共查询到20条相似文献,搜索用时 31 毫秒
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Leimajam Vartima Chanu Okram Mukherjee Singh 《Journal of heterocyclic chemistry》2021,58(12):2207-2225
In the last decade, silica-supported heterogeneous catalysts have emerged as efficient green catalysts for the development of synthetic protocols of bioactive heterocycles. These catalysts possess better significant features when compared with the activities of homogeneous catalysts. Azoles are five-membered nitrogen-containing heterocyclic compounds that possess a wide range of medicinal properties. In this review, a summary of the recent progress on silica-supported heterogeneous catalyzed synthetic methods of azoles and related five-membered heterocycles is presented. 相似文献
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The development of synthetic catalysts is inspired by nature's use of enzymes to achieve high reaction rates and 100% selectivity. These natural catalysts often contain inorganic nanoclusters at the active site, and it is an understanding of the activity and selectivity of these nanoclusters and their interaction with the surrounding protein, which can aid in the design of synthetic catalysts. Since natural and synthetic catalysts are composed of these nanoclusters, the fields of catalysis and nanoscience are inextricably linked. 相似文献
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负载型烯烃聚合催化剂合成的新方法 总被引:3,自引:0,他引:3
介绍了负载型烯烃聚合催化剂合成的新方法,探讨了不同载体负载的Ziegler- Natta催化剂各组分之间的相互作用机理及活性中心的形成途径。对负载茂金属催 化剂的新型载体及新的负载方法进行了评述。 相似文献
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近年来, 单原子催化剂因其最大化的金属原子利用效率和高催化性能, 已成为能量存储和转化领域中的研究热点. 单原子催化剂的高活性主要来源于其低配位结构、 量子尺寸效应和原子与载体之间的强相互作用. 因此, 如何根据构-效关系开发通用且简单的制备高效单原子催化剂的方法具有重要的意义. 从实际应用的角度而言, 湿化学法因具有工艺简单和易于大规模生产的特性, 被认为是一种实现工业化制备单原子催化剂的方法, 现已开发了一系列制备负载型单原子催化剂的策略. 本文从独特的抑制反应物前驱体物质形核的角度出发, 总结了冷冻合成方法对形核的抑制机制, 进一步针对不同方面的应用, 探讨了单原子材料的催化机理, 并对其未来的发展进行了展望. 相似文献
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Photoredox catalysis is emerging as a powerful tool in synthetic organic chemistry. The aim of this synopsis is to provide an overview of the photoelectronic properties of photoredox catalysts as they are applied to organic transformations. In addition, recent synthetic applications of photoredox catalysis are presented. 相似文献
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开发可替代铂的非贵金属催化剂是今后燃料电池催化剂的重要发展方向,本文结合课题组研究的工作,总结了近年来非贵金属在氧还原催化方面的研究进展。并着重从材料合成和机理两个方面分析了目前在开发过渡金属氧化物、含过渡金属的氮掺杂碳材料和杂原子掺碳材料中存在的问题,提出了这些非金属催化剂今后的研究重点和努力方向。 相似文献
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Mélanie Bordeaux Dr. Anne Galarneau Dr. Jullien Drone 《Angewandte Chemie (International ed. in English)》2012,51(43):10712-10723
Selective catalysts for sustainable oxidation of alkanes are highly demanded because of the abundance of these molecules in the environment, the possibility to transform them into higher‐value compounds, such as chemicals or synthetic fuels, and the fact that, kinetically speaking, this is a difficult reaction. Numerous chemical and biological catalysts have been developed in the lasts decades for this purpose, rendering the overview over this field of chemistry difficult. After giving a definition of the ideal catalyst for alkane oxyfunctionalization, this review aims to present the catalysts available today that are closest to ideal. 相似文献
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Bernardi L Fochi M Comes Franchini M Ricci A 《Organic & biomolecular chemistry》2012,10(15):2911-2922
Several small organic molecule catalysts are reminiscent of natural enzymes in their mode of action and substrate interaction/activation. This striking similarity has been a great source of inspiration for the development of new organocatalytic asymmetric processes. A few representative examples, mostly dealing with catalysts interacting through multiple hydrogen-bonds (synthetic oxyanion holes), are highlighted in this perspective. 相似文献
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单原子催化剂(SACs)是一类仅含有孤立的单个金属原子作为催化活性中心的催化材料. 由于其具有100%的原子利用率、 独特的化学结构及优异的催化活性等优点, 近年来在电化学催化和电能转换设备领域备受关注. 本文综合评述了单原子催化材料的设计理念、 合成方法和表征方法, 同时对其在氢电化学循环 (电解水制氢和氢燃料电池领域)的实际应用进行了系统介绍, 并对单原子催化材料的研究和应用前景进行了展望. 相似文献
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Although driven by different research interests, single-site catalysts and single-atom catalysts are both believed to be model systems bridging homogeneous and heterogeneous catalysis. The two concepts are similar but different. In this review, we will first explain the difference between single-atom catalysis and single-site catalysis, in terms of their goals, synthetic methods and coordination structures of corresponding catalysts. Then, we will introduce the surface organometallic chemistry method, a method traditionally used for synthesizing single-site catalyst. We will explain why it might benefit the single-atom catalysis community. At last, the choice of support to accommodate the method for synthesizing single-atom catalysts will be discussed. 相似文献
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电化学分解水(Water Splitting)是获得高纯度氢能的重要手段。 因此,开发具有高活性低成本的电化学析氢反应(Hydrogen Evolution Reaction,HER)催化剂成为目前能源环境的研究热点之一。 本文总结了常用于HER反应的过渡金属硫化物以及磷化物非贵金属催化剂材料的合成方法,并且概况了如何构建特殊结构的金属硫化物及磷化物材料以调高材料的HER催化反应性能的方法,为开发其它高活性的非贵金属催化剂提供依据。 相似文献
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The synthetic methods of heterogeneous metallocene catalysts reported so far in academic journals are summarized together with their catalyst performance. Some of our new results in this field are also described in brief. 相似文献
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对苯二酚合成方法的研究进展 总被引:10,自引:0,他引:10
对苯二酚是一种重要的化工原料和中间体。本文综述了目前国内外对苯二酚合成方法的研究进展,特别对苯酚过氧化氢羟基化法这一洁净合成方法及其所用催化剂的种类和性能进行了较为详尽的综述。 相似文献
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Navjeet Kaur 《合成通讯》2013,43(19):2457-2474
The nitrogen-, oxygen- and sulfur-heterocycles possess a number of pharmacological activities and recently many reports appeared for the synthesis of these heterocycles. In few past years, metals are applied for the production of these heterocycles. These synthetic strategies involving metal catalysts became highly significant in the synthetic organic chemistry. This review article features the applications of rhodium metal catalysts for the preparation of five-membered N-polyheterocylces. 相似文献