蓄冷球堆积床动态放冷性能研究

根据蓄冷球和载冷剂之间的能量平衡,并考虑载冷剂与蓄冷球之间的换热系数变化、载冷剂的导热、蓄冷球堆积床热损失的影响,建立了蓄冷球堆积床放冷过程的数理模型。采用数值计算方法模拟了蓄冷球堆积床的放冷过程,并讨论载冷剂流速、载冷剂入口温度以及堆积床孔隙率对放冷过程中载冷剂出口温度和放冷量的影响。     

蓄冷球堆积床动态充冷性能模拟

根据蓄冷球和载冷剂之间的能量平衡,建立了蓄冷球堆积床充冷过程的数理模型。该模型考虑了载冷剂与蓄冷球之间的换热系数变化、载冷剂的导热、相变蓄冷材料的过冷度以及蓄冷球堆积床热损失的影响。采用数值计算方法模拟了蓄冷球堆积床的充冷过程,讨论了载冷剂入口温度、初始温度和流速对充冷过程蓄冷材料温度、载冷剂温度和蓄冰率的影响。     

球形堆积床蓄冷空调系统实验性能研究

文中对球形堆积床蓄冷空调系统的蓄冷和放冷特性进行实验研究。在实验过程中,测量堆积床内流体温度、蓄冷时蒸发器进出口温度、放冷时换热器进出口温度以及室内机组进风和出风温度。通过测量的数据,得出蓄冷和放冷过程中的蓄冷、放冷速率和蓄冷、放冷量随时间的变化。在放冷时,出风温度稳定在16℃。因此,该系统可以用于空调系统的蓄冷和放冷过程,既有利于电力负荷"移峰填谷",又能满足室内温度调节的需求。     

生物质定向气化制合成气—气化热力学模型与模拟

通过对气化炉内反应的热力学模型构建和模拟,探讨了实现生物质定向气化为合成气(H2∶CO=2∶1) 的条件,以便使用该合成气直接合成液体燃料—甲醇.在考虑气化过程中物质平衡、能量平衡和化学反应平衡的 基础上,建立了生物质气化模型,并使用PASICAL语言及其外挂DELPHI程序,编写了FBGB程序,用于模拟生物 质、水蒸气输入量与产气中各种气体组分含量之间的关系.通过模拟,发现水蒸气与生物质输入速率的比值 (S/B)是影响H2/CO值的关键参数.模拟结果显示当其它反应条件确定时,S/B与H2/CO呈线性递增关系,通 过调节S/B,H2与CO的比例可以得到控制.     

Tar analysis from biomass gasification by means of online fluorescence spectroscopy

Optical methods in gas analysis are very valuable mainly due to their non-intrusive character. That gives the possibility to use them for in-situ or online measurements with only optical intervention in the measurement volume. In processes like the gasification of biomass, it is of high importance to monitor the gas quality in order to use the product gas in proper machines for energy production following the restrictions in the gas composition but also improving its quality, which leads to high efficient systems. One of the main problems in the biomass gasification process is the formation of tars. These higher hydrocarbons can lead to problems in the operation of the energy system. Up to date, the state of the art method used widely for the determination of tars is a standardized offline measurement system, the so-called “Tar Protocol”. The aim of this work is to describe an innovative, online, optical method for determining the tar content of the product gas by means of fluorescence spectroscopy. This method uses optical sources and detectors that can be found in the market at low cost and therefore it is very attractive, especially for industrial applications where cost efficiency followed by medium to high precision are of high importance.     

随机填充增殖剂球床内载气流动特性数值模拟

固态氚增殖包层是聚变堆及聚变-裂变混合堆产氚包层的重要候选结构之一,其球床通道内载气流动特性将影响氚提取效率。利用离散元方法（DEM）生成随机填充增殖剂球床,通过径向孔隙率分布验证其合理性,计算流体力学（CFD）模拟计算其通道内气体流场特征。模拟得到：球床内吹扫氦气流速随孔隙率波动并随入口流速增大而均匀增大,通道内氦气流向及流速变化显著,Blake-Kozeny方程可良好预测该随机填充球床通道压降。     

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在同轴圆柱单介质内外双水冷结构的DBD臭氧发生器的放电间隙内分别填充玻璃珠、高铝瓷、石英砂和熔融石英砂等颗粒,研究填充颗粒材料、粒径大小、间隙宽度等参数对臭氧生成效率的影响.结果表明:颗粒材料的介电常数是影响其臭氧制取效果的主要因素,随着介电常数的增加,间隙击穿电压降低,但由于颗粒导致电场的畸变,间隙折合场强增加,臭氧生成的最大能效降低,饱和浓度提升;高铝瓷具有最高的臭氧饱和浓度,与未填充的空床相比,饱和浓度提升136％;对于填充不同粒径熔融石英砂颗粒,随着粒径的增加,间隙击穿电压上升,间隙的折合场强提高,臭氧生成的最大能效降低,而饱和浓度提升;通过在宽间隙内填充介质颗粒可以得到窄间隙宽度的臭氧制取效果.     

颗粒填充对介质阻挡放电制臭氧性能的影响

在同轴圆柱单介质内外双水冷结构的DBD臭氧发生器的放电间隙内分别填充玻璃珠、高铝瓷、石英砂和熔融石英砂等颗粒,研究填充颗粒材料、粒径大小、间隙宽度等参数对臭氧生成效率的影响。结果表明：颗粒材料的介电常数是影响其臭氧制取效果的主要因素,随着介电常数的增加,间隙击穿电压降低,但由于颗粒导致电场的畸变,间隙折合场强增加,臭氧生成的最大能效降低,饱和浓度提升;高铝瓷具有最高的臭氧饱和浓度,与未填充的空床相比,饱和浓度提升136%;对于填充不同粒径熔融石英砂颗粒,随着粒径的增加,间隙击穿电压上升,间隙的折合场强提高,臭氧生成的最大能效降低,而饱和浓度提升;通过在宽间隙内填充介质颗粒可以得到窄间隙宽度的臭氧制取效果。     

随机填充增殖剂球床内载气流动特性数值模拟

固态氚增殖包层是聚变堆及聚变-裂变混合堆产氚包层的重要候选结构之一,其球床通道内载气流动特性将影响氚提取效率。利用离散元方法(DEM)生成随机填充增殖剂球床,通过径向孔隙率分布验证其合理性,计算流体力学(CFD)模拟计算其通道内气体流场特征。模拟得到:球床内吹扫氦气流速随孔隙率波动并随入口流速增大而均匀增大,通道内氦气流向及流速变化显著,Blake-Kozeny方程可良好预测该随机填充球床通道压降。     

生物质洁净能源研究中的流化床动力学模型

分别对最小流化床、鼓泡流化床和腾涌流化床及相应的全混模型、鼓泡模型、气泡汇集模型等加以综述 ,分析其优缺点 ,并在此基础上提出动力学模拟研究的新思路 .根据流化床内在的本质———流化态的不同 ,将流化床分为最小流化床、鼓泡流化床和腾涌流化床三种 .总结了前人针对各种流化床提出的全混模型、鼓泡模型、气泡汇集模型等思想 ,建议今后可以在以下几个方面进行深入研究 :⑴使得模型更有普适性 .⑵由于气泡有效直径尚不能在理论上求得 ,可以在理想气泡直径变化公式的基础上 ,加入非线性化学的计算 .⑶确定不同情况下的参数 ,使得工作更有延续性 ,也使得模型更加具有生命力 .⑷从高压的角度去进行模型的计算 ,并得到相应的试验数据支持 .     

In-situ gasification chemical looping combustion of plastic waste in a semi-continuously operated fluidized bed reactor

Conventional air incineration of plastic waste has been considered as one of important sources of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) through de novo synthesis and precursor conversion. Chemical looping combustion (CLC) is an attractive technology for the conversion of plastic wastes to energy with the potential to drastically suppress the formation of PCDD/Fs. In this paper, the iG-CLC (in-situ gasification CLC) experiments of plastic waste were implemented in a semi-continuously operated fluidized bed reactor, which actually simulates the fuel reactor of a continuously-operated interconnected fluidized bed reactor. A kind of low-cost material, natural iron ore without/with 5 wt% CaO adsorbent through the ultrasonic impregnation method, was used as oxygen carrier (OC). Firstly, some key performances of the reactor system, such as the relevance of the bed inventory to the flow rate of fluidizing agent as well as the relationship between the feeding rate and overflow rate of OC, were calibrated. Then, 90 min of single experiment was conducted for each experimental case and an accumulative operation of more than 10 h was attained. Typically, the combustion efficiency can reach at about 98%, and both the carbon conversion and CO₂ yield can approach to 95% at 900 °C and input thermal power of 150 W with a mixture of 5 vol% H₂O and 95 vol% N₂ as the fluidizing agent (U_FR/U_mf = 3). Moreover, the results obtained in the semi-continuously operated fluidized bed reactor demonstrated that CaO decoration to iron ore is conductive to suppressing the formation of chlorobenzene (as a toxic matter and precursor/intermediate of PCDD/Fs) and does not obviously deteriorate the OC performance.     

Effects of inclined impermeable bed on the turbulent characteristics of the flow using particle image velocimetry

In this study, the turbulent characteristics of the flow in an open channel with horizontal and inclined impermeable beds were studied experimentally using two-dimensional particle image velocimetry (PIV). The experiments were conducted in a channel of 6.5 m in length, 7.5 cm in width and 25 cm in height. The slope of the channel was S = 0 for the horizontal impermeable bed and for S = ?0.002, S = ?0.004 and S = ?0.006 for the inclined impermeable bed. Hydraulic characteristics such as distributions of velocities, turbulent intensities and Reynolds stress are investigated at a fine resolution using the PIV. Velocity is measured above the horizontal and inclined impermeable bed for the same different heights (h = 5, 7, 9, 11 and 13 cm) and for the same different discharges (Q = 0.735, 0.845 and 0.970 lt/s). Results show that the channel slope influences significantly near the impermeable bed but not near the free surface the variation of turbulent characteristics of the flow and also the alteration of the channel slope from ?0.002 to ?0.006 doesn't influence the variation of turbulent characteristics of the flow, which are the longitudinal turbulent intensity u′U_*, the vertical turbulent intensity v′/U_* and the turbulent kinetic energy. The channel slope doesn't influence the Reynolds stress.     

Analysis of the product gas from biomass gasification by means of laser spectroscopy

The use of biomass and waste for decentralised combined heat and power production (CHP) requires highly efficient gasification processes. In the Technische Universität München (TUM), an innovative gasification technology has been developed. This allothermal gasifier is producing a hydrogen- rich, high-calorific gas, that can be further used in a microturbine or a fuel cell producing energy. For the operation of such a system, the online analysis of the composition of the product gas is of high importance, since the efficient working of the machines is linked with the gas quality. For this purpose an optical measurement system based on laser spectroscopy has been applied. This system can measure not only the basic components of the product gas (H₂, CH₄, CO, CO₂, H₂O), but it also gives information concerning the content of high hydrocarbons, the so-called tars, in the product gas.     

Discharge characteristics and abatement of volatile organic compounds using plasma reactor packed with ceramic Raschig rings

Discharge characteristics and abatement of volatile organic compounds using plasma reactor packed with ceramic Raschig rings were investigated. It was found that the gap equivalent capacitance decreased with increasing voltage while the dielectric barrier equivalent capacitance increased initially and stabilized at about 700 pF. Compared with empty reactor, toluene removal was significantly enhanced by ceramic Raschig rings, 97% against 48%. With respect to the energy yield in the presence of padding, the efficiency was remarkably improved up to 10 g/kWh, which was 2 times higher than that of 5 g/kWh in the absence of padding with removal ratio exceeding 50%.     

热重红外光谱法考察木质生物质综纤维素热转化特性

热重红外光谱联用考察了木质生物质纤维素、半纤维素以及综纤维素的热转化特性,并与微晶纤维素和木聚糖等模型化合物进行了对比分析。应用三维扩散模型计算了活化能、指前因子等热转化动力学参数,拟合效果良好。通过分析气相产物三维IR图谱,在最大失重速率附近,观察到了H₂O,CO,CO₂,CH₄和含氧化合物的明显特征峰。讨论了主要气体产物可能的生成途径,发现其产量顺序为CO₂>H₂O>CO≈CH₄。综合分析得出,综纤维素的热转化过程是纤维素主导下、纤维素和半纤维素综合作用的结果。     

中国 HCCB-TBM 氚增殖球床热工水力学特性数值模拟

基于 CFD 软件平台,针对中国 HCCB-TBM 氚增殖区球床热工水力学特性开展 3 维数值模拟研究。 依据 ITER 实际运行工况给出吹氚氦气和结构冷却剂氦气在硅酸锂球床内的流动与传热特性,获取球床内详细的 速度分布、温度分布和压力降。计算结果表明：圆球的排列方式影响球床内氦气流场和球床的最高温度;ITER 运行工况下 HCCB-TBM 增殖区硅酸锂小球及其壁面的最高温度不会超过设计温度。研究结果为增殖区热工水力 学方案的设计验证和下一步开展实验提供参考。     

CFETR水冷包层两元混合增殖球床流动特性研究

作为中国聚变工程实验堆(CFETR)候选包层之一的水冷包层(WCCB),拟采用不同尺寸的两元混合增殖球床以增加球床的填充率,从而满足氚增殖比(TBR)要求。采用离散元方法(DEM)建立了满足中子学要求的CFETR水冷包层两元球床填充结构,通过CFD计算分析获取了氦气在球床颗粒间隙之间的流动特性,包括孔隙率分布、速度分布和压降等。     

Experimental study of transient heat transfer characteristics of single-phase natural convection in multidimensional porous bed with volumetric heat generation

Natural convection in an internally heated porous bed of height and diameter of 450 mm and 500 mm, respectively, and superposed with the fluid layer has been experimentally investigated. The onset of natural convection in the bed is indicated by change in the rate of temperature rise within the bed. An empirical model based on local Nusselt number and local Rayleigh number has been developed. A comparison of the present model with the models in literature is made to draw out the differences between the local heat transfer of large multidimensional beds and the average heat transfer of small beds.     

Characteristic analysis of low-velocity gas filtration combustion in an inert packed bed

This paper investigates the low-velocity filtration combustion of lean methane–air mixtures occurring in inert packed beds by using a modified one-temperature model, considering the axial thermal diffusion owing to the convective gas–solid heat transfer. Based on the scaling analysis of various transport terms in different conservation equations, a high-activation energy asymptotic method is applied in the flame zone and results in a set of powerful analytical solutions for combustion macrocharacteristics under the fully developed conditions. These are then combined with the eigenvalue method of the modified one-temperature model in the whole flow region to study the flame behaviour analytically and numerically. Our results have shown that the combustion wave velocity is a key characteristic parameter in the filtration combustion process. Compared with other existing theoretical results, the present analytical solutions demonstrate the intricate relationships among the combustion wave velocity, the flame speed, the peak flame temperature and the effects of the variable thermo-physical properties, and show better prediction performance for the combustion wave velocity, the flame speed and the peak flame temperature. Excellent agreements with experimental results have been observed, especially for very lean filtration combustion with stream-wise propagating combustion fronts.