five-fold, seven-fold, and higher-order rotational axes of symmetry lie at the heart of nanosized clusters.     

Theoretical calculation of surface tension and its temperature coefficient associated with liquid Cu–Ti alloys

In this work, the surface tension of Cu–Ti binary liquid alloys is calculated in the framework of Eyring theory as a function of composition and temperature. It is observed that for all investigated alloys the surface tension can be described by a linear function of the temperature with negative slope, and the temperature coefficient of surface tension decreases as Ti-content of the alloys increases linearly. The obtained theoretical results are compared to the experimental data available in the literature as well as to the theoretical results evaluated by using four models, such as the compound formation model, the quasi-chemical approximation for regular solutions, ideal solution model and Butler model treated in literature frequently.     

Surface texture and density–density correlation in films of adamantane-containing polyimides and copolyimides

By means of electron microscopy, the spatial correlation of gold nanoparticles are studied, obtained by thermal vacuum sputtering of metal on a bromine-activated surface of films of adamantane-containing polyimides and copolyimides based on pyromellitic anhydride (PMDA), 4,4'-oxydianiline (ODA), and 1-aminoethyl-3-(4'-aminophenyl)adamantane (AEAPhA) or 3,4,3',4'-tetracarboxydiphenyloxide dianhydride (ODPA), ODA, and AEAPhA with varying ratio of ODA and AEAPhA fragments. It is shown that with increasing ratio of mole fractions [AEAPhA]/[ODA], the texture of the film surface, free volume, the correlation length, and the frequency of alternation of the particle distribution density change. The shortrange order decreases, while the long-range order increases in ensembles of particles. The supramolecular structure of the polymer is transformed similarly because of structural transitions in the amorphous state of ODPA–ODA–AEAPhA and the mesomorphic state of PMDA–ODA–AEAPhA.

     

Atomic mobility in a ternary liquid Ga–In–Sn alloy of the eutectic composition

The nuclear spin–lattice relaxation and Knight shift of ⁷¹Ga, ⁶⁹Ga, and ¹¹⁵In nuclei in a ternary liquid gallium–indium–tin alloy of the eutectic composition, which was introduced into pores of an opal matrix and porous glasses with pore sizes of 18 and 7 nm, have been investigated and compared with those for the bulk melt. It has been found that longitudinal relaxation is accelerated and the Knight shift is decreased, depending on the size of pores. The correlation time of the atomic motion has been calculated for the nanostructured melt in porous matrices. It has been shown that the atomic mobility in the melt decreases with decreasing size of pores in the glasses.

     

Ultrasonic semi-solid coating soldering 6061 aluminum alloys with Sn–Pb–Zn alloys

In this paper, 6061 aluminum alloys were soldered without a flux by the ultrasonic semi-solid coating soldering at a low temperature. According to the analyses, it could be obtained that the following results. The effect of ultrasound on the coating which promoted processes of metallurgical reaction between the components of the solder and 6061 aluminum alloys due to the thermal effect. Al₂Zn₃ was obtained near the interface. When the solder was in semi-solid state, the connection was completed. Ultimately, the interlayer mainly composed of three kinds of microstructure zones: α-Pb solid solution phases, β-Sn phases and Sn–Pb eutectic phases. The strength of the joints was improved significantly with the minimum shear strength approaching 101 MPa.     

A study of Bi–Pb–Sn–Cd–Sb penta-alloys rapidly quenched from melt

Optical microscopy, X-ray diffractometry, the double bridge method, the Vickers microhardness testing and dynamic resonance techniques have been used to investigate structure, electrical resistivity, hardness, internal friction and elastic modulus of quenched Bi–Pb–Sn–Cd–Sb penta-alloys. The properties of these penta-alloys are greatly affected by rapid quenching. The intermetallic compound χ(Pb–Bi) or Bi₃Pb₇ is obtained after rapid quenching using the melt-spinning technique, and this is in agreement with reports by other authors [Marshall, T. J., Mott, G. T. and Grieverson, M. H. (1975). Br. J. Radiol., 48, 924; Kamal, M., El-Bediwi, A. B. and Karman, M. B. (1998). Structure, mechanical properties and electrical resistivity of rapidly solidified Pb–Sn–Cd and Pb–Bi–Sn–Cd alloys. J. Mater. Sci.: Mater. Electron., 9, 425; Borromêe-Gautier, C., Giessen, B. C. and Grrant, N. J. (1968). J. Chem. Phys., 48, 1905; Moon, K.-W., Boettinger, W. J., Kattner, U. R., Handwerker, C. A. and Lee, D.-J. (2001). The effect of Pb contamination on the solidification behavior of Sn–Bi solders. J. Electron. Mater., 30, 45.]. The quenched Bi_43.5Pb_44.5Cd₅Sn₂Sb₅ alloy has important properties for safety devices in fire detection and extinguishing systems.     

Liquid–liquid structure transition in Sn–3.5Ag–3.5Bi melts

The liquid–liquid structure transition (LLST) as the function of temperature and time in Sn–3.5Ag–3.5Bi melts was investigated with the help of direct current four-probe method. The LLST which occurs during first cycle heating of two cycles heating/cooling experiments can divide into two different structure changes: irreversible LLST of 650°C isothermal and step reversible LLST at 770°C–806°C on subsequent heating process. Obvious kinetic phenomena are observed during isothermal experiments. Irreversible and reversible LLST are analysed from the viewpoint of short-range order. These results will help to understand the law and mechanism of liquid field, and provide some scientific reference for the innovation of lead-free solder manufacturing.     

Thermodynamics and surface properties of liquid Al–Ga and Al–Ge alloys

The surface properties of Al–Ga and Al–Ge liquid alloys have been theoretically investigated at a temperature of 1100 K and 1220 K respectively. For the Al–Ga system, the quasi chemical model for regular alloy and a model for phase segregating alloy systems were applied, while for the Al–Ge system the quasi chemical model for regular and compound forming binary alloys were applied. In the case of Al–Ga, the models for the regular alloys and that for the phase segregating alloys produced the same value of order energy and same values of thermodynamic and surface properties, while for the Al–Ge system, the model for the regular alloy reproduced better the thermodynamic properties of the alloy. The model for the compound forming systems showed a qualitative trend with the measured values of the thermodynamic properties of the Al–Ge alloy and suggests the presence of a weak complex of the form Al₂Ge₃. The surface concentrations for the alloys show that Ga manifests some level of surface segregation in Al–Ga liquid alloy while the surface concentration of Ge in Al–Ge liquid alloy showed a near Roultian behavior below 0.8 atomic fraction of Ge.