Effects of counter anion on mixed-valence states of binuclear ferrocene derivatives

The mixed-valence states of iron atoms in 1, 1-dialkylbiferrocenium cations were found to be affected by the kind of their counter anions. The TCNQ salts showed only an averaged-valence state from 78 K to room temperature, while the triiodide salts showed only a trapped-valence state or a temperature dependent trapped-to-averaged valence state depending on the kind of alkyl group.     

Polarization of photo-luminescence of ZnS: Cu monocrystals

Different models of luminescence centres are discussed on the basis of measurements of the composition of ZnS monocrystal photo-luminescence in different polarizations and temperature dependence of the degree of polarization. Those of the models submitted by Birman, which assume the polarization to be due to the different force of the oscillators for transitions withEc andEc, or models assuming luminescence polarization to be due to the orientation of the luminescence centres, agree with the results of experiments, i.e. the temperature independence of the degree of polarization and the conformable spectral composition of both polarizations. It is also shown that measurements made up to now of the degree of polarization must be taken as orientational as a consequence of the depolarizing influence of the diffused rays of luminescence on its value.

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ZnS: Cu

ZnS , . , . . , , , E E, , . , , - .

     

The influence of plastic deformation on the magnetostriction constant of nickel

The magnetostriction constant of nickel was measured as a function of plastic deformation up to an elongation of 30%. The values of the magnetostriction constant in deformed samples deviate considerably, a fact which cannot be explained by errors of measurement. The absolute value of the magnetostriction constant decreases with increasing plastic deformation (by around 5%).

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30% . , . ( 5%).

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In conclusion the authors thank J. Kaczér, C. Sc. and B. esták, C. Sc. for carefully reading the paper and for their remarks, J. Míová for help in the measurements and workers of the chemical department of our Institute for careful preparation of the samples.     

Honeycomb domain structure

A theory is given of a new structure produced when demagnetizing uniaxial single crystals (e.g. magnetoplumbite) in a field normal to thec axis. The experimental results fully support the theory on the assumption that domain structures produced under normal conditions are metastable. Methods are given by which stable structures can be prepared from such metastable ones. On the basis of these results opinions are expressed as to the nucleation of plate and honeycomb structures, produced either by reducing the field from saturation or by cooling below the Curie point.

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, (, ) , c. , , , , , . , . , .

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In conclusion the authors would like to thank C. Novák from the Institute of Technical Physics, Czechoslovak Academy of Sciences, for checking the calculation of the harmonic analysis and Z. Málek and J. Eousek for carefully reading the paper and for valuable remarks.     

ОПРЕДЕЛЕНИЕ ОРИЕНТА ЦИИ МОНОКРИСТАЛЛОВ С НЕПРАВИЛЬНОЙ ПОВЕР ХНОСТьЮ ПРИ ПОМОЩИ РЕНТГЕНОВСКОГО СПЕК ТРОМЕТРА CO СЧЕТЧИКОМ ГАЙГЕРА-МЮЛЛЕРА

, - -; - (hkl) . , (hkl) - , . - . .     

ВЛИЯНИЕ ОСВЕЩЕНИЯ НА ПРОВОДИМОСТЬ И ФОТОПРОВОДИМОСТЬ З АКИСИ МЕДИ

, Cu₂O - 130–200 °C - . . - . , , , , - , - . - . - .     

СЕРНИСТЫЙ ТЕЛЛУР — ПО ЛУПРОВОДИОЕ СОЕДИНЕ НИЕ

, , , , .     

ОПРЕДЕЛЕНИЕ ПОСТОЯН НЫХ ДВУХПАРАМЕТРОВЫ Х РЕШЕТОК МЕТОДОМ ОТНО ШЕНИЙ

. . - 10^–4.     

A possible test of quantum electrodynamics by means of polarization effects in electron-nucleon scattering

The differential cross-section is given for the electromagnetic scattering of polarized relativistic electrons on polarized nucleons. The finite size of each particle is taken into account by means of two form-factors. The effect of the possible non-punctiform structure of the electron on the polarization effects in scattering is discussed. It is shown that the internal structure of the anomalous magnetic moment of the electron would show itself in the cross-section by terms depending on the transversal polarization of the incident electrons.

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. . . , , .

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Summary of results of a diploma-thesis for the degree of graduate physicist.

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In conclusion the author wishes to express his sincere gratitude to prof. V. Votruba and J. Kvasnica for suggesting this problem, for helpful discussions and valuable advice.     

Les absorbants de son resonants

Résumé Dans la présente étude, on trouve un bref résumé des travaux de l'auteur, de ses collègues et collaborateurs, concernant l'utilisation des résonateurs dans l'acoustique architecturale. On explique tout d'abord le problème de l'inpluence des résonateurs sur la durée de la réverbération des salles. Se basant sur des considérations théoriques, l'auteur déduit le critère de l'emplacement le plus favorable des matières absorbant le son dans le résonateur même et discute la possibilité de l'absorption totale du son par le résonateur. Dans le cas des systèmes de résonateurs pareils disposés régulièrement sur les murs, le diapason pouvant être obtenu d'une importante absorption est relativement faible. En se servant de systèmes résonants d'absorption comportant plusieurs couches de résonateurs, reliés en série, le diapason de l'absorption importante peut être notablement élargi. L'auteur explique la corrélation du coefficient d'absorption et de l'angle d'incidence de l'onde sonore. En conclusion, on mentionne des exemples de l'utilisation pratique des résonateurs d'absorption les plus simples pour obtenir la caractéristique de l'absorption de fréquence exigée. On discute aussi le problème de l'influence des vibrations simultanées de la paroi extérieure du système de résonance sur la caractéristique de l'absorption du son.

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. . . , , . , , . . ; .

     

Измерение некоторых нейтронных спектров методом ядерных эмулъсий

. Ra+Be . , , . 8.     

ВЛИЯНИЕ ПАРНЫХ СИЛ НА ЭНЕРГИЮ ГИГАНТСКОГО РЕЗОНАНСА

, , . .

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Influence of pair forces on the giant resonance energy

The influence of various nucleon-nucleon forces on the giant resonance energy is investigated with the help of the sum rules. The dependence of the contribution of exchange forces to the integral cross-section of the gamma quantum absorption on the number of protons and neutrons is obtained for light nuclei.

     

The influence of elastic deformation on the magnetostriction constant of nickel and iron-nickel alloys

The dependence of the magnetostriction constant of different materials in the form of a wire on the elastic elongation was measured. With pure nickel the magnetostriction constant is independent of the elastic deformation. All three alloys of iron and nickel and the triple alloy Fe-Ni-Co exhibit a linear dependence on the deformation, which differs for different crystallographic texture. In two iron-nickel alloys the dependence of the magnetostriction constants of the single crystal on the elastic deformation was calculated from measurements on polycrystals having different crystallographic textures. In the triple alloy Fe-Ni -Co a considerable linear decrease in the volume magnetostriction with the elastic elongation was also found. The observed changes can be explained by assuming the influence of the lattice deformation on the spinorbital interaction in alloys.

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. . - Fe-Ni-Co , . - . , Fe-Ni-Co . - .

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A preliminary report on some of the results of this paper was given at the conference on magnetism in Kyoto (Japan) in September 1961.

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In conclusion the authors thank Z. Frait C. Sc. and S. Libovický for remarks, J. Míová for help in the measurements, members of the chemical department of our institute for annealing and analyzing the samples and members of the Metal Research Institute in Panenské Beany for their exceptional helpfulness in preparing the wires.     

Ermüdungserscheinungen der infrarotbestrahlten Silber-Cäsium-Photokathoden

Zusammenfassung In dieser Arbeit werden die Erscheinungen der normalen und anomalen, durch Infrarotstrahlung verursachten und von uns schon früher an diesen Photokatoden beobachteten Ermüdung von Silber-Cäsium-Photokathoden untersucht. Diese Erscheinungen wurden an durchsichtigen sowie undurchsichtigen, durch verschiedene Technologien zubereiteten Photokathoden festgestellt. Es wurden Messungen der Strahlungsintensitäts-, Temperatur- und Spektralverteilungsabhängigkeit der normalen und anomalen Ermüdung durchgeführt. Es werden die Ursachen der Unübereinstimmigkeit im Vergleich mit Arbeiten von De Boer und Teves besprochen. Ferner wurden die Zeitverläufe der Ermüdung bei der Abwechslung der Bestrahlungs- und Dunkelzyklen studiert.

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-

, , . , . , . . .

     

ИЗЛУЧЕНИЕ ЭЛЕКТРИЧЕ СКОГО ДИПОЛЯ НАД ГРАН ИЦЕЙ ДВУХ СРЕД

, , . , - - . - . -, - , . , - ; , , .     

The lattice spacings of equilibrium solid solutions of silver in aluminium

This paper describes the measured dependence of the lattice spacings of equilibrium Al-Ag solid solutions on temperature and composition. The form of the lattice spacing composition curve is found to differ considerably from that for the supersaturated Al-Ag solid solutions. The differences between the spacings of equilibrium and quenched Al-Ag solid solutions plotted against the electron concentration yield a curve similar to that constructed from the analogous measurements on Al-Zn given by Ellwood. The differences can be attributed to the influence of changes accompanying the increased solute clustering introduced by quenching the solid solutions into the supersaturated state.

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Al-Ag . , Al-Ag . Al-Ag, (. . , ), Al-Zn, , . , .

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The author wishes to express her thanks to Ing. J. Lagek for his care in carrying out the chemical analysis of the aluminium-silver alloys. The careful density measurements of these alloys made by J. Bednfi [are greatly appreciated.     

Bemerkung zur Theorie der Elektrolumineszenz in ZnS-Kristallen

Zusammenfassung Nach Zalm sind die Kristalle von ZnS mit einer dünnen Halbleiterschicht bedeckt, aus der auf Grund des Tunneleffekts Elektronen in den Kristall eindringen können. Im vorliegenden Artikel wird vorausgesetzt, da die Elektrolumineszenz bei der Rekombination dieser Elektronen mit den ionisierten Aktivatorzentren eintritt, die sich im Kristall zu Beginn eines jeden Zyklus vorfinden, und die Folgen dieser Voraussetzung werden mit den experimentell erhaltenen Daten verglichen.

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ZnS

ZnS , . , , ; .

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Dieser Artikel entstand aus einer Diplomarbeit, die im Physikalischen Institut der Tschechosl. A. d. W., Prag, ausgearbeitet wurde.

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Abschlieend möchte ich RNDr. Miroslav Trlifaj für seine zahlreichen wertvollen Hinweise wie auch für sein Interesse an dieser Arbeit danken.     

ВЛИЯНИЕ ПРЕДВАРИТЕЛ ЬНОГО ОСВЕЩЕНИЯ ha ХАРАКТЕРИСТИКИ МЕДН ОЗАКИСНЫХ ВЫПРЯМИТЕ ЛЕЙ

, 150° , . - . -. . ( ).     

Method of moments in analysis of x-ray diffraction lines

A general relation between the moments of the functionsf,g, andh, in the integral equationh(x)=f(y)g(x–y) dy, is derived. This enables any moment of the unknown functionf to be calculated from the moments of the functionsg andh. In particular, if certain assumptions are fulfilled, the moments of the components of the doublet can be calculated with advantage from the moments of the total profile. The statistical significance of the moment characteristics is also emphasized.

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f, g, h h(x)=f(y)g(x–) dy, f g h. , . .