The Becker-Döring cluster equations: Basic properties and asymptotic behaviour of solutions

Existence and uniqueness results are established for solutions to the Becker-Döring cluster equations. The density is shown to be a conserved quantity. Under hypotheses applying to a model of a quenched binary alloy the asymptotic behaviour of solutions with rapidly decaying initial data is determined. Denoting the set of equilibrium solutions byc ⁽⁾, 0 _s , the principal result is that if the initial density _{0 s} then the solution converges strongly toc ^(o), while if ₀ > _s the solution converges weak* toc ^(s). In the latter case the excess density ₀– _s corresponds to the formation of larger and larger clusters, i.e. condensation. The main tools for studying the asymptotic behaviour are the use of a Lyapunov function with desirable continuity properties, obtained from a known Lyapunov function by the addition of a special multiple of the density, and a maximum principle for solutions.     

Geometric expansion of the boundary free energy of a dilute gas

We consider a dilute classical gas in a volume ^–1 which tends to ^d by dilation as 0. We prove that the pressurep(^–1) isC ^q in at =0 (thermodynamic limit), for anyq, provided the boundary isC ^q and provided the Ursell functionsu _n (x ₁, ...,x _n) admit moments of degreeq and have nice derivatives.     

Manifestation of Extracoordination in the Resonance Raman Spectra of Water‐Soluble Cation Co‐Porphyrins

Resonance Raman spectra (RRS) of Co(II) and Co(III)5,10,15,20tetrakis(4Nmethylpyridinium)porphyrin ((Co^II(TmpyP4), and Co^III(TMPyP4)) in aqueous solutions at different pH as well as in organic solvents (methanol, ethanol, DMSO, DMF) are obtained. The increased sensitivity of the oscillation frequencies ₂, ₄, ₈, and ₆ — the markers of the oxidation state of a metal — to the nature of an axial ligand has been revealed. For Co^III(TmpyP4), the shifts of the indicated frequencies in extracoordination have turned out to be twofold larger than those for Co^II(TmpyP4). The spectral effects observed are related to different electron influence of the extraligands on the system of the porphyrin ring. In the case of Co(III)porphyrin, interaction of the d orbitals of the metal and the e _g ^*orbitals of the macrocycle is more efficient since its ionic radius is smaller than for the Co(II)complex. For Co^III(TmpyP4), a linear correlation between the oscillation frequencies ₂, ₄, ₈, and ₆ and the experimental Gutmann parameters characterizing the electronacceptor properties of solvents is found.     

Exact distribution of cluster size and perimeter for two-dimensional percolation

Exact series expansion data of Sykes et al. are used to calculate the average numberc _n and perimeters _n of clusters of sizen20 in the site percolation problem for the triangular, square, and honeycomb lattice. At the percolation thresholdp _n we find a sharply peaked distribution of perimeterss _n with mean s _n =((1–p _n )/p _c )n+O(n ) and width s _n ² –S _n ²n ^1.6 where1/=0.39. This perimeter s _n should not be interpreted as a cluster surface in the usual sense. Two tests confirm the universality hypothesis with reasonable accuracy. The asymptotic decay of the cluster numbersc _n withn is consistent with the postulated asymmetry aboutp _c : logc _n –n forn with1 forp<p _c and1/2 forp>p _c .     

On the stability of spin waves at finite temperatures

The temperature dependent exchange stiffnessD, defined for long wavelength spin waves by=Dq ², is calculated for very weak itinerant ferromagnets. It is found that for a general single band of d-electrons,D reduces to a very simple form givingD(T)=D(0)/ ₀ in the limit ₀0. The stability condition for spin waves at finite temperatures is thenD(0) > 0 and/ ₀ > 0, where is the relative occupation ± spin sub-bands and ₀ its value at 0°K.The authors are grateful to E. P. Wohlfarth for helpful discussions.     

Thes-f model with Coulomb repulsion: Thermodynamics of two atomic cluster. Spin 1/2

A cluster of two atoms described by thes-f model with Coulomb repulsion has been considered. The interaction between localized 4f electrons (S=1/2) is taken in the molecular field approximation. The thermodynamic quantities like magnetization, specific heat and correlation functions n , n , S ^z n , S ^z n , S ^z (n –n ), n n and S ⁺ a ⁺ a as functions of temperature are presented for different band fillingN=0, 0.5, 1, 1.5, 2. The dependence of Curie temperature onN is calculated. The phase diagram forN=1 (T=0K) shows the possibility of existence of two phases: paramagnetic and ferromagnetic.The Curie temperature and the specific heat as functions ofN exhibit similar trends as found in experiments on doped magnetic semiconductors.     

On the asymptotic behaviour of infinite gradient systems

We consider gradient systems of infinitely many particles in one-dimensional space interacting via a positive invariant pair potential with a hard core. The main assumption is that is strictly convex within the rangeR of (whereR is a fixed number ). Under some technical conditions we prove the following theorems: Let the initial distribution be given by a translation invariant point process onR ¹. Then there exists only one extreme equilibrium state with a given intensityI() satisfyingI()R ^–1, and all ergodic initial distributions with an intensityI()R ^–1 converge weakly ast to the extreme equilibrium state with the same intensity.     

Electron velocity and momentum density

A null 4-vector ^°, based on Dirac's relativistic electron equation, is shown explicitly for a plane wave and various Coulomb states. This 4-vector constitutes a mechanical model for the electron in those states, and expresses the important spinor quantities represented conventionally byn, f, g, m, j, ,1, ands. The model for a plane wave agrees precisely with the relation between velocity and phase gradient customarily used in quantum theory, but the models for Coulomb states contradict that relation.     

Large-Deviation Principle for One-Dimensional Vector Spin Models with Kac Potentials

We consider the one-dimensional planar rotator and classical Heisenberg models with a ferromagnetic Kac potential J (r)=J(yr), J with compact support. Below the Lebowitz-Penrose critical temperature the limit (mean-field) theory exhibits a phase transition with a continuum of equilibrium states, indexed by the magnetization vectors m s, s any unit vector and m the Curie–Weiss spontaneous magnetization. We prove a large-deviation principle for the associated Gibbs measures. Then we study the system in the limit 0 below the above critical temperature. We prove that the norm of the empirical spin average in blocks of order ^–1 converges to m , uniformly in intervals of order ^–p , for any p 1. We also give a lower bound to the scale on which the change of phase occurs, by showing that the empirical spin average is approximately constant on intervals having length of order ^-1-with (0,1) small enough.     

μ + Residual polarization in water,CS2, C6F6 and hydrocarbons under strong decoupling fields

The ⁺ decay asymmetry was measured as a function of longitudinal magnetic field (LF) between zero and 10 kG in spin decoupling experiments on muons in water, c-hexane, CS₂, C₆F₆, C₆H₆ etc. The results were compared both with the diamagnetic polarization,P _D, measured by transverse-field (TF) experiments ⁺SR, and with the asymmetry observed in ⁺ spin resonance experiments under longitudinal field. These results have been interpreted in terms of spin conversion and chemical reactions of muonium (Mu) with paramagnetic species such as free radicals in the muon track or spur. It is argued that spin-conversion reactions are responsible for the so-called missing fraction of ⁺ polarization in various media.     

The Homogeneous Hamilton–Jacobi and Bernoulli Equations Revisited

The one-dimensional case of the homogeneous Hamilton–Jacobi and Bernoulli equations S_t S _x ² =0, where S(x, t) is Hamilton's principal function of a free particle and also Bernoulli's momentum potential of a perfect liquid, is considered. Non-elementary solutions are looked for in terms of odd power series in t with x-dependent coefficients and even power series in x with t-dependent coefficients. In both cases, and depending upon initial conditions, unexpected regularities are observed in the terms of these expansions and this suggests that S(^x, ^t) should be written as a product of the elementary solution x²/(2^t) and a function f=f() where =(x, |t|) owing to the symmetry property which is that S(x, –t)=–S(x, t). Requiring that this Ansatz satisfies the said equation and choosing the simplest realization of (x, |t|)=₀ |t/t₀| (x/x ₀)0 with , results in a soluble ordinary differential equation, of first order in u=ln and quadratic in f. This ODE has two fixed points: f=1, obviously, and f=0, a new fixed point which is often called trivial. The phase plane (f_u, f) consists of a family of parabolas, all of which pass through the two fixed points. Explicit solutions of the general case are given close to these fixed points. A one-parameter family of solution is found to emerge from the trivial fixed point with non-trivial initial values S(x, 0). Detailed analyses of these findings will be reported elsewhere, bearing in mind that Bernoulli's equation has to be supplemented by the continuity equation satisfied by the density of the liquid.     

Fock representations of the affine Lie algebraA 1 (1)

The aim of this note is to show that the affine Lie algebraA ₁ ⁽¹⁾ has a natural family _, ,v of Fock representations on the spaceC[x _i,y _j;i andj ], parametrized by (,v) C ². By corresponding the highest weight _, of _, to each (,), the parameter spaceC ₂ forms a double cover of the weight spaceC₀C –₁ with singularities at linear forms of level –2; this number is (–1)-times the dual Coxeter number. Our results contain explicit realizations of irreducible non-integrable highest wieghtA ₁ ⁽¹⁾ -modules for generic (,v).     

Orientation of an oxygen-induced non-axially symmetric electric field gradient at Ta in Nb

The interaction of dilute Hf in Nb with interstitially dissolved oxygen has been investigated via the --TDPAC-technique applied to the 482 keV state of¹⁸¹Ta. After melting the parent radioactivity¹⁸¹Hf with Nb the trapping of oxygen at the probe atoms leads to a quadrupole interaction frequency _Q =268(1) MHz with an asymmetry parameter of =0.68(1). The temperature dependence of this frequency between 17 K and 293 K was found to be very weak whereas varies considerably. In a single crystal experiment the orientation of the three principal axes of the electric field gradient tensor leading to _Q has been determined. TheV _zz -axis points into a 110, theV _yy -axis into a 100 and theV _x -axis into a 110 direction. The results can be explained in the point charge model by assuming that one oxygen atom is trapped on the second nearest neighbour octahedral position next to the substitutional atom and the covalent bonds between the daughter Ta and the oxygen lead to a localization of charge near the probe atom.     

The form factors of the decays π− → e−¯veγ and K− → e−¯veγ

In the special type of the quark model we obtain the ratio=h _A/h_V of the axial (h_A) and vector (h_V) form factors for the decays ^– e^– ¯v_e and K^– e^–¯v_e different from unity. The low-energy theorem, relating the electric polarizability of the charged pion with the ratio, is analyzed. It is shown that < 1 corresponds to , calculated by accounting the contribution of the scalar meson(700) into the amplitude of the Compton effect on the pion. In the absence of the(700) contribution we have=1.Dedicated to Academician Václav Votruba on the occasion of his eightieth birthday.     

Self-gravitating three-dimensional solitons in nonlinear scale-invariant electrodynamics

A scale-invariant nonlinear modification of Maxwellian electrodynamics within general relativity is proposed. The starting point is the Mie model and its scale-invariant generalization in flat space-timeE ₄. We prove that all static, spherically symmetrical regular field configurations in this new theory, as well as those in the Mie model, possess negative energy. In search of solitonlike solutions with positive masses, we take into account their proper gravitational fields. We show first that in Riemannian space any gauge-invariant electrodynamic theory does not admit regular solutions. Supposing the gauge invariance to be broken inside the particle, we prove the existence of static particlelike solutions with spherical symmetry and positive energy in the scale-invariant electrodynamics described by a Lagrangian density of the form =-Y(I)R/(2)-W(I)F F _u/2+2X(I)R A A , withY, W, andX arbitrary functions of the invariantI=A A . The correspondence with the Maxwellian theory is required.     

The number of bound states of singular oscillating potentials

For a spherically symmetric potential such that rVL ¹(a, ), a>0, and is such that, if we define W=– _r V(t) d(t), W belongs to L ¹ (0, ) and rW0 as r0, we show that the number of bound states in any partial-wave satisfies the bound n2 ₀ r W ² dr. It was shown in a previous paper [1] that this class of potentials is regular from the point of view of abstract scattering theory as well as from the time-independent theory and the Jost function approach. We show also that, for large values of the coupling constant, n(gV) has the asymptotic behaviour C _±g ₀ W(r) dr as g±.     

Parametric excitation of spherical modes in ferromagnetic spheres by perpendicular and parallel pumping

The fine structures of the threshold of subsidiary absorption and parallel pumping, observed on highly polished YIG spheres in 1975 by W. Jantz et al., are discussed with a model which uses instead of plane spin-waves the true modes regarding the shape of the sphere. These spherical modes are magnetostatic modes taking additionally the exchange interaction into account. At the closely spaced resonances of the fine structure of parallel pumping single spherical modes with angular-momentum quantum numberm=0 are excited, whereas at the resonances of subsidiary absorption pairs of spherical modes with big angular-momentum quantum numbers (|m|1000) satisfying the selection rulem+m=1 are excited. The analysis of the fine structure of subsidiary absorption shows that in regimes where the plane wave approximation predicts the excitation of spin-waves with formalk0, modes withk1.5·10⁵ cm^–1 have the lowest threshold. This discrepancy is discussed with the effect of surface pit scattering, which increases the threshold of modes withk < 2/_pit, where _pit is a typical size of the surface pits. Consequently modes withk22/_pit instead ofk0 have the lowest threshold.     

Logical independence in quantum logic

The projection latticesP(₁),P(₂) of two von Neumann subalgebras ₁, ₂ of the von Neumann algebra are defined to be logically independent if A B0 for any 0AP(₁), 0BP(₂). After motivating this notion in independence, it is shown thatP(₁),P(₂) are logically independent if ₁ is a subfactor in a finite factor andP(₁),P(₂ commute. Also, logical independence is related to the statistical independence conditions called C^*-independence W^*-independence, and strict locality. Logical independence ofP(₁,P(₂ turns out to be equivalent to the C^*-independence of (₁,₂) for mutually commuting ₁,₂ and it is shown that if (₁,₂) is a pair of (not necessarily commuting) von Neumann subalgebras, thenP(₁,P(₂ are logically independent in the following cases: is a finite-dimensional full-matrix algebra and ₁,₂ are C^*-independent; (₁,₂) is a W^*-independent pair; ₁,₂ have the property of strict locality.     

More inequalities for critical exponents

A variety of rigorous inequalities for critical exponents is proved. Most notable is the low-temperature Josephson inequalitydv +2 2–. Others are 1 1 +v, 1 1 , 1,d 1 + 1/ (for d),dv, ₃ + (for d), ₄ , and _{2m 2m+2} (form 2). The hypotheses vary; all inequalities are true for the spin-1/2 Ising model with nearest-neighbor ferromagnetic pair interactions.NSF Predoctoral Fellow (1976–1979). Research supported in part by NSF Grant PHY 78-23952.     

Linear and non-linear ac response of the stochastic classical model for sliding charge density waves

A comprehensive study of the ac response properties of the classical stochastic model for sliding charge density waves (CDW) in quasi one-dimensional metals is made by numerically solving the associated Fokker-Planck equation. Above the conductivity threshold a noise mechanism is indispensable to give finite line widths to the resonances of the applied ac signal of frequency with the narrow band noise frequency _OSC inherent in the model. In the present investigation a current noise of strengthT _N proportional to the CDW current is used in the Fokker-Planck equation in order to model the broad band current noise frequently observed above threshold. The present model thus incorporates three characteristic frequency scales: _OSC,T _N ,and a crossover frequency _OSC. Results are evaluated for the ac conductivity (;E ₀,E ) as function of frequency , dc bias electric fieldE ₀ and ac signal field strengthE . ForE 0 the linear ac response is obtained by a separate treatment of the Fokker-Planck equation. The resonances near =_OSC are studied in detail. Strong ac signals reduce the response at the fundamental resonance and lead to a harmonic interference structure nearn=_OSC. The overall agreement of the present results with recent measurements of the linear ac response is not good. In reality our results seem to be superimposed on a background not reproduced by the classical model with one cross over frequency. However, the peak in Im (;E ₀,E =0) vs.E ₀, when the narrow band noise frequency is near , is well reproduced. The spectral width of this peak which corresponds to the inductive dip in the susceptibility is studied as function of current noise strengthT _N .The results stress the need for a complete Fokker-Planck treatment sinceT _N is not simply related to the line width.