共查询到20条相似文献,搜索用时 31 毫秒
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Enzyme‐loaded magnetic polyelectrolyte multilayer nanotubes prepared by layer‐by‐layer assembly combined with the porous template could be used as biomimetic nanoreactors. It is demonstrated that calcium carbonate can be biomimetically synthesized inside the cavities of the polyelectrolyte nanotubes by the catalysis of urease, and the size of the calcium carbonate precipitates was controlled by the cavity dimensions. The metastable structure of the calcium carbonate precipitates inside the nanotubes was protected by the outer shell of the polyelectrolyte multilayers. These features may allow polyelectrolyte nanotubes to be applied in the fields of nanomaterials synthesis, controlled release, and drug delivery.
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Narong An Yanxia Li Yuming Yang Fusheng Yu Lisong Dong 《Macromolecular rapid communications》2006,27(12):955-960
Summary: Bisphenol A solid epoxy serves as an effective reaction compatibilizer to the bisphenol A polycarbonate (PC)/PMMA bilayer systems. Addition of epoxy to the bottom PMMA layer can retard or even prevent the dewetting of PC films by introducing crosslinking between both components at the interface. This is the first investigation of polymer bilayers stabilized by chemical reactions.
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Summary: A novel method, situ polymerization stringed assembly (SPSA), is proposed to prepare stable solid or hollow supramolecular polymer particles, which are assembled by numerous nanoparticles. By this method, the fabrication of primary nanoparticles (poly(methyl methacrylate), PMMA), the linkers (polyvinylpyrrolidone, PVP, chains) between the nanoparticles, and the final assembled solid or hollow particles could be achieved in just one‐pot by methyl methacrylate (MMA)/N‐vinylpyrrolidone (NVP) microemulsion polymerization under UV irradiation. The structures of the supramolecular particles can be changed from solid to hollow by tuning the mass ratio of MMA/NVP in the microemulsion. AFM, TEM, and SEM experiments are performed to identify the results.
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Hitoshi Sashiwa Naoki Yamamori Yoshifumi Ichinose Junzo Sunamoto Sei‐ichi Aiba 《Macromolecular bioscience》2003,3(5):231-233
The Michael reaction of chitosan with acrylic acid was carried out successfully, even in water alone as the reaction medium. As a consequence of its good solubility in water, the reaction product, N‐carboxyethylchitosan, showed excellent biodegradable properties with standard activated sludge.
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Jiaqi Liu Guoshan Song Changcheng He Huiliang Wang 《Macromolecular rapid communications》2013,34(12):1002-1007
Polymer hydrogels that are capable of spontaneously healing injury are being developed at a rapid pace because of their great potential in biomedical applications. Here, the self‐healing property of tough graphene nanocomposite hydrogels fabricated by using graphene peroxide as polyfunctional initiating and cross‐linking centers is reported. The hydrogels show excellent self‐healing ability at ambient temperature or even lower temperatures for a short time and very high recovery degrees (up to 88% tensile strength) can be achieved at a prolonged healing time. The healed gels exhibit very high tensile strengths (up to 0.35 MPa) and extremely high elongations (up to 4900%). The strong interactions between the polyacrylamide chains and the graphene oxide sheets are essential to the mechanical strengths of the healed gels.
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Summary: We consider the shape of strongly adsorbed polymer chains in poor solvents. Using both SCF theory and Monte Carlo simulations, we find these chains undergo an instability which is driven, surprisingly, by polymer entropy. This instability occurs above some critical grafting separation and the intermediate segregation regime. An analytical calculation also suggests that this instability occurs for strongly adsorbed polymer chains. We proceed to study multi‐chain systems and observe a number of novel morphological structures including circular polymer droplets, lamellae and a polymer layer with a solvent‐filled hole.
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Darren C. Watters Hunan Yi Andrew J. Pearson James Kingsley Ahmed Iraqi David Lidzey 《Macromolecular rapid communications》2013,34(14):1157-1162
A new donor–acceptor polymer based on 9,9‐dioctylfluorene is synthesized and tested in organic photovoltaic devices. Results show that the polymer exhibits good solubility in a range of organic solvents and has a high hole mobility. When blended with a PC70BM acceptor and fabricated into a bulk heterojunction, photovoltaic devices having a maximum power conversion efficiency (PCE) of 6.2% and a peak external quantum efficiency of 74% are created. Such efficiencies are realized without any necessity for solvent additives or thermal annealing protocols.
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Yasuhiro Morisaki Hiroaki Imoto Junpei Miyake Yoshiki Chujo 《Macromolecular rapid communications》2009,30(13):1094-1100
We report syntheses of phenylene‐, biphenylene‐, and terphenylene‐layered polymers with a xanthene scaffold by the modified Suzuki‐Miyaura coupling reaction. Their optical properties were studied in detail. The polymer end‐capped by nitrobenzene units, which act as fluorescence quenchers, exhibited the photo‐excited energy transfer from the layered oligophenylenes to the terminal units.
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Patrice Castignolles Marianne Gaborieau Emily F. Hilder Ewan Sprong Christopher J. Ferguson Robert G. Gilbert 《Macromolecular rapid communications》2006,27(1):42-46
Summary: Oligo(acrylic acid)s, produced by RAFT polymerization, have been separated and analyzed for the first time by capillary zone electrophoresis. The resolution obtained by capillary electrophoresis in borate buffers is far higher than that currently achieved using size exclusion chromatography. This work demonstrates that capillary electrophoresis is the technique of choice for the characterization of oligomers of acrylic acid and of other water‐soluble monomers involved in emulsion polymerization processes.
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Caixia Cheng Ye Tian Yanqiao Shi Rupei Tang Fu Xi 《Macromolecular rapid communications》2005,26(15):1266-1272
Summary: Fabrication of honeycomb‐patterned films from amphiphilic dendronized block copolymer (PEO113‐b‐PDMA82) by ‘on‐solid surface spreading’ and ‘on‐water spreading’ method is reported. Highly ordered honeycomb films with quasi‐horizontally paralleled double‐layered structure can be fabricated by the on‐solid surface spreading method. This work raises the possibility that such structures can be formed in amphiphilic dendronized block copolymers and extends the family of source materials.
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Wenbin Zhong Xianhong Chen Shoumei Liu Yongxin Wang Wantai Yang 《Macromolecular rapid communications》2006,27(7):563-569
Summary: Polyaniline (PANI) nanowires and sub‐micro/nanostructured dendrites are synthesized and immobilized on PP‐g‐PAA film surfaces via routine oxidative polymerization of aniline under different conditions, where grafting poly(acrylic acid) (PAA) served as a template and dopant, and SDS as a surfactant. The immobilized PANI enhances the surface hydrophilicity of the poly(propylene) (PP) films, and a superhydrophilic surface is obtained in this way. The mechanism of forming different morphologies of PANI and of correspondingly obtaining a superhydrophilic surface are briefly discussed.
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Shingo Maeda Yusuke Hara Ryo Yoshida Shuji Hashimoto 《Macromolecular rapid communications》2008,29(5):401-405
A novel self‐oscillating gel actuator with gradient structure, which generates a pendulum motion by fixing one edge of the gel without external stimuli was achieved. The gel was synthesized by copolymerizing the ruthenium catalyst for the Belousov‐Zhabotinsky reaction with N‐isopropylacrylamide and 2‐acrylamido‐2‐methylpropane sulfonic acid. Furthermore, we clarified that the period and amplitude for the self‐oscillating behavior of the gel actuator are controllable by changing the composition, temperature, and size of the gel. The maximum amplitude of the novel gel actuator is about a 100 times larger than that of the conventional self‐oscillating gel system.
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Summary: A water‐soluble gold nanoparticle aggregate 2 was prepared by chloroauric acid and a polypseudorotaxane 1 of mono‐6‐thio‐β‐cyclodextrin with poly(propylene glycol) bis(2‐aminopropyl ether) ( ≈ 2 000) in the presence of sodium borohydride in N,N‐dimethylformamide (DMF) solution. The investigative results indicated that the gold nanoparticle aggregate 2 might act as an efficient DNA‐cleavage reagent.