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1.
We show that self-broadening of the ammonia inversion lines with J = K can be explained by taking account of the rotational resonance effect.  相似文献   

2.
Laplace inversion has been widely used in analyzing nuclear magnetic resonance data to obtain a spectrum of decay time constant, such as the T(2) spectrum. However, due to the ill-conditioned nature of such inversion, it is difficult to determine the reliability and error of the resulting spectrum. This article describes methods used to analyze resolution and to obtain bounds of integral quantities of the spectrum.  相似文献   

3.
针对从散射谱反演颗粒尺寸分布测量中,由于衍射近似要求近前向取值而带来的反演噪声问题,提出了一种改进的方法.在Chin-Shifrin(C-S)积分变换反演中,插入一种调节函数使得噪声基本消失,又不至于影响反演谱的分布峰位置.对理想单分散颗粒群的模拟效果说明了该法的可行性.对以线阵CCD为接受器件的实验测量和反演结果显示...  相似文献   

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5.
When the spin Hamiltonian is a linear function of the magnetic field intensity the resonance fields can be determined, in principle, by an eigenfield equation. In this report, we show a new technical approach to the resonance field problem where the eigenfield equation leads to a dynamic equation or, more specifically, to a first order differential equation of a variable L(x), where x is associated with the magnetic field h. Such differential equation has the property that: its stationary solution is the eigenfield equation and the spectral information contained in L(x) is directly related to the resonance spectrum. Such procedure, known as the "harmonic inversion problem" (HIP), can be solved by the "filter diagonalization method" (FDM) providing sufficient precision and resolution for the spectral analysis of the dynamic signals. Some examples are shown where the resonance fields are precisely determined in a single procedure, without the need to solve eigenvalue equations.  相似文献   

6.
《光谱学快报》2012,45(9):541-552
Abstract

In traditional nuclear magnetic resonance T2 inversion methods, the components with long T2 absorb the components with short T2, especially for low magnetic field intensity. As a result, the true distribution of all components often cannot be reflected by their solutions, and thus obtaining short T2 components is an important T2 inversion problem. Herein, a weighted iterative inversion method for T2 spectrum in nuclear magnetic resonance is proposed to solve this problem. The weight-based method is applied to ensure that the short T2 components are not eliminated. The weight scheme is determined by two parameters: the number of weights and maximum weight. The number of weights is determined by the rate of decay, and the maximum weight is mainly determined by three parameters: signal-noise ratio, curvature, and slope of collected signal. To avoid the mutations of results caused by weights, the iteration process was adopted to obtain the optimal solution. The proposed method provides good results, and it was verified to be robust and accurate though simulations and experiments.  相似文献   

7.
根据相似性准则,对采集到的干涉图像进行干涉图元的拆分,通过寻址定位,得到与离散光程差序列相匹配的采样干涉图序列。采用过零采样方式,对大单边干涉图序列与小双边干涉图序列利用不同的窗函数进行切趾。为了校正相位误差,结合所研究采样干涉图的特点,对频域光谱乘积校正和空域干涉图卷积校正进行了研究和改进,获得了比较理想的光谱线形,其中空域干涉图卷积校正后的光谱偏差仅为0.012088,具有最好的校正效果。  相似文献   

8.
在基于干涉光谱成像的气体成分实时遥测应用中,为了对推扫获取的原始干涉数据进行快速、有效的反演处理,提出一种结合计算统一设备架构(CUDA)的并行时空混合调制型长波红外干涉光谱反演算法。通过分析自主研制的时空混合调制型干涉光谱仪的数据获取模式,结合CUDA平台实现了并行反演算法。实验结果表明,基于CUDA平台的并行计算技术比仅使用CPU进行计算在效率上提升了5至20倍,为后期进一步做光谱识别打下了基础。  相似文献   

9.
A new method for the determination of the local plasma emissivity on the basis of measuring of the radiation intensity is presented. The method is related to the axial symmetric discharges with undefined radius (free burning arcs, etc.). In this method, the experimental profile of the radiative intensity is approximated by the linear combination of Gaussian functions, while the requested plasma emissivity is obtained in a similar oblique. The essence of the presented method lies in the procedure of determination of the coefficients in this linear combinations, as well as the parameters by which the exponents of Gaussian functions are expressed. The method was tested on a large number of examples which are related to almost all practically important cases of the profiles of local plasma emissivity. It was shown that the method works with high precision, which makes it a certain tool for an operative laboratorial application.  相似文献   

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11.
The vibrational spectrum for a fine particle is obtained by exactly solving the wave equation for a homogeneous elastic sphere with free surface. In terms of this frequency spectrum, enhancements in the specific heat of fine particles are calculated and compared with the experiments at low temperatures. Qualitative features of the experimental results are consistently explained in our theory.  相似文献   

12.
A hybrid inversion scheme of geoacoustic parameters, which combines dispersion characteristics of normal modes with transmission loss, has been proposed based on the facts that different parameters have different effects on sound field. First, considering the dispersion characteristics of normal modes were sensitive to the density and the sound speed of seabottom, and not sensitive to the seabottom attenuation coefficient, the group time delays of different modes and different frequencies were acquired through adaptive optimal kernel time-frequency representation, then the group time delays were taken as the cost function, and using a global optimal algorithm, the seabottom density and the profile of seabottom sound speed were deduced. Successively, the validity of inversion results was evaluated by the a posteriori probability. Last, the attenuation coefficient of sediment is inverted using the transmission loss data recorded from the ship radiation noise. The validity of the total inversion results has been evaluated by making use of the matched field processing source localization.  相似文献   

13.
一种地声参数的联合反演方法   总被引:1,自引:1,他引:0  
根据地声参数对不同声场物理量影响不同,提出了一种利用简正波频散特征结合声传播损失反演地声参数的联合反演方法。首先,考虑到简正波的频散特性(群速度)对海底的密度和声速较为敏感,而对海底吸收系数不敏感,利用自适应时频分析方法,获得不同频率不同号数简正波的到达时间差,以此作为代价函数,采用全局优化算法,反演出海底密度和海底声速的分层结构,并用概率统计的方法评价反演结果的有效性。反演出海底密度和声速后,利用实验船辐射噪声得到随距离连续的声传播损失来反演出海底吸收系数。最后,把反演的参数很好的用于声源匹配定位验证了反演结果的有效性。  相似文献   

14.
Infrared spectra of MnFe2O4 with inversion degrees of 0.05 and 0.2 are reported. It can be concluded that the absorption observed at 335 cm?1 has to be the third fundamental IR active mode.  相似文献   

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16.
矿物成分的野外快速鉴定在遥感地质研究与矿产勘探中至关重要,特征光谱线性反演模型可利用野外获得的岩矿光谱信息快速提取矿物组分,但是在实际使用中发现,使用同一样品的不同类型反射率光谱,模型结果存在显著差异.文章通过对连续统快速傅里叶变换(CFFT)滤波方法和特征光谱线性反演模型(CSLM)的研究,一方面获得了使用CFFT研究岩矿光谱的最佳参数设置,设置低通滤波截止频率为150Hz;另一方面通过对CSLM使用不同光谱数据结果的评价分析,发现使用CFFT滤波后的ASD光谱在野外提取矿物时效果更好.  相似文献   

17.
The many-to-one mapping from representations in the speech articulatory space to acoustic space renders the associated acoustic-to-articulatory inverse mapping non-unique. Among various techniques, imposing smoothness constraints on the articulator trajectories is one of the common approaches to handle the non-uniqueness in the acoustic-to-articulatory inversion problem. This is because, articulators typically move smoothly during speech production. A standard smoothness constraint is to minimize the energy of the difference of the articulatory position sequence so that the articulator trajectory is smooth and low-pass in nature. Such a fixed definition of smoothness is not always realistic or adequate for all articulators because different articulators have different degrees of smoothness. In this paper, an optimization formulation is proposed for the inversion problem, which includes a generalized smoothness criterion. Under such generalized smoothness settings, the smoothness parameter can be chosen depending on the specific articulator in a data-driven fashion. In addition, this formulation allows estimation of articulatory positions recursively over time without any loss in performance. Experiments with the MOCHA TIMIT database show that the estimated articulator trajectories obtained using such a generalized smoothness criterion have lower RMS error and higher correlation with the actual measured trajectories compared to those obtained using a fixed smoothness constraint.  相似文献   

18.
The engineering applications of high temperature superconducting (HTS) single domain YBCO block require the material with larger size and more complex shape. However, traditional top-seeded melt growth (TSMG) method cannot meet this requirement. In this paper, solder technology of YBCO blocks using Ag2O-doped YBCO slice has been performed in air with a rapid cooling rate, and the oxygen treatment techniques with a shorter time were used in the process. Microstructure analysis and superconducting characterization of the joint were investigated. The results show that a high quality joint is obtained without any macro cracks. Furthermore, the grains in the joint are well oriented as same as that of the base YBCO block. However, some defects such as voids and Cu–Ba–O phase segregations are discovered in the middle of the joint. Much finer Y211 (Y2BaCuO5) grains are attained in the soldering zone compared with that in the base YBCO. The trapped field measurement on bonded YBCO blocks shows a single maximum, indicating good superconducting properties in the joint.  相似文献   

19.
Inversion frequencies of 15NH3 in the ground vibrational state are measured to an accuracy of ±0.01 MHz. The observed 115 lines, up to J = 18, including 54 new lines, are analyzed with 15-term Costain's exponential expression. The parameters reproduce the observed frequencies with a standard deviation of 0.053 MHz. Coupling constants of higher order vibration-rotation interaction for K = 3 and K = 6 levels are included in the analysis.  相似文献   

20.
利用野外测量21种地表岩石的高光谱发射率数据,进行包络线去除和归一化处理后,运用逐步回归法进行波段选择,分析了SiO2含量与包络线去除后特征波段发射率的定量关系。在此基础上,通过比较12种SiO2光谱指数,建立了定量反演SiO2含量的最优模型。结果表明:构建的SiO2光谱指数能有效预测SiO2含量,其中基于11.18和12.36μm波段的归一化SiO2光谱指数(normalization silicon dioxide index,NSDI)的预测能力最高;与回归模型相比,光谱指数更简单、实用;研究结果在岩石种类鉴定及SiO2含量的高精度提取方面有重要应用价值。  相似文献   

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