Time-, stress-, and temperature-dependent deformation in nanostructured copper: Creep tests and simulations

In the present work, we performed experiments, atomistic simulations, and high-resolution electron microscopy (HREM) to study the creep behaviors of the nanotwinned (nt) and nanograined (ng) copper at temperatures of 22 °C (RT), 40 °C, 50 °C, 60 °C, and 70 °C. The experimental data at various temperatures and different sustained stress levels provide sufficient information, which allows one to extract the deformation parameters reliably. The determined activation parameters and microscopic observations indicate transition of creep mechanisms with variation in stress level in the nt-Cu, i.e., from the Coble creep to the twin boundary (TB) migration and eventually to the perfect dislocation nucleation and activities. The experimental and simulation results imply that nanotwinning could be an effective approach to enhance the creep resistance of twin-free ng-Cu. The experimental creep results further verify the newly developed formula (Yang et al., 2016) that describes the time-, stress-, and temperature-dependent plastic deformation in polycrystalline copper.     

Shear,dilation, and swap: Mixing in the limit of fast diffusion

Molecules of different species mix by local rearrangement and long-range migration. Under certain conditions, the molecules are partially jammed: they rearrange slowly, but migrate fast. Here we formulate a theory of mixing when the long-range migration of molecules is fast, and the local rearrangement of molecules sets the time needed for mixing. In this limit, the time needed for mixing is independent of the length scale of inhomogeneity. We identify three modes of local rearrangement: shear, dilation, and swap. All three modes break and form intermolecular bonds. We place the three modes on equal footing, as distinct, concurrent, nonequilibrium processes. Our theory thus removes the bias that assumes local chemical equilibrium but allows the nonequilibrium process of shear. We propose a kinetic model of four independent viscosity-like coefficients, and a thermodynamic model of ideal mixing of molecules of unequal sizes and nonzero volume of mixing. We illustrate the theory with several examples, including the development of growth stress, the homogenization of a bilayer, and the disappearance of an inclusion in a matrix.     

Coupled heat transfer and viscous flow,and magnetic effects in weld pool analysis

A finite element formulation and analysis is developed to study coupled heat transfer and viscous flow in a weld pool. The thermal effects generate not only buoyancy forces but also a variation in the surface tension which acts to drive the viscous flow in the molten weld pool. A moving phase boundary separates molten and solid material. Numerical experiments reveal the nature of the highly convective flow in the weld pool and the associated thermal profiles. The relative importance of buoyancy, surface tension, phase change, convection, etc. are examined. We also consider the sensitivity of the solution to the finite element mesh and related non-linear numerical instabilities. Of particular interest is the coupling of the thermal and viscous flow fields for the case when radial flow is inward or outward.     

Creep and anelasticity in the springback of aluminum

Draw-bend tests, devised to measure springback in previous work, revealed that the specimen shapes for aluminum alloys can continue to change for long periods following forming and unloading. Steels tested under identical conditions showed no such time-dependent springback. In order to quantify the effect and infer its basis, four aluminum alloys, 2008-T4, 5182-O, 6022-T4 and 6111-T4, were draw-bend tested under conditions promoting the time-dependent response (small tool radius and low sheet tension). Detailed measurements were made over 15 months following forming, after which the shape changes were difficult to separate from experimental scatter. Earlier tests were re-measured up to 7 years following forming. The shape changes are generally proportional to log(time) up to a few months, after which the kinetics become slower. In order to understand the basis of the phenomenon, two models were considered: residual stress-driven creep, and anelastic deformation. In the first case, creep properties of 6022-T4 were measured and used to simulate creep-based time-dependent springback. Qualitative agreement was obtained using a crude finite element model. For the second possibility, novel anelasticity tests following reverse-path loading were performed for 6022-T4 and drawing-quality silicon-killed (DQSK) steel. Based on the experiments and simulations, it appears that anelasticity is unlikely to play a large role in long-term time-dependent springback of aluminum alloys.     

Thermodynamically consistent phase field approach to dislocation evolution at small and large strains

A thermodynamically consistent, large strain phase field approach to dislocation nucleation and evolution at the nanoscale is developed. Each dislocation is defined by an order parameter, which determines the magnitude of the Burgers vector for the given slip planes and directions. The kinematics is based on the multiplicative decomposition of the deformation gradient into elastic and plastic contributions. The relationship between the rates of the plastic deformation gradient and the order parameters is consistent with phenomenological crystal plasticity. Thermodynamic and stability conditions for homogeneous states are formulated and satisfied by the proper choice of the Helmholtz free energy and the order parameter dependence on the Burgers vector. They allow us to reproduce desired lattice instability conditions and a stress-order parameter curve, as well as to obtain a stress-independent equilibrium Burgers vector and to avoid artificial dissipation during elastic deformation. The Ginzburg–Landau equations are obtained as the linear kinetic relations between the rate of change of the order parameters and the conjugate thermodynamic driving forces. A crystalline energy coefficient for dislocations is defined as a periodic step-wise function of the coordinate along the normal to the slip plane, which provides an energy barrier normal to the slip plane and determines the desired, mesh-independent height of the dislocation bands for any slip system orientation. Gradient energy contains an additional term, which excludes the localization of a dislocation within a height smaller than the prescribed height, but it does not produce artificial interface energy. An additional energy term is introduced that penalizes the interaction of different dislocations at the same point. Non-periodic boundary conditions for dislocations are introduced which include the change of the surface energy due to the exit of dislocations from the crystal. Obtained kinematics, thermodynamics, and kinetics of dislocations at large strains are simplified for small strains and rotations, as well.     

Relations Between Relaxation Modulus and Creep Compliance in Anisotropic Linear Viscoelasticity

The results obtained previously for scalar and class P completely monotone relaxation moduli are extended to arbitrary anisotropy. It is shown for general anisotropic viscoelastic media that, if the relaxation modulus is a locally integrable completely monotone function, then the creep compliance is a Bernstein function and conversely. The elastic and equilibrium limits of the two material functions are related to each other. The relaxation modulus or its derivative can be singular at 0. A rigorous general formulation of the relaxation spectrum in an anisotropic viscoelastic medium is given. The effect of Newtonian viscosity on creep compliance is examined. Put some makeup on him and lay him to rest. Anonymous     

A phase-field theory of dislocation dynamics, strain hardening and hysteresis in ductile single crystals

A phase-field theory of dislocation dynamics, strain hardening and hysteresis in ductile single crystals is developed. The theory accounts for: an arbitrary number and arrangement of dislocation lines over a slip plane; the long-range elastic interactions between dislocation lines; the core structure of the dislocations resulting from a piecewise quadratic Peierls potential; the interaction between the dislocations and an applied resolved shear stress field; and the irreversible interactions with short-range obstacles and lattice friction, resulting in hardening, path dependency and hysteresis. A chief advantage of the present theory is that it is analytically tractable, in the sense that the complexity of the calculations may be reduced, with the aid of closed form analytical solutions, to the determination of the value of the phase field at point-obstacle sites. In particular, no numerical grid is required in calculations. The phase-field representation enables complex geometrical and topological transitions in the dislocation ensemble, including dislocation loop nucleation, bow-out, pinching, and the formation of Orowan loops. The theory also permits the consideration of obstacles of varying strengths and dislocation line-energy anisotropy. The theory predicts a range of behaviors which are in qualitative agreement with observation, including: hardening and dislocation multiplication in single slip under monotonic loading; the Bauschinger effect under reverse loading; the fading memory effect, whereby reverse yielding gradually eliminates the influence of previous loading; the evolution of the dislocation density under cycling loading, leading to characteristic ‘butterfly’ curves; and others.     

Effect of thermal diffusion and electrostatic force on evolution of wind-blown sand flow

A theoretical model is suggested to mathematically describe the effect of thermal diffusion from a sand-bed on evolution of a wind-blown sand flow.An upward wind field is engendered by the thermal diffusion and the coupling interaction among the horizontal and upward wind flow,saltating grains,and a kind of electrostatic force exerted on the grains are considered in this theoretical model.The numerical results show that the effect of the thermal diffusion on the evolution process of wind-blown grain flow is quite obvious and very similar to the effect of the electrostatic force on the evolution.Not only the time for the entire system to reach a steady state(called the duration time),the transport rate of grains,the mass-flux profiles and the trajectory of saltating grains are affected by the thermal diffusion and the electrostatic force exerted on saltating grains, but also the wind profiles and the temperature profiles at the steady state are affected by the wind-blown sand flow.     

Numerical study on the two-phase flow distribution in a T-junction

The main objective of this paper is to investigate the ability of a two-dimensional two-fluid computer code to predict the phase separation in a T-junction. A new semi-implicit numerical scheme is developed for solving the two-fluid model equations. Special attention is directed to the modelling of the constitutive for the interfacial friction term. Detailed distribution of void fraction, pressure and velocities are obtained for an air–water mixture in a vertical tee. Good agreement was obtained between the computer code results and the experimental data for the phase separation in the T-junction.     

A mesoscopic approach on stability and phase transition between different traffic flow states

It is understood that congestion in traffic can be interpreted in terms of the instability of the equation of dynamic motion. The evolution of a traffic system from an unstable or metastable state to a globally stable state bears a strong resemblance to the phase transition in thermodynamics. In this work, we explore the underlying physics of the traffic system, by examining closely the physical properties and mathematical constraints of the phase transitions therein. By using a mesoscopic approach, one entitles the catastrophe model the same physical content as in the Landau's theory, and uncovers its close connections to the instability of the equation of motion and to the transition between different traffic states. In addition to the one-dimensional configuration space, we generalize our discussions to the higher-dimensional case, where the observed temporal oscillation in traffic flow data is attributed to the curl of a vector field. We exhibit that our model can reproduce the main features of the observed fundamental diagram including the inverse-λ shape and the wide scattering of congested traffic data. When properly parameterized, the main feature of the data can be reproduced reasonably well either in terms of the oscillating congested traffic or in terms of the synchronized flow.     

Numerical simulation of the flow field in a thermal plasma reactor

A numerical simulation is presented for a thermal plasma reactor with particle-trajectory model in this paper.Turbulance is considered by using simple SGS model.Thegoverning equations are solved by means of the algorithm of SIMPLER.The calculatedresults give the velocity and the temperature fields within plasma reactor,and thetrajectories of the injected particles.     

A two-fluid model of gas-assisted atomization including flow through the nozzle,phase inversion,and spray dispersion

This paper describes a new approach to modelling compressible gas–liquid flows that undergo change of the continuous phase. The presented model includes the system of the ensemble averaged Navier–Stokes equations together with the particle number density equation for each phase. The constitutive equations that depend on the flow regime are obtained from many sub-models that have been developed alongside the main model. Droplet size is allowed to vary in the flow field but is considered constant within a control volume. Bubbles and droplets break-up and coalescence models are adapted to the flow conditions. The proposed model for atomization treats it as a catastrophic phase inversion that takes place over the surface determined by the local values of phase volume fractions. The model is applied to simulate the premixed air-assisted atomization of water in a nozzle-type device. The computational domain includes the nozzle and the surrounding area of the spray dispersion. The model performance has been verified by comparing the predicted and measured liquid flow rates in the spray as well as the pressure values along the nozzle wall. Computational results are analysed, and the main flow features are presented.     

Hysteresis and imperfection sensitivity in small ferromagnetic particles

The classical results of Stoner and Wohlfarth for the prediction of hysteresis loops in small ferromagnetic particles are extended to specimens of non-ellipsoidal shape, and shown to be a consequence of micromagnetics. The insensitivity to surface roughness is proposed as a possible explanation of the high coercivity behavior of small particles.

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Sommario Si deducono i classici risultati di Stoner e Wohlfarth dalla teoria del micromagnetismo, e si dimostra la loro validità per la previsione di cicli di isteresi magnetica anche per particelle di forma non ellissoidale. Viene proposta, quale possibile spiegazione della notevole ampiezza dei cicli di isteresi caratteristici di particelle di piccole dimensioni, l'indifferenza alla presenza di rugosità superficiale.

     

Investigation of the effects of two parallel wires' non-uniform magnetic field on heat and biomagnetic fluid flow in an aneurysm

ABSTRACT

In this paper, effects of two wires magnetic field on heat transfer and biomagnetic fluid flow in an aneurysm have been investigated using the ferrohydrodynamics model. Using the finite volume method and the SIMPLE algorithm, the governing equations have been discretised. Simulations have been carried out for both conditions of wires in the same and opposite directions and different magnetic numbers of 41 and 82. Results show that the magnetic field causes a decrease in heat transfer of blood flow towards the walls. Moreover, major energy loss or pressure drop, arising from mean wall shear stress, decreases but local or minor energy loss, arising from aneurysm vortexes, increases. Furthermore, risk factors of aneurysm rupture is decreased under the effect of the magnetic field. The effective contact surface between drug-coated magnetic nanoparticles and the aneurysm tissue may increase and residence time of drug on the cells of the region would decrease.     

A finite strain model of stress, diffusion, plastic flow, and electrochemical reactions in a lithium-ion half-cell

We formulate the continuum field equations and constitutive equations that govern deformation, stress, and electric current flow in a Li-ion half-cell. The model considers mass transport through the system, deformation and stress in the anode and cathode, electrostatic fields, as well as the electrochemical reactions at the electrode/electrolyte interfaces. It extends existing analyses by accounting for the effects of finite strains and plastic flow in the electrodes, and by exploring in detail the role of stress in the electrochemical reactions at the electrode-electrolyte interfaces. In particular, we find that that stress directly influences the rest potential at the interface, so that a term involving stress must be added to the Nernst equation if the stress in the solid is significant. The model is used to predict the variation of stress and electric potential in a model 1-D half-cell, consisting of a thin film of Si on a rigid substrate, a fluid electrolyte layer, and a solid Li cathode. The predicted cycles of stress and potential are shown to be in good agreement with experimental observations.     

Atomistically determined phase-field modeling of dislocation dissociation,stacking fault formation,dislocation slip,and reactions in fcc systems

The purpose of the current work is the development of a phase field model for dislocation dissociation, slip and stacking fault formation in single crystals amenable to determination via atomistic or ab initio methods in the spirit of computational material design. The current approach is based in particular on periodic microelasticity (Wang and Jin, 2001, Bulatov and Cai, 2006, Wang and Li, 2010) to model the strongly non-local elastic interaction of dislocation lines via their (residual) strain fields. These strain fields depend in turn on phase fields which are used to parameterize the energy stored in dislocation lines and stacking faults. This energy storage is modeled here with the help of the ”interface” energy concept and model of Cahn and Hilliard (1958) (see also Allen and Cahn, 1979, Wang and Li, 2010). In particular, the “homogeneous” part of this energy is related to the “rigid” (i.e., purely translational) part of the displacement of atoms across the slip plane, while the “gradient” part accounts for energy storage in those regions near the slip plane where atomic displacements deviate from being rigid, e.g., in the dislocation core. Via the attendant global energy scaling, the interface energy model facilitates an atomistic determination of the entire phase field energy as an optimal approximation of the (exact) atomistic energy; no adjustable parameters remain. For simplicity, an interatomic potential and molecular statics are employed for this purpose here; alternatively, ab initio (i.e., DFT-based) methods can be used. To illustrate the current approach, it is applied to determine the phase field free energy for fcc aluminum and copper. The identified models are then applied to modeling of dislocation dissociation, stacking fault formation, glide and dislocation reactions in these materials. As well, the tensile loading of a dislocation loop is considered. In the process, the current thermodynamic picture is compared with the classical mechanical one as based on the Peach-Köhler force.     

Review of two-phase flow and flow boiling of mixtures in small and mini channels

Two-phase flow and flow boiling phenomena of fluidic mixtures in small and mini channels are becoming important in the miniaturization of thermal systems. This paper aims to present a state-of-the-art review in this important area and to identify what have been done so far and what still need to be done in the future. Firstly, various definitions of small and mini channels are described and the criteria based on these definitions are compared with each other. Comments on different viewpoints of the channel size classifications are acknowledged. Secondly, the background of two-phase flow and flow boiling of mixtures is described. Then, the current research status of two-phase flow and flow boiling of mixtures in normal size channels is presented as it is a basis for the study of two-phase flow and flow boiling of mixtures in small and mini channels. Finally, an overall review of two-phase flow and flow boiling of mixtures in small and mini channels is presented. It is concluded that the available study of two-phase flow and flow boiling of mixtures in small and mini channels is rather scarce and a systematic knowledge of two-phase flow and flow boiling of mixtures in small and mini channels is required. Based on this review, the future research directions including both fundamental and applied research in this area have been indicated.     

Convection,diffusion and reaction inside a spherical porous pellet in the presence of oscillatory flow

The problem of convection, diffusion and reaction inside a spherical porous pellet is investigated analytically. Unsteady Stokes equation is used for the flow outside the porous pellet and Darcy’s law is used inside the pellet. A solenoidal decomposition method is employed for the hydrodynamic problem. Following the above findings, the convection–diffusion–reaction problem is formulated and solved analytically for a first order reaction. The behavior of the nutrient transport is discussed with respect to various parameters like Darcy number, Peclet number, frequency and Thiele modulus. Also the effectiveness factor corresponding to the first order reaction is computed.     

Adiabatic and diabatic two-phase venting flow in a microchannel

The growth and advection of the vapor phase in two-phase microchannel heat exchangers increase the system pressure and cause flow instabilities. One solution is to locally vent the vapor formed by capping the microchannels with a porous, hydrophobic membrane. In this paper we visualize this venting process in a single 124 μm by 98 μm copper microchannel with a 65 μm thick, 220 nm pore diameter hydrophobic Teflon membrane wall to determine the impact of varying flow conditions on the flow structures and venting process during adiabatic and diabatic operation. We characterize liquid velocities of 0.14, 0.36 and 0.65 m/s with superficial air velocities varying from 0.3 to 8 m/s. Wavy-stratified and stratified flow dominated low liquid velocities while annular type flows dominated at the higher velocities. Gas/vapor venting can be improved by increasing the venting area, increasing the trans-membrane pressure or using thinner, high permeability membranes. Diabatic experiments with mass flux velocities of 140 and 340 kg/s/m² and exit qualities up to 20% found that stratified type flows dominate at lower mass fluxes while churn-annular flow became more prevalent at the higher mass-flux and quality. The diabatic flow regimes are believed to significantly influence the pressure-drop and heat transfer coefficient in vapor venting heat exchangers.