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In this paper, an atomic absorption spectrometric method has been established to determine adrenaline using Cu(II) as probe reagent. In the presence of SCN?, it has been demonstrated that Cu(II) is reduced to Cu(I) by adrenaline at pH 6.0, and the in situ formed Cu(I) reacts with SCN‐ to form the white emulsion of CuSCN. According to the amount of residual Cu(II) which is measured by atomic absorption spectrometry, the amount of adrenaline can be determined indirectly. Beer's law is obeyed in the range of adrenaline concentration of 0.080‐6.00 mg mL‐1, and the linear regression equation is A = 0.20342 ‐ 0.02756C (μg mL?1) with a correlation coefficient of 0.9998. The detection limit is 0.033 μg mL?1 and R.S.D. is 0.56%. This method has been successfully applied to determine adrenaline in pharmaceutical and serum samples with satisfactory results. 相似文献
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用光温控制石墨炉原子吸收法测定人血清和人发中Se的含量,是一种精确、灵敏、快速的分析方法,可供科研人员和临床医生参考。 相似文献
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为了探讨原子吸收光谱法和原子发射光谱法测定工业废水中的总铬分析方法的异同,本文分别采用两种方法对工业废水中的总铬进行对比分析,对样品前处理方法、标准曲线、方法检出限、准确度、精密度、干扰及消除等进行比较,并对两种方法的测定结果进行t检验。结果表明,两种方法具有良好的一致性。相对来说,原子发射光谱法各方面指标要优于原子吸收光谱法。 相似文献
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《Analytical letters》2012,45(8):935-950
Abstract Lead is the most frequently quantitated toxic metal in biological matrices. We describe methodologies for lead determinations in whole blood and urine using Zeeman effect flameless atomic absorption spectroscopy. The whole blood determination requires a simple aqueous 1:10 dilution while the urine lead methodology utilizes a twofold dilution with 5% nitric acid. Within-run relative standard deviations (RSD) for the whole blood determination are approximately 4. 9%, while urine lead within-run PSD's are approximately 6.7%. Detection limits for both the whole blood lead determination and the urine lead determination are 3 ppb. Linearity for both assays is to 200 ppb in the diluted specimens. 相似文献