Theoretical study of charge-exchange and excitation processes in collisions of He<Superscript>+</Superscript> ions with C<Superscript>5+</Superscript>, N<Superscript>6+</Superscript>, and O<Superscript>7+</Superscript> hydrogen-like ions

Data on the cross sections for single-electron charge exchange and excitation in collisions of He⁺ ions with C⁵⁺, N⁶⁺, and O⁷⁺ ions in the He⁺ ion energy range of 0.2–3.0 MeV are obtained for the first time. The cross sections for the single-electron charge transfer into the singlet and triplet 1snl states of C⁴⁺, N⁵⁺, and O⁶⁺ (2≤n≤5) ions and for the 1s → 2p _{0, ±1} electronic excitation of He⁺(1s) ions are calculated. The calculations were performed by solving close-coupling equations on the basis of ten two-electron quasi-molecular states.     

Excitation of doublet <Emphasis Type="Italic">D</Emphasis>-levels of a lutetium atom by electron impact

The electron-impact excitation of doublet D-levels of the lutetium atom is studied by the method of extended crossing beams. At the exciting electron energy of 50 eV, 64 excitation cross sections are measured. In the electron energy range of 0–250 eV, nine excitation optical functions are recorded. The occurrence of perturbations in the spectral series 6s ²(¹ S)6p ² P ₁^2/○ − 6s ²(¹ S)nd ² D _3/2 is discussed.     

Detection of trielectronic recombination of In<Superscript>+</Superscript> ion

The trielectronic recombination of an In⁺ (4d ¹⁰5s ^{2 1} S ₀) ion in collisions with slow electrons, including the two-electron excitation of the 5s2 core of the ion with the simultaneous capture of the triply excited 5p ³ intermediate autoionizing state with its subsequent radiative stabilization 5p ³ → 5s5p ² + hν has been detected and experimentally examined for the first time. The maximum effective cross section of trielectronic recombination is 1.6 × 10⁻¹⁶ cm², which is comparable to the effective cross sections for both dielectronic recombination and electron excitation of the In⁺ ion.     

Electron impact excitation cross sections of <Superscript>1</Superscript><Emphasis Type="Italic">F</Emphasis><Superscript>o</Superscript> levels of the strontium atom

The behavior of excitation cross sections of the strontium atom was studied experimentally in the spectral series 5s4d¹D₂-5snf¹F ₃ ^o in the range n = 4–26, and also the optical excitation functions for lines in the same series in the range n = 4–12. It was established that the beginning of the series is perturbed. The effect of the perturbation is manifested both in the irregular course of the dependence of the absolute values of the cross sections on n, and in the difference between the shapes of the optical excitation functions for different terms of the series. The results obtained are compared with available experimental data. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 5, pp. 557–560, September–October, 2007.     

Radiative transitions in the system of autoionizing levels of cesium atoms excited by electron impact

We study the energy dependences of electron excitation cross sections of the autoionizing levels (5p ⁵6s ²)² P _3/2 and (5p ⁵5d(³ P)6s)² P _3/2, as well as the autoionization cross sections of cesium atoms in the impact energy range from the excitation threshold to 600 eV. It is established that an increase in the excitation cross section of the ² P _3/2 levels (to 60% of the maximum value) and the deep minimum in the autoionization cross section observed in the energy region of 17–27 eV are caused by the predominance of the radiative decay channel for autoionizing levels with excitation thresholds above 17 eV. The high efficiency of the process is mainly related to the resonance excitation of these levels in the near-threshold energy region.     

Spectroscopic investigation of thallium 6<Emphasis Type="Italic">s</Emphasis>6<Emphasis Type="Italic">p</Emphasis><Superscript>2</Superscript> configuration at electron-atom collisions: I. Spectra

Thallium emission spectra in the 115–300 nm range excited by electron-atom collisions at electron energies of 12–300 eV are investigated. A number of weak lines that cannot be unidentified using spectroscopic tables are found in the 140–170 nm range. Two of them (144.9 and 148.0 nm) are attributed to the radiative decay of levels that belong to the 6s6p ² configuration and that lie above the ionization potential. A weak emission with an excitation threshold of about 9 eV is revealed in the vicinity of the Tl II resonance line at 132.2 nm. The excitation function of the emission is measured for electron energies below 15.5 eV. It is found that the emission consists of two lines, which also appear due to the excitation of the 6s6p ² configuration and correspond to the radiative decay of levels that are common with the lines at 144.9 and 148.0 nm mentioned above. Their calculated wavelengths are 130.2 and 132.7 nm, respectively.     

Electron impact excitation into the 3p<Superscript>5</Superscript>4p levels from the 3p<Superscript>5</Superscript>4s metastable levels of argon

Electron impact excitation cross sections of argon from the 3p ⁵4s matastable states to the excited states of 3p ⁵4p configuration were calculated by using the fully relativistic distorted wave method, based on the multi-configuration Dirac-Fock (MCDF) theory. The influence of electron correlation effects on cross sections were discussed in detail. For low energy impact, it is found that the electron correlation effects have a large influence on the cross sections and make the cross sections smaller. However, this influence become smaller with the increasing of incident electron energy. The present results are in good agreement with the experiments of Boffard et al. [Phys. Rev. A 59, 2749 (1999)] in most cases.     

H<Superscript>+</Superscript><Emphasis Type="Bold">and He</Emphasis><Superscript>2+</Superscript> impact single and double ionization of lead

H⁺ and He²⁺ impact single and double ionization cross sections of ground state lead atoms have been calculated in the binary encounter approximation. Calculations of direct double ionization cross sections have been performed in the modified double binary encounter model. The accurate expressions of σ_ΔE (cross-section for energy transfer ΔE) and Hartree-Fock velocity distributions for the target electrons have been used throughout the calculations. Contributions to double ionization from Auger effect following ionization of inner shells have been considered in the present work. Our H⁺ impact single and double ionization cross sections are in good agreement with the experimental observations. In calculations of He²⁺ impact cross sections, the present theoretical approach shows limited success in the experimentally investigated region (50–350 keV amu^-1).     

Charge exchange collisions of H<Superscript>+</Superscript>/D<Superscript>+</Superscript> ions with alkaline Earth atoms (Ca,Mg)

The Classical Trajectory Monte Carlo (CTMC) Method has been used to calculate the differential, partial and total single electron capture cross sections for the collision of H⁺/D⁺ with Ca and Mg atoms in the energy range of 1–100 keV. The differential cross sections at angles near the diffraction limit (<0.1^○) in both systems show a forward peak followed by an asymptotic fall at higher angles. Total and partial capture cross sections are found to be in good agreement with the experimental observations. Oscillations in the partial capture cross sections have been explained due to the swapping of the field electron. Isotope effect in the electron transfer is reported to be negligible.     

Electron impact dissociation of ND<Superscript>+</Superscript>: formation of D<Superscript>+</Superscript>

Absolute cross sections for electron impact dissociation of ND⁺ leading to the formation of D⁺ have been measured by applying the animated electron-ion beam method in the energy range from the reaction threshold up to 2.5 keV. The maximum inclusive cross section is observed to be (16.8 ± 0.8) × 10⁻¹⁷ cm² at the electron energy of 65.1 eV. The appearance energy for the D⁺ production is measured to be (4.0 ± 0.5) eV. Collected data are analyzed in details by means of an original procedure in order to determine separately the contributions of dissociative channels. A specific Monte Carlo modeling has been developed, which is proven to reconstruct adequately the dissociative ionization cross section. The present energy thresholds provide information about the ground and excited states of the molecular ion, as well as about the possible population of the vibrational levels. The reaction D₂(v) + N⁺ (or H₂(v) + N⁺) is a probable source for that population and it constitutes the first step of the molecular activated processes, so the corresponding chain of reactions has to be considered to study the chemistry of plasma sources.     

Excitation cross sections of thulium atom transitions terminating at 4f13(2Fo)6s6p(3Po (7/2, J2) levels with J2 = 0, 1

The excitation of odd levels of the thulium atom, spontaneous transitions from which terminate at the 4f ¹³(² F ^o)6s6p(³ P ^o) (7/2, J ₂) levels with J ₂ = 0, 1, is studied by the method of extended crossing beams. Fifty four excitation cross sections are measured at an excitation electron energy of 50 eV. Seven optical excitation functions are recorded in the electron energy range of 0–200 eV.     

Two-electron excitations in helium-like ions by inelastic photon scattering

Inelastic photon scattering by helium atoms and helium-like ions with simultaneous excitation of the two-electron transition 1s ²→2s ² is examined in the nonrelativistic energy range I≪ω≪m (I is the ionization potential, ω is the photon energy, m is the electron mass, and ℏ=c=1). The electrons are assumed to be moving in the Coulomb field of the nucleus, and the electron-electron interaction is taken into account in the lowest perturbation order. The differential and total cross sections of the process and the autoionization width of the 2s ² energy level are calculated. The numerical value of the autoionization width is found to agree with the results of the more rigorous calculations of other researchers. Zh. éksp. Teor. Fiz. 113, 539–549 (February 1998)     

Electron-impact detachment from S<Superscript>-</Superscript>

Absolute cross sections for single and double electron-impact detachment of the S^- ion have been investigated over collision energy ranges of 0-60 eV and 0-30 eV, respectively. The experiment was performed at the ion storage ring, CRYRING. The threshold energies were measured to be 6.6 eV for single detachment and 19.8 eV in the case of double detachment. The single detachment cross section has a maximum of 6.7 x 10^-16 cm² at 30 eV. The double detachment cross section was studied only in the threshold region. No sharp structures were observed in either of the cross sections.Received: 24 April 2003, Published online: 29 July 2003PACS: 34.80.Dp Atomic excitation and ionization by electron impact - 34.80.Kw Electron-ion scattering; excitation and ionization     

Electron-impact excitation of the S°, P°, and D° doublet levels of cobalt atoms

The excitation of transitions from the ² S ^∘, ² P ^∘, and ² D ^∘ levels of the cobalt atom is studied by the method of extended crossing beams. Seventy-six excitation cross sections are measured at an exciting electron energy of 50 eV. Nine optical excitation functions are recorded in the electron energy region of 0–200 eV. Possible channels of excitation of levels under study are discussed.     

Application of R-matrix method to electron-H<Subscript>2</Subscript>S collisions in the low energy range

Electron-H₂S collision process is studied using the R-matrix method. Nine low-lying states of H₂S molecule are considered in the R-matrix formalism to obtain elastic integral, differential, momentum transfer and excitation cross sections for this scattering system. We have represented our target states using configuration interaction (CI) wavefunctions. We obtained adequate representation of vertical spectrum of the target states included in the scattering calculations. The cross sections are compared with the experiment and other theoretical results. We have obtained good agreement for elastic and momentum transfer cross sections with experiment for entire energy range considered. The differential cross sections are in excellent agreement with experiment in the range 3–15 eV. A prominent feature of this calculation is the detection of a shape resonance in ²B₂ symmetry which decays via dissociative electron attachment (DEA). Born correction is applied for the elastic and dipole allowed transition to account for higher partial waves excluded in the R-matrix calculation. The electron energy range is 0.025–15 eV.     

Wavelength and oscillator strength of dipole transition 1s<Superscript>2</Superscript>2p—1s<Superscript>2</Superscript><Emphasis Type="Italic">n</Emphasis>d for Mn<Superscript>22+</Superscript> ion

The transition energies, wavelengths and dipole oscillator strengths of 1s²2p—1s² nd (3⩽n⩽9) for Mn²²⁺ ion are calculated. The fine structure splittings of 1s² nd (n</9) states for this ion are also evaluated. In calculating energy, the higher-order relativistic contribution is estimated under a hydrogenic approximation. The quantum defect of Rydberg series 1s² nd is determined according to the quantum defect theory. The results obtained in this paper excellently agree with the experimental data available in literatures. Supported by the National Natural Science Foundation of China (Grant No. 10774063)     

Subthreshold and near threshold K+ meson photoproduction\newline on nuclei

The inclusive K⁺ meson production in photon–induced reactions in the near threshold and subthreshold energy regimes is analyzed with respect to the one–step (γN→K ⁺ Y, Y=Λ,Σ) incoherent production processes on the basis of an appropriate new folding model, which takes properly into account the struck target nucleon removal energy and internal momentum distribution (nucleon spectral function), extracted from recent quasielastic electron scattering experiments and from many–body calculations with realistic models of the NN interaction. Simple parametrizations for the total and differential cross sections of the K⁺ production in photon–nucleon collisions are presented. Comparison of the model calculations of the K⁺ differential cross sections for the reaction γ+C¹² in the threshold region with the existing experimental data is given, that displays the contributions to the K⁺ production at considered incident energies coming from the use of the single–particle part as well as high momentum and high removal energy part of the nucleon spectral function. Detailed predictions for the K⁺ total and differential cross sections from γH², γC¹² and γPb²⁰⁸ reactions at subthreshold and near threshold energies are provided. The influence of the uncertainties in the elementary K⁺ production cross sections on the K⁺ yield is explored. Received: 12 April 1999 / Revised version: 11 September 1999     

Autoionization cross section of lithium atoms excited by electron impact

We measure the full autoionization cross section of lithium atoms excited by electrons in the energy range from the first autoionization threshold at 56.39 to 600 eV. Data are obtained by determining the total intensity of electron spectrum of autoionization states 1sn ₁ l ₁ n ₂ l ₂ detected at the “magic” observation angle of 54.7°. The cross section behavior is characterized by a sharp increase to a maximum value of 1.7 × 10⁻¹⁸ cm² in the energy interval of 56.4–60 eV and a subsequent monotonic drop to a value of 10⁻¹⁸ cm² at 600 eV. We have discovered a “thin” cross section structure that reflects the presence of strong resonances of Li⁻ ions in the near-threshold area of excitation of the lowest energy autoionization states (1s2s2)2S, (1s2s2p)⁴ P, 1s(2s2p ³ P)² P), and 1s(2s2p ¹ P)² P. We have established that the contribution of autoionization to the absolute cross section of single ionization of lithium atoms does not exceed 4%. We perform a comparative analysis of the data with analogous data for potassium and cesium atoms.     

The excitation cross section of cadmium atoms from metastable 5<Emphasis Type="Italic">s</Emphasis>5<Emphasis Type="Italic">p</Emphasis><Superscript>3</Superscript><Emphasis Type="Italic">P</Emphasis><Subscript>0, 2</Subscript> states by electron impact

By means of the optical method using the technique of crossed electron and atomic beams, we obtained the absolute values of the excitation cross sections of metastable cadmium atoms and their energy dependences. The absolute cross section values reach ∼10⁻¹⁶ cm² (at 30 eV). Sharp resonance-like maxima are observed in the energy dependences of the excitation cross section near the excitation thresholds, which are supposedly related to the formation and decay of negative-ion excited states of.     

Electron collisions with the BeH<Superscript>+</Superscript> molecular ion in the R-matrix approach

The R-matrix method is used to study electron collisions with the BeH⁺ molecular ion. The diatomic version of the UK Molecular R-matrix codes is used and a configuration-interaction calculation is first performed for the BeH⁺ target to obtain its potential energy curves for 19 lowest singlet and triplet states. Scattering calculations are then done to yield excitation and rotational excitation cross sections in the energy range 0 − 14 eV. Additionally we also obtain bound states of BeH and their quantum defects at the BeH equilibrium bond length 2.5369a ₀. Resonance positions and widths for Feshbach resonances in the e-BeH⁺ system are also obtained and presented at the equilibrium bond length 2.5369a ₀.