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在微波辐射无溶剂条件下快速、高产率地合成了2,4,6-三芳基吡啶四氟硼酸盐化合物, 并对其进行核磁共振、红外光谱、元素分析表征. 同时得到了化合物4f的晶体, 对其进行了X单晶射线衍射表征. 结果表明, 该晶体属正交晶系, 空间群Pbca, a=2.1050(2) nm, b=1.64360(17) nm, c=2.9209(3) nm, α=β=90.00°, γ=90.00°, Dc=1.276 g•cm-3, V=10.1057(17) nm-3, Z=16. 相似文献
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苯乙烯基吡啶化合物,由于它可能在医学方面[1]和光电子功能材料[2]方面有实际应用前景,已引起人们的兴趣。苯乙烯吡啶化合物的光化学性质类似于二苯乙烯化合物,在光照下可以发生顺-反异构反应[3]、加成反应和二聚反应[4]等不同的光化学反应。 相似文献
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本文以等摩尔的芳醛,巴比妥酸(或1,3-二甲基巴比妥酸),5-氨基-2-甲基苯[d]噻唑为原料,以醋酸和乙二醇为溶剂,微波辐射下多组分一锅法合成了一系列新的吡啶[2,3-d]嘧啶衍生物。这种方法具有产率高,操作简便,反应时间短等优点。 相似文献
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A novel three‐component reaction of o‐bromobenzaldehyde, terminal alkynes and tert‐butyl amine has been established, which proceeded smoothly to give 3‐substituted isoquinolines in good yields in the presence of palladium/copper catalysts under microwave irradiation. 相似文献
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An efficient and environmentally friendly procedure for the one-pot synthesis of tetrahydropyrimidinones from aldehydes, β-diketones and urea/thiourea by using magnesium bromide as an inexpensive and easily available catalyst under solvent-free conditions was described. Compared with the classical Biginelli reaction conditions, this new method has the advantage of good to excellent yields (74%-94%) and short reaction time (45-90 min). The structure of the Biginelli reaction product from β-diketone, salicylaldehyde and urea has been proposed to possess an oxygen-bridge by cyclization (intramolecular Michael-addition). 相似文献
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Employing green and economic solvent‐free synthesis route, hexagonal iron sulfide (Fe7S8) nanoflowers were successfully synthesized for the first time. In the experiment, ferric hexadecylxanthate was used as the precursor, and hexagonal iron sulfide (Fe7S8) nanoflowers were obtained by thermal decomposition of the precursor at 260°C without any additional solvent or inert gas protection. The as‐prepared iron sulfide nanoflowers were characterized by means of X‐ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS). The characterization results indicated that the nanoflowers had uniform size distribution with an average size of about 160 nm. The proposed strategy provides a possible general route for the synthesis of other metal chalcogenide nanostructures. 相似文献
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A simple, general and efficient method has been developed for synthesis of various β-enamino ketones and esters by reacting β-dicarbonyl compounds with amines using a catalytic amount of L-proline at room temperature under solvent-free conditions in excellent yields. 相似文献
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Masoumeh Zakeri Majid M. Heravi Mina Saeedi Narges Karimi Hossein A. Oskooie Niloofar Tavakoli‐Hoseini 《中国化学》2011,29(7):1441-1445
An efficient one‐pot condensation of β‐naphthol, aldehydes and cyclic 1,3‐dicarbonyl compound has been achieved with ionic liquids as catalyst, thus a variety of 8,9,10,12‐tetrahydrobenzo[a]xanthen‐11‐one derivatives were prepared in good yields. The present approach offers several advantages such as shorter reaction times, good yields and mild reaction conditions. 相似文献
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SHATERIAN Hamid Reza YARAHMADI Hossein GHASHANG Majid SAFARI MEHMANDOSTI Moharram 《中国化学》2008,26(11):2093-2097
An efficient, facile and expeditious direct protocol for the preparation of acetamidobenzyl naphthols employing a multi-component and one-pot condensation reaction of 2-naphthol, benzaldehydes, and acetamide in the presence of N-bromosuccinimide (NBS) under thermal and microwave irradiation conditions has been described. The present protocol with NBS catalyst is convincingly superior to the recently reported catalytic methods. 相似文献