低功率电弧放电辅助甲烷燃烧的实验研究

利用低功率电弧放电辅助甲烷燃烧,研究了在不同甲烷/空气比例的情况下,等离子体对甲烷燃烧的影响。采用发射光谱仪进行光谱诊断,比较有/无等离子体辅助甲烷燃烧火焰发射光谱的异同,讨论了等离子体辅助燃烧可能发生的过程和机理。比较有/无等离子体辅助甲烷燃烧火焰温度的变化。利用气相色谱和烟气分析仪对甲烷燃烧产物中的CH₄、CO 和O₂ 进行分析。实验结果表明,加等离子体后,火焰的温度升高,尾气中的可燃性成分减少,氧气含量降低,在很大程度上提高了甲烷的燃烧效率;甲烷/空气的比例越低,燃烧效率的提高越明显;甲烷的富燃燃烧极限从16%调高到21%。     

湿天然气凝结流动的双组分模型

基于气液相间滑移的影响,建立了适用于湿天然气凝结系统的水蒸气-甲烷双组分自发凝结流动数理模型,研究了水蒸气在以甲烷为载气的超声速流动中的凝结规律,对比了不考虑相间滑移的单流体模型与加入了相间滑移因素的双组分模型在自发凝结过程中的凝结规律的区别,分析了压力、温度对湿天然气在Laval喷管中自发凝结的影响.结果表明,湿天然气中相间滑移作用对凝结参数影响较大,本文建立的包含相间滑移因素的双组分模型能更准确的预测湿天然气的凝结特性;在凝结初始阶段相间滑移速度较大达到7.2 m/s,对湿天然气的自发凝结规律影响较大,随凝结过程的不断进行气液两相逐渐达到平衡,相间滑移速度逐渐降低至1.8 m/s;随入口温度的降低、入口压力的升高最大凝结成核率位置向入口方向移动。     

甲烷-煤尘爆炸物火焰传播特性

 在10 m³的爆炸罐中对体积分数为8%的甲烷和75 g/m³煤尘的混合物进行了系统的燃烧爆炸实验。分别利用光测方法和压力方法得到了爆炸物的层流燃烧速度、火焰传播速度、火焰厚度、马克斯坦长度以及爆炸特征值的变化规律。结果表明,在常温常压下,当点火能为40 J时：利用光测法得到的8%甲烷与75 g/m³煤尘混合物的燃烧速度为0.437 m/s,而根据压力-时间关系得到的混合物燃烧速度为0.459 m/s,两者符合较好;用火焰厚度与马克斯坦长度判定的火焰发展趋势相同,即向外传播的火焰趋于稳定;爆炸物的爆炸特征值最大值出现在0.5 m处,壁面的爆炸特征值偏小。     

微通道粗糙度对甲烷催化燃烧影响的数值研究

采用详细化学反应机理对甲烷空气预混气体在不同粗糙度下微通道内催化燃烧进行了数值模拟。结果表明:粗糙度的存在使得微通道内甲烷转化率减小,出口温度降低,粗糙表面将阻碍催化反应的进行,而且粗糙度越大这种阻碍作用越大;在同一粗糙度下,随着当量比、混合气入口速度的增加,粗糙度对催化反应的阻碍作用越明显,粗糙度越大,燃烧效率越低。     

入口温度对微型凹腔燃烧器中H_2/air燃烧效率的影响

通过数值模拟研究了入口温度对贫燃H_2/air混合气燃烧效率的影响。结果表明:当量比为0.5时,即使入口温度为300 K也能获得很高的燃烧效率,而当量比为0.3和0.4时,由于火焰尖端发生分裂,导致燃料泄漏和燃烧效率下降。入口温度上升50~100 K时,火焰尖端分裂得到显著改善。分析表明:一方面,依据Arrhenius定律,提高混合气温度可以直接增加燃烧反应速率;另一方面,提高入口温度在一定程度上可以增加混合气的有效Lewis数;此外,提高入口温度可使火焰高度变小,削弱火焰拉伸效应的影响。总之,对于贫燃H_2/air火焰来说,小幅提高混合气的初始温度就能明显增加火焰尖端的燃烧强度,抑制火焰尖端分裂现象的发生,提高燃烧效率。     

惰性多孔介质内过滤燃烧特性分析

以惰性堆积床内甲烷/空气低速过滤燃烧为例,因次分析系统特征尺度,基于修正的单温度模型,提出一种封闭的耦合解析方法,对燃烧过程进行理论分析.研究了燃烧波波速、火焰传播速率、最高燃烧温度等燃烧特性参数,将计算结果与实验结果以及前人的理论结果进行对比.     

氩气/甲烷/空气介质阻挡放电等离子体的发射光谱诊断

为了获得可燃气体的放电及等离子体发射光谱特性,进一步揭示等离子体助燃作用下燃料在稀燃状态的点火与燃烧特性,在常压下以氩气作为载气对预混的甲烷和空气进行放电研究。实验基于平行板电极射频(13.56 MHz)介质阻挡放电的等离子体发生装置,首先在常压下对体积分数为90%氩气/10%空气的混合气体开展放电研究;再在90%氩气含量不变的情况下,调节空气含量并加入与之能形成燃烧化学当量比Φ＝1的甲烷,氩气/甲烷/空气的混合气体同样能实现稳定而均匀的放电;最后分别在90%氩气含量不变,甲烷和空气在当量比为Φ＝0.4～1.9六种情况下进行放电实验。由光谱仪记录不同放电工况下的发射光谱信息,诊断反应产物类型,利用观测到的氮分子第二正带系(0-2)380.4 nm和(1-3)375.4 nm处的发射谱线,与自编程序计算的模拟谱线拟合,得出分子转动温度(即气体温度)。研究结果表明：通过拟合模拟光谱与实验所测发射光谱的方法推测分子转动温度,进而获得气体的平动温度,氩气/空气放电的气体温度可达到1 150 K,氩气/甲烷/空气Φ＝1时放电气体温度升高到1 390 K;甲烷与空气形成不同当量比时,所测等离子体气体温度相对于90%氩气/10%空气混合气体温度的温升在70～240 K范围变化;由光谱信息观测到CH,H,OH和CH₂O等活性粒子的存在以及气体温度的升高,表明可燃成分混合气在射频电场放电作用下发生等离子体燃烧化学反应并释放出化学热。     

燃煤锅炉微油点火燃烧器的数值计算分析

结合煤粉锅炉微油点火燃烧器的结构特点,用数值仿真软件对圆形截面燃烧器的内部燃烧特性进行了三维流动数值模拟,计算了从燃烧器入口到炉膛的燃烧特性.分析了一次、二次燃烧室两个方向上的温度、速度分布.模拟结果表明.燃烧器一次风速度的提高对煤粉气流的着火不利,太低又会引起堵粉,同时使一次燃烧室结焦的可能性增大;微油点火燃烧器在喷口处形成了风包火的着火工况,降低了燃烧器喷口边缘温度,改善了燃烧器的工作环境.     

温度对微通道CH4/O2/H2O自热重整暂态特性的影响

利用计算流体力学软件CFD和化学反应动力学软件CHEMKIN研究了微通道内催化壁面温度、反应混合气体初始温度对镍基催化剂上CH₄/O₂/H₂O自热重整反应暂态特性的影响。结果表明,微通道内的甲烷自热重整反应暂态特性与温度关系密切。温度越高,反应趋于平衡所需的时间越短;当反应器壁面温度较高时,提高反应混合气入口温度对反应影响不大;在相同的温升下,提高反应器壁面温度比提高反应混合气体初始温度对反应过程中氢气的产生和甲烷的转化更有利。     

阵列喷嘴干冰喷雾冷却特性数值研究

针对高热载荷电子设备散热冷却问题,开展阵列喷嘴干冰升华喷雾冷却特性数值模拟研究。分析了阵列喷嘴入口速度、喷雾高度和模拟热源加热热流密度对干冰喷雾冷却特性和温度均匀性的影响。结果表明：入口速度50 m/s时,热源表面平均温度达到最低值276.3 K;喷雾高度为3 mm时,热源表面的温度均匀性效果最佳。提高干冰入口速度和降低喷雾高度可强化冷却效果和热源表面热均匀性,模拟热源加热热流密度对干冰喷雾冷却换热系数影响不明显。     

流化床燃烧超低浓度煤层气的轴向气体分布

超低浓度煤层气由于甲烷含量低、浓度变化大而较难加以利用。采用实验和数值模拟的方法,研究了超低浓度煤层气在流化床中燃烧特性,得到燃烧产物的轴向分布规律,分析了进气浓度、床层温度、流化风速等因素对甲烷浓度轴向分布的影响。研究结果表明:随着床层高度的增加,无量纲甲烷浓度逐渐减小,在床层表面达到最小值,然后突然增加,随后达到稳定。实验范围内,CO浓度均小于20mL/m~3减小进气浓度、增加床层温度、降低流化风速部会使相同床层高度处的无量纲甲烷浓度减小。燃烧反应主要发生在密相区,随着进气浓度的减小、床层温度的增加、流化风速的降低,反应区域逐渐向床层下部移动。     

Methane flames in a jet impinging onto a wall

Traditionally, research has focused on positive stretch in the stagnation flow and negative stretch along the Bunsen flame. Only a very limited amount of research has been devoted to studying the behavior of a conical Bunsen flame established in a stagnation flow, which is significantly affected by the combined effects of the curvature stretch and the aerodynamic straining. This investigation is aimed at studying the characteristics of laminar conical premixed flames in an impinging jet flow experimentally and theoretically. First, we analyze the transport processes of a nonreactive impinging jet flow numerically. For lower burner-to-plate distance, the potential core becomes concave at the top. Hence, a conical Bunsen flame established in such a flow field may suffer positive flow stretch. The predicted flame shapes using a simple model incorporated with the numerical results agree well with the experimental observations. Flame shapes exhibit double-solution characteristics in a certain range of methane concentrations. Experimentally, by following different paths of adjusting methane concentration (decreasing from rich to lean or increasing from lean to rich), two different flame configurations (planar or conical flame) may exist at the same flow conditions, namely burner-to-plate distance, inlet velocity, and methane concentration. At the higher (or lower) critical methane concentration, the transition from a flat flame to a conical flame (or from a conical flame to a flat flame) occurs. The calculation of stretch and measurement of flame temperature for the low inlet velocity, 0.8 m/s, show that the stretch of a conical flame established in a stagnation flow is negative (dominated by the flame curvature). However, it is important to emphasize that at high velocity, e.g., U_in = 1.6 m/s, a negatively stretched flame tip can suffer positive flow stretch. This significant finding has been verified in the experiment since the conical flame tip is higher than the positively stretched flat flame.     

基于显热回收的分离式热管传热特性的实验研究

针对新风空调机组,采用倾角为15°的分离式热管用于显热回收.研究充液率,迎面风速及空气进口温度对显热效率的影响,分析了其影响规律.研究表明,采用热管空调机组设计风速范围内,充液率介于66％～75％时,其换热效率最高.迎面风速较低时,空气进口温度介于34℃～36℃,其显热效率较高.因此,采用分离式热管机组适合用于高热地区...     

Influence of Burner Geometry on Heat Transfer Characteristics of Methane/Air Flame Impinging on Flat Surface

An experimental study has been conducted to find the heat transfer characteristics of methane/air flames impinging normally to a flat surface using different burner geometries. The burners used were of nozzle, tube, and orifice type each with a diameter of 10 mm. Due to different exit velocity profiles, the flame structures were different in each case. Because of nearly flat velocity profile, the flame spread was more in case of orifice and nozzle burners as compared to tube burner. Effects of varying the value of Reynolds number (600–2500), equivalence ratio (0.8–1.5) and dimensionless separation distance (0.7–8) on heat transfer characteristics on the flat plate have been investigated for the tube burner. Different flame shapes were observed for different impingement conditions. It has been observed that the heat transfer characteristics were intimately related to flame shapes. Heat transfer characteristics were discussed for the cases when the flame inner reaction cone was far away, just touched, and was intercepted by the plate. Negative heat fluxes at the stagnation point were observed when the inner reaction cone was intercepted by the plate due to impingement of cool un-burnt mixture directly on the surface. Different heat transfer characteristics were observed for different burner geometries with similar operating conditions. In case of tube burner, the maximum heat flux is around the stagnation point and decay is faster in the radial direction. In case of nozzle and orifice burner, the heat transfer distribution is more uniform over the surface.     

石墨狭缝中甲烷吸附的分子动力学模拟

用分子动力学模拟研究石墨狭缝中甲烷的吸附,考察狭缝宽度和温度对甲烷吸附的影响.模拟发现甲烷在石墨狭缝中出现分层现象,吸附层中甲烷具有类液特征,第一吸附层内甲烷中总有两个氢原子的连线与另外两个氢原子的连线分别位于平行于狭缝壁的两个平面内,游离层中甲烷呈现气体的特征;碳原子间的平均作用势说明吸附层中甲烷分子间结合能力大于游离层,吸附态是甲烷在石墨狭缝中的主要赋存形式之一;伦敦力以及由吸附层净电荷产生的电场力是甲烷吸附和分层的主要原因;甲烷的吸附量随狭缝宽度增大或温度升高而减少,当狭缝宽度小于16.46Å时,甲烷仅以吸附形态存在.甲烷在第一吸附层中的扩散能力最弱、游离层中最强,甲烷扩散系数随狭缝宽度的增大或温度的升高而增大.     

聚氨酯泡沫反向阴燃的数值模拟

本文根据两步反应机理,建立了2维非稳态燃料阴燃的数学模型.该模型考虑了气体在多孔介质内扩散系数的变化.应用该模型模拟了来流速度对阴燃速度及平均最高温度的影响,结果表明;首先阴燃传播速度随着来流速度的增大而增大,当风速为0.2 cm/s时,阴燃速度达到最大值0.0093 cm/s,而后随着风速的增大阴燃速度逐渐降低直至熄灭;来流速度对阴燃最高温度影响不大.同时还模拟了氧气浓度的影响、燃料阴燃中气体组分和固体成分的变化以及温度分布情况.     

超临界压力煤油传热不稳定实验研究

在压力2.5~4 MPa, 质量流量0.7~1.7g/s, 入口温度20~250 ℃的实验条件下, 对煤油在内径1 mm, 长度300 mm竖直上升圆管中的流动及传热不稳定现象进行了实验研究.结果表明, 当热流密度增大到一定程度后, 传热不稳定开始发生.不稳定发生的起始热流密度随压力和流量的增加而增大, 随入口油温的升高而减小, 且当入口油温升高到一定程度后无不稳定现象发生.不稳定发生的初始时刻, 出口油温迅速增加, 管道壁温明显下降, 传热系数增大; 实验段局部流速增大, 进而在管道内部形成压力脉动并产生声音.不稳定结束后, 出口油温几乎保持不变, 壁温会缓慢增加, 直至下一次不稳定发生.      

HEAT TRANSFER AND PRESSURE DROP MEASUREMENTS FOR IN-TUBE CONDENSATION OF CFC-113 USING MICROFIN TUBES AND WIRE INSERTS

Accurate, repeatable heat transfer and pressure-drop measurements have been made for condensation of CFC-113 with downflow inside enhanced microfin tubes and tubes containing twisted-wire inserts. In the latter case measurements have also been made for CFC-113/air mixtures. The heat transfer rate was calculated from the coolant flow rate and temperature rise, the latter measured using a 10-junction thermopile with careful attention paid to adequate coolant mixing and isothermal immersion of the thermopile leads. The surface temperature was found from thermocouples embedded in the tube wall. One plain tube, nine microfin tubes (with different fin heights, helix angles, and number of fins), and four twisted-wire inserts (with different wire densities) were tested. Enhancement ratios (i.e., vapor-side heat transfer coefficient for the enhanced tube divided by that for a smooth tube at the same vapor-side temperature difference and vapor inlet velocity) between 1.6 and 5.6 for the microfin tubes and between 1.2 and 1.6 for the twisted-wire inserts were found, with values depending on vapor-side temperature difference, vapor inlet velocity, and air inlet mole fraction in the case of CFC-113/air mixtures. The microfin tubes showed moderate pressure-drop penalties of around 50% compared to the plain tube, while the twisted-wire inserts showed increasing pressure-drop penalty with increasing wire density.     

催化剂薄层内甲烷水蒸气重整反应强化管内对流换热的数值模拟

本文以竖直圆管内壁催化剂薄层内发生甲烷水蒸气重整反应强化对流换热作为研究对象,对其进行了数值模拟．结果发现,催化剂薄层内的吸热化学反应可以有效地强化对流换热,降低流体和壁面温度,从而对壁面起到保护作用;极限热流密度的大小与流体的入口温度有关,存在最佳入口温度使极限热流密度最大．