飞秒脉冲激光加热金属薄膜的理论和实验研究

超短脉冲激光加热可应用于研究材料中载能子之间的超快相互作用,同时也广泛应用于超快激光加工.此前人们提出的双温度模型和抛物一步模型都只能用于描述超短脉冲激光加热金属薄膜后热量传递过程的特定片段.基于双温度模型和傅里叶导热定律,提出普适的理论模型可用于完整描述飞秒激光加热金属薄膜/基底时的整个热量传递过程.同时在300 K温度下,采用背面抽运-表面探测瞬态热反射法实验研究了飞秒脉冲激光加热金属薄膜的热量传递过程,理论预测曲线和实验测量结果符合较好,验证了理论模型的正确性.基于此模型测量得到了金薄膜的电子-声子 关键词： 飞秒脉冲激光 电子-声子耦合 界面热导 瞬态热反射     

飞秒激光热反射系统测量金属薄膜中的热波

金属材料中的热波现象可以利用包含电子弛豫时间影响的双曲两步模型进行理论分析.通过飞秒激光热反射实验系统对金属薄膜材料进行了测量.利用偏振分光棱镜将飞秒激光分成抽运光和探测光,其中较强的抽运光用于加热金属薄膜而较弱的探测光用于探测薄膜表面反射率随时间的变化,两束光之间的光程差通过步进电机进行精确控制.利用金属薄膜反射率和电子温度的正比例关系就可以得到电子温度随时间的变化规律.实验发现在加热激光脉冲过后的电子温度下降区间会出现另一个较弱的电子温度波峰,并利用相同厚度的两块金属薄膜样品重复测量对实验结果进行了验证.理论上这一现象可以解释为金属薄膜中热波在背面反射的结果,并且实验结果和双曲两步模型给出的热波理论计算结果相符合.根据实验结果计算出热波传递速度约为5×105m/s,对应的电子弛豫时间为60fs.     

温度和压力对Au反射特性影响及动高压下的测温应用分析

基于金属电子气模型,进行了温度、压力对Au反射率变化影响的研究与分析。利用DAC装置开展了压力对Au反射率变化测量实验,以及激光加热的动态温升条件下温度对Au反射率变化测量实验,获得了探测光束波长为488 nm条件下,温度(室温至350 ℃)和压力(11 GPa范围内)对Au反射特性影响的实验结果。结果表明：在11 GPa压力范围内,与温度因素相比,压力对Au的反射率变化影响可忽略;Au对488 nm波长激光的反射率变化趋势为单调递增,变化幅值达约10%,且具有反射率与温度的一一对应特性。通过动高压加载下材料温度瞬态测量要求分析,认为基于Au在488 nm波长下的反射变化特性,可建立一种适用于动高压加载下低温段(低于1000 K)的瞬态测温方法,用于解决材料动高压领域的瞬态测温技术难点。     

温度和压力对Au反射特性影响及动高压下的测温应用分析

基于金属电子气模型,进行了温度、压力对Au反射率变化影响的研究与分析。利用DAC装置开展了压力对Au反射率变化测量实验,以及激光加热的动态温升条件下温度对Au反射率变化测量实验,获得了探测光束波长为488 nm条件下,温度(室温至350 ℃)和压力(11 GPa范围内)对Au反射特性影响的实验结果。结果表明:在11 GPa压力范围内,与温度因素相比,压力对Au的反射率变化影响可忽略;Au对488 nm波长激光的反射率变化趋势为单调递增,变化幅值达约10%,且具有反射率与温度的一一对应特性。通过动高压加载下材料温度瞬态测量要求分析,认为基于Au在488 nm波长下的反射变化特性,可建立一种适用于动高压加载下低温段(低于1000 K)的瞬态测温方法,用于解决材料动高压领域的瞬态测温技术难点。     

多晶碲化锌薄膜载能子超快动力学实验研究

利用双波长飞秒激光抽运-探测实验方法测量了掺氮多晶ZnTe薄膜在飞秒激光加热情况下载能子超快动力学过程. 采用包含电子弛豫过程和晶格加热过程的理论模型拟合实验数据, 二者符合得很好. 拟合得到10 ps以内影响掺氮多晶ZnTe薄膜表面超快反射率变化的三个弛豫过程的时间常数均为亚皮秒量级. 其中, 正振幅电子弛豫过程是由电子-光子相互作用引起的载流子扩散和带间载流子冷却过程, 负振幅电子弛豫过程是由缺陷造成的光激载能子的俘获效应引起的, 晶格加热过程主要通过电子-声子耦合过程进行的.     

飞秒脉冲激光作用下金属薄膜的热弹性研究

利用双曲-双温两步热传导和热电子崩力模型,考虑到晶格温度与应变速率的耦合效应,得到了用于描述飞秒激光作用下金属薄膜热力效应的超快热弹性模型。以飞秒脉冲激光辐照金属铜薄膜为例,运用具有人工粘性和自适应步长的有限差分算法,对不同能量密度和脉冲宽度条件下薄膜体内温度场和应力场的变化规律进行了数值模拟,对比分析了电子晶格耦合系数对超快加热过程的影响。结果表明,飞秒脉冲激光辐照早期为明显的非平衡加热过程,电子温度迅速升高,而晶格温度的升高却相对较慢;激光辐照早期的热力耦合效应导致薄膜前表面附近的热应力表现为压应力,随着时间的推移,热应力由压应力转变为张应力,为激光加工和激光对抗提供了理论参考。     

室温下金属中电子格林艾森常数的测量

在室温条件下用自己研制的超快电子衍射实验设备精确测量了金属铝的电子格林艾森常数(γ_e).当飞秒脉冲激光瞬间加热铝膜时,电子和晶格对固体热膨胀的作用在时间域上是不同步的,借助于超快电子衍射实验设备的高时间分辨能力,可以摆脱以往测量非磁性金属材料时低温的限制,在室温条件下,实验通过直接观测瞬间加热的铝膜中电子和晶格对热膨胀的不同贡献得到电子的格林艾森常数. 关键词： 格林艾森常数 超快电子衍射 晶格热运动 电子热运动     

1.06 μm连续激光辐照TiO2/SiO2/K9薄膜元件温升规律研究

利用1．06μm连续激光在不同强度下辐照TiO2／SiO2／K9薄膜元件,实验中用红外热像仪测量激光辐照在TiO2／SiO2／K9元件表面引起的温升随时间的变化,通过数据处理,获得激光辐照区域最高温度随辐照时间的增加而增加。同时,给出材料温升随材料发射率的变化关系。并用程序模拟不同激光强度下薄膜温度场的分布,通过实验测量数据校正数值模拟计算结果,给出TiO2／SiO2／K9薄膜元件温度随激光辐照强度和辐照时间的变化规律。并且获得在薄膜厚度方向：薄膜表面温度最高,基底与薄膜接触处温度最低;沿径向：激光辐照中心温度最高,边沿温度最低。     

1.06 μm连续激光辐照TiO2/SiO2/K9薄膜元件温升规律研究

利用1.06 μm连续激光在不同强度下辐照TiO2/SiO2/K9薄膜元件,实验中用红外热像仪测量激光辐照在TiO2/SiO2/K9元件表面引起的温升随时间的变化,通过数据处理,获得激光辐照区域最高温度随辐照时间的增加而增加。同时,给出材料温升随材料发射率的变化关系。并用程序模拟不同激光强度下薄膜温度场的分布,通过实验测量数据校正数值模拟计算结果,给出TiO2/SiO2/K9薄膜元件温度随激光辐照强度和辐照时间的变化规律。并且获得在薄膜厚度方向：薄膜表面温度最高,基底与薄膜接触处温度最低;沿径向：激光辐照中心温度最高,边沿温度最低。     

1.06μm连续激光辐照TiO_2/SiO_2/K_9薄膜元件温升规律研究

利用1.06μm连续激光在不同强度下辐照TiO2/SiO2/K9薄膜元件,实验中用红外热像仪测量激光辐照在TiO2/SiO2/K9元件表面引起的温升随时间的变化,通过数据处理,获得激光辐照区域最高温度随辐照时间的增加而增加。同时,给出材料温升随材料发射率的变化关系。并用程序模拟不同激光强度下薄膜温度场的分布,通过实验测量数据校正数值模拟计算结果,给出TiO2/SiO2/K9薄膜元件温度随激光辐照强度和辐照时间的变化规律。并且获得在薄膜厚度方向:薄膜表面温度最高,基底与薄膜接触处温度最低;沿径向:激光辐照中心温度最高,边沿温度最低。     

基于改进布谷鸟算法识别瞬态热传导问题的导热系数

基于改进布谷鸟算法反演瞬态热传导问题随温度变化的导热系数.采用Kirchhoff变换将非线性热传导问题转换为线性热传导问题,使用边界元法求解瞬态热传导正问题.将导热系数的反演转化为函数表达式中未知参数的反演,使用改进布谷鸟算法求解未知参数.与共轭梯度法相比,改进布谷鸟算法对迭代初值不敏感;与布谷鸟算法相比,改进布谷鸟算法迭代次数大大减少.数值算例表明对改进布谷鸟算法,增加测点数量迭代次数增加;增加鸟巢数量迭代次数减少;减小测量误差计算结果更精确,同时迭代次数更少.数值算例验证了改进布谷鸟算法反演导热系数的准确性和有效性.     

纳米悬浮液热导率测量及其预测模型的探讨

纳米颗粒悬浮液具有广泛应用于强化传热的潜在优势。本文采用加入表面活性剂的方法提高纳米悬浮液的悬浮稳定性,并用瞬态热线法测量了热导率。在分析现有理论模型和纳米悬浮液热导率影响因素研究的基础上,从弹性传动和非弹性传动两方面分析了纳米尺度效应导致纳米悬浮液热导率提高的机理。发现已有的理论公式仍然存在一定欠缺,预测值比实验值偏低,有关机理尚有待于深入探讨。     

Modelling of thermal conductance during microthermal machining with scanning thermal microscope using an inverse methodology

In this study, a general methodology for determining the thermal conductance between the probe tip and the workpiece during microthermal machining using Scanning Thermal Microscopy (SThM) has been proposed. The processing system was considered as an inverse heat conduction problem with an unknown thermal conductance. Temperature dependence for the material properties and thermal conductance in the analysis of heat conduction is taken into account. The conjugate gradient method is used to solve the inverse problem. Furthermore, this methodology can also be applied to estimate the thermal contact conductance in other transient heat conduction problems, like metal casting process, injection molding process, and electronic circuit systems.     

Conservation laws and associated Lie point symmetries admitted by the transient heat conduction problem for heat transfer in straight fins

Some new conservation laws for the transient heat conduction problem for heat transfer in a straight fin are constructed. The thermal conductivity is given by a power law in one case and by a linear function of temperature in the other. Conservation laws are derived using the direct method when thermal conductivity is given by the power law and the multiplier method when thermal conductivity is given as a linear function of temperature. The heat transfer coefficient is assumed to be given by the power law function of temperature. Furthermore, we determine the Lie point symmetries associated with the conserved vectors for the model with power law thermal conductivity.     

Analysis of the Properties of Fractional Heat Conduction in Porous Electrodes of Lithium-Ion Batteries

Research on the heat transfer characteristics of lithium-ion batteries is of great significance to the thermal management system of electric vehicles. The electrodes of lithium-ion batteries are composed of porous materials, and thus the heat conduction of the battery is not a standard form of diffusion. The traditional heat conduction model is not suitable for lithium-ion batteries. In this paper, a fractional heat conduction model is used to study the heat transfer properties of lithium-ion batteries. Firstly, the heat conduction model of the battery is established based on the fractional calculus theory. Then, the temperature characteristic test was carried out to collect the temperature of the battery in various operating environments. Finally, the temperature calculated by the fractional heat conduction model was compared with the measured temperature. The results show that the accuracy of fractional heat conduction model is higher than that of traditional heat conduction model. The fractional heat conduction model can well simulate the transient temperature field of the battery. The fractional heat conduction model can be used to monitor the temperature of the battery, so as to ensure the safety and stability of the battery performance.     

Numerical Simulation of the Non-Fourier Heat Conduction in a Solid-State Laser Medium

A hyperbolic model of non-Fourier heat conduction with non-uniform heat source is used to simulate the transient heat transfer in a high-pulse-pumped solid-state laser medium. The temperature fields are numerically analysed using the finite difference method combined with the TDMA algorithm for different pump power densities, pulse durations, thermal relaxation time and cooling intensities, respectively. The calculated results are compared with those predicted by the parabolic heat conduction model based on the Fourier law. The results indicate that the non-Fourier heat conduction phenomenon in laser media should be considered when the pump power density exceeds 104 W/m^2 or under low pulse duration. In addition, the conditions of non-Fourier effects and their influencing factors are analysed.     

含对流与蒸发表面的有限厚度材料的双曲型热传导分析

本文对于含有对流与蒸发表面的有限厚度材料,在遭受一脉冲表面热流作用时的双曲型热传导进行了分析,采用热势函数描述的双曲型热传导方程来描述该问题,并用有限差分法进行数值求解．同时,本文还就表面对流与蒸发对材料表面与内部瞬态温度变化的影响以及材料双曲型热传导对表面蒸发的影响进行了分析．     

0.53 μm毫秒脉冲激光对GaAs热分解损伤特性

针对波长0.53 m的毫秒脉冲激光辐照GaAs的表面热分解损伤问题,建立了二维轴对称热传导模型,在考虑材料的热物性参数随温度变化的基础上,采用有限元法模拟了材料的瞬态温度场,得到了温度场分布特征及其随时间的变化规律,给出了材料表面发生热分解损伤阈值曲线。数值结果表明：毫秒脉冲激光对GaAs作用时,热传导影响着激光作用全过程,对应的损伤机理主要为热损伤;在激光作用下,被作用表面中心处温度最高,并且首先发生热分解损伤;随着作用激光能量密度的增加,GaAs表面发生热分解损伤的时刻不断提前。     

Experimental Validation of a Two-Dimensional Model of the Transient and Steady-State Characteristics of a Wicked Heat Pipe

Abstract

The transient behavior of a copper-water wicked (80 mesh SS-304 screen) heat pipe during start-up is studied. The transient axial temperature distributions are measured and successfully compared for all the three sections of the heat pipe with the numerical solution of a developed two-dimensional model that utilizes the concept of a growing thermal layer in the wall and the wick region and takes into account axial conduction during transient operation. Steady-state temperature profiles are obtained as a limiting case. The experimental and theoretically predicted time required to attain steady state are in close agreement as well.     

Thermal Conductivity Measurement of Gases by the Transient Short-Hot-Wire Method

Measurements of the thermal conductivity of helium and hydrogen are performed using the transient short-hot-wire method. The short hot wire is made of platinum and has a diameter of about 10 μm and a length of about 15 mm. It is attached by spot welding to platinum terminals with a diameter of 1.5 mm. The probe is inserted into the sample vessel that has a volume of 35 cm³ and an inner diameter of 30 mm. The thermal conductivity is evaluated by comparing a numerical solution of the heat conduction in and around the short wire with the experimentally obtained temperature rise of the wire. The measured thermal conductivities show good reproducibility. Also, the measured thermal conductivities agree with the reference equations within a deviation of ± 1%.