A Fe<Superscript>3+</Superscript>/Hg<Superscript>2+</Superscript>-Selective Anthracene-Based Fluorescent PET Sensor with Tridentate Ionophore of Amide/β-Amino Alcohol

A new anthracene-based fluorescent PET sensor 1 with a tridentate ionophore of amide/β-amino alcohol displays very good selectivity and sensitivity for Fe³⁺ (K _a = 1.6 × 10³ M⁻¹) and Hg²⁺ (K _a = 2.1 × 10³ M⁻¹) in CH₃CN–H₂O (3:7, v/v) with detection limit of 1 μM. More fluorescence enhancement was observed when 1 selectively detected Fe³⁺ or Hg²⁺ in CH₃CN and its detection limit was up to 0.03 μM.     

Contribution to the theory of Lorentzian ionization

The probability w _L of Lorentzian ionization, which arises when an atom or ion moves in a constant magnetic field, is calculated in the quasiclassical approximation. The nonrelativistic (v≲e ²/ℏ=1, v is the velocity of the atom) and ultrarelativistic (v→c=137) cases are examined and the stabilization factor S, which takes account of the effect of the magnetic field on tunneling of an electron, is found. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 5, 391–396 (10 March 1997)     

Magnetic and structural transitions in La1−x Sr x MnO3: T-x phase diagram

The electrical conductivity, magnetic susceptibility, magnetization, and submillimeter (v=5∓20 cm⁻¹) permittivity and dynamic conductivity of La_1−x Sr _x MnO₃ (0≤x≤ 0.45) single crystals are investigated. The anomalies in the temperature dependences of these quantities are identified with diverse magnetic and structural phase transformations, including antiferromagnetic and ferromagnetic ordering, structural transitions between strongly distorted (Jahn-Teller) and weakly distorted (pseudocubic) orthorhombic phases, structural transitions to a rhombohedral phase and unusual transitions to a polaron-ordering state. As a result, the complete T-x phase diagram of the system La_1−2x Sr _x MnO₃ is constructed in a wide interval of temperatures T=4.2∓1050 K and concentrations x=0−0.45. Pis’ma Zh. éksp. Teor. Fiz. 68, No. 4, 331–336 (25 August 1998)     

Preliminary results on the operation of a 2270 kg cryogenic gravitational-wave antenna with a resonant capacitive transducer and a d.c. SQUID amplifier

Summary In November 1985 the gravitational-wave antenna of the Rome group, installed at CERN, has started operating. It consists of a 5056 aluminium cilinder 3 m long, 2270 kg heavy, cooled at 4.2 K. The antenna vibrations are detected by means of a resonant capacitive transducer that together with the bar makes a two-coupled-oscillator system. The low-noise amplification is obtained with a d.c. SQUID amplifier. The frequencies of the two resonant modes are:v _-=907.116 Hz andv ₊=923.083 Hz, with merit factorsQ ₋=3.2·10⁶ andQ ₊=5.6·10⁶. The sensitivity to short gravitational bursts, expressed in terms of effective noise temperature, is 18 mK. This corresponds to a change in the metric tensor whose Fourier transform isH=1.1·10⁻²¹ Hz⁻¹. For monochromatic waves the antenna is sensitive (SNR=1) toh∼2·10⁻²⁵ in a band width of about 1/3 Hz, with a three months integration time.

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Riassunto Nel novembre 1985 è stata messa in funzione l'antenna gravitazionale del gruppo di Roma, installata al CERN. Questa consiste di un cilindro d'alluminio 5056 lungo 3 m e pesante 2270 kg, raffeeddato a 4.2 K. Le vibrazioni dell'antenna vengono rivelate mediante un transduttore capacitivo risonante, che assieme alla sbarra forma un sistema di due oscillatori accoppiati. L'amplificazione a basso rumore è ottenuta con un amplificatore a d.c.-SQUID. Le frequenze dei due modi risonanti sono:v _-=907.116 Hz ev ₊=923.083 Hz, con fattori di meritoQ ₋=3.2·10⁶ eQ ₊ =5.6·10⁶. La sensibilità per brevi fiotti di onde gravitazionali, espressa in termini di temperatura efficace di numore, è 18 mK. Questa corrisponde a una variazione di tensore metrico con trasformata di Fourier:H=1.1·10⁻²¹ Hz. Per le onde monocromatiche l'antenna è sensibile (SNR=1) ah∼2·10⁻²⁵ in una banda di circa 1/3 Hz, con tempo d'integrazione di tre mesi.

     

Effect of carbon ion bombardment and surface oxidation on the twinning rate of single-crystal bismuth

A study is made of the change in the dependences of the normal velocity of twinning boundaries on the magnitude of shear stresses in the twinning plane v _n =v _n (τ) in bismuth crystals owing to ion-cluster doping and oxidation of the irradiated surface. Irradiation was by 25 keV carbonions at a dose of 10¹⁷ ion/cm². Twinning of the crystals took place under pulsed loading conditions with pulse durations of 10⁻⁵−10⁻⁴ s and stress amplitudes of (0.2–2.0)×10³ g/mm³. Carbon ion bombardment of single-crystal bismuth causes a shift in the v _n =v _n (τ) curve toward lower stresses. An oxide film slows down the motion of twinning dislocations. Zh. Tekh. Fiz. 69, 130–131 (May 1999)     

Electronic thermal capacity in one-dimensional mesoscopic rings

Summary We have investigated the Aharonov-Bohm (AB) effects of electronic thermal capacityC _v in a one-dimensional normal ring using the free-electron model. The results show that the thermal capacity is an oscillation function of external magnetic flux with periods ϕ₀=hc/e, ϕ₀/2, ϕ₀/3,... The amplitude of the capacity fluctuation decreases when temperature increases forT>3T ^* (T ^*=ħ V _F/(K _BπL)). We suggest an appropriate temperatureT∼3T ^* to observe in experiment the capacity-flux characteristic for metallic rings. The authors of this paper have agreed to not receive the proofs for correction.     

Thermal conductivity of YbInCu4

The electrical and thermal conductivities of an YbInCu₄ polycrystalline sample have been measured within the 4.2–300-K range. The behavior of the heat conductivity has been found to change sharply above and below T _v =70–75 K, the temperature corresponding to an isostructural phase transition from a state with an integral valence (T>T _v ) to a mixed-valence state (T<T _v ) of Yb ions. A preliminary qualitative analysis of the results is presented. Fiz. Tverd. Tela (St. Petersburg) 41, 1548–1551 (September 1999)     

Fourier spectrometry: Rovibrational analysis of an infrared Π → Σ system of yttrium monoiodide

The infrared spectrum of yttrium monoiodide has been excited in an electrodeless microwave discharge and explored between 2500 and 12 000cm⁻¹ with a high-resolution Fourier transform spectrometer. A unique system is observed (ν₀₀ = 9905.520 cm⁻¹), which we attribute to a ¹Π → ¹Σ transition and an extensive analysis is made. Rovibrational constants are obtained for both states mainly from a simultaneous multiband fitting. This procedure is applied to the whole set of 2231 observed line wavenumbers in the 1-0, 0-0, and 0–1 bands, yielding a final weighted standard deviation of 0.0038 cm⁻¹. Furthermore, a partial analysis of the 2-0 and 3-1 bands is performed. The following equilibrium constants are derived (cm⁻¹): ω′_e=192.210 ω′_ex′_e=0.463B′_e=0.0399133 α′_e=0.0001150ω″_e=215.815 ω″_ex″_e=0.514B″_e=0.0422163 α″_e=0.0001125 High-order constants D_v and H_v are also calculated for the various vibrational levels (v′ = 0, 1, 2, 3; v″ = 0, 1).     

Upper limit on the solar antineutrino flux according to LSD data

The experimental data obtained on the liquid scintillation detector LSD are analyzed for the purpose of searching for the solar electron antineutrino flux predicted in the model of spin-flavor precession of the neutrino. The currently most accurate upper limit on the solar v̄_e/v _e flux ratio is established: Φ_v̄/Φ_v⩽1.7% (90% confidence range). Pis’ma Zh. éksp. Teor. Fiz. 63, No. 10, 753–757 (25 May 1996) The spelling of the authors names are presented here in English as requested by the Russian Editorial office.     

Ionization of hydrogen and helium atoms by highly charged fast ions in collisions with small momentum transfer

Ionization of hydrogen and helium atoms is studied for the case of “soft” collisions with highly charged fast ions with v≲Z≪v² and v≫v ₀, where Z is the ion charge, v is the collision velocity, and v ₀∼1 is the characteristic velocity of the electron in the ground state of the atom. Analytical expressions are derived for the singly and doubly differential cross section for ionization of a hydrogen atom accompanied by the ejection of a slow electron v _e≲v ₀, where v _e is the velocity of the ejected electron with respect to the recoil ion). The results are generalized to the case of single ionization of helium. It is shown that soft collisions provide the main contribution to the hydrogen ionization cross section and for all practical purposes determine the cross section for single ionization of helium. The asymmetry in the angular distribution of the ejected slow electrons and the properties of momentum exchange in such collisions are discussed. Finally, a formula for the cross section for single ionization of helium is proposed. Zh. éksp. Teor. Fiz. 112, 1966–1977 (December 1997)     

TDPAC studies of Hf doped YBCO

Time differential perturbed angular correlation measurements of the 133–482 keVγ-γ cascade of¹⁸¹Ta in Hf-doped YBa₂Cu₃O_7−x are presented. The¹⁸¹Hf precurser nuclei are incorporated into the sample by thermal neutron irradiation. Two quadrupole interaction frequencies are observed in the as-irradiated sample:v _Q1=161±10 MHz with intensityf ₁=75%, asymmetry parameterη ₁=0.32 and damping parameter Λ₁=0.42, andv _Q2=1108±40 MHz withf ₂=25%,η ₂=0.62, and Λ₂=0.60. On annealing the sample in air at various temperaturesT _a and quenching to room temperature,f ₁ remained nearly constant forT _a<600°C andv _Q1 for all annealing temperatures indicating that these are insensitive to oxygen stoichiometry. This frequency is interpreted to be due to¹⁸¹Hf substitutingY sites. BeyondT _a=600°C,f ₁ increased and reached a constant value of 90% forT _a=800°C. The value ofv _Q2 showed a slight variation between 1086 and 1160 MHz, whilef ₂ remained nearly constant at 25% forT _a<600°C. This component is identified to be due to¹⁸¹Hf substituting Cu 1 sites in the Cu-O chains of YBCO. Above 600°Cv _Q2 decreased and reached a value of 808 MHz beyond 750°C.     

Coherent backscattering of electromagnetic waves in a magnetised plasma

Summary A microwave coherent backscattering experiment has been carried out on Mirabelle, a weakly ionised plasma device, with the objective of measuring the electron density fluctuation level. The experiment is a preliminary step in order to prepare the detection system for a microwave stimulated backscattering experiment. The incident electromagnetic wave is focused in front of a plane grid which excites ion acoustic or electron Bernstein waves inducing fluctuations in the plasma. The backscattering signal is collected by the launching circuit and detected by homodyne mixing. The typical ratio of the scattered power to the incident power is about 10⁻¹² and the relative density fluctuations are of the order of δn _e/n _e=10⁻³ against a background electron density ofn _e=1–5·10⁹ cm⁻³. The backscattering measurement is compared with Langmuir probe measurements. The spectral width of the backscattered signal has also been studied, by taking into account effects due to the incident wave focusing and plasma wave damping. The authors of this paper have agreed to not receive the proofs for correction     

Magnetooptical microwave spectroscopy of the coherent magnetic state in the mixed valence compound SmB6 in the frequency range 40–120 GHz

In undoped pure single crystals of the mixed valence compound SmB₆ anomalous ESR absorption is observed in the frequency range v=40–120 GHz at temperatures of 1.8–4.2 K. The ESR for the case of the coherent ground state consists of two components corresponding to g-factors g ₁=1.907±0.003 and g ₂=1.890±0.003. The amplitude of both ESR lines strongly depends on temperature in the temperature range studied: the amplitude of the first line with g=g ₁ increases and the amplitude of the second line decreases with temperature. A model based on consideration of intrinsic defects in the SmB₆ crystalline lattice, with a densit ∼10¹⁵−10¹⁶ cm⁻³, is suggested as an explanation for the anomalous ESR-behavior. In the frequency range v>70 GHz at T=4.2 K, in addition to the main ESR lines, a new magnetic resonance with a hysteretic field dependence is discovered. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 10, 707–712 (25 November 1996) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Electron fluid and quasiparticles in the quantum Hall effect

To explain fractional quantum Hall effect, it is necessary to take into account both the interaction between electrons and their interaction with impurities. We propose a simple model, where the Coulomb repulsion is replaced by a short range potential. For this model we are able to find many-body wave functions of the electron system interacting with impurities and calculate the Hall conductivityσ _xy. A simple physical picture, arising in the framework of this model, provides the understanding of a general reason for both fractional and integral quantum Hall effect. In the model, electrons forming a two-dimensional system, is supposed to occupy the first Landau level. The interaction of electrons is regarded as being small compared with the distance between the Landau levels. The radius of interaction is much less than the magnetic length. The following statements have been proved (Pokrovsky and Talapov 1985a,b; Trugman and Kivelson 1985). For the fillingν=1/m of the first Landau level the ground state is nondegenerate and has the wave functionΩ _w, proposed by Laughlin (1983). Forν, which is slightly less than 1/m the ground state is highly degenerate in the absence of impurities. It can be described as a system of noninteracting quasiholes as proposed by Laughlin (1983). These quasiholes float in the uniform incompressible fluid. Each quasihole has the charge |e|/m. The total number of quasiholes isq=S?mN, whereS is a number of states on the Landau level,N is the number of electrons. The impurities capture quasiholes. If the number of quasiholesq is less than the number of impuritiesN _i, then the ground state becomes nondegenerate. This fact permits us to calculateσ _xy (Pokrovsky and Talapov 1985b). Let there be a small electric fieldE in the system. In the absence of impurities the electron fluid is at rest in the frame of reference, moving with velocityν=cE/H. In this frame of reference the impurities move with the velocity ?v, carrying captured quasiholes. Therefore, the quasihole currents isj _q=(?ν)(| e|/m)q. Hence, in the initial frame of reference the total current isj=Nev+j _q=Sev/m. This means thatσ _xy=(1/m)e ²/2π?).     

Evaluation of the rate constants of dissociative and ternary recombination reactions of argon ions on the basis of the results of ballistic experiments

AbstractExperimental data on the change in the electron density in the wake of a ballistic object traveling at velocities V _∞=3.4–4.9 km/s in argon at pressures p _∞=30–100 Torr are processed and analyzed. A reaction scheme is proposed which takes into account the recombination of charged particles, processes of ionic conversion, and the excited states of the atom. The solution of the equations of a nonequilibrium boundary layer for flow in the wake is used to formulate the inverse problem of determining the rate constants for dissociative recombination Ar ₂ ⁺ +e→Ar+Ar and ternary recombination Ar⁺+e+Ar→Ar+Ar. The “nearest-neighbor” approximation is used to obtain theoretically an expression for the ternary recombination coefficient as a function of temperature and pressure. Numerous solutions of inverse problems and a comparison with experiments demonstrates the validity of the expression obtained for the ternary recombination coefficient. It is shown that this expression is valid for moderate pressures and complements the Pitaevskii result for low pressures and the Langevin result for high pressures. Zh. Tekh. Fiz. 67, 12–18 (May 1997)     

Synchrotron and annihilation channels for axion production in an external electromagnetic field

We consider axion formation processes in the synchrotron (e ⁻→e ⁻ a) and annihilation (e ⁻ e ⁺→a) channels in a constant crossed field F _μν F^μν=Fμν*F ^μν =0, which approximates constant fields of other configurations in the ultrarelativistic asymptotic limit. The probability and intensity of axion emission are obtained, and we analyze the energy and field asymptotics. A comparison with the characteristic neutrino channel yields the constraints on the axion mass and the energy scale for Peccei-Quinn symmetry breaking. Possible astrophysical applications are discussed. Zh. éksp. Teor. Fiz. 112, 25–31 (July 1997)     

Propagation of axions in a strongly magnetized medium

The polarization operator of an axion in a degenerate gas of electrons occupying the ground-state Landau level in superstrong magnetic fields H≫H ₀=m _e ² c ³/eℏ=4.41×10¹³ G is investigated in a model with a tree-level axion-electron coupling. It is shown that a dynamic axion mass, which can fall within the allowed range of values 10⁻⁵ eV≲m _a≲10² eV, is generated under the conditions of strongly magnetized neutron stars. As a result, the dispersion relation for axions is appreciably different from that in a vacuum. Zh. éksp. Teor. Fiz. 115, 3–11 (January 1999)     

Kinematics of Cherenkov’s effect with noninvariant velocity of light

The kinematics of Cherenkov’s effect is considered for an electron moving in the Minkowski space with universal time and velocity of light c = c ₀ (1 + v ²/c ₀²)^1/2, where c ₀ = 3⋅10 m/s is the invariant constant and v is the particle velocity. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 47–50, January, 2009.